HIL01062
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Material Safety Data Sheet
HEALTH 1 0
REACTIVITY
PERSONAL PROTECTION
FLAMMABILITY 2 None
Note: Blank spaces are not permitted. If any item is not applicable, or no
Identity: HAND SANITIZER
information is available, the space must be marked to indicate that.
Formula: B909
Part numbers: 90901, 90910, 90956, 90985, 90991
SECTION 1: Company Identification
DISTRIBUTED BY: DATE:
HILLYARD INDUSTRIES, INC. September 6, 2006
Address (Number, Street, City, State, and ZIP Code) Emergency Telephone Number
302 North Fourth Street (P.O. BOX 909) 1-800-424-9300
Telephone Number for Information
St. Joseph, MO 64502 1-800-233-1321 ext. 8285
Signature of Preparer (Optional)
www.hillyard.com Regulatory Dept.
SECTION 2: Ingredients/Identity Information
Components (Chemical Identity, Other Limits
Common Name(s)) CAS No. OSHA PEL ACGIH-TLV Recommended % (Opt.)
Water 7732-18-5 None None None 60 ?100%
Ethyl Alcohol 64-17-5 1000 ppm 1000 ppm 3300 ppm (IDLH) 10 ?30%
Any substance listed as hazardous by the States of California, Florida, Illinois, Michigan, New Jersey, Ohio, Pennsylvania or
Texas is described above if known present in regulated concentrations.
SECTION 3: Hazards Identification
Route(s) of Entry Eyes? Inhalation? Skin? Ingestion?
Yes Yes No Yes
Acute Health Hazards - Warning. Causes Eye Irritation. May be harmful if swallowed. Deliberate concentration and inhalation of vapors may
cause central nervous system effects. Follow good chemical hygiene practices to avoid these hazards.
Chronic Health Hazards - Prolonged skin exposure may lead to dermatitis.
Carcinogenicity:
Chemical: OSHA: NTP: IARC:
None No No No
Signs and Symptoms of Exposure - Redness, tearing or burning in eyes. Redness, burning, drying or cracking of skin. Swallowing may cause
nausea, diarrhea, doziness', dizziness, fatigue, or loss of coordination.
Medical Conditions Generally Aggravated by Exposure - Pre-existing skin or gastrointestinal disorders may be adversely affected. Follow good
chemical hygiene practices to avoid these hazards.
SECTION 4: Emergency and First Aid Procedures:
Eyes - Flush with plenty of water for at least 15 minutes lifting eyelids to insure complete removal. See a physician immediately.
Ingestion - Not a likely exposure route. If a large quantity of liquid is swallowed call a physician or poison control center immediately.
Inhalation - Unlikely route of exposure as liquid is impregnated on a towel. If overexposed move into fresh air. If breathing has stopped, qualified
personnel should administer artificial respiration and seek medical attention.
Skin - None usually required. If irritation persists seek medical attention.
SECTION 5: Fire Fighting Measures
Flash Point, Concentrate (Method Used) Flammable Limits LEL UEL
107o F (PMCC) No Data No Data No Data
Extinguishing Media - Use carbon dioxide, dry chemical, foam, or fog. Do not use water as it may froth and cause fire to spread.
Formula: B909
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Special Fire Fighting Procedures - Keep containers cool and vapors down with water spray. Prevent runoff from entering sewers and public
waterways. Wear SCBA in chemical fires.
Hazardous Products of Combustion-Carbon dioxide, carbon monoxide, formaldehyde, nitrous oxide, ammoniacal vapors, smoke, soot and
various organic oxidation by-products.
Unusual Fire and Explosion Hazards - Combustible liquid on a polypropylene towel.
SECTION 6: Accidental Release Measures
Small Spill ?Caution, slip hazard. Wipe up small releases with a dry absorbent cloth or other absorbent material.
Large Spill ?Not likely due to type of product.
SECTION 7: Handling and Storage
Handling - Do not get into eyes. Do not swallow. Avoid prolonged skin contact. For external use only. Not for use around the mouth or eyes for
an extended period of time. Use from original container only. Do not smoke while using. Do not contaminate water, food or feed by use or
storage. Follow label directions carefully.
Storage ?Store in a cool well ventilated area. Keep away from heat sources. Keep out of reach of children. Keep from freezing. Keep container
tightly sealed when not in use.
SECTION 8: Exposure Controls / Personal Protection
Eye Protection ?None necessary. Do not allow towel to directly contact eyes.
Skin Protection ?None necessary. Product is designed for direct skin use.
Respiratory Protections ?Not usually necessary. Use with adequate ventilation. Use NIOSH/MSHA approved respirator if PELs or TLVs are
exceeded.
Engineering Controls ?Ventilation not usually necessary but should be provided in the event of overexposure.
SECTION 9: Physical and Chemical Properties
Colorless liquid with an alcohol ?floral scent saturated on a towel
Appearance and Odor:
6.0 + 0.5
PH
Specific Gravity (70oF) 0.970
212o F
Boiling Point:
N/A
Melting Point:
N/A
Evaporation Rate (Butyl Acetate = 1)
Vapor Pressure (mm-Hg @ 70oF) N/A
Greater than 1
Vapor Density (AIR = 1)
Complete
Solubility in Water
179 grams per liter or 18.5% by weight VOCs.
Volatile Organic Compounds (VOCs)
SECTION 10: Stability and Reactivity
Hazardous Polymerization ?This product will not undergo hazardous polymerization.
Hazardous Decomposition or Byproducts ?Carbon dioxide, carbon monoxide, formaldehyde, nitrous oxide, ammoniacal vapors, smoke, soot
and various organic oxidation by-products.
Chemical Stability - Stable
Incompatibility (Materials to Avoid) - Strong oxidizing agents such as acetyl chloride, nitric acid, and hydrogen peroxide.
SECTION 11: Toxicological Information
Ethyl Alcohol: Inhalation LC50: 20,000 ppm/10H, rat
Oral LD50: 7060 mg/kg, rat
Eye Irritation: 50 mg/24 H Severe, rabbit
SECTION 12: Ecological Information
Ethyl Alcohol: Soil: readily biodegrades, quickly evaporates, leaches into groundwater
Formula: B909
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Water: readily biodegrades, evaporates to moderate extent, Does not bioaccumulate
Air: readily degrades by reaction with photochemically produced hydroxyl radicals, readily removed by dry and
wet deposition, has a half-life between 1 and 10 days.
SECTION 13: Disposal Consideration
Disposal Method - Dispose of in accordance with all applicable local, state, and federal regulations.
RCRA Waste Information ?If this product becomes a waste, the liquid would be considered a flammable liquid (D001) as defined by RCRA (40
CFR 261). However the waste should be properly characterized to evaluate whether its composition has been modified prior to disposal.
SECTION 14: Transport Information
DOT Information ?49 CFR 172.101
Proper Shipping Description: Not Regulated
Hazard Class: None
Identification Number: None
Packing Group: None
Water Transportation:
Proper Shipping Description: Flammable liquid, N.O.S., (Ethanol)
Hazard Class: 3
Identification Number: UN 1993
Packing Group: III
Air Transportation:
Proper Shipping Description: Flammable liquid, N.O.S., (Ethanol)
Hazard Class: 3
Identification Number: UN 1993
Packing Group: III
Marine Pollutants: None
SECTION 15: Regulatory Information
US Federal Regulations:
TSCA (Toxic Substances Control Act) Status
All ingredients are on the TSCA inventory or are not required to be listed on the TSCA inventory.
CERCLA RQ ?40 CFR 302.4 (a)
None Listed
SARA 313 Components ?40 CFR 372.65
tert-Butyl alcohol ?0.02% (CAS # 75-65-0)
State and Local Regulations:
California Proposition 65
None
Section 16: Additional Information
Formula: B909
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WARNING! The use of this product is beyond the control of the manufacturer; therefore, no guarantee, expressed or implied, is made as to the effects of such or
the results to be obtained if not used in accordance with directions or established safe practice. The user must assume all responsibility, including injury or damage,
resulting from its misuse as such, or in combination with other materials. The manufacturer warrants only that this product meets the manufacturer's specifications for
such product. THIS WARRANTY IS IN LIEU OF ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, AS TO DESCRIPTION, QUALITY,
MERCHANTABILITY. FITNESS FOR ANY PARTICULAR PURPOSE, PRODUCTIVENESS, OR ANY OTHER MATTER, OF THIS PRODUCT. THE
MANUFACTURER SHALL BE IN NO WAY RESPONSIBLE FOR THE IMPROPER USE OF THIS PRODUCT. The sole and exclusive remedy against the
manufacturer for breach of warranty shall be reimbursement of the purchase price of the product in the event that a defective condition of the product shall be found to
exist. NO OTHER REMEDY (INCLUDING BUT NOT LIMITED TO INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR INJURY TO PERSON OR
PROPERTY OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE.
Formula: B909
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