3M MATERIAL SAFETY DATA SHEET COMPUBLEND (TM) II NON-ACID BATHROOM CLEANER (Ready-to-Use) 08/23/2005
Material Safety Data Sheet
Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: COMPUBLEND (TM) II NON-ACID BATHROOM CLEANER (Ready-to-Use)
MANUFACTURER: 3M
DIVISION: Commercial Care Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 08/23/2005 Downloaded 4/3/2007
Supercedes Date: 08/22/2005
Document Group: 11-3764-5
Product Use:
Specific Use: Designed for daily use in cleaning toilet bowls and urinals, and other hard surface bathroom areas.
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
WATER 7732-18-5 > 95
1-METHOXY-2-PROPANOL 107-98-2 0.1 - 1
ALCOHOLS, C12-14, ETHOXYLATED PROPOXYLATED 68439-51-0 0.1 - 1
2-BUTOXYETHANOL 111-76-2 0.1 - 1
ACRYLIC ACID, POLYMERS 9003-01-4 0.1 - 1
EDTA TETRASODIUM SALT 64-02-8 0.1 - 1
SODIUM HYDROXIDE 1310-73-2 0.1 - 1
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Liquid
Odor, Color, Grade: Clear light turquoise, citrus scent
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: May cause target organ effects.
3.2 POTENTIAL HEALTH EFFECTS
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3M MATERIAL SAFETY DATA SHEET COMPUBLEND (TM) II NON-ACID BATHROOM CLEANER (Ready-to-Use) 08/23/2005
Eye Contact:
Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Not Applicable
Flash Point
Not Applicable
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Material will not burn.
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Nonflammable.
Unusual Fire and Explosion Hazards: Not applicable.
SECTION 6: ACCIDENTAL RELEASE MEASURES
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3M MATERIAL SAFETY DATA SHEET COMPUBLEND (TM) II NON-ACID BATHROOM CLEANER (Ready-to-Use) 08/23/2005
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be
cleaned up by qualified personnel. Ventilate the area with fresh air. Contain spill. For larger spills, cover drains and build dikes to
prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite,
vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much
of the spilled material as possible. Clean up residue with water. Collect the resulting residue containing solution. Place in a closed
container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Keep out of the reach of children. Avoid breathing of vapors, mists or spray. Avoid prolonged or repeated skin contact. Avoid eye
contact with vapors, mists, or spray.
7.2 STORAGE
Store under normal warehouse conditions.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use in a well-ventilated area.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin Protection
Avoid prolonged or repeated skin contact. Gloves not normally required.
If prolonged or repeated skin contact is expected, select and use gloves and/or protective clothing to prevent skin contact based on the
results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate
compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber, Neoprene, Nitrile Rubber.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray. Under normal use conditions, airborne exposures are not expected to be significant enough
to require respiratory protection.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
1-METHOXY-2-PROPANOL ACGIH TWA 100 ppm
1-METHOXY-2-PROPANOL ACGIH STEL 150 ppm
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3M MATERIAL SAFETY DATA SHEET COMPUBLEND (TM) II NON-ACID BATHROOM CLEANER (Ready-to-Use) 08/23/2005
1-METHOXY-2-PROPANOL OSHA TWA 100 ppm Table Z-1A
1-METHOXY-2-PROPANOL OSHA STEL 150 ppm Table Z-1A
2-BUTOXYETHANOL ACGIH TWA 20 ppm Table A3
2-BUTOXYETHANOL OSHA TWA, Vacated 25 ppm Skin Notation*
2-BUTOXYETHANOL OSHA TWA 50 ppm Skin Notation*; Table Z-1
POLYETHYLENE GLYCOLS AIHA TWA, as aerosol 10 mg/m3
SODIUM HYDROXIDE ACGIH CEIL 2 mg/m3
SODIUM HYDROXIDE CMRG TWA 2 mg/m3
SODIUM HYDROXIDE OSHA CEIL 2 mg/m3 Table Z-1A
SODIUM HYDROXIDE OSHA TWA 2 mg/m3 Table Z-1
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,
either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Specific Physical Form:
Clear light turquoise, citrus scent
Odor, Color, Grade:
Liquid
General Physical Form:
Not Applicable
Flash Point
Approximately 212 篎
Boiling point
Approximately 1 [Ref Std: WATER=1]
Specific Gravity
Approximately 9.4
pH
Complete
Solubility in Water
1 - 3 % [Test Method: calculated per CARB title 2]
Volatile Organic Compounds
300 - 700 g/l [Test Method: calculated per CARB title 2]
VOC Less H2O & Exempt Solvents
< 100 centipoise
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: None known
Hazardous Polymerization: Hazardous polymerization will not occur.
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3M MATERIAL SAFETY DATA SHEET COMPUBLEND (TM) II NON-ACID BATHROOM CLEANER (Ready-to-Use) 08/23/2005
Hazardous Decomposition: Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous
decomposition products may occur as a result of oxidation, heating, or reaction with another material.
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
CHEMICAL FATE INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Discharge spent solutions and small quantities (less than 5 gal.(19 L)) to a wastewater treatment system.
Reduce discharge rate if foaming occurs. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical
waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
STATE REGULATIONS
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
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3M MATERIAL SAFETY DATA SHEET COMPUBLEND (TM) II NON-ACID BATHROOM CLEANER (Ready-to-Use) 08/23/2005
The components of this product are listed on the Australian Inventory of Chemical Substances.
All the components of this product are listed on China's Inventory of Chemical Substances.
The components of this product are in compliance with notification requirements in the Philippines.
INTERNATIONAL REGULATIONS
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 1 Flammability: 0 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 1 Flammability: 0 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS? hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS?ratings are to be used with a fully implemented HMIS?program. HMIS?is a registered mark of the National Paint and Coatings
Association (NPCA).
Revision Changes:
Section 4: First aid for eye contact - medical assistance - was modified.
Section 3: Potential effects from inhalation information was modified.
Section 3: Potential effects from ingestion information was modified.
Section 4: First aid for skin contact - decontamination - was modified.
Section 4: First aid for inhalation - termination of exposure - was modified.
Section 4: First aid for inhalation - medical assistance - was modified.
Section 3: Immediate other hazard(s) was modified.
Section 3: Carcinogenicity heading was deleted.
Section 3: Other potential health effects heading was deleted.
Section 3: Carcinogenicity phrase was deleted.
Section 3: Other health effects information was deleted.
Section 3: Carcinogenicity table was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
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3M MATERIAL SAFETY DATA SHEET COMPUBLEND (TM) II NON-ACID BATHROOM CLEANER (Ready-to-Use) 08/23/2005
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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