Rev. 0710.1
Material Safety Datasheet
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION 5. FIRE FIGHTING MEASURES 10. STABILITY AND REACTIVITY 14. TRANSPORT INFORMATION:
Product Name: Manufacturer: Extinguishing Media: No restrictions. Use extinguishing media Stability: Stable when used under normal conditions and within DOT: This substance is considered to be non-hazardous for
HRP Detection System Cell Marque Corporation appropriate to surrounding fire conditions. the scope of the intended application. transport.
6600 Sierra College Blvd.
Flash Point: N/A; Non-flammable Conditions to Avoid: Exposure to light and moisture Proper Shipping Name: N/A
Rocklin, CA 95677 USA
Flammability: Non-flammable Materials to Avoid: Metals and strong oxidizers IATA: At product concentrations, this material is not subject to
Product Number(s): +916-746-8900
a hazard classification in accordance with IATA Dangerous Goods
CMD337 Protective Equipment: Wear latex gloves and protective eye Hazardous Decomposition Products: N/A
Regulations
wear.
11. TOXICOLOGICAL INFORMATION
15. REGULATORY INFORMATION:
6. ACCIDENTAL RELEASE MEASURES
To the best of our knowledge, the chemical, physical, and toxico-
These products are for immunohistochemistry use. EU Additional Classification:
Spill Control: Exercise appropriate precautions to minimize direct logical properties have not been thoroughly investigated at product
Safety Statements: Avoid Contact With Eyes and Skin.
contact with skin or eyes. Protective equipment and clothing is
2. COMPOSITION/INFORMATION ON INGREDIENTS concentrations.
S: 24/25 22
recommended during cleanup procedures. Avoid contact during
Skin Contact: May cause local discomfort.
removal. At product concentrations, solution may be absorbed us- U.S. Classification and Label text:
Hazard
ing a paper towel or absorbent pad. Solution may also be absorbed Skin Absorption: May cause local discomfort.
Component CAS No. Composition Classification U.S. Statements: Caution: Avoid Contact
into earth, sand or vermiculite. Place in a closed container and hold
Eye Contact: May cause irritation.
(pure form) U.S. Regulatory Information:
for waste disposal.
3'3' Diaminobenzidine Xn (Carc3): R40 SARA Listed: No
Inhalation: May cause irritation to mucous
7. HANDLING AND STORAGE
Tetrahydrochloride: 7411-49-6 0.1% Xn(Muta3): R68 TSCA Inventory Item: This product complies with all TSCA inven-
membranes and upper respiratory
Xn: R22-43 tory requirements.
tract.
Keep containers tightly closed. Store at 2-8癈 in a location pro-
Threshold limit value (pure form): 300ug/m3 CANADA REGULATORY INFORMATION:
Ingestion: May be harmful if swallowed.
tected from light. Store away from oxidizers and ignition sources.
WHMIS Classification: This product has been classified in accor-
NOTE: This material is NOT CLASSIFIED AS HAZARDOUS at Target organs: None Identified dance with the hazard criteria of the CPR, and the MSDS contains all
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
product concentrations. In accordance with OSHA regulations
the information required by the CPR.
12. ECOLOGICAL INFORMATION:
and European Union Directives, this MSDS contains valuable
Eye Protection: Chemical safety glasses or goggles California Proposition 65: The following statement is made in
information critical to the safe handling and proper use of the
order to comply with the California State Drinking Water and Toxic
product. This MSDS should be retained and is available for 3'3' Diaminobenzidine Orl-rat LD50: 27 mg/kg
Hand Protection: Latex gloves
Enforcement Act of 1986. 3'3' Diaminobenzidine Tetrahydrochlo-
employees and other users of the product. The Hazard Clas- Tetrahydrochloride Skn-rbt: LD50: 20mg/kg
Respiratory Protection: None required if used in a laboratory (pure form): ride is NOT on California's listing of known or potential carcinogens.
sification listed in this section refers to the chemical at a pure Orl-hmn TDLO: 710 ug/kg
with an adequate air-exchange HVAC.
concentration. Inv-mus LD50: 330mg/kg Hazard Symbol: Not Required
General Hygiene: Wash thoroughly after handling. Mobility: This product is water-soluble and may spread in water
3. HAZARDS IDENTIFICATION
16. OTHER INFORMATION
systems. This product is not particularly volatile.
9. PHYSICAL & CHEMICAL PROPERTIES
Potential irritant liquid.
Degradability: N/A For laboratory use only. Not for drug, household or other uses.
Appearance:............. purple or brown Interpretation of the test results is solely the responsibility of the
4. FIRST AID MEASURES Accumulation: N/A
Physical State: ......... liquid user. There are no warranties, expressed or implied, which extend
Ecotoxicity: N/A
Eye Contact: In case of contact, immediately flush eyes with beyond this description. The information contained in this sheet
Odor:.......................... pungent
generous amounts of water. Assure adequate flushing by separat- is believed to be accurate but it is the responsibility of the user to
pH: ............................. 7.0 Other Hazardous Effects: N/A
ing the eyelids with fingers. If exposure symptoms develop, seek determine the applicability of this data to the formulation of neces-
Solubility: ................ Water-soluble
medical attention. sary safety precautions. Cell Marque Corporation shall not be held
13. DISPOSAL CONSIDERATIONS
Specific Gravity: ...... N/A
responsible for any damages resulting from the use of the above
Skin Contact: In case of contact, immediately wash skin with soap Evaporation Rate:... N/A
Contact a licensed professional waste disposal service to dispose product or the information contained in this MSDS Sheet.
and generous amounts of water. Melting Point: ......... N/A of this material. Dissolve or mix the material with a combustible
Ingestion: If swallowed, wash out mouth with water. Seek Vapor Pressure: ....... 0.013 kPa solvent and burn in a chemical incinerator equipped with an
medical attention. Boiling Point: .......... N/A afterburner and scrubber. Observe all federal, state, local or other
Vapor Density:......... 1.000 (gm/mL @ 20癈) country-specific environmental regulations.
Cell Marque Corporation ?6600 Sierra College Blvd., Rocklin, CA 95677 USA ?1-800-665-7284 ?+1-916-746-8900 ?www.cellmarque.com
Rev. 0710.1
Material Safety Datasheet
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION 5. FIRE FIGHTING MEASURES 10. STABILITY AND REACTIVITY 14. TRANSPORT INFORMATION:
Product Name: Manufacturer: Extinguishing Media: No restrictions. Use extinguishing media Stability: Stable when used under normal conditions and within DOT: This substance is considered to be non-hazardous for
HRP Detection System Cell Marque Corporation appropriate to surrounding fire conditions. the scope of the intended application. transport.
6600 Sierra College Blvd.
Flash Point: N/A; Non-flammable Conditions to Avoid: Exposure to light and moisture Proper Shipping Name: N/A
Rocklin, CA 95677 USA
Flammability: Non-flammable Materials to Avoid: Metals, Acidic pH IATA: At product concentrations, this material is not subject to
+916-746-8900
a hazard classification in accordance with IATA Dangerous Goods
Protective Equipment: Wear latex gloves and protective eye Hazardous Decomposition Products: CO, CO2, nitrogen oxides
Product Number(s):
Regulations
wear.
CMD337
11. TOXICOLOGICAL INFORMATION
15. REGULATORY INFORMATION:
6. ACCIDENTAL RELEASE MEASURES
To the best of our knowledge, the chemical, physical, and toxico-
EU Additional Classification:
Spill Control: At product concentrations, solution may be washed logical properties have not been thoroughly investigated at product
Safety Statements: Avoid Contact With Eyes and Skin.
These products are for immunohistochemistry use. to drain with large quantities of water. Flush to sewer if allowed. concentrations.
S: 36
Residual residue removed by mop or cloth.
Skin Contact:
2. COMPOSITION/INFORMATION ON INGREDIENTS May cause local discomfort.
U.S. Classification and Label text:
7. HANDLING AND STORAGE Skin Absorption: May cause local discomfort. U.S. Statements: Caution: Avoid Contact
Hazard
Eye Contact: May cause irritation.
Component CAS No. Composition Classification U.S. Regulatory Information:
Keep containers tightly closed. Store at 2-8癈 in a location pro-
tected from light. Store away from oxidizers and ignition sources. SARA Listed: No
Inhalation: May cause irritation to mucous
(pure form)
TSCA Inventory Item: This product complies with all TSCA inven-
membranes and upper respiratory
Bronidox L 300D7-47-7 0.02% Xn ,R22, R38, S36 8. EXPOSURE CONTROLS, PERSONAL PROTECTION tory requirements.
tract.
CANADA REGULATORY INFORMATION:
Ingestion:
Eye Protection: May be harmful if swallowed.
Chemical safety glasses or goggles
NOTE: This material is NOT CLASSIFIED AS HAZARDOUS at
WHMIS Classification: This product has been classified in accor-
product concentrations. In accordance with OSHA regulations
Target organs:
Hand Protection: N/A
Latex gloves dance with the hazard criteria of the CPR, and the MSDS contains all
and European Union Directives, this MSDS contains valuable
the information required by the CPR.
Respiratory Protection: None required if used in a laboratory
information critical to the safe handling and proper use of the 12. ECOLOGICAL INFORMATION:
with an adequate air-exchange HVAC.
product. This MSDS should be retained and is available for California Proposition 65: The following statement is made in
employees and other users of the product. The Hazard Clas- order to comply with the California State Drinking Water and Toxic
Bronidox L Orl-rat LD50: 455 ug/24 Hr.
General Hygiene: Wash thoroughly after handling.
sification listed in this section refers to the chemical at a pure (pure form): Enforcement Act of 1986. Bronidox L is NOT on California's listing of
Skn-rat: LD50: 2500 ug/24 Hr.
concentration. 9. PHYSICAL & CHEMICAL PROPERTIES known or potential carcinogens.
Mobility: This product is water-insoluble.
Hazard Symbol: Not required at product concentrations
3. HAZARDS IDENTIFICATION Appearance:............. Colorless Degradability: N/A
Physical State: ......... liquid 16. OTHER INFORMATION
Potential irritant liquid. Accumulation: N/A
Odor:.......................... N/A
Ecotoxicity: N/A For laboratory use only. Not for drug, household or other uses. Interpre-
4. FIRST AID MEASURES pH: ............................. 6.0 - 7.0
tation of the test results is solely the responsibility of the user. There
Solubility: ................ Water-insoluble Other Hazardous Effects: N/A
Eye Contact: In case of contact, immediately flush eyes with are no warranties, expressed or implied, which extend beyond this
Specific Gravity: ...... 1.07
generous amounts of water. Assure adequate flushing by separat- description. The information contained in this sheet is believed to
13. DISPOSAL CONSIDERATIONS
Evaporation Rate:... N/A
ing the eyelids with fingers. If exposure symptoms develop, seek be accurate but it is the responsibility of the user to determine the
Melting Point: ......... 60 癈
medical attention. Flush to sewer if allowed; residue may be removed by wipe or applicability of this data to the formulation of necessary safety
Vapor Pressure: ....... N/A mop. Observe all federal, state, local or other country-specific precautions. Cell Marque Corporation shall not be held responsible
Skin Contact: In case of contact, immediately wash skin with soap
Boiling Point: .......... N/A environmental regulations. for any damages resulting from the use of the above product or the
and generous amounts of water.
Vapor Density:......... N/A information contained in this MSDS Sheet.
Ingestion: If swallowed, wash out mouth with water. Seek
medical attention.
Cell Marque Corporation ?6600 Sierra College Blvd., Rocklin, CA 95677 USA ?1-800-665-7284 ?+1-916-746-8900 ?www.cellmarque.com
Rev. 0710.1
Material Safety Datasheet
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION 5. FIRE FIGHTING MEASURES 10. STABILITY AND REACTIVITY 14. TRANSPORT INFORMATION:
Stability: Stable when used under normal conditions and within DOT: This substance is considered to be non-hazardous for transport.
Product Name: Manufacturer: Extinguishing Media: No restrictions. Use extinguishing media
the scope of the intended application.
Proper Shipping Name: N/A
HRP Detection System Cell Marque Corporation appropriate to surrounding fire conditions.
Conditions to Avoid: Avoid light and heat.
6600 Sierra College Blvd. IATA: At product concentrations, this material is not subject to
Flash Point: N/A; Non-flammable
Rocklin, CA 95677 USA a hazard classification in accordance with IATA Dangerous Goods
Materials to Avoid: Avoid reducing agents, organic materials, dirt,
Flammability: Non-flammable
Product Number(s): +916-746-8900 Regulations
alkalis, rust, and metals.
CMD337 Protective Equipment: Wear appropriate protective clothing &
15. REGULATORY INFORMATION:
Hazardous Decomposition Products: Decomposes to water
protective eyewear.
and oxygen.
EU Additional Classification:
6. ACCIDENTAL RELEASE MEASURES Hazardous Polymerization: Will not occur. Safety Statements: Avoid Contact With Eyes and Skin.
U.S. Classification and Label text:
Spill Control: Exercise appropriate precautions to avoid direct 11. TOXICOLOGICAL INFORMATION
These products are for immunohistochemistry use.
U.S. Statements: Caution: Avoid Contact
contact with skin or eyes. At product concentrations, solutions may
be absorbed using a paper towel or absorbent pad. Solutions may U.S. Regulatory Information:
2. COMPOSITION/INFORMATION ON INGREDIENTS To the best of our knowledge, the chemical, physical, and toxico-
also be rinsed into a general drainage system provided it is accept- logical properties have not been thoroughly investigated at product SARA Listed: No
able according to applicable regulations. concentrations. TSCA Inventory Item: This product complies with all TSCA inven-
Component CAS No. Comp. Hazard Classification
tory requirements.
Skin Contact: May cause local discomfort.
7. HANDLING AND STORAGE
(pure form)
OSHA Status: At product concentrations, the chemical compo-
Hydrogen Peroxide: 7722-84-1 < 3% R: 5-8-20/22-35 Skin Absorption: May cause local discomfort. nents listed on this MSDS are NOT classified as hazardous.
S: 1/2-17-26-28-36 Keep all containers tightly closed. Store in a cool, well-ventilated
Eye Contact: May cause irritation.
S: 37/39-45 dark area. Protect from freezing. California Proposition 65: The following statement is made in
order to comply with the California State Drinking Water and Toxic
Inhalation: May cause irritation.
NOTE: It has been determined that at product concentrations,
8. EXPOSURE CONTROLS, PERSONAL PROTECTION Enforcement Act of 1986. Sodium Azide is NOT on California's listing
the chemical listed above is NOT CLASSIFIED AS HAZARDOUS
Ingestion: May be harmful if swallowed. of known or potential carcinogens.
due to the physical and/or chemical nature and/or concentra-
Eye Protection: Chemical safety glasses or goggles
tion in solution, in accordance with California and Federal OSHA Target organs: N/A Contains: <3% Hydrogen Peroxide
regulations (Federal Register 29CFR 1910.1200), and The Chemi-
Hand Protection: Latex gloves Hazard Symbol: Not Required
cals (Hazard Information and Packaging for Supply) Regulations
12. ECOLOGICAL INFORMATION:
(European Community). Respiratory Protection: None required if used in a laboratory
16. OTHER INFORMATION
with an adequate air-exchange HVAC. Hydrogen Peroxide
3. HAZARDS IDENTIFICATION
(pure form): For laboratory use only. Not for drug, household or other uses. Interpre-
General Hygiene: Wash thoroughly after handling
tation of the test results is solely the responsibility of the user. There
Despite the classification as non-hazardous at product concentra- Mobility: This product is water-soluble and may spread in water are no warranties, expressed or implied, which extend beyond this
9. PHYSICAL & CHEMICAL PROPERTIES
tions, we strongly recommend using prudent laboratory practices: systems. This product is not particularly volatile. description. The information contained in this sheet is believed to
avoiding unnecessary contact, use of personal protective equip-
Degradability: Biodegradable be accurate but it is the responsibility of the user to determine the
Appearance:............. colorless Evap. Rate: ......... N/A
ment, which may include latex gloves, eye protection, and lab
applicability of this data to the formulation of necessary safety
Physical State: ......... liquid Melting Point: ... ca. 32癋 Accumulation: N/A
coats, during the use of any laboratory reagent. May be harmful if
precautions. Cell Marque Corporation shall not be held responsible
Odor:.......................... none Vapor Pressure: . N/A Ecotoxicity: N/A
swallowed. May cause eye irritation. for any damages resulting from the use of the above product or the
pH: ............................. N/A Boiling Point: .... ca. 212癋 Other Hazardous Effects: N/A
information contained in this MSDS Sheet.
Solubility: ................ Water-soluble Vapor Density:... N/A
4. FIRST AID MEASURES
Specific Gravity: ...... ca. 1.0
13. DISPOSAL CONSIDERATIONS
Eye Contact: In case of contact, immediately flush eyes with
generous amounts of water. Assure adequate flushing by separat-
Flush to sewer if allowed; residue may be removed by wipe or
ing the eyelids with fingers. If exposure symptoms develop, seek
mop. Observe all federal, state, local or other country-specific
medical attention.
environmental regulations.
Skin Contact: In case of contact, immediately wash skin with soap
and generous amounts of water.
Ingestion: If swallowed, wash out mouth with water. If exposure
symptoms develop, seek medical attention.
Cell Marque Corporation ?USA ?6600 Sierra College Blvd. ?Rocklin, CA 95677 ?1-800-665-7284 ?+1-916-746-8900 ?www.cellmarque.com
Rev. 0710.1
Material Safety Datasheet
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION 4. FIRST AID MEASURES 9. PHYSICAL & CHEMICAL PROPERTIES 13. DISPOSAL CONSIDERATIONS
Eye Contact: In case of contact, immediately flush eyes with In accordance with US Federal OSHA regulations, at product
Appearance:............. colorless Evaporation Rate:... N/A
Product Name: Manufacturer:
generous amounts of water. Assure adequate flushing by separat- concentrations, the disposal of solutions containing Sodium Azide is
Physical State: ......... liquid Melting Point: ......... N/A
HRP Detection System Cell Marque Corporation
ing the eyelids with fingers. If exposure symptoms develop, seek not restricted. Check with all applicable regulations to ensure that
Odor:.......................... none Vapor Pressure: ....... N/A
6600 Sierra College Blvd.
medical attention. this disposal practice is allowable. If the disposal of these solutions
pH: ............................. N/A Boiling Point: .......... N/A
Rocklin, CA 95677 USA
is acceptable, flush with large volumes of water to prevent the
Solubility: ................ Water-soluble Vapor Density:......... N/A
Skin Contact: In case of contact, immediately wash skin with soap
Product Number(s): +916-746-8900
build-up of azides in the plumbing.
Specific Gravity: ...... N/A
and generous amounts of water.
CMD337
14. TRANSPORT INFORMATION:
Ingestion: If swallowed, wash out mouth with water. Seek 10. STABILITY AND REACTIVITY
medical attention.
DOT: This substance is considered to be non-hazardous for transport.
Stability: Stable when used under normal conditions and within
5. FIRE FIGHTING MEASURES the scope of the intended application. Proper Shipping Name: N/A
These products are for immunohistochemistry use. IATA: At product concentrations, this material is not subject to
Conditions to Avoid: Do not allow solutions containing sodium
Extinguishing Media: No restrictions. Use extinguishing media a hazard classification in accordance with IATA Dangerous Goods
azide to concentrate. Avoid acidic pH conditions.
appropriate to surrounding fire conditions.
2. COMPOSITION/INFORMATION ON INGREDIENTS Regulations
Materials to Avoid: Avoid contact with metals.
Flash Point: N/A; Non-flammable
15. REGULATORY INFORMATION:
Component CAS No. Composition Hazard Classification Hazardous Decomposition Products: N/A
Flammability: Non-flammable
EU Additional Classification:
(pure form)
11. TOXICOLOGICAL INFORMATION
Protective Equipment: Wear latex gloves & protective eyewear. Safety Statements: Avoid Contact With Eyes and Skin.
Sodium Azide: 26628-22-8 < 0.1% T; R28-32-50/53
Respirator: Use to protect against carbon monoxide & nitrous oxides. U.S. Classification and Label text:
Threshold limit value (pure form): 300ug/m3 To the best of our knowledge, the chemical, physical, and toxico-
U.S. Statements: Caution: Avoid Contact
logical properties have not been thoroughly investigated at product
NOTE: It has been determined that at product concentrations, 6. ACCIDENTAL RELEASE MEASURES
concentrations. U.S. Regulatory Information:
the chemical listed above is NOT CLASSIFIED AS HAZARDOUS
due to the physical and/or chemical nature and/or concentra- SARA Listed: No
Spill Control: Exercise appropriate precautions to avoid direct Skin Contact: May cause local discomfort.
tion in solution, in accordance with California and Federal TSCA Inventory Item: This product complies with all TSCA inven-
contact with skin or eyes. At product concentrations, solutions
OSHA regulations (Federal Register 29CFR 1910.1200), and The Skin Absorption: May cause local discomfort. tory requirements.
containing sodium azide may be absorbed using a paper towel
Chemicals (Hazard Information and Packaging for Supply)
or absorbent pad. Solutions may also be rinsed into a general Eye Contact: May cause irritation. OSHA Status: At product concentrations, the chemical compo-
Regulations (European Community).
drainage system provided it is acceptable according to applicable nents listed on this MSDS are NOT classified as hazardous.
Inhalation: May cause irritation.
3. HAZARDS IDENTIFICATION regulations.
California Proposition 65: The following statement is made in
Ingestion: May be harmful if swallowed.
order to comply with the California State Drinking Water and Toxic
7. HANDLING AND STORAGE
Despite the classification as non-hazardous at product concentra-
Target organs: Enforcement Act of 1986. Sodium Azide is NOT on California's listing
Lungs, Gastrointestinal System, Skin
tions, we strongly recommend using prudent laboratory practices:
of known or potential carcinogens.
Keep all containers tightly closed. Store and handle as described in
avoiding unnecessary contact, use of personal protective equip-
12. ECOLOGICAL INFORMATION:
the product's specification sheet. Contains: <0.1% (15 mM) / Sodium Azide
ment, which may include latex gloves, eye protection, and lab
coats, during the use of any laboratory reagent. Hazard Symbol: Not Required
Sodium Azide Orl-rat LD50: 27 mg/kg
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
(pure form):
NFPA Ratings: Skn-rbt: LD50: 20mg/kg
16. OTHER INFORMATION
0
Health-1 Orl-hmn TDLo: 710 ug/kg
Eye Protection: Chemical safety glasses or goggles
10
Fire-0 Inv-mus LD50: 19mg/kg For laboratory use only. Not for drug, household or other uses. Interpre-
Hand Protection: Latex gloves
Reactivity-0 tation of the test results is solely the responsibility of the user. There
Mobility: This product is water-soluble and may spread in water
None
Special-None are no warranties, expressed or implied, which extend beyond this
Respiratory Protection: None required if used in a laboratory systems. This product is not particularly volatile.
description. The information contained in this sheet is believed to
with an adequate air-exchange HVAC.
HMIS Ratings: Degradability: Biodegradable be accurate but it is the responsibility of the user to determine the
Health-1 1
HEALTH General Hygiene: Wash thoroughly after handling Accumulation: N/A applicability of this data to the formulation of necessary safety
Fire-0 FLAMMABILITY 0 precautions. Cell Marque Corporation shall not be held responsible
Ecotoxicity: N/A
Physical Hazard-B PHYSICAL HAZARD B for any damages resulting from the use of the above product or the
Other Hazardous Effects: N/A
information contained in this MSDS Sheet.
Cell Marque Corporation ?6600 Sierra College Blvd., Rocklin, CA 95677 USA ?1-800-665-7284 ?+1-916-746-8900 ?www.cellmarque.com
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