Material Safety Data Sheet
Trade name: ALEXSEAL-Accelerator Finish Primer 442 A4429
Status: 10/10/2007
Product no.: 9071700000000 Version: 1.0.1 / USA
1.) Identification of the substance/preparation and of the
company/undertaking
Identification of the substance or preparation
Trade name
ALEXSEAL-Accelerator Finish Primer 442 A4429
Company/undertaking identification
Address
Mankiewicz Coatings L.L.C
831 South 21st Street
St. Louis, Missouri 63103
USA
Telephone no. +1 314 783-2110
Emergency telephone
CHEMTREC: 800-424-9300 OR 703-527-3887
2.) Hazards identification
Immediate hazards
General
DANGER
Causes severe irritation to skin and eyes.
Harmful if inhaled, absorbed through skin, or swallowed.
Flammable liquid and vapor.
May cause respiratory tract irritation.
Potential Health Effects
Eye
Causes: eye burns
Skin
Causes: skin burns; Harmful if absorbed through the skin.
Inhalation
May cause respiratory tract irritation.
Ingestion
Harmful if swallowed. Ingestion of this product may result in central nervous system effects including
headache, sleepiness, dizziness, slurred speech and blurred vision.
Cancer
Suspect cancer hazard (contains material which) may cause cancer.
3.) Composition / information on ingredients
Chemical characterization
Mixture (preparation)
Hazardous ingredients
XYLENE
CAS no. 1330-20-7
Concentration > 50 < 70 %-b.w.
ETHYLBENZENE
CAS no. 100-41-4
Concentration > 10 < 30 %-b.w.
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Material Safety Data Sheet
Trade name: ALEXSEAL-Accelerator Finish Primer 442 A4429
Status: 10/10/2007
Product no.: 9071700000000 Version: 1.0.1 / USA
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL
CAS no. 90-72-2
Concentration > 10 < 30 %-b.w.
4.) First aid measures
General information
In all cases of doubt, or when sickness symptoms persist, seek medical attention. Never give anything
by mouth to an unconscious person. Remove soiled or soaked clothing immediately.
After inhalation
Remove to fresh air, keep patient warm and at rest. Irregular breathing/no breathing: artificial
respiration. If unconscious place in recovery position and seek medical advice.
After skin contact
Wash skin thoroughly with soap and water or use recognised skin cleaner. Do NOT use solvents or
thinners !
After eye contact
Remove contact lenses, irrigate copiously with clean, fresh water for at least 10 minutes, holding the
eyelids apart and seek medical advice.
After ingestion
Do not induce vomiting. Keep at rest. Call a doctor.
5.) Firefighting measures
Suitable extinguishing media
Alcohol resistant foam, CO2, powders, water spray
Extinguishing media that must not be used for safety reasons
Full water jet
Special exposure hazards arising from the substance or preparation itself, its combustion
products or from resulting gases
Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Special protective equipment for firefighting
As in any fire, wear self-contained breathing apparatus pressure - demand, MSHA/ NIOSH (approved
or equivalent) and full protective gear.
Other information
Cool endangered containers with water in case of fire. Do not allow run-off from firefighting to enter
drains or water courses.
6.) Accidental release measures
Personal precautions
Exclude sources of ignition and ventilate the area. Do not inhale vapours. Refer to protective measures
listed in sections 7 and 8.
Environmental precautions
Do not allow to enter drains. If the product contaminates lakes, rivers or sewage, inform appropriate
authorities in accordance with local regulations.
Methods for cleaning up/taking up
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in suitable container for disposal.
7.) Handling and storage
Handling
Advice on safe handling
Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour
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Material Safety Data Sheet
Trade name: ALEXSEAL-Accelerator Finish Primer 442 A4429
Status: 10/10/2007
Product no.: 9071700000000 Version: 1.0.1 / USA
concentrations higher than the occupational exposure limits. The product should only be used in areas
from which all naked lights and other sources of ignition have been excluded. Comply with the health
and safety at work laws. Do not eat or drink during work - no smoking.
Advice on protection against fire and explosion
Preparation may charge electrostatically: always use earthing leads whentransferring from one
container to another. Operators should wear anti-static footwear and clothing. No sparking tools
should be used. Vapors are heavier than air and may spread along floors. Vapors may form explosive
mixtures with air.
Storage
Requirements for storage rooms and vessels
Electrical equipment should be protected to the appropriate standard. Floors should be of the
conducting type. Keep container tightly closed. Never use pressure to empty: container isnot a
pressure vessel. No smoking. Prevent unauthorized access. Containers which are opened must be
carefully resealed and kept upright to prevent leakage.
Hints on storage assembly
Keep away from oxidizing agents, from strongly alkaline and strongly acid materials.
Further information on storage conditions
Always keep in containers of same material as the original one. See also instructions on the label.
Avoid heating and direct sunlight. Keep container dry in a cool, well-ventilated place.
8.) Exposure controls / personal protection
Exposure limit values
XYLENE
CAS no. 1330-20-7
EC no. 215-535-7
ACGIH
Xylene, isomers
TWA 100 ml/m?br>
STEL 150 ml/m?br>
LIMITS FOR AIR CONTAMINANTS (OSHA)
Xylenes (o-, m-, p-isomers)
TWA 435 mg/m? 100 ml/m?br>
ETHYLBENZENE
CAS no. 100-41-4
EC no. 202-849-4
ACGIH
Ethyl benzene
TWA 100 ml/m?br>
STEL 125 ml/m?br>
LIMITS FOR AIR CONTAMINANTS (OSHA)
Ethyl benzene
TWA 435 mg/m? 100 ml/m?br>
Exposure controls
Occupational exposure controls
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local
exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations
of particulates and solvent vapour below the OEL, suitable respiratory protection must be worn.
Personal protective equipment
Respiratory protection
Use NIOSH-approved organic vapor respirator, air-supplied or self-contained breathing apparatus
depending on exposure potential. Air-supplied or self-contained breathing apparatus must be used
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Material Safety Data Sheet
Trade name: ALEXSEAL-Accelerator Finish Primer 442 A4429
Status: 10/10/2007
Product no.: 9071700000000 Version: 1.0.1 / USA
when airborne concentations are ten times above applicable exposure limits.
Hand protection
Glove permeation data does not exist for this material. The following glove(s) should be used for
splash protection only.
Appropriate Material nitrile
Eye protection
Use chemical splash goggles and face shield (ANSI Z87.1 or approved equivalent).
Skin protection
Personal should wear antistatic clothings made of natural fiber or of high temperature resistant
synthetic fiber. All parts of the body should be washed after contact.
General protective and hygiene measures
Avoid product contact with skin, eyes and clothing; Avoid the inhalation of dust from sanding,
particulates and spray mist arising from the application of this preparation. When operators, whether
spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed
air-fed respirator during the spraying process until such time as the particulates and solvent vapour
concentration has fallen below the exposure limits.
9.) Physical and chemical properties
General information
Form liquid
Color yellowish
Odor amine-like
Important health, safety and environmental information
Changes in physical state
Type Boiling point
Value > 212 癋
Pressure 1013 mbar
Flash point
Value 77 癋
Vapor pressure
Value appr. 100 hPa
Reference temperature 70 癋
Density
Value 7.34 lbs/gallon
Reference temperature 68 癋
Viscosity
Type Efflux time
Value 11 sec
Method DIN cup 4 mm
Reference temperature 68 癋
Solubility in water
Remarks insoluble
pH value
Remarks alkaline
10.) Stability and reactivity
Conditions to avoid
Stable under recommended storage and handling conditions(See section 7).
Materials to avoid
Keep away from oxidizing agents, strongly alkaline and strongly acid materials in order to avoid
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Material Safety Data Sheet
Trade name: ALEXSEAL-Accelerator Finish Primer 442 A4429
Status: 10/10/2007
Product no.: 9071700000000 Version: 1.0.1 / USA
exothermic reactions.
Hazardous decomposition products
When exposed to high temperatures may produce hazardous decomposition products such as carbon
monoxide and dioxide, smoke, oxides of nitrogen.
Thermal decomposition
Remarks No decomposition if used as prescribed.
11.) Toxicological information
Experience in practice
Exposure of vapour concentration in excess of the stated OEL's may result in adverse health effects
such as mucous membrane and respiratory system irritation and adverse effects on kidney, liver and
central nervous system. Symptoms and signs include headache, dizziness, fatigue muscular
weakness, drowsiness and in extrem cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin
resulting in non-allergic contact dermatitis and absorption through the skin.
The liquid splashed in the eyes may cause irritation and reversible damage.
Other information
Product specific toxicological data are not known.
12.) Ecological information
Other adverse effects
Ecological data are not available.
Do not discharge product unmonitored into the environment.
13.) Disposal considerations
Product
Dispose in accordance with federal, state and local regulations.
14.) Transport information
US DOT
Class 3
Packaging group III
Label 3, 8
UN/NA number UN2924
Technical name Flammable liquid, corrosive, n.o.s.
Danger releasing substance ETHYLBENZENE
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL
Marine transport IMDG
Class 3
Subsidiary-hazard 8
Packaging group III
UN number 2924
Proper shipping name Flammable liquid, corrosive, n.o.s.
Danger releasing substance ETHYLBENZENE
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL
EmS F-E,S-C
Label 3+8
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Material Safety Data Sheet
Trade name: ALEXSEAL-Accelerator Finish Primer 442 A4429
Status: 10/10/2007
Product no.: 9071700000000 Version: 1.0.1 / USA
Air transport ICAO/IATA
Class 3
Subsidiary-hazard 8
Packaging group III
UN number 2924
Proper shipping name Flammable liquid, corrosive, n.o.s.
Danger releasing substance ETHYLBENZENE
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL
Label 3+8
15.) Regulatory information
Regulations
US Federal Regulations
TSCA (Toxic Substances Control Act)
All of the components of this product are either listed on the TSCA Inventory or are not subject to the
notification requirements (exempt).
Clean Water Act (CWA):
Following ingredients are listed:
CAS-No. 1330-20-7; 100-41-4
Clean Air Act:
None of the ingredients is listed.
OSHA: Hazardous by definition of Hazard Communication Standard ( 29 CFR 1910.1200)
Following ingredients are Hazardous by definition of Hazard Communication Standard:
CAS-No. 90-72-2; 1330-20-7; 100-41-4
SARA Section 302 (RQ):
None of the ingredients is listed.
SARA HAZARD CATEGORY (Section 311/312)
Fire, Health Hazards.
SARA Section 313 INFORMATION:
Following ingredients are listed:
CAS-No. 1330-20-7; 100-41-4
HAPS (Hazardous Air Pollutants):
Following ingredients are listed:
CAS-No. 1330-20-7 65%; 100-41-4 21%
State Regulations
California Proposition 65.
WARNING: Following ingredients are known to cause cancer or reproductive toxicity:
CAS-No. 100-41-4
Pennsylvania HAZARDOUS SUBSTANCE LIST
Following ingredients are listed:
CAS-No. 1330-20-7; 100-41-4
New Jersey Worker and Community Right to Know Act.
Following ingredients are listed:
CAS-No. 1330-20-7; 100-41-4
Other international listings
IARC
Following ingredients are listed in Group 2B:
CAS-No. 100-41-4
Volatile organic compounds (VOC)
pound/gallon 6.3
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Material Safety Data Sheet
Trade name: ALEXSEAL-Accelerator Finish Primer 442 A4429
Status: 10/10/2007
Product no.: 9071700000000 Version: 1.0.1 / USA
16.) Other information
HMIS Classification
Health 3
Flammability : 1
Reactivity 0
PPE E
NFPA Rating
Health 3
Fire Hazard 1
Reactivity 0
Other information
Abbreviations:
ACGIH American Conference of Governmental Hygienics
CAS Chemical Abstracts Service
HAPS Hazardous Air Pollutants
HMIS Hazardous Material Identifikation System
IARC International Agency for Research on Cancer
IDLH Immediate Dangerous to Life and Health
LEL Lower Explosion Limit
NTP National Toxicology Program
OEL Occupational Exposure Limit
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
PPE Personal Protection Equipment
SARA Superfund Amendments and Reauthorization Act
STEL Short-Term Exposure Level (15 minutes)
TWA Time-Weighted Average (8 hours)
UEL Upper Explosion Limit
VOC Volatile Organic Compounds
WEEL Workplace Environmental Exposure Level
Department issuing safety data sheet
UMCO Umwelt Consult GmbH
Georg-Wilhelm-Str. 183 b, D-21107 Hamburg
Tel.: +49 40 / 41 92 13 00 Fax: +49 40 / 41 92 13 57 e-mail: umco@umco.de
This information is based on our present state of knowledge. However, it should not constitute a
guarantee for any specific product properties and shall not establish a legally valid relationship.
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