MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2001, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: ENGINEERED ADHESIVES
TRADE NAME:
3M(TM) Super 77(TM) Spray Adhesive
ID NUMBER/U.P.C.:
62-4437-0921-7 - - - 62-4437-0922-5 00-21200-25463-5
62-4437-0925-8 00-21200-30091-2 62-4437-0926-6 - - -
62-4437-0927-4 00-21200-25463-5 62-4437-0928-2 00-21200-25463-5
62-4437-0929-0 00-21200-25463-5 62-4437-0930-8 - - -
62-4437-0931-6 - - - 62-4437-0933-2 00-21200-25463-5
62-4437-0934-0 00-21200-25463-5 62-4437-4026-1 00-21200-76098-3
62-4437-4030-3 00-21200-76098-3 62-4437-4830-6 00-21200-85853-6
62-4437-4835-5 00-21200-85853-6 62-4437-4840-5 00-21200-85853-6
62-4437-4925-4 00-21200-21210-9 62-4437-4926-2 00-21200-45160-7
62-4437-4930-4 00-21200-21210-9 62-4437-4931-2 00-21200-39245-0
62-4437-4933-8 00-21200-85846-8 62-4437-4935-3 - - -
62-4437-4936-1 00-21200-21210-8 62-4437-4937-9 00-21200-89541-8
62-4437-4938-7 00-21200-21210-9 62-4437-4939-5 00-21200-21210-9
62-4437-9999-4 - - - CS-0406-2131-3 - - -
CS-0406-6984-1 - - - CS-0406-7003-9 - - -
ISSUED: November 16, 2001
SUPERSEDES: November 13, 2001
DOCUMENT: 11-4257-9
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1. INGREDIENT C.A.S. NO. PERCENT
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NON-VOLATILE COMPONENTS - N.J. TRADE
SECRET (T.S.) REGISTRY NO. 04499600-
5776P++............................... TradeSecret 20.0 - 30.0
CYCLOHEXANE............................. 110-82-7 10.0 - 20.0
2-METHYLPENTANE......................... 107-83-5 5.0 - 15.0
ISOBUTANE............................... 75-28-5 7 - 13
PROPANE................................. 74-98-6 7 - 13
DIMETHYL ETHER.......................... 115-10-6 7 - 13
3-METHYLPENTANE......................... 96-14-0 3 - 7
2,3-DIMETHYLBUTANE...................... 79-29-8 3 - 7
2,2-DIMETHYLBUTANE...................... 75-83-2 1 - 5
HEXANE.................................. 110-54-3 .1 - 1
IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24
HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Super 77(TM) Spray Adhesive
November 16, 2001 PAGE 2
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1. INGREDIENT C.A.S. NO. PERCENT
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The components of this product are in compliance with the chemical
notification requirements of TSCA.
++ rosin, synthetic polymer, resin and antioxidant. Not hazardous
according to Canadian WHMIS criteria. Non-WHMIS controlled.
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
CYCLOHEXANE
HEXANE
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2. PHYSICAL DATA
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BOILING POINT:................. Compressed gas
VAPOR PRESSURE:................ Compressed gas
VAPOR DENSITY:................. 2.97 Air=1
EVAPORATION RATE:.............. 1.90 Ether=1
SOLUBILITY IN WATER:........... nil
SPECIFIC GRAVITY:.............. 0.697 Water=1
PERCENT VOLATILE:.............. 75 % by wt
pH:............................ ca. 6.7
VISCOSITY:..................... N/A
MELTING POINT:................. N/D
APPEARANCE AND ODOR:
liquid in aerosol, light cream colored, sweet/fruity odor.
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... -42.00 F TCC
FLAMMABLE LIMITS - LEL:........ ca. 1.5 % by vol
FLAMMABLE LIMITS - UEL:........ ca. 8.6 % by vol
AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA:
Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Super 77(TM) Spray Adhesive
November 16, 2001 PAGE 3
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3. FIRE AND EXPLOSION HAZARD DATA (continued)
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UNUSUAL FIRE AND EXPLOSION HAZARDS:
Closed containers exposed to heat from fire may build pressure and
explode. Vapors may travel long distances along the ground or floor
to an ignition source and flash back.
NFPA HAZARD CODES: HEALTH: 2 FIRE: 4 REACTIVITY: 0 AEROSOL STORAGE: 3
UNUSUAL REACTION HAZARD: none
OSHA FIRE HAZARD CLASS: Class IA Flammable Liquid
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Heat.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Toxic Vapors, Gases or
Particulates.
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Ventilate area. Extinguish all
ignition sources. Cover with absorbent material. Collect using non-
sparking tools. Place in a U.S. DOT-approved container.
RECOMMENDED DISPOSAL:
Incinerate in a permitted hazardous waste incinerator in the presence
of a combustible material. Facility must be capable of handling
aerosol cans. Dispose of empty cans in a sanitary landfill. Dispose
of waste product in a facility permitted to accept chemical waste.
RECYCLE EMPTY AEROSOL CONTAINERS WHERE AVAILABLE.
ENVIRONMENTAL DATA:
Not determined.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Super 77(TM) Spray Adhesive
November 16, 2001 PAGE 4
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5. ENVIRONMENTAL INFORMATION (continued)
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REGULATORY INFORMATION:
Volatile Organic Compounds: 75 % tested per SCAQMD method 305.
Volatile Organic Compounds: ca. 4.4 lb/gal.
VOC Less H2O & Exempt Solvents: 527 gms/liter tested per SCAQMD method
305.
Hazardous Air Pollutants: < 1 % by wt.
Hazardous Air Pollutants: 0.04 #/# solids calculated.
Since regulations vary, consult applicable regulations or authorities
before disposal. U.S. EPA Hazardous Waste Number = D001 (Ignitable)
OTHER ENVIRONMENTAL INFORMATION:
HALOGEN ANALYSIS: The dry ingredients of 3M Super 77 Spray Adhesive
were subjected to combustion in a Parr oxygen bomb. The decomposition
products were analyzed by Ion Chromotographic analysis for halogen
and sulfur content. Chlorine 0.05%; Fluorine <0.001%, Bromine
<0.001%; Sulfur <0.035%.
EPCRA HAZARD CLASS:
FIRE HAZARD: Yes PRESSURE: Yes REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
INHALATION:
If signs/symptoms occur, remove person to fresh air. If
signs/symptoms continue, call a physician.
IF SWALLOWED:
If swallowed, call a physician immediately. Only induce vomiting at
the instruction of a physician. Never give anything by mouth to an
unconscious person.
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact with vapor, spray, or mist. Wear safety glasses
with side shields.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Super 77(TM) Spray Adhesive
November 16, 2001 PAGE 5
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7. PRECAUTIONARY INFORMATION (continued)
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SKIN PROTECTION:
Avoid prolonged or repeated skin contact.
RECOMMENDED VENTILATION:
Do not use in a confined area or areas with little or no air
movement. If exhaust ventilation is not adequate, use appropriate
respiratory protection. Provide ventilation adequate to control vapor
concentrations below recommended exposure limits and/or control spray
or mist.
RESPIRATORY PROTECTION:
Avoid breathing of vapors, mists or spray. Select one of the
following NIOSH approved respirators based on airborne concentration
of contaminants and in accordance with OSHA regulations: half-mask
organic vapor respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Do not ingest.
RECOMMENDED STORAGE:
Store at temperatures below 120 degrees F (49 degrees C). Store out
of direct sunlight. Keep out of the reach of children.
FIRE AND EXPLOSION AVOIDANCE:
Aerosol container contains flammable gas under pressure. Keep away
from heat, sparks, open flame, and other sources of ignition.
Extremely flammable liquid and vapor. Do not pierce or burn
container, even after use. No smoking while handling this material.
Avoid static discharge.
HMIS HAZARD RATINGS: HEALTH: 2 FLAMMABILITY: 4 REACTIVITY: 0
PERSONAL PROTECTION: X (See precautions, section 7.)
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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NON-VOLATILE COMPONENTS - N.J.
TRADE SECRET (T.S.) REGISTRY NO.
04499600-5776P++................... NONE NONE NONE NONE
CYCLOHEXANE.......................... 300 PPM TWA ACGIH
CYCLOHEXANE.......................... 300 PPM TWA OSHA
2-METHYLPENTANE...................... 500 PPM TWA ACGIH
2-METHYLPENTANE...................... 1000 PPM STEL ACGIH
ISOBUTANE............................ NONE NONE NONE NONE
PROPANE.............................. 1000 PPM TWA OSHA
PROPANE.............................. 2500 PPM TWA ACGIH
DIMETHYL ETHER....................... 1000 PPM TWA CMRG
DIMETHYL ETHER....................... 500 PPM TWA AIHA
3-METHYLPENTANE...................... 500 PPM TWA ACGIH
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Super 77(TM) Spray Adhesive
November 16, 2001 PAGE 6
EXPOSURE LIMITS (continued)
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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3-METHYLPENTANE...................... 1000 PPM STEL ACGIH
2,3-DIMETHYLBUTANE................... 500 PPM TWA ACGIH
2,3-DIMETHYLBUTANE................... 1000 PPM STEL ACGIH
2,2-DIMETHYLBUTANE................... 500 PPM TWA ACGIH
2,2-DIMETHYLBUTANE................... 1000 PPM STEL ACGIH
HEXANE............................... 50 PPM TWA ACGIH Y
HEXANE............................... 50 PPM TWA OSHAV
OSHA VACATED PEL
HEXANE............................... 500 PPM TWA OSHA
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- AIHA: American Industrial Hygiene Assoc. Workplace Environmental
Exposure Level Guideline
- CMRG: Chemical Manufacturer Recommended Exposure Guidelines
- OSHA: Occupational Safety and Health Administration
- OSHAV: Occupational Safety and Health Administration Vacated PEL.
Vacated Permissible Exposure Limits (PEL) are enforced as
the OSHA PEL in some states. Check with your local
regulatory authority.
- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Moderate Eye Irritation: signs/symptoms can include redness, swelling,
pain, tearing, and hazy vision.
SKIN CONTACT:
Mild Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, and itching.
INHALATION:
Intentional concentration and inhalation may be harmful or fatal.
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction time,
slurred speech, giddiness and unconsciousness.
Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Super 77(TM) Spray Adhesive
November 16, 2001 PAGE 7
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8. HEALTH HAZARD DATA (continued)
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WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Peripheral Neuropathy: signs/symptoms can include tingling of
extremities, incoordination, numbness, weakness and tremors.
Prolonged or repeated exposure may cause:
Kidney Effects: signs/symptoms can include reduced urine volume,
blood in urine and back pain.
Liver Effects: signs/symptoms can include yellow skin(jaundice)
and tenderness of upper abdomen.
IF SWALLOWED:
Ingestion is not a likely route of exposure to this product.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can
include pain, vomiting, abdominal tenderness, nausea, blood in
vomitus, and blood in feces.
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SECTION CHANGE DATES
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HEALTH HAZARD DATA SECTION CHANGED SINCE November 13, 2001 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M(TM) Super 77(TM) Spray Adhesive
November 16, 2001 PAGE 8
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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