MATERIAL SAFETY DATA SHEET
Product:
058902 EGC II MSA EluGen Methanesulfonic Acid Cartridge
DIONEX Corporation Emergency Phone: 1-800-424-9300 (CHEMTREC)
1228 Titan Way Information Phone: (408) 737-0700
P.O. Box 3603 Date Prepared: 1/16/2009
Sunnyvale, California 94088-3603
The following information is believed to be accurate and is currently the best information available to us. However, we make no
warranties, express or implied, with respect to the information supplied and we assume no liability resulting from its use.
2. HAZARDOUS IDENTIFICATION
HAZARD NFPA HMIS
Corrosive - Acid
CLASS
Corrosive
Eyes: 3 3
HEALTH
Corrosive
Skin: 0 0
FLAMMABILITY
Corrosive
Ingestion: 0 0
REACTIVITY
Corrosive NFPA SPECIAL
Inhalation:
- -
HMIS PPE
3. COMPOSITION/INFORMATION ON INGREDIENTS
053922 053922 058902 058902
HAZARDOUS
Water 2 M MSA Water 2 M MSA
COMPONENTS
80.80 19.2 80.8 19.2
PERCENT (%)
7732-18-5 75-75-2 7732-18-5 75-75-2
CAS NO.
231-791-2 200-898-6 231-791-2 200-898-6
EINECS NO.
R20/22, R34, R20/22, R34,
RISKS
R36 R36
S20, S26, S20, S26,
S36/37/39, S36/37/39,
SAFETY
S45 S45
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4. FIRST AID MEASURES
Remove contaminated clothing, wash thoroughly before reuse.
GENERAL:
Flush with water for at least 15 minutes occasionally raising upper and lower eyelids.
EYES:
Remove contaminated clothing and flush with water thoroughly
SKIN:
Move to fresh air
INHALATION:
If large amounts are swallowed, get medical help immediately. If patient is conscious, give large quantities
INGESTION:
of water
5. FIRE FIGHTING MEASURES
UNUSUAL FIRE AND
Not Applicable
EXPLOSION:
Corrosive
HAZARDS:
Carbon Dioxide, Foam, Dry Chemical
EXTINGUISHING MEDIA:
(Note: Carbon Dioxide is one of the decomposition products)
Although the product is not combustible, firefighters subject to products of combustion
SPECIAL FIRE FIGHTING
should wear full-protective clothing including self-contained breathing apparatus
PROCEDURES:
6. ACCIDENTAL RELEASE MEASURES
Ventilate area.
Wear appropriate protective clothing and eye protection.
Contain spill.
Collect or absorb with an inert material (vermiculite, dry sand, earth, etc.)
Mop up and store in a suitable waste container.
Wash contaminated areas with soap and water.
7. HANDLING AND STORAGE
Ensure good ventilation.
Have an eye wash in the immediate area in case of emergency.
Store at room temperature
Keep container tightly closed
Use good laboratory practice when working with any chemical whether it is considered hazardous or not.
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8. EXPOSURE CONTROL/PERSONAL PROTECTION
ROUTES OF ENTRY
Yes
INHALATION:
Yes
SKIN:
Yes
INGESTION:
HEALTH HAZARDS
May cause irritation of eyes and mucous membranes
ACUTE:
Unknown
CHRONIC:
VENTILATION
Good laboratory ventilation is acceptable.
LOCAL EXHAUST:
Use in hoods if possible
MECHANICAL (GENERAL):
None
SPECIAL:
None
OTHER:
PROTECTIVE CLOTHING OR EQUIPMENT
Disposable laboratory gloves are adequate
GLOVES:
Glasses or goggles.
EYE PROTECTION:
None
RESPIRATORY:
Lab coats
OTHER:
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Clear
ODOR: None
pH: < 1.0
96.106 g/mol
MOLECULAR WEIGHT:
Not Applicable
MELTING POINT:
approximately 167 degrees C
BOILING POINT:
Not Applicable
AUTOIGNITION TEMPERATURE:
Not Applicable
FLASH POINT:
Undetermined
LOWER EXPLOSION LIMIT:
Undetermined
UPPER EXPLOSION LIMIT:
Approximately 1.49 (pure MSA)
SPECIFIC GRAVITY:
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10. STABILITY & REACTIVITY
STABILITY/CONDITIONS TO AVOID: Stable
Water-reactive materials
INCOMPATIBILITY (MATERIALS TO AVOID):
Toxic oxides of sulfur
HAZARDOUS DECOMPOSITION OR
BY-PRODUCTS:
Will not occur
HAZARDOUS POLYMERIZATION:
11. TOXICOLOGY INFORMATION
PRODUCT TOXICOLOGY INFORMATION:
May cause minor soreness or redness of eyes or mucous membranes.
SYMPTOMS AND
SIGNS OF EXPOSURE:
Unknown
MEDICAL CONDITIONS
GENERALLY AGGRAVATED BY
EXPOSURE:
In case of contact, wash skin with copious amounts of water.
EMERGENCY AND FIRST AID
PROCEDURES: Flush eyes with copious amounts of water for at least 15 minutes.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen.
Submit to medical examination.
No data found
CARCINOGENICITY:
No data found
RTECS #:
No data found
ACGIH TLV TWA:
No data found
OSHA PEL:
No data found
NTP:
No data found
IARC Monographs:
HAZARDOUS COMPONENT TOXICOLOGY INFORMATION:
053922 058902 058902 058902 058902
053922 053922 053922
Hazardous
Water 2 M MSA Water 0.5 M MSA Water 2 M MSA Water 0.30 M MSA
Components: As Shipped As Shipped After Use After Use As Shipped As Shipped After Use After Use
RTECS # ZC0110000 PB2100000 ZC0110000 PB2100000 ZC0110000 PB2100000 ZC0110000 PB2100000
OSHA PEL Not Found Not Found Not Found Not Found Not Found Not Found Not Found Not Found
ACGIH TLV Not Found Not Found Not Found Not Found Not Found Not Found Not Found Not Found
TOXICITY None ORL-RAT None ORL-RAT None ORL-RAT None ORL-RAT
LDLo: 200 LDLo: 200 LDLo: 200 LDLo: 200
DATA None None None None
mg/kg mg/kg mg/kg mg/kg
IPR-RAT IPR-RAT IPR-RAT IPR-RAT
DLLo: 50 DLLo: 50 DLLo: 50 DLLo: 50
mg/kg mg/kg mg/kg mg/kg
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12. ECOLOGICAL INFORMATION
No information is found on environmental toxicity for this solution
13. DISPOSAL CONSIDERATIONS
Contact local hazardous materials or chemical waste disposal agency for regulations.
14. TRANSPORT INFORMATION
IATA CLASSIFICATION: IATA Dangerous Goods
3265
UN ID NUMBER:
Corrosive liquid, acidic, organic, n.o.s., (Methanesulfonic acid)
PROPER SHIPPING NAME:
8
CLASS OR DIVISION:
None
SUB RISK:
Corrosive
HAZARD LABEL(S):
II
PACKAGING GROUP:
Y818
LIMITED QUANTIY PKG INSTRUCTION:
1L
MAXIMUM LIMITED QUANTIY:
None
SPECIAL PROVISIONS:
8P
ERG CODE:
Shippers must be trained and certified.
TRAINING:
State and Operator Variations may exist.
VARIATIONS:
15. REGULATORY INFORMATION
R34 Causes burns
PRODUCT RISK STATEMENTS:
S1 Keep locked up
PRODUCT SAFETY STATEMENTS:
S2 Keep out of reach of children
S26 In case of contact with eyes, rinse immediately with plenty
of water and seek medical advice
S36 Wear suitable protective clothing
S45 In case of accident or if you feel unwell, seek medical
advice immediately
16. OTHER INFORMATION
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