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MSDS Material Safety Data Sheet
CAS

409-21-2 7732-18-5 107-21-1 8001-79-4 102-71-6 9003-01-4

File Name: 409-21-2_7732-18-5_107-21-1_8001-79-4_102-71-6_9003-01-4.asp

LOCTITE CORPORATION                                                            09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 01 of 05

Valve Grinding Compound
80036

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: Valve Grinding Compound
Item No.: 80036
Part No.: 34A
Product Type: Aqueous dispersion

2. COMPOSITION, INFORMATION ON INGREDIENTS


Ingredients CAS No. %

SILICON CARBIDE 409-21-2 40-45
Water 7732-18-5 40-45
ETHYLENE GLYCOL* 107-21-1 10-15
Vegetable oil 8001-79-4 1-5
Triethanolamine 102-71-6 0.1-0.5
Acrylic acid polymer 9003-01-4 0.1-0.5

* This component is listed as a SARA Section 313 Toxic Chemical.


Ingredients which have exposure limits

Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)

SILICON CARBIDE 10 mg/m3 TWA 10 mg/m3 dust None
5 mg/m3 resp
ETHYLENE GLYCOL None 50 ppm ceiling None
125mg/m3ceiling
Vegetable oil 10 mg/m3 mist 15mg/m3mistdust None
5mg/m3mist resp
Triethanolamine 5 mg/m3 None None

Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)

ETHYLENE GLYCOL 39.4ppm ceil ar None
100mg/m3 ceil a

3. HAZARDS IDENTIFICATION

Toxicity: Moderately toxic by ingestion or inhalation.
Possible eye irritant.
Primary Routes of Entry: Skin, ingestion, inhalation.
Signs and symptoms
of Exposure: None expected except by inhalation. Glycol gives
initial central nervous system stimulation
followed by depression.
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 02 of 05

Product Name: Valve Grinding Compound
Item No.: 80036

3. HAZARDS IDENTIFICATION (continued)

Existing Conditions
Aggravated by Exposure: None known

Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA

SILICON CARBIDE NUI NO NO NO
Water No Data NO NO NO
ETHYLENE GLYCOL AC4 CNS DEV IRR KID MET NO NO NO
Vegetable oil IRR NO NO NO
Triethanolamine ALG IRR NO NO NO
Acrylic acid polymer No Data NO N/A NO
-------------------------------------------------------------------------------

Abbreviations

N/A Not Applicable AC4 ACGIH-Unclassifiable as human carc.
ALG Allergen CNS Central nervous system
DEV Developmental IRR Irritant
KID Kidney MET Metabolic
NUI Nuisance dust


4. FIRST AID MEASURES

Ingestion: Induce vomiting. Obtain medical attention.
Inhalation: Remove to fresh air. If symptoms persist obtain
medical attention.
Skin Contact: Wash with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.

5. FIRE FIGHTING MEASURES

Flash Point: None (water based) Method: Not Applicable
Recommended
Extinguishing Agents: Water
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Unusual Fire or
Explosion Hazards: None

Explosive Limits:
(% by volume in air)Lower 3.2% Ethylene glycol
(% by volume in air)Upper 15.3% Ethylene glycol
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 03 of 05

Product Name: Valve Grinding Compound
Item No.: 80036

6. ACCIDENTAL RELEASE MEASURES

Steps to be taken in case
of spill or leak: Soak up in an inert absorbent. Residues may be
cleaned up with soap and water.

7. HANDLING AND STORAGE

Safe Storage: Keep from freezing.
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid skin or eye contact.

8. EXPOSURE CONTROLS, PERSONAL PROTECTION

Eyes: Safety glasses or goggles.
Skin: Not needed for occasional use, but rubber or
plastic gloves recommended for prolonged or
frequent exposure.
Ventilation: Required only if material is used hot or if mist
is produced by automatic machinery.

See Section 2 for Exposure Limits.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Grey paste
Odor: None
Boiling Point: Approximately 212癋
pH: Mildly basic
Solubility in Water: 55-60%
Specific Gravity 1.36
Volatile Organic Compound
(EPA Method 24) 55.6%
Vapor Pressure: Not available
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available

10. STABILITY AND REACTIVITY

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
Hazardous Decomposition
Products (non-thermal): None
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 04 of 05

Product Name: Valve Grinding Compound
Item No.: 80036

11. TOXICOLOGICAL INFORMATION

See Section 3.

12. ECOLOGICAL INFORMATION

No data available

13. DISPOSAL CONSIDERATIONS

Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material

14. TRANSPORT INFORMATION

DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None

15. REGULATORY INFORMATION

CA Proposition 65: No Prop65 chemicals are known to be present.

16. OTHER INFORMATION

Estimated NFPA(R) Code:
Health Hazard: 1
Fire Hazard: 0
Reactivity Hazard: 0
Specific Hazard: Does not apply

Estimated HMIS(R) Code:
Health Hazard: 1
Flammability Hazard: 0
Reactivity Hazards: 0
Personal Protection: See Section 8.

NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100

MATERIAL SAFETY DATA SHEET Page 05 of 05

Product Name: Valve Grinding Compound
Item No.: 80036

16. OTHER INFORMATION (continued)

Prepared By: Stephen Repetto
Title: Research Chemist, Health and Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: September 09, 1996 Revision: 0026

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