MICROFAB PB-300 MAKE-UP (FILE #050622)
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MATERIAL SAFETY DATA SHEET
MSDS NUMBER: AS24
MSDS DATE: 08/10/98
SPSDS DATE: 09/26/95
STILL CURRENT: 11/00
1 PRODUCT AND COMPANY INFORMATION
PRODUCT NAME: MICROFAB PB-300 MAKE-UP
HMIS HAZARD RATING: HEALTH: 3 FIRE: 0 REACTIVITY: 0
COMPANY IDENTIFICATION
ENTHONE-OMI INC.
P.O. Box 1900
New Haven CT 06508
CONTACT REGULATORY AFFAIRS
TELEPHONE/FAX: (203)934-8611 / (203)799-8179
EMERGENCY CHEMTREC: (800)424-9300
PREPARER: Deborah Friday / Regulatory Specialist
MICROFAB is a registered trademark of Enthone-OMI Inc.
2 INGREDIENT AND HAZARD INFORMATION
INGREDIENT NAME CAS NUMBER PERCENT TSCA
WATER 7732-18-5 < 85.0 Y
METHANESULFONIC ACID 75-75-2 < 15.0 Y
LEAD METHANE SULFONATE 17570-76-2 < 5.0 Y
TIN METHANE SULFONATE 53408-94-9 < 1.0 Y
All ingredients comply with applicable rules or orders
under TSCA. Weight percents listed above are within 5%
of the actual value.
CARCINOGEN:
Lead has been indicated in renal tumor production in
rodent studies. Human studies have been inconclusive.
REFERENCE:
Lead: IARC Group 2B (limited evidence in humans in
the absence of sufficient evidence in animals); NTP
2B (sufficient evidence of carcinogenicity from studies
in experimental animals)
3 HAZARDS IDENTIFICATION
INHALATION:
Mist or vapor may damage upper respiratory tract and
lung tissue which may cause chemical pneumonia depending
upon severity of exposure.
SKIN CONTACT: Can cause burns.
EYE CONTACT:
Causes severe burns with damage to eyes and possible
blindness.
INGESTION:
Can cause severe burns to mouth, esophagus and stomach.
CHRONIC:
Prolonged or repeated exposures can cause severe damage
to blood forming, nervous, urinary, and reproductive
systems in humans.
4 FIRST AID MEASURES
SKIN CONTACT:
Immediately wash contaminated skin with plenty of
water for 15 minutes. Remove contaminated clothing
and footwear. Wash clothing before reuse. Discard
footwear if it cannot be decontaminated. Seek
immediate medical attention.
EYE CONTACT:
Immediately flush eyes with plenty of water for at
least 15 minutes holding lids apart to ensure flushing
of entire surface. Washing eyes within several seconds
of exposure is essential to minimize damage. Seek
immediate medical attention.
INGESTION:
Never give anything by mouth to an unconscious person,
obtain immediate medical attention. If vomiting occurs
spontaneously, keep airway clear. If swallowed DO NOT
INDUCE VOMITING, give large amounts of water. Seek
immediate medical attention.
INHALATION:
Remove person from contaminated area. If breathing
has stopped, resuscitate and administer oxygen if
available. Seek immediate medical attention.
5 FIREFIGHTING MEASURES
FLASH POINT > 200.0 DEG.F
GCC - General Closed Cup
SPECIAL FIRE-FIGHTING PROCEDURES:
Wear self-contained breathing apparatus (SCBA) and
complete personal protective equipment when potential
for exposure to vapors or products of combustion exists.
UNUSUAL FIRE-FIGHTING HAZARDS:
Thermal decomposition may yield toxic oxides of sulfur
and carbon.
EXTINGUISHING MEDIA:
This product is not combustible. Use water fog or spray.
Use carbon dioxide. Use dry chemical. Use foam.
6 ACCIDENTAL RELEASE MEASURES
Avoid contact with skin, eyes and clothing. Wear
protective equipment(see Section VIII), including
self-contained breathing apparatus(SCBA). Do not
breathe mist or vapors. Contain spill and soak up
in suitable alkaline absorbent, such as lime or soda
ash. Shovel into plastic lined steel containers.
Dilute residual material with large amounts of water
and neutralize with dilute alkali or soda ash. Dispose
of in accordance with Local, State and Federal regulations.
7 HANDLING AND STORAGE
Store in a cool, dry place. Keep away from alkalies
and oxidizers. Loosen cover cautiously when opening.
ADDITIONAL INFORMATION:
Wash thoroughly after handling. Decontaminate clothing
before disposal.
WORK/HYGIENIC PRACTICES:
Emergency eye wash and safety shower should be available.
Wash thoroughly after handling.
8 EXPOSURE CONTROLS AND PERSONAL PROTECTION
OCCUPATIONAL EXPOSURE LIMITS
ACGIH ACGIH ACGIH OSHA OSHA
TLV TLV-C STEL STEL PEL
WATER NA NA NA NA NA
METHANESULFONIC
ACID NA NA NA NA NA
LEAD METHANE
SULFONATE 0.05mg/M3 NA NA NA 0.05mg/M3
TIN METHANE
SULFONATE 2.00mg/M3 NA NA NA 2.00mg/M3
Exposure limits for inorganic tin compounds, except tin
hydride, are as Sn. Exposure limits for lead compounds are
as Pb. See 29 CFR 1910.1025 for further information on lead
requirements.
RESPIRATOR:
Use NIOSH approved respirator when air concentration is
greater than the TLV or PEL. Use cartridge filter for acid mist.
EYE PROTECTION:
Chemical safety goggles recommended.
Face shield recommended.
PROTECTIVE CLOTHING OR EQUIPMENT:
Chemically resistant coveralls, hat, and shoes or boots.
Neoprene gloves. Natural rubber gloves.
VENTILATION: Local exhaust recommended.
9 PHYSICAL AND CHEMICAL PROPERTIES
FORM: Liquid
COLOR: Clear, Pale Yellow
ODOR: Slight Alcohol
SOLUBILITY: Complete
pH VALUE: < 1.0
BOILING POINT: 212.0 Deg.F
VAPOR PRESSURE (mmHg): Not Available
MELTING POINT: 30.0 Deg.F
EVAPORATION RATE: Non Volatile
% VOLATILE BY WEIGHT: Not Applicable
SPECIFIC GRAVITY: 1.022
10 STABILITY AND REACTIVITY
STABILITY:
Stable under normal conditions. See Incompatibility Information.
INCOMPATIBILITY (MATERIALS TO AVOID): Oxidizing agents, alkalis.
HAZARDOUS DECOMPOSITION PRODUCTS: Toxic oxides of carbon and sulfur.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
CONDITIONS TO AVOID: NA
11 TOXICOLOGICAL INFORMATION
Route Species Exposure and Dose
METHANESULFONIC ACID Oral Rat, adult LD50 200.0 mg/kg
12 ECOLOGICAL INFORMATION
Ecological information on this product is not available.
DISPOSAL CONSIDERATIONS
For waste disposal of operating solutions consult Enthone-
OMI Waste Disposal Procedures. For major spills consult
Enthone-OMI for disposal assistance. Dispose of in
accordance with Local, State, and Federal regulations.
13 TRANSPORT INFORMATION
Please contact the Regulatory Affairs Department at
(203) 799-4917 for the most current shipping information.
14 REGULATORY INFORMATION
SARA TITLE III SECTION 313:
This product contains the following toxic chemicals
subject to the reporting requirements of Section 313
of the Emergency Planning and Community Right to Know
Act of 1986 and of 40 CFR 372:
INGREDIENT NAME CAS NUMBER PERCENT
LEAD METHANE SULFONATE 17570-76-2 < 5.0
PROP 65 (CARCINOGEN)
WARNING:
This product contains a chemical known to the state of
California to cause cancer.
INGREDIENT NAME CAS NUMBER PERCENT
LEAD METHANE SULFONATE 17570-76-2 < 5.0
16 OTHER INFORMATION
This Material Safety Data Sheet may be used to comply with OSHA's
Hazard Communication Standard, 29 CFR 1910.1200. ENTHONE-OMI Inc.
furnishes the data contained herein in good faith at customer's
request without liability or legal responsibility for same whatsoever,
and no warranty or guarantee, express or implied, is made with respect
to such data; nor does ENTHONE-OMI Inc. grant permission,
recommendation, or inducement to infringe any patent whether owned by
ENTHONE-OMI Inc. or others. The data is offered solely for your
information and consideration. Since conditions of use are beyond
ENTHONE-OMI's control, user assumes all responsibility and risk.
CAS = Chemical Abstract Service
IARC = International Agency for Research on Cancer
NA = Not Applicable
NI = No Relevant Information Available
NTP = National Toxicology Program
PEL = Permissible Exposure Limit
SDT = Standard Draize Test
STEL = Short Term Exposure Limit
TLV = ACGIH Threshold Limit Value
TLV-C = ACGIH Threshold Limit Value, Ceiling
TRADE SECRET = Claimed As Allowed Under 29 CFR 1910.1200
ENTHONE-OMI Inc.
a subsidiary of ASARCO
www.ENTHONE-OMI.com
MICROFAB PB-300 MAKE-UP
MICROFAB PB - 300 MAKE-UP
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