CHEM ONE CORPORATION           -- SODIUM CARBONATE PEROXYHYDRATE

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MSDS Safety Information

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FSC: 6810

MSDS Date: 01/20/1995

MSDS Num: BXYRT

LIIN: 00D004119

Product ID: SODIUM CARBONATE PEROXYHYDRATE

MFN: 02

Responsible Party

Cage: CHEMO

Name: CHEM ONE CORPORATION

Address: 15150 SOMMERMEYER, SUITE 100

City: HOUSTON TX 77704

Info Phone Number: 713-896-9966/800--424-9300

Emergency Phone Number: 713-896-9966/800--424-9300

Preparer's Name: CLARE WELKER

Review Ind: Y

Published: Y

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Contractor Summary

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Cage: CHEMO

Name: CHEM ONE CORPORATION

City: HOUSTON TX 77041-5308

Phone: 713-896-9966

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Ingredients

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Cas: 479-19-8

RTECS #: 1004436SC

Name: SODIUM CARBONATE

% Wt: 65-70

Other REC Limits: NONE RECOMMENDED

OSHA PEL: NOT ESTABLISHED

ACGIH TLV: NOT ESTABLISHED

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Cas: 7722-84-1

RTECS #: MX0899500

Name: HYDROGEN PEROXIDE

% Wt: 25-30

Other REC Limits: NONE RECOMMENDED

OSHA PEL: NOT ESTABLISHED

ACGIH TLV: NOT ESTABLISHED

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Health Hazards Data

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LD50 LC50 Mixture: ORAL LD50 (RAT) IS UNKNOWN

Route Of Entry Inds - Inhalation: YES

Skin: YES

Ingestion: YES

Carcinogenicity Inds - NTP: NO

IARC: NO

OSHA: NO

Effects of Exposure: EYES-THIS PRODUCT MAY CAUSE SEVERE EYE IRRITATION.

  SKIN-THIS PRODUCT MAY CAUSE IRRITATION TO THE SKIN. INGESTION-THIS PRODUCT

  MAY BE TOXIC BY INGESTION. INHALATION-AVOID BREATHING DUSTS. INHALATION MAY

  CAUSE IRRITATION TO THE MUCOUS MEMEBRA NES OF THE UPPER RESPIRATORY SYSTEM.

Explanation Of Carcinogenicity: NONE SPECIFIED BY MANUFACTURER.

Signs And Symptions Of Overexposure: NONE SPECIFIED BY MANUFACTURER.

Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.

First Aid: EYE-IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR 20 MIN. SEEK

  MEDICAL AID. SKIN-WASH GENTLY & THOROUGHLY WITH WATER & NONABRASIVE

  SOAP. SEEK MEDICAL ADVICE. INGESTION-IMMEDIATELY GIVE LARGE AMOUNTS OF

  WATER.IF VOMITING OCCURS, RINSE MOU TH & REPEAT ADMINISTRATION OF WATER.

  INHALATION-REMOVE SOURCE OF CONTAMINATION OR MOVE VICTIM TO FRESH AIR. IF

  NOT BREATHING, APPLY ARTIFICIAL RESPIRATION.

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Handling and Disposal

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Spill Release Procedures: IF SWEEPING OF A CONTAMINATED AREA IS NECESSARY,

  USE A DUST SUPPRESSANT. VENTILATE THE CONTAMINATED AREA. VACUUM UP THE

  SPILLED MATERIAL. DO NOT ALLOW THE SPILLED PRODUCT TO ENTER PUBLIC DRAINAGE

  SYSTEM OR OPEN WATER COURSES. PUT IN COVERED , CANS.

Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods: REVIEW FEDERAL, PROVINCIAL AND LOCAL GOVERNMENT

  REQUIREMENTS PRIOR TO DISPOSAL. DISPOSE BY CONTROLLED INCINERATION OR

  SECURE LANDFILL MAY BE ACCEPTABLE.

Handling And Storage Precautions: KEEP CONTAINER TIGHTLY CLOSED & IN A

  COOL, WELL-VENTILATED PLACE. DO NOT STORE THIS MATERIAL IN OPEN OR

  UNLABELED CONTAINERS. GUARD AGAINST DUST.

Other Precautions: EVACUATION PROCEDURES: KEEP UNNECESSARY PERSONNEL

  AWAY.CLOSE OFF AREA. SPECIAL INSTRUCTIONS: AVOID INHALATION OF DUSTS. HAVE

  ACCESS TO AN EYEWASH FOUNTAIN AND SAFETY SHOWER.

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Fire and Explosion Hazard Information

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Extinguishing Media: FLOOD WITH WATER. APPLY WATER FROM AS FAR A DISTANCE AS

  POSSIBLE.

Fire Fighting Procedures: FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE CLOTHING

  INCLUDING SELF-CONTAINED BREATHING APPARATUS.

Unusual Fire/Explosion Hazard: DECOMPOSITION CAUSES A RELEASE OF OXYGEN &

  HEAT WHICH CAN SUPPORT COMBUSTION. DECONTAMINATION CAN PROMOTE

  DECOMPOSITION.THE OXYGEN EVOLVED CAN BURST SEALED CAN

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Control Measures

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Respiratory Protection: USE A DUST MASK & MAINTAIN ADEQUATE VENTILATION FOR

  GENERAL CONTACT WITH THIS MATERIAL. WEAR A POSITIVE PRESSURE SELF-CONTAINED

  BREATHING APPARATUS WHEN FIGHTING FIRES.

Ventilation: USE A GENERAL MECHANICAL VENTILATION. LOCAL EXHAUST IS SUGGESTED

  FOR ENCLOSED OR CONFINED SPACES.

Protective Gloves: RUBBER GLOVES ARE RECOMMENDED.

Eye Protection: SAFETY GLASSES/CHEMICAL GOGGLES.

Other Protective Equipment: WEAR CHEMICAL PROTECTIVE BOOTS.

Work Hygienic Practices: USE GOOD HYGIENE PRACTICES WHEN HANDLING THIS

  MATERIAL INCLUDING CHANGING AND LAUNDERING WORK CLOTHING AFTER USE.

Supplemental Safety and Health: AS SHIPPED THIS PRODUCT IS CONSIDERED A D001

  HAZARDOUS WASTE BY EPA. OXIDIZERS!!!

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Physical/Chemical Properties

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HCC: D1

M.P/F.P Text: DECOMPOSES

PH: 10.5

Solubility in Water: 140 G/L

Appearance and Odor: WHITE. SOLID. ODORLESS.

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Reactivity Data

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Stability Indicator: YES

Stability Condition To Avoid: STABLE WHEN DRY.

Materials To Avoid: ORGANIC MATERIALS, HEAVY METALS, OILS AND GREASES.

  MOISTURE, REDUCING AGENTS & METALLIC IONS. REACTION MAY BE VIOLENT.

Hazardous Decomposition Products: HYDROGEN PEROXIDE, CARBONATE AND OXYGEN.

Hazardous Polymerization Indicator: NO

Conditions To Avoid Polymerization: NONE

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Toxicological Information

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Ecological Information

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MSDS Transport Information

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Regulatory Information

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Other Information

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Transportation Information

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Responsible Party Cage: CHEMO

Trans ID NO: 3121

Product ID: SODIUM CARBONATE PEROXYHYDRATE

MSDS Prepared Date: 01/20/1995

Review Date: 12/11/1995

MFN: 2

AF MMAC Code: NO

Multiple KIT Number: 0

Review IND: Y

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Detail DOT Information

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DOT PSN Code: HMJ

DOT Proper Shipping Name: HYDROGEN PEROXIDE, AQUEOUS SOLUTIONS

DOT PSN Modifier: WITH NOT LESS THAN 8 PER CENT BUT LESS THAN 20 PER CENT

  HYDROGEN PEROXIDE (STABILIZED AS NECESSARY)

Hazard Class: 5.1

UN ID Num: UN2984

DOT Packaging Group: III

Label: OXIDIZER

Special Provision: 17,A1,T8,T37

Packaging Exception: 152

Non Bulk Pack: 203

Bulk Pack: 241

Max Qty Pass: 2.5 L

Max Qty Cargo: 30 L

Vessel Stow Req: B

Water/Ship/Other Req: 25,75,106

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Detail IMO Information

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IMO PSN Code: IIK

IMO Proper Shipping Name: HYDROGEN PEROXIDE, AQUEOUS SOLUTION,

IMO PSN Modifier: WITH NOT LESS THAN 8% BUT LESS THAN 20% HYDROGEN PEROXIDE

  (STABILIZED AS NECESSARY)

IMDG Page Number: 5150

UN Number: 2984

UN Hazard Class: 5.1

IMO Packaging Group: III

Subsidiary Risk Label: -

EMS Number: 5.1-02

MED First Aid Guide NUM: 735

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Detail IATA Information

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IATA PSN Code: NTW

IATA UN ID Num: 2984

IATA Proper Shipping Name: HYDROGEN PEROXIDE, AQUEOUS SOLUTION

IATA PSN Modifier: WITH 8% OR MORE BUT LESS THAN 20% HYDROGEN PEROXIDE

  (STABILIZED AS NECESSARY)

IATA UN Class: 5.1

IATA Label: OXIDIZER

UN Packing Group: III

Packing Note Passenger: 514

Max Quant Pass: 2.5L

Max Quant Cargo: 30L

Packaging Note Cargo: 515

Exceptions: A17

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Detail AFI Information

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AFI PSN Code: NTW

AFI Proper Shipping Name: HYDROGEN PEROXIDE, AQUEOUS SOLUTIONS

AFI PSN Modifier: WITH NOT LESS THAN 8% BUT LESS THAN 20% HYDROGEN PEROXIDE

  (STABILIZED AS NECESSARY)

AFI Hazard Class: 5.1

AFI UN ID NUM: UN2984

AFI Packing Group: III

Special Provisions: P5, A1, 17

Back Pack Reference: A9.7

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HAZCOM Label

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Product ID: SODIUM CARBONATE PEROXYHYDRATE

Cage: CHEMO

Assigned IND: Y

Company Name: CHEM ONE CORPORATION

City: HOUSTON TX

Zipcode: 77041-5308

Health Emergency Phone: 713-896-9966/800--424-9300

Label Required IND: Y

Date Of Label Review: 12/11/1995

Status Code: C

Label Date: 12/11/1995

Origination Code: F

Chronic Hazard IND: Y

Eye Protection IND: YES

Skin Protection IND: YES

Signal Word: WARNING

Respiratory Protection IND: YES

Health Hazard: Moderate

Contact Hazard: Moderate

Fire Hazard: None

Reactivity Hazard: None

Hazard And Precautions: OXIDIZER!!!IN CASE OF SPILL: VENTILATE THE

  CONTAMINATED AREA. VACUUM UP THE SPILLED MATERIAL. DO NOT ALLOW THE SPILLED

  PRODUCT TO ENTER PUBLIC DRAINAGE SYSTEM OR OPEN WATER COURSES. PUT IN

  COVERED, CANS.FIRST AID: EYE-IMMEDIATELY FLUSH EYE S WITH PLENTY OF WATER

  FOR 20 MIN. SEEK MEDICAL AID. SKIN-WASH GENTLY & THOROUGHLY WITH WATER &

  NONABRASIVE SOAP. SEEK MEDICAL ADVICE. INGESTION-IMMEDIATELY GIVE LARGE

  AMOUNTS OF WATER.IF VOMITING OCCURS, RINSE MOUTH & REPEAT ADMINISTRATIO N

  OF WATER.INHALATION-REMOVE SOURCE OF CONTAMINATION OR MOVE VICTIM TO FRESH

  AIR. IF NOT BREATHING, APPLY ARTIFICIAL RESPIRATION.

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Disclaimer (provided with this information by the compiling agencies): This

  information is formulated for use by elements of the Department of Defense.

  The United States of America in no manner whatsoever expressly or implied

  warrants, states, or intends said information to have any application, use

  or viability by or to any person or persons outside the Department of

  Defense nor any person or persons contracting with any instrumentality of

  the United States of America and disclaims all liability for such use. Any

  person utilizing this instruction who is not a military or civilian

  employee of the United States of America should seek competent professional

  advice to verify and assume responsibility for the suitability of this

  information to their particular situation regardless of similarity to a

  corresponding Department of Defense or other government situation.