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Safety data sheet www.chasephipps.com
MASTERFLOW 648CP PLUS GROUT PTB
Revision date : 2009/04/30 Page: 1/6
Version: 1.0 (30367923/SDS_GEN_US/EN)
1. Substance/preparation and company identification
Company 24 Hour Emergency Response Information
BASF Construction Chemicals CHEMTREC: 1-800-424-9300
100 Campus Drive BASF HOTLINE: 1-800-832-HELP
Florham Park, NJ 07932
2. Composition/information on ingredients
CAS Number Content (W/W) Chemical name
68953-36-6 40.0 - 70.0 % Fatty acids, tall-oil, reaction products with tetraethylenepentamine
112-24-3 10.0 - 30.0 % triethylenetetramine
112-57-2 7.0 - 13.0 % 3,6,9-triazaundecamethylene-1,11-diamine
90-72-2 5.0 - 10.0 % 2,4,6-tris(dimethylaminomethyl)phenol
3. Hazard identification
Emergency overview
DANGER: MAY CAUSE BURNS.
MAY BE HARMFUL IF INHALED.
MAY BE HARMFUL IF SWALLOWED.
MAY CAUSE ALLERGIC SKIN REACTION.
Keep container tightly closed.
Avoid contact with the skin, eyes and clothing.
Wash thoroughly after handling.
Potential health effects
Primary routes of exposure
Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for
gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.
Acute toxicity:
Information on: 2,4,6-tris(dimethylaminomethyl)phenol
Of moderate toxicity after single ingestion.
EU-classification
Information on: triethylenetetramine
Of moderate toxicity after short-term skin contact.
Virtually nontoxic after a single ingestion.
Irritation:
Information on: triethylenetetramine
Corrosive! Damages skin and eyes. May cause severe damage to the eyes.
Sensitization:
Safety data sheet
MASTERFLOW 648CP PLUS GROUT PTB
Revision date : 2009/04/30 Page: 2/6
Version: 1.0 (30367923/SDS_GEN_US/EN)
May produce an allergic reaction. Sensitization after skin contact possible.
Information on: triethylenetetramine
Sensitization after skin contact possible.
4. First-aid measures
General advice:
First aid personnel should pay attention to their own safety. Immediately remove contaminated clothing.
If inhaled:
After inhalation of dust. Keep patient calm, remove to fresh air, seek medical attention.
If on skin:
After contact with skin, wash immediately with plenty of water and soap. Under no circumstances should
organic solvent be used. If irritation develops, seek medical attention.
If in eyes:
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
If swallowed:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce vomiting
unless told to by a poison control center or doctor.
Note to physician
Treatment: Treat according to symptoms (decontamination, vital functions), no known
specific antidote, administer corticosteroid dose aerosol to prevent pulmonary
odema.
5. Fire-fighting measures
Flash point: 148.89 癈 (ASTM D3278)
Autoignition: 294 癈
Lower explosion limit: No data available.
Upper explosion limit: No data available.
Suitable extinguishing media:
foam, water spray, dry extinguishing media, carbon dioxide
Unsuitable extinguishing media for safety reasons:
water jet
Hazards during fire-fighting:
carbon dioxide, carbon monoxide, nitrogen oxides, fumes/smoke, corrosive gases/vapours, carbon black
Protective equipment for fire-fighting:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing
water must be disposed of in accordance with official regulations.
6. Accidental release measures
Personal precautions:
Avoid contact with skin and eyes. Use personal protective clothing. Handle in accordance with good building
materials hygiene and safety practice.
Safety data sheet
MASTERFLOW 648CP PLUS GROUT PTB
Revision date : 2009/04/30 Page: 3/6
Version: 1.0 (30367923/SDS_GEN_US/EN)
Environmental precautions:
Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.
Cleanup:
For small amounts: Pick up with suitable appliance and dispose of. Dispose of absorbed material in
accordance with regulations.
For large amounts: Pick up with suitable appliance and dispose of. Dispose of absorbed material in
accordance with regulations.
7. Handling and storage
Handling
General advice:
Avoid inhalation of mists/vapours. Avoid contact with the skin, eyes and clothing.
Storage
General advice:
Keep container tightly closed in a cool, well-ventilated place.
8. Exposure controls and personal protection
Personal protective equipment
Respiratory protection:
Wear a NIOSH-certified (or equivalent) amine/organic vapor respirator. Wear a NIOSH-certified (or equivalent)
respirator as necessary.
Hand protection:
Wear chemical resistant protective gloves.
Eye protection:
Tightly fitting safety goggles (chemical goggles).
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots,
chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures:
Avoid contact with the skin, eyes and clothing. In order to prevent contamination while handling, closed
working clothes and working gloves should be used. Handle in accordance with good building materials
hygiene and safety practice. When using, do not eat, drink or smoke. Hands and/or face should be washed
before breaks and at the end of the shift. At the end of the shift the skin should be cleaned and skin-care
agents applied. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole
leaks).
9. Physical and chemical properties
Form: paste
Odour: ammonia-like
Colour: amber
pH value: Unspecified
Melting point: No data available.
Boiling point: Unspecified
Vapour pressure: < 1 hPa ( 20 癈)
Density: 0.96 g/cm3
Safety data sheet
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Revision date : 2009/04/30 Page: 4/6
Version: 1.0 (30367923/SDS_GEN_US/EN)
Vapour density: Heavier than air.
Partitioning coefficient No data available.
n-octanol/water (log Pow):
Viscosity, dynamic: No data available.
Solubility in water: insoluble
Solubility in other solvents: insoluble
10. Stability and reactivity
Conditions to avoid:
See MSDS section 7 - Handling and storage.
Substances to avoid:
strong acids, strong bases, strong oxidizing agents
Hazardous reactions:
The product is stable if stored and handled as prescribed/indicated.
Decomposition products:
carbon oxides, nitrogen oxides, aldehydes
Thermal decomposition:
No decomposition if stored and handled as prescribed/indicated.
11. Toxicological information
Sensitization:
Can sensitize the skin and/or respiratory tract of allergic persons. May produce an allergic reaction.
Genetic toxicity:
Information on: triethylenetetramine
The substance was mutagenic in various test systems with bacterias and cell cultures; however, these results
could not be confirmed in tests with mammals.
----------------------------------
12. Ecological information
Environmental toxicity
Other ecotoxicological advice:
Ecological data are not available.
13. Disposal considerations
Waste disposal of substance:
Observe national and local legal requirements.
Residues should be disposed of in the same manner as the substance/product.
Container disposal:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after
being thoroughly cleaned.
Safety data sheet
MASTERFLOW 648CP PLUS GROUT PTB
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Version: 1.0 (30367923/SDS_GEN_US/EN)
14. Transport information
Land transport
USDOT
Hazard class: 8
Packing group: III
ID number: UN 2735
Hazard label: 8
Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (contains
3,6,9-TRIAZAUNDECAMETHYLENEDIAMINE, TRIENTINE)
Sea transport
IMDG
Hazard class: 8
Packing group: III
ID number: UN 2735
Hazard label: 8
Marine pollutant: NO
Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (contains
3,6,9-TRIAZAUNDECAMETHYLENEDIAMINE, TRIENTINE)
Air transport
IATA/ICAO
Hazard class: 8
Packing group: III
ID number: UN 2735
Hazard label: 8
Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (contains
3,6,9-TRIAZAUNDECAMETHYLENEDIAMINE, TRIENTINE)
15. Regulatory information
Federal Regulations
Registration status:
TSCA, US released / listed
SARA hazard categories (EPCRA 311/312): Acute, Chronic
State regulations
State RTK
CAS Number Chemical name State RTK
112-24-3 triethylenetetramine MA, NJ, PA
112-57-2 3,6,9-triazaundecamethylene-1,11-diamine MA, NJ, PA
16. Other information
Safety data sheet
MASTERFLOW 648CP PLUS GROUT PTB
Revision date : 2009/04/30 Page: 6/6
Version: 1.0 (30367923/SDS_GEN_US/EN)
HMIS III rating
Health: 3 Flammability: 1 Physical hazard: 0
HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the substance
possesses essentially no hazard; a rating of four indicates high hazard.
Local contact information
BASF Construction Chemicals
bcc_prps@basf.com
END OF DATA SHEET
Distributed By:
Cleveland 1-800-362-9267
Canton 1-877-258-7601
Toledo 1-800-860-3352
www.chasephipps.com
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