SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 17/AUG/2009
Date Updated: 03/AUG/2007
Version 1.6
Regulation (EC) No 1907/2006
1 - Product and Company Information
Product Name HYDROGEN PEROXIDE, 30-32 WT. % SOLUTION
IN WATER, SEMICONDUCTOR GRADE, 99.999%
METALS BASIS
Product Number 316989
Company Sigma-Aldrich Korea Ltd.,
698-84 Maeng-ri, Wonsam-myun,
449-871 Yongin-city, Kyunggi-do,
Technical Phone # +82-31-329-9000
Fax +82-31-329-9090
E-mail Address sakr@sial.com
2 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Harmful if swallowed. Risk of serious damage to eyes.
3 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
HYDROGEN PEROXIDE, 30% SOLUTION 7722-84-1 231-765-0 008-003-00-9
Ingredient Name Percent CAS # EC no Annex I
Index Number
HYDROGEN PEROXIDE 30 7722-84-1 231-765-0 008-003-00-9
Symbols: O-C
R-Phrases: 5-8-20/22-35
Heating may cause an explosion. Contact with combustible material
may cause fire. Harmful by inhalation and if swallowed. Causes
severe burns.
WATER 70 7732-18-5 231-791-2 None
Formula H2O2
Synonyms Albone 35 * Albone 50 * Albone 70 * Albone 35CG
* Albone 50CG * Albone 70CG * Hydrogen peroxide,
solution, 30% * Interox * Kastone * Perone 30 *
Perone 35 * Perone 50
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.
AFTER SKIN CONTACT
In case of contact, immediately wash skin with soap and copious
amounts of water.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
5 - Fire Fighting Measures
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Absorb on sand or vermiculite and place in closed containers for
disposal. Ventilate area and wash spill site after material
pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe vapor. Avoid
contact with eyes, skin, and clothing. Avoid prolonged or
repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed.
Store at 2-8癈
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US)
or CEN (EU). Where risk assessment shows air-purifying respirators
are appropriate use a full-face respirator with multi-purpose
combination (US) or type AXBEK (EN 14387) respirator cartridges as
a backup to engineering controls. If the respirator is the sole
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means of protection, use a full-face supplied air respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Physical State: Clear liquid
Color: Colorless
Property Value At Temperature or Pressure
pH N/A
BP/BP Range N/A
MP/MP Range N/A
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
SG/Density 1.11 g/cm3
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Stable: Stable.
Materials to Avoid: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: .
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
RTECS NUMBER: MX0899000
ACUTE TOXICITY
LDLO
Oral
Woman
2.626 mg/kg
Remarks: Gastrointestinal:Nausea or vomiting. Lungs, Thorax, or
Respiration:Cyanosis. Behavioral:Coma.
LDLO
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Oral
Man
1429 mg/kg
Remarks: Behavioral:Coma. Gastrointestinal:Changes in structure
or function of esophagus. Gastrointestinal:Nausea or vomiting.
LD50
Skin
Rat
3000 mg/kg
LD50
Intravenous
Mouse
>50 GM/KG
LD50
Oral
Rabbit
820 mg/kg
Remarks: Gastrointestinal:Peritonitis. Blood:Pigmented or
nucleated red bIood cells. Blood:Changes in leukocyte (WBC)
count.
SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes severe eye irritation.
Inhalation: Material may be irritating to mucous membranes and
upper respiratory tract. May be harmful if inhaled.
Ingestion: Harmful if swallowed.
TARGET ORGAN INFORMATION
Eyes. Respiratory system. Skin.
CHRONIC EXPOSURE - CARCINOGEN
Result: This product is or contains a component that is not
classifiable as to its carcinogenicity based on its IARC, ACGIH,
NTP, or EPA classification.
Mouse
Route of Application: Oral
Exposure Time: 2Y
Result: Tumorigenic:Carcinogenic by RTECS criteria.
Gastrointestinal:Tumors.
Mouse
Route of Application: Oral
Exposure Time: 2Y
Result: Gastrointestinal:Tumors. Tumorigenic:Carcinogenic by
RTECS criteria.
IARC CARCINOGEN LIST
Rating: Group 3
CHRONIC EXPOSURE - MUTAGEN
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Human
9 UMOL/L
Cell Type: lymphocyte
DNA damage
Human
50 UMOL/L
Cell Type: Embryo
Other mutation test systems
Human
20 UMOL/L
Cell Type: Embryo
Cytogenetic analysis
Rat
50 UMOL/L
Cell Type: lymphocyte
DNA damage
Hamster
250 UMOL/L
Cell Type: ovary
DNA inhibition
Hamster
60 UMOL/L
Cell Type: ovary
Cytogenetic analysis
Hamster
40 UMOL/L
Cell Type: ovary
Sister chromatid exchange
Hamster
1 MMOL/L
Cell Type: lung
Mutation in mammalian somatic cells.
12 - Ecological Information
No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Observe all federal, state, and local
environmental regulations.
14 - Transport Information
RID/ADR
UN#: 2014
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: Hydrogen peroxide, aqueous
solution
IMDG
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UN#: 2014
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: Hydrogen peroxide, aqueous
solution
Marine Pollutant: No
Severe Marine Pollutant: No
IATA
UN#: 2014
Class: 5.1
PG: II
Subrisk: 8
Proper Shipping Name: Hydrogen peroxide, aqueous
solution
Inhalation Packing Group I: No
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
ANNEX I INDEX NUMBER: 008-003-00-9
INDICATION OF DANGER: Xn
Harmful.
R-PHRASES: 22-41
Harmful if swallowed. Risk of serious damage to eyes.
S-PHRASES: 26-39
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice. Wear eye/face protection.
COUNTRY SPECIFIC INFORMATION
Germany
WGK: 1
Self-Classification
NORWAY
Declaration Number: 68197
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2009 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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