Dickler Chemical Labs, Inc.
02-05-2007 MATERIAL SAFETY DATA SHEET Page 1 of 5
Section 1: PRODUCT AND COMPANY IDENTIFICATION
DISTRIBUTOR: M.D. STETSON
Address: 92 YORK AVE RANDOLPH, MA 02368
Company Phone Number: (800) 255-8651
Medical Emergency: (800) 426-1127
Chemical Emergency: (800) 345-6789
Product Name: CITRIS-SAN
Issue Date: 02-05-2007
Supersedes Date:
Section 2: COMPOSITION/INFORMATION ON INGREDIENTS
Component/CAS # % by Wt.
Hyrdogen peroxide (CAS# 7722-84-1) 5.0-12.0
Nonylphenoxypolyethleneoxy Ethanols
(CAS# 9016-45-9) 1.0-5.0
D'Limonene (CAS# 5989-27-5) 0.0-2.0
Section 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
Hazardous in case of eye, skin contact (irritant)or ingestion.
Appearance/Odor: Thin, Clear Colorless Liquid
Acute Effects Routes of Entry
Likely Routes of Exposure: Eye contact, skin contact, inhalation
Skin: Hazardous in case of skin contact (irritant). Prolonged or repeated
contact may dry skin and cause irritation.
Eyes: May cause eye irritation.
Inhalation: May cause respiratory tract irritation.
Ingestion: No data on acute toxicity of the product when ingested. May cause
mild gastric irritation, abdominal spasms, nausea/vomiting.
Potential Health Effects: See Section 11 for more information
This material is not considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910. 1200).
Potential Environmental Effects: See Section 12 for more information)
Dickler Chemical Labs, Inc.
02-05-2007 MATERIAL SAFETY DATA SHEET Page 2 of 5
Section 4: FIRST AID MEASURES
FOR SKIN: Immediately remove contaminated shoes and clothing.
Thoroughly flush affected area with water for at least 15 minutes.
If irritation or burns are apparent, get medical aid.
FOR EYES: Immediately flush with water for at least 15 minutes. Get immediate
medical aid. Speed in flushing eyes may save sight.
IF INGESTED: Harmful if swallowed. DO NOT INDUCE VOMITING. Give milk or water.
Get immediate medical aid.
INHALATION: Move victim to fresh air. If not breathing administer artificial
respiration. Get immediate medical aid.
CONDITIONS AGGRAVATED BY EXPOSURE: None known.
Section 5: FIRE FIGHTING MEASURES
FLASH POINT (篎): None. FLAMMABLE LIMITS: Not determined
FLAMMABILITY: Non combustible.
SPECIAL PROCEDURES: Flood area and cool containers with water. Wear full
protective gear including boots, rubber suit, chemical splash goggles and self
contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Substance releases oxygen when heated, which
may increase the severity of an existing fire. Cool closed containers exposed to
fire with water.
Fire-Fighting Procedures: Wear special protective clothing and positive
pressure, self-contained breathing apparatus.
Section 6: ACCIDENTAL RELEASE MEASURES
Spill Clean up: Put on appropriate personal protective equipment(see Section 8).
Dilute with water and mop up, or absorb with an inert dry material and place in
an appropriate waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional
authority requirements. Prevent entry into waterways, sewers, basements or
confined areas.
Section 7: HANDLING AND STORAGE
Handling Procedures: Avoid contact with skin and eyes. Use good personal
hygiene practices. Do not wear leather. Wash contaminated clothing before
reusing. Wash hands before eating, drinking, smoking, or using toilet
facilities. Wash thoroughly after work using soap and water.
Storage Procedures: Do not store below 32篎(0癈) or above 95篎(35癈). Keep away
from heat and direct sunlight. Exposure to heat and sunlight accelerates
decomposition. Avoid contact with wood. KEEP OUT OF THE REACH OF CHILDREN. FOR
SALE, USE AND STORAGE BY SERVICE PERSONNEL ONLY.
Dickler Chemical Labs, Inc.
02-05-2007 MATERIAL SAFETY DATA SHEET Page 3 of 5
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Provide adequate local exhaust ventilation to maintain
worker exposure below exposure limits.
Personal Protective Equipment:
Eyes/Face: Wear chemical goggles. Use a face shield if splashing is possible.
Skin: Use impervious gloves (rubber, nitrile or neoprene). Wear suitable
protective clothing.
Respiratory: Avoid breathing vapors or spray mists. If exposure limits are
exceeded or if irritation is experienced, a NIOSH/MSNA approved respirator or an
organic/vapor removing cartridge respirator protection device should be worn.
Ventilation and other forms of engineering controls are often the preferred
means for controlling chemical exposures. Respiratory protection may be needed
for non-routine or emergency situations.
General Hygiene Considerations: Wash thoroughly after handling. Have eye-wash
facilities immediately available.
The following ingredients have established exposure guidelines:
Ingredient Exposure Guideline Guideline Value
OSHA PEL
Hydrogen Peroxide 1 ppm TWA
7722-84-1 ACGIH (TLV 1 ppm/m3
All TWAs are for an 8-hour period unless specifically noted as being for
another time period.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT (篎): Not determined SPECIFIC GRAVITY: 1.025
VAPOR PRESSURE: = Not determined % VOLATILES BY WEIGHT: 86+
% VOC = 0.5
VAPOR DENSITY: = Not determined EVAPORATION RATE: = Not determined
SOLUBILITY IN WATER: Complete pH: 4.5-5.0
APPEARANCE: Thin, Clear Colorless Liquid
ODOR: Citrus
Section 10: STABILITY AND REACTIVITY
STABILITY: Stable under normal conditions.
CONDITIONS TO AVOID: Long term storage.
INCOMPATIBILITY: Reactive with flammables, oxidizing agents, reducing agents,
powdered metals, and strong alkalis.
HAZARDOUS DECOMPOSITION PRODUCTS: Exposure to heat and exposure to sunlight
accelerates decomposition - carbon oxides (CO, CO2)
HAZARDOUS POLYMERIZATION: Will not occur.
Dickler Chemical Labs, Inc.
02-05-2007 MATERIAL SAFETY DATA SHEET Page 4 of 5
Section 11: TOXICOLOGY INFORMATION
ACUTE EFFECTS
Oral LD50: No data available
Dermal LDSO: No data available
Inhalation: No data available
Eye Irritation: No data available
Skin irritation: No data available
Sensitization: No data available
CHRONIC EFFECTS
Carcinogenicity: No ingredient of this product is listed as carcinogen by OSHA,
NTP or IARC.
Mutagenicity: No data available
Reproductive Effect: No data available
Developmental Effects: No data available
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity: No data available
Persistence/ Degradability: Biodegradable
Bioaccumulation/ Accumulation: No data available
Mobility in Environment: No data available
Section 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Follow local, state and federal guidelines.
Section 14: TRANSPORTATION INFORMATION
US DOT (ground)
Proper Shipping Description:
HYDROGEN PEROXIDE,AQUEOUS SOLUTION,5.1,UN 2984,
PG III, LTD QTY
Canadian TDG (ground): See US DOT
ICAO (air) See US DOT
IMDG (water) See US DOT
Dickler Chemical Labs, Inc.
02-05-2007 MATERIAL SAFETY DATA SHEET Page 5 of 5
Section 15: REGULATORY INFORMATION
TSCA Status
All ingredients are listed on the TSCA Chemical Inventory or exempt from
listing.
SARA 313 Information: To the best of our knowledge, this product contains no
chemical substances subject to SARA Title III Section 313 supplier notification
requirements.
Section 16: OTHER INFORMATION
HMIS HAZARD CODE: HEALTH: 2 FLAMMABILITY: 0 REACTIVITY: 1 OTHER: 0
The information contained in this document applies to this specific material as
supplied. It may not be valid for this material if it is used in combination
with any other materials. It is the user's responsibility to satisfy oneself as
to the suitability and completeness of this information for his own particular
use.
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