MATERIAL SAFETY DATA SHEET
1 CHEMICAL PRODUCT & COMPANY IDENTIFICATION
TRADE NAME(S) KOCHKLEEN?L-07
MIXTURE
CAS NUMBER
MSDS NUMBER 68
PRODUCT CODE ND
PRODUCT USE MEMBRANE CLEANER
MANUFACTURER / SUPPLIER Koch Membrane Systems, Inc.
850 Main Street
Wilmington, MA
01887 USA
TELEPHONE NUMBERS - 24 HOUR ASSISTANCE
Canutec: 613-996-6666
Chemtrec: 800-424-9300 (inside USA)
+1-703-527-3887 (outside USA)
TELEPHONE NUMBERS - GENERAL ASSISTANCE
(8-5, M-F EST) Product 978-657-4250
Assistance
2 COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient Name CAS Number Concentration* Exposure Limits / Health Hazards
GLYCINE, N,N'-1,2-ETHANEDIYL 64-02-8 3-7% ND
BIS- (N- (CARBOXYMETHYL)
-TETRA SODIUM SALT
POLYACRYLIC ACID 9003-01-4 1-5% ND
SODIUM LAURYL SULFATE 151-21-3 <1% ND
TRISODIUM NITRILOTRIACETATE 5064-31-3 < 0.2 % ND
*Values do not reflect absolute minimums and maximums; these values are typical which may vary from time to time.
WHMIS Classification: D2B.
The percentage concentrations and concentration ranges reported are an expression of the ratio of the weight
of the ingredient or complex mixture to the weight of the controlled product.
Local authorities should be consulted for exposure limits in effect in your region.
ND = No Data NA = Not Applicable Printed On 10/13/2005 1/ 7
Material Id 68 Trade Name KOCHKLEEN?L-07
3 HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING!
HEALTH HAZARDS
IRRITATING TO THE EYES, RESPIRATORY SYSTEM, AND SKIN
**SEE "TOXICOLOGICAL INFORMATION" (SECTION 11) FOR MORE INFORMATION
FLAMMABILITY HAZARDS
NON-COMBUSTIBLE
REACTIVITY HAZARDS
STABLE
POTENTIAL HEALTH EFFECTS, SKIN
The following evaluation is based on a component(s) of this material.
IRRITATING. Prolonged or repeated exposure may cause skin irritation, even a burn. Contact may cause
reddening, itching and inflammation. Repeated or prolonged skin contact may cause drying, reddening, itching
and cracking.
POTENTIAL HEALTH EFFECTS, EYE
The following evaluation is based on a component(s) of this material.
MODERATELY TO SEVERELY IRRITATING. May cause severe irritation with corneal injury which may result
in permanent impairment of vision, even blindness. Mists may cause eye irritation. Direct contact may cause
pain, tears, burns, sensitivity to light, swelling and possible corneal damage.
POTENTIAL HEALTH EFFECTS, INHALATION
The following evaluation is based on a component(s) of this material.
Under normal conditions, inhalation is not expected to be a problem. However, respiratory tract irritation may
occur if exposed to fumes or mists. Symptoms may include sore throat, coughing, labored breathing, sneezing
and burning sensation, depending on the concentration and duration of exposure.
POTENTIAL HEALTH EFFECTS, INGESTION
Ingestion of large amounts may cause gastrointestinal disturbances. SLIGHTLY TOXIC. May cause irritation of
the mouth, throat and gastrointestinal tract.
Overexposure to this material may cause systemic damage including target organ effects listed under
"Toxicological Information" (Section 11).
Other specific symptoms of exposure are listed under "Toxicological Information" (Section 11).
4 FIRST AID MEASURES
SKIN
Immediately wash skin with plenty of soap and water while removing contaminated clothing and shoes. GET
IMMEDIATE MEDICAL ATTENTION.
Place contaminated clothing in closed container for storage until laundered or discarded. If clothing is to be
laundered, inform person performing operation of contaminant's hazardous properties. Discard contaminated
leather goods.
EYE
Flush immediately with large amounts of water for at least 15 minutes. Eyelids should be held away from the
eyeball to ensure thorough rinsing. GET IMMEDIATE MEDICAL ATTENTION.
INHALATION
Remove to fresh air. If not breathing, institute rescue breathing. If breathing is difficult, ensure airway is clear
and give oxygen.
Keep affected person warm and at rest. GET IMMEDIATE MEDICAL ATTENTION.
ND = No Data NA = Not Applicable Printed On 10/13/2005 2/ 7
Material Id 68 Trade Name KOCHKLEEN?L-07
INGESTION
Keep affected person warm and at rest. GET IMMEDIATE MEDICAL ATTENTION.
Never give anything by mouth to an unconscious person. Do not induce vomiting. If victim is conscious and
alert, give 1-3 glasses of water or milk to dilute stomach contents. If spontaneous vomiting occurs keep head
below hips to prevent aspiration and monitor for breathing difficulty.
5 FIRE FIGHTING MEASURES
HAZARDOUS COMBUSTION PRODUCTS
Combustion may produce COx, NOx
EXTINGUISHING MEDIA
Use water spray, dry chemical, alcohol foam, all purpose AFFF or carbon dioxide to extinguish fire.
BASIC FIRE FIGHTING PROCEDURES
Evacuate area and fight fire from a safe distance.
If leak or spill has not ignited, ventilate area and use water spray to disperse gas or vapor and to protect
personnel attempting to stop a leak.
Use water spray to cool adjacent structures and to protect personnel. Shut off source of flow if possible. Stay
away from storage tank ends. Withdraw immediately in case of rising sound from venting safety device or any
discoloration of storage tank due to fire.
Firefighters must wear MSHA/NIOSH approved positive pressure breathing apparatus (SCBA) with full face
mask and full protective equipment.
UNUSUAL FIRE & EXPLOSION HAZARDS
Reacts with most metals to produce hydrogen gas which can form an explosive mixture with air.
Flash Point WILL NOT FLASH
Autoignition Temperature ND
Flammability Limits in Air, Lower, % by Volume ND
Flammability Limits in Air, Upper, % by Volume ND
6 ACCIDENTAL RELEASE MEASURES
EMERGENCY ACTION
Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind. (See Exposure
Controls/Personal Protection in Section 8.)
ENVIRONMENTAL PRECAUTIONS
If product is released to the environment, take immediate steps to stop and contain release. Caution should be
exercised regarding personnel safety and exposure to the released product.
Notify local, provincial and/or federal authorities, if required.
SPILL OR LEAK PROCEDURE
Absorb spill with inert material (e. g. dry sand or earth) then place in a chemical waste container. Large Spills:
Dike far ahead of liquid spill for later disposal. Stop leak when safe to do so.
Spilled material may be slippery.
See Exposure Controls/Personal Protection (Section 8).
ND = No Data NA = Not Applicable Printed On 10/13/2005 3/ 7
Material Id 68 Trade Name KOCHKLEEN?L-07
7 HANDLING & STORAGE
HANDLING
Avoid overheating or freezing.
Spilled material may be slippery.
Do not eat, drink or smoke in areas of use or storage.
STORAGE
Store in tightly closed containers in a cool, dry, isolated, well-ventilated area away from heat, sources of ignition
and incompatibles. Avoid contact with strong oxidizers.
Store at room temperature (45癋 to 110癋).
Avoid contact with carbon steel, zinc, nickel, copper, copper alloy and aluminum. Contact with aluminum may
produce flammable hydrogen gas.
Empty containers may contain product residue. Do not reuse without adequate precautions.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
General or local exhaust ventilation and other forms of engineering controls are the preferred means for
controlling exposures.
EYE PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE)
Wear chemical safety goggles and face shield. Have eye washing facilities readily available where eye contact
can occur.
SKIN PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE)
Avoid skin contact with this material. If skin contact is anticipated, protective clothing, including impervious
gloves, should be worn.
Provide safety showers at any location where skin contact can occur. Use good personal hygiene.
RESPIRATORY PROTECTION: PERSONAL PROTECTION EQUIPMENT (PPE)
A NIOSH/MSHA approved air purifying respirator with an appropriate cartridge or canister may be appropriate
under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection
provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any
potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air
purifying respirators may not provide adequate protection.
9 PHYSICAL & CHEMICAL PROPERTIES
ODOR AND APPEARANCE
CLEAR TO SLIGHTLY YELLOW LIQUID WITH SLIGHT ODOR
ND = No Data NA = Not Applicable Printed On 10/13/2005 4/ 7
Material Id 68 Trade Name KOCHKLEEN?L-07
Boiling Point 212 ?F (100?C)
Specific Gravity 1.03 - 1.05 ND
Melting Point 32 ?F (0?C)
Percent Volatile < 90
Vapor Pressure ND
Vapor Density ND
Bulk Density 8.6 - 8.8 LBS/GAL
Solubility in Water MISCIBLE
Octanol/Water Partn ND
Volatile Organic ND
Pour Point ND
pH Value 7
Freezing Point ND
Viscosity ND
Evaporation Rate ND
Molecular Formula NA
Molecular Weight ND
Chemical Family CLEANING SOLUTION
Odor Threshold ND
10 STABILITY & REACTIVITY
STABILITY/INCOMPATIBILITY
Incompatible with strong oxidizing agents.
Avoid contact with aluminum. Flammable hydrogen gas may be formed in the presence of aluminum.
See precautions under Handling & Storage (Section 7).
HAZARDOUS REACTIONS/DECOMPOSITION PRODUCTS
Combustion may produce COx, NOx, SOx, reactive hydrocarbons, hydrogen sulfide and ammonia.
11 TOXICOLOGICAL INFORMATION
ROUTES OF EXPOSURE
Inhalation, ingestion, skin and eye contact.
LD50
LD50 (skin-rabbit) > 5,000 mg/kg [For EDTA tetrasodium salt]
LD50 (oral-rats) = 3,030 mg/kg [For EDTA tetrasodium salt]
CARCINOGENICITY
This material contains a very small amount of the trisodium salt of nitrilotriacetic acid which is listed as a
potential carcinogen by IARC, NTP and OSHA. Although large dietary doses of trisodium nitrilotriacetate have
caused urinary tumors in laboratory animals, there is little likelihood that it could cause cancer in humans,
especially at subtoxic doses.
TERATOGENICITY, MUTAGENICITY, OTHER REPRODUCTIVE EFFECTS
EDTA and its sodium salts have been reported to cause birth defects in laboratory animals only at exaggerated
doses that were toxic to the mother. These effects are likely associated with zinc deficiency due to chelation.
Exposures having no effect on the mother should have no effect on the fetus.
PRE-EXISTING CONDITIONS AGGRAVATED BY EXPOSURE
Pre-existing medical conditions which may be aggravated by exposure include disorders of the eye, skin and
respiratory system.
ND = No Data NA = Not Applicable Printed On 10/13/2005 5/ 7
Material Id 68 Trade Name KOCHKLEEN?L-07
12 ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined on product as a whole. Studies using EDTA sodium salts did not show toxicity below 100
mg/kg.
13 DISPOSAL CONSIDERATIONS
WASTE DISPOSAL
This product,as supplied, when discarded or disposed of, is not a hazardous waste according to Federal
regulations (40 CFR 261). Under the Resource Conservation and Recovery Act (RCRA), it is the responsibility
of the user of the product to determine, at the time of disposal, whether the material is a hazardous waste
subject to RCRA.
The transportation, storage, treatment and disposal of RCRA waste material must be conducted in compliance
with 40 CFR 262, 263, 264, 268 and 270. Disposal can occur only in properly permitted facilities. Check state
and local regulations for any additional requirements as these may be more restrictive than federal laws and
regulations. Chemical additions, processing or otherwise altering this material may make the waste
management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. Disposal
of this material must be conducted in compliance with all federal, state and local regulations.
In Canada, wastes should be disposed of according to federal, state, provincial and local regulations.
14 TRANSPORT INFORMATION
INTERNATIONAL TRANSPORTATION REQUIREMENTS
Non-Regulated
BILL OF LADING - BULK (U. S. DOT)
Non-Regulated
BILL OF LADING - NON-BULK (U. S. DOT)
Non-Regulated
15 REGULATORY INFORMATION
FEDERAL REGULATIONS
All components of this product are listed on the TSCA Inventory.
This product, as supplied, contains no hazardous substances regulated under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302), or any extremely
hazardous substances regulated under the Superfund Amendments and Reauthorization Act (SARA) (40 CFR
355), and thus a release of this product as supplied has no reporting requirements under these regulations.
Failure to report may result in substantial civil and criminal penalties. Check state and local regulations for any
additional requirements as these may be more restrictive than federal laws and regulations.
This product does not contain toxic chemicals (in excess of the applicable de minimis concentration) that are
subject to the annual toxic chemical release reporting requirements of the Superfund Amendments and
Reauthorization Act (SARA) Section 313 (40 CFR 372).
There may be specific regulations at the local, regional or state/provincial level that pertain to this product.
SARA TITLE III RATINGS
Immediate Hazard: X Delayed Hazard: - Fire Hazard: - Pressure Hazard: -
Reactivity Hazard: -
STATE REGULATIONS
WARNING: This product contains a chemical known to the State of California to cause cancer. WARNING:
This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
PENNSYLVANIA - Non-hazardous ingredients present at >3%: Water, CAS # 7732-18-5
ND = No Data NA = Not Applicable Printed On 10/13/2005 6/ 7
Material Id 68 Trade Name KOCHKLEEN?L-07
INTERNATIONAL REGULATIONS
CANADA
All known major components of this product are listed on the Canadian DSL.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and this MSDS contains all the information required by the CPR.
WHMIS Classification: D2B.
WHMIS RATINGS
Compressed Gas - Flammable/Combustible - Oxidizer - Acutely Toxic -
Other Toxic Effects X Bio Hazardous - Corrosive - Dangerously Reactive -
NFPA RATINGS
Health 2 Flammability 0 Reactivity 0 Special Hazards
HMIS RATINGS
Health 2 Flammability 0 Reactivity 0
16 OTHER INFORMATION
DISCLAIMER
NOTICE: The information presented herein is based on data considered to be accurate as of the date of
preparation of this Material Safety Data Sheet. However, MSDS may not be used as a commercial
specification sheet of manufacturer or seller, and no warranty or representation, expressed or implied, is made
as to the accuracy or comprehensiveness of the foregoing data and safety information, nor is any authorization
given or implied to practice any patented invention without a license. In addition, no responsibility can be
assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to
recommended practices, or from any hazards inherent in the nature of the product.
Current Revision Date 13-Oct-2005 Replaces Sheet Dated 13-Oct-2005
Completed By Koch Chemical Technology Group, LLC, call (978) 694-7346 or (978) 657-4250
ND = No Data NA = Not Applicable Printed On 10/13/2005 7/ 7
Material Id 68 Trade Name KOCHKLEEN?L-07
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