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Material Safety Data Sheet
According to 91/155 EEC
Printing date 13.09.2006 Reviewed on 13.09.2006
1 Identification of substance:
?Product details:
?Trade name: XP BOND
?Application of the substance / the preparation Adhesive
?Manufacturer/Supplier:
DENTSPLY DeTrey GmbH
De-Trey-Str. 1
D-78467 Konstanz
GERMANY
Tel.: +49-7531-583-0
Fax: +49-7531-583-104
?Further information obtainable from:
- Departement Analytical Research / Research & Development for technical information
- Departement Marketing & Sales for distribution of the safety data sheets
?Information in case of emergency: +49-7531-583-0
2 Composition/Data on components:
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
methacrylate with the exception of thosespecified elsewhere in this Annex 25-50%
Xi; R 36/37/38
CAS: 75-65-0 2-methylpropan-2-ol 10-25%
EINECS: 200-889-7 Xn, F; R 11-20
acrylates with the exception of those specified elsewhere in this Annex 10-25%
Xi, N; R 36/37/38-51/53
?Additional information For the wording of the listed risk phrases refer to section 16.
3 Hazard identification
?Hazard description:
Xi Irritant
F Highly flammable
?Information concerning to particular hazards to man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Classification system
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
4 First aid measures
?After inhalation Supply fresh air; consult doctor in case of complaints.
?After skin contact Immediately wash with water and soap and rinse thoroughly.
?After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing If symptoms persist consult doctor.
GB
(Contd. on page 2)
DR
Page 2/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 13.09.2006 Reviewed on 13.09.2006
Trade name: XP BOND
(Contd. of page 1)
5 Fire fighting measures
?Suitable extinguishing agents CO2, sand, extinguishing powder. Do not use water.
?For safety reasons unsuitable extinguishing agents
Water.
Water with full jet.
?Protective equipment: Wear self-contained respiratory protective device
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection:
Prevent seepage into sewage system, workpits and cellars.
Inform respective authorities in case of seepage into water course or sewage system.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7 Handling and storage
?Handling Product is intended for dental use only.
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Observe normal care for working with chemicals.
?Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
?Storage
?Requirements to be met by storerooms and receptacles:
Store only in the original receptacle.
Store in a cool location.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
8 Exposure controls and personal protection gear
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
75-65-0 2-methylpropan-2-ol
OES Short-term value: 462 mg/m? 150 ppm
Long-term value: 308 mg/m? 100 ppm
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment
?General protective and hygienic measures
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
(Contd. on page 3)
GB
DR
Page 3/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 13.09.2006 Reviewed on 13.09.2006
Trade name: XP BOND
(Contd. of page 2)
?Respiratory protection: Not necessary if room is well-ventilated.
?Protection of hands:
Protective gloves.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection: Safety glasses
?Body protection: Protective work clothing.
9 Physical and chemical properties:
?General Information
Fluid
Form:
Light yellow
Colour:
Characteristic
Odour:
?Change in condition
Melting point/Melting range: undetermined
Boiling point/Boiling range: undetermined
19癈
?Flash point:
Product is not selfigniting.
?Self-igniting:
Product is not explosive. However, formation of explosive air/vapour
?Danger of explosion:
mixtures are possible.
Not determined
?Density:
?Solubility in / Miscibility with
Partly miscible
Water:
2.5
?pH-value at 20癈:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known
?Dangerous decomposition products: No dangerous decomposition products known
GB
(Contd. on page 4)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 13.09.2006 Reviewed on 13.09.2006
Trade name: XP BOND
(Contd. of page 3)
11 Toxicological information
?Acute toxicity:
?Primary irritant effect:
?on the skin:
Irritant to skin and mucous membranes.
The unpolymerized product may be irritant to the skin for succeptible persons.
?on the eye: Irritating effect.
?Sensitization:
Repeated or prolonged contact with the not polymerized product may cause sensitization for acrylates /
methacrylates.
?Additional toxicological information:
Irritant
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version.
12 Ecological information:
?Ecotoxical effects:
?Remark: Harmful to fish
?General notes: Harmful to aquatic organisms
13 Disposal considerations
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage
system.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?Land transport ADR/RID (cross-border)
3 (F1) Flammable liquids.
?ADR/RID class:
?Danger code (Kemler): 33
1993
?UN-Number:
II
?Packaging group:
3
?Hazard label
?Description of goods: 1993 FLAMMABLE LIQUID, N.O.S., (2-Methylpropanol-2, mixture) (vapor
pressure at 50癈 at most 110 kPa)
?Maritime transport IMDG:
3
?IMDG Class:
1993
?UN Number:
(Contd. on page 5)
GB
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 13.09.2006 Reviewed on 13.09.2006
Trade name: XP BOND
(Contd. of page 4)
3
?Label
II
?Packaging group:
F-E,S-E
?EMS Number:
No
?Marine pollutant:
?Proper shipping name: FLAMMABLE LIQUID, N.O.S., (2-Methylpropanol-2, mixture)
?Air transport ICAO-TI and IATA-DGR:
3
?ICAO/IATA Class:
1993
?UN/ID Number:
3
?Label
II
?Packaging group:
?Proper shipping name: FLAMMABLE LIQUID, N.O.S., (2-Methylpropanol-2, mixture)
15 Regulations
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials
?Code letter and hazard designation of product:
Xi Irritant
F Highly flammable
?Risk phrases:
11 Highly flammable.
36/37/38 Irritating to eyes, respiratory system and skin.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Safety phrases:
9 Keep container in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
28 After contact with skin, wash immediately with plenty of water.
33 Take precautionary measures against static discharges.
16 Other information:
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
The attached safety data sheet covers the dangers and measures to be taken when large quantities of material
are released, for example due to accidents during transport or storage by the dealer.
For quantities of material typically used in clinical practice, information necessary for safe use and storage
of the product is given in the DFU.
?Relevant R-phrases
11 Highly flammable.
20 Harmful by inhalation.
36/37/38 Irritating to eyes, respiratory system and skin.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Department issuing MSDS: Analytical Research
GB
DR
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