M102-0413 PRE-CATALYZED SANDING SEALER
MATERIAL SAFETY DATA SHEET
RPM Wood Finishes Group
3194 Hickory Boulevard
Hudson, North Carolina 28638
828-728-8266
EMERGENCY PHONE (CHEM TREC): . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-800-424-9300
FOR ALL INTERNATIONAL TRANSPORTATION ACCIDENTS. . . . . . . . . . . . . . . . .1-703-527-3887 (collect)
Health: 1 Flammability: 4 Reactivity 0
PRODUCT NAME: M102-0413 PRE-CATALYZED SANDING SEALER
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
REVISION DATE: 24/01/06
SUPERCEDES: 06/03/03
MSDS NO. M102-0413
OSHA HAZ. CLASS: Eye irritant. Neurotoxin - may cause nervous system damage.
Mucous membrane (respiratory tract) irritant.
II. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL NAME % CAS # PEL
acetone 21-30 67-64-1 1000 ppm TWA; 2400 mg/m3 TWA
propane 11-20 74-98-6 1000 ppm TWA; 1800 mg/m3 TWA
isopropanol 11-20 67-63-0 400 ppm TWA; 980 mg/m3 TWA
t-butyl acetate 1-10 540-88-5 ACGIH 1987 TWA 200ppm 8 hrs Skin-No
OSHA 1971 TWA 200ppm 8 hrs Skin-No
n-butyl acetate 1-10 123-86-4 150 ppm TWA; 710 mg/m3 TWA
isobutane 1-10 75-28-5 No PEL established
butanol 1-10 78-92-2 150 ppm TWA; 450 mg/m3 TWA
PM acetate 1-10 108-65-6 No PEL established
Methanol 1-10 67-56-1 200 ppm TWA; 260 mg/m3 TWA
Cellulose Nitrate, Cellulose Ester 1-10 9004-70-0 No PEL established
toluene 1-10 108-88-3 200 ppm TWA; C 300 ppm
diisononyl phthalate 1-10 68515-48-0 No PEL established
isobutanol 1-10 78-83-1 100 ppm TWA; 300 mg/m3 TWA
m-xylene <1 108-38-3 No PEL established
o-xylene <1 95-47-6 No PEL established
ethylbenzene <1 100-41-4 100 ppm TWA; 435 mg/m3 TWA
p-xylene <1 106-42-3 No PEL established
formaldehyde <1 50-00-0 0.75 ppm TWA
t-butanol <1 75-65-0 ACGIH 1995 TWA100ppm 8 hrs Skin-No
OSHA 1989 TWA100ppm 8 hrs Skin-No
OSHA 1989 STEL 150 ppm 15 min Skin-No
M102-0413 PRE-CATALYZED SANDING SEALER Page 1 of 7
III. HAZARDS IDENTIFICATION
Absorption., Inhalation, ingestion, skin, eyes.
Routes of Entry:
Skin disease including eczema and sensitization. Respiratory disease including
Medical Conditions Aggravated:
asthma and bronchitis. Eye disease. Digestive tract disease. Kidney disease. Liver
disease.
Immediate (Acute) Health Effects
Irritation may be delayed for several hours. Can cause severe respiratory irritation,
Inhalation:
dizziness, weakness, fatigue, nausea, headache and possible unconsciousness.
Substance causes moderate skin irritation. Continued or prolonged contact may
Skin Contact:
irritate the skin and cause a skin rash (dermatitis). Moderately irritating to the skin.
Can cause minor skin irritation, defatting, and dermatitis.
Irritating but will not permanently injure eye tissue. Contact with the eyes may cause
Eye Contact:
moderate to severe eye injury. Eye contact may result in tearing and reddening, but
not likely to permanently injure eye tissue. Temporary vision impairment (cloudy or
blurred vision) is possible. Can cause moderate irritation, tearing and reddening, but
not likely to permanently injure eye tissue.
Contains methanol. Upon prolonged or repeated exposure, may cause deterioration of
Skin Absorption:
the optic nerve if large quantities are absorbed through the skin. Repeated absorption
of large quantities may lead to blindness. Can be absorbed through the skin but
exposure must be extensive before adverse health effects occur. Component(s) may
be absorbed through intact skin, but it is unlikely that harmful affects will occur
unless contact is prolonged, repeated, and extensive. Toxic and may be harmful if
absorbed through the skin; may produce target organ damage. Minimal hazard in
normal industrial use. May cause gastrointestinal discomfort.
May cause nausea. Aspiration of material into the lungs can cause chemical
Ingestion:
pneumonitis which can be fatal. Minimal toxicity Irritating to mouth, throat, and
stomach. Can cause abdominal discomfort, nausea, vomiting and diarrhea.
Target Organ Acute Toxicity:
Acetone respiratory system, skin, eyes, CNS
Propane CNS
Isopropyl alcohol eyes, skin, respiratory system
tert-Butyl acetate respiratory system, eyes, skin, CNS
n-Butyl acetate eyes, skin, respiratory system, CNS
Isobutane CNS
n-Butyl alcohol eyes, CNS, skin, respiratory system
Methyl alcohol skin, eyes, CNS, GI tract, respiratory system
Toluene CNS, liver, kidneys, skin, eyes, respiratory system
Isobutyl alcohol eyes, skin, respiratory system, CNS
m-Xylene CNS, eyes, blood, liver, kidneys, skin, GI tract, respiratory system
o-Xylene CNS, eyes, blood, liver, kidneys, skin, GI tract, respiratory system
Ethyl benzene eyes, respiratory system, skin, CNS
p-Xylene CNS, eyes, blood, liver, kidneys, skin, GI tract, respiratory system
Formaldehyde (and formalin) eyes, skin, respiratory system, nasal cancer
tert-Butyl alcohol eyes, skin, respiratory system, CNS
M102-0413 PRE-CATALYZED SANDING SEALER Page 2 of 7
Long-Term (Chronic) Health Effects:
ACGIH. IARC. NIOSH. NTP. OSHA. Contains a substance that is a probable cancer
Carcinogenicity:
hazard based on human studies.
Possible reproductive hazard. A component in this product has been shown to cause
Reproductive and Developmental
Toxicity: birth defects and reproductive disorders in laboratory animals at doses that could be
encountered in the workplace.
No data available to indicate product or any components present at greater than 0.1%
Mutagenicity:
is mutagenic or genotoxic.
Upon prolonged and/or repeated exposure, can cause severe respiratory irritation,
Inhalation:
dizziness, weakness, fatigue, nausea, headache and possible unconsciousness.
Prolonged or repeated contact may cause irritation. May cause lingering affects but
Skin Contact:
not likely to result in permanent damage if the exposure is eliminated. Upon
prolonged or repeated contact, can cause moderate skin irritation, defatting, and
dermatitis. Not likely to cause permanent damage.
Upon prolonged or repeated contact, can cause severe irritation. Eye contact may
Eye Contact:
result in corneal injury. Symptoms may include discomfort or pain, excess blinking
and tear production, with marked redness and swelling of the conjunctiva. Temporary
vision impairment (cloudy or blurred vision) is possible.
Upon prolonged or repeated exposure, toxic if absorbed through the skin. Likely to
Skin Absorption:
cause systemic damage.
Respiratory Tract. Skin. Eyes. Nervous System. Skin. Respiratory Tract. Nervous
Target Organ Chronic Toxicity:
System. Eyes. Digestive Tract. Kidneys. Liver. Blood.
No additional health information available.
Supplemental Health Hazard
Information:
IV. FIRST AID
Remove to fresh air. If breathing is difficult, have a trained individual administer
Inhalation:
oxygen. If not breathing, give artificial respiration and have a trained individual
administer oxygen. Get medical attention immediately.
Flush immediately under running water for 15 minutes. If redness or irritation occurs,
Eyes:
seek medical attention. Immediately flush eyes with plenty of water for at least 20
minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to
the uncontaminated eye. Get immediate medical attention and monitor the eye daily as
advised by your physician.
Wash with soap and water. Remove contaminated clothing and launder. Get medical
Skin Contact:
attention if irritation develops or persists.
Drink 3-4 glasses of water and DO NOT induce vomiting. Do not give anything by
Ingestion:
mouth to an unconscious or convulsing person. Get medical attention. No hazard in
normal industrial use. Do not induce vomiting. Seek medical attention if symptoms
develop. Provide medical care provider with this MSDS.
Treat according to symptoms present.
Notes to MD:
M102-0413 PRE-CATALYZED SANDING SEALER Page 3 of 7
V. FIRE FIGHTING MEASURES
Flammability Summary:
o
-144 (CALC.) F
Flash Point:
12.8 @ 77?F
Upper Flammable/Explosive
Limit, % in air:
1.3 @ 77?F
Lower Flammable/Explosive
Limit, % in air:
Flammable Liquid. Can release vapors that form explosive mixtures at temperatures at
Fire Hazards:
or above the flash point. If product is heated above its flash point it will release
flammable vapors which can burn in the open or be explosive in confined spaces if
exposed to ignition source. Keep unnecessary people away. Isolate hazard area and
deny entry. Stay upwind, out of low areas, and ventialte closed spaces before entering.
Vapors may be ignited by heat, sparks, flames or other sources of ignition at or above
the low flash point giving rise to a Class B fire. Vapors are heavier than air and may
travel to a source of ignition and flash back.
Use alcohol resistant spray, Carbon Dioxide, water spray or dry chemical to
Extinguishing Media:
extinguish a fire involving this chemical. Flammable component(s) of this material
may be lighter than water and burn while floating on the surface. Water fog, foam,
CO2, or dry chemical. Use alcohol resistant foam, carbon dioxide, or dry chemical
extinguishing agents. Water spray or fog may also be effective for extinguishing if
swept across the base of the fire. Water can also be used to absorb heat and keep
exposed material from being damaged by fire.
Flammable component(s) of this material may be lighter than water and burn while
Fire Fighting Instructions:
floating on the surface. Use methods for the surrounding fire. Water spray may be
used to cool containers however be careful not to spread the fire with the water used
for cooling purposes.Do not enter fire area without proper protection including self-
contained toxic breathing apparatus and full protective equipment. Fight fire from a
safe distance and a protected location due to the potential of hazardous vapors and
decomposition products. Flammable component(s) of this material may be lighter than
water and burn while floating on the surface. Use water spray/fog for cooling.
Hazardous Combustion Products: Carbon dioxide, Carbon monoxide Hydrogen cyanide Nitrogen containing gases
Toxic gases
VI. ACCIDENTAL RELEASE MEASURES
No health affects expected from the clean-up of this material if contact can be
Health Consideration for Spill
Response: avoided. Follow personal protective equipment recommendations found in Section
VIII of this MSDS
No special spill clean-up considerations. Collect and discard in regular trash.
Spill Mitigation Procedures
General Methods:
VII. HANDLING AND STORAGE
Use spark-proof tools and explosion-proof equipment. Use bonding and grounding
Handling:
when transferring quantities of material. Wash thoroughly after handling. Avoid
contact with material. Ground and bond containers when transferring material. Keep
in air-tight containers- material is hygroscopic. Remove contaminated clothing and
wash before reuse. "Empty" containers retain product residue (liquid and/or vapor)
and can be dangerous. Mildly irritating material. Avoid unnecessary exposure.
M102-0413 PRE-CATALYZED SANDING SEALER Page 4 of 7
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Vent
Storage:
container carefully, periodically, as needed to relieve pressure. Store in a cool place in
original container and protect from sunlight. Do not store in direct sunlight. Store in a
cool dry ventilated location. Isolate from incompatible materials and conditions. Keep
container(s) closed.
VIII. ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT
Ventilation should effectively remove and prevent buildup of any vapor/mist/fume
Engineering Controls:
generated from the handling of this product. General room or local exhaust
ventilation is usually required to meet employee exposure standards and/or to ensure
employees are not overexposed to airborne material as described in Section III.
Explosion proof exhaust ventilation should be used. Local exhaust ventilation or
other engineering controls are normally required when handling or using this product
to avoid overexposure.
Protective Equipment
Respirators should be selected by and used under the direction of a trained health and
Respiratory Tract:
safety professional following requirements found in OSHA's respirator standard (29
CFR 1910.134) and ANSI's standard for respiratory protection (Z88.2-1992). A
written respiratory protection program, including provisions for medical certification,
training, fit testing, exposure assessments, maintenance, inspection, cleaning, and
convenient, sanitary storage should be implemented.
Wear chemically resistant safety glasses with side shields when handling this product.
Eyes:
Wear additional eye protection such as chemical splash goggles and/or face shield
when the possibility exists for eye contact with splashing or spraying liquid, or
airborne material. Do not wear contact lenses. Have an eye wash station available.
Avoid skin contact by wearing chemically resistant gloves, an apron and other
Skin:
protective equipment depending upon conditions of use. Inspect gloves for chemical
break-through and replace at regular intervals. Clean protective equipment regularly.
Wash hands and other exposed areas with mild soap and water before eating,
drinking, and when leaving work.
IX. PHYSICAL DATA
CLOUDY LIQUID
Physical State:
STRONG SOLVENT
Odor:
6.0093
Solids Vol %:
10.1456
Solids Wt %:
3.9162
Material VOC lbs/gal:
470.2969
Material VOC gms/l:
5.3025
Coatings VOC lbs/gal:
636.789
Coatings VOC gms/l:
6.333
Weight per gallon lbs:
VOC data per US EPA guidelines. State and local variations may apply.
X. STABILITY AND REACTIVITY
Stable. Normally stable. Keep away from heat, sparks and flame.
Stability Information:
Avoid: heat, sparks, flame and oxidizing agents. None known.
Conditions to Avoid:
M102-0413 PRE-CATALYZED SANDING SEALER Page 5 of 7
Strong oxidizing agents. Strong acids. Strong alkalies. Acids. Acetic anhydride.
Chemical Incompatibility:
Peroxides. Oxidizing materials. Amines.
Hazardous Polymerization will not occur.
Hazardous Polymerization:
XI. TOXICOLOGICAL INFORMATION
Chemical Name CAS Number LD50/LC50
Acetone 67-64-1 Inhalation LC50 Rat : 50100 mg/m3/8H; Inhalation LC50 Mouse : 44
gm/m3/4H; Oral LD50 Rat : 5800 mg/kg; Oral LD50 Mouse : 3 gm/kg
Isopropyl alcohol 67-63-0 Inhalation LC50 Rat : 16000 ppm/8H; Oral LD50 Rat : 5045 mg/kg; Oral
LD50 Mouse : 3600 mg/kg; Dermal LD50 Rabbit : 12800 mg/kg
Acetic acid, butyl ester 123-86-4 Inhalation LC50 Rat : 2000 ppm/4H; Inhalation LC50 Mouse : 6 gm/m3/2H;
Oral LD50 Rat : 10768 mg/kg; Oral LD50 Mouse : 6 gm/kg; Dermal LD50
Rabbit : >17600 mg/kg
Propane, 2-methyl- 75-28-5 Inhalation LC50 Rat : 57 pph/15M
sec-Butyl alcohol 78-92-2 Inhalation LC50 Rat : 8000 ppm/4H; Oral LD50 Rat : 790 mg/kg; Oral LD50
Mouse : 2680 mg/kg; Dermal LD50 Rabbit : 3400 mg/kg
Acetic acid, 2-methoxy-1-methylethyl 108-65-6 Oral LD50 Rat : 8532 mg/kg; Dermal LD50 Rabbit : >5 gm/kg
ester
Methanol 67-56-1 Inhalation LC50 Rat : 64000 ppm/4H; Oral LD50 Rat : 5628 mg/kg; Oral
LD50 Mouse : 7300 mg/kg; Dermal LD50 Rabbit : 15800 mg/kg
Nitrocellulose 9004-70-0 Oral LD50 Rat : >5 gm/kg; Oral LD50 Mouse : >5 gm/kg
Toluene 108-88-3 Inhalation LC50 Rat : 49 gm/m3/4H; Inhalation LC50 Mouse : 400 ppm/24H;
Oral LD50 Rat : 636 mg/kg; Dermal LD50 Rabbit : 14100 uL/kg
Isobutyl alcohol 78-83-1 Oral LD50 Rat : 2460 mg/kg; Dermal LD50 Rabbit : 3400 mg/kg
m-Xylene 108-38-3 Oral LD50 Rat : 5 gm/kg; Dermal LD50 Rabbit : 14100 uL/kg
Benzene, ethyl- 100-41-4 Oral LD50 Rat : 3500 mg/kg; Dermal LD50 Rabbit : 17800 uL/kg
p-Xylene 106-42-3 Inhalation LC50 Rat : 4550 ppm/4H; Oral LD50 Rat : 5 gm/kg
Formaldehyde 50-00-0 Inhalation LC50 Rat : 203 mg/m3; Inhalation LC50 Mouse : 454 gm/m3/4H;
Oral LD50 Rat : 100 mg/kg; Oral LD50 Mouse : 42 mg/kg; Dermal LD50
Rabbit : 270 uL/kg
tert-Butyl alcohol 75-65-0 Oral LD50 Rat : 3500 mg/kg
XII. ECOLOGICAL INFORMATION
Keep out of waterways. Slight ecological hazard. In high concentrations, this product
Overview (for ingredients):
may be dangerous to plants and/or wildlife.
XIII. DISPOSAL CONSIDERATIONS
The waste may be a listed and/or characteristic hazardous waste. The waste may be a
Waste Description for Spent
Product: listed hazardous waste. Spent or discarded material is a hazardous waste.
Comply with all Local, State, Federal, and Provincial Environmental Regulations.
Disposal Methods:
Incinerate spent or discarded material a permitted hazardous waste facility. Dispose of
by incineration following Federal, State, Local, or Provincial regulations.
If discarded, this product is considered a RCRA ignitable waste, D001.
Potential EPA Waste Codes:
Components Subject to USEPA Land Disposal Restrictions:
Acetone 67-64-1 20.66 %
n-Butyl alcohol 78-92-2 5.57 %
Methanol 67-56-1 3.58 %
Toluene 108-88-3 3.34 %
Isobutyl alcohol 78-83-1 1.02 %
Ethyl benzene 100-41-4 0.3 %
XIV. TRANSPORTATION INFORMATION
Aerosols, flammable, 2.1, UN 1950
DOT
See 49CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations.
M102-0413 PRE-CATALYZED SANDING SEALER Page 6 of 7
XV. REGULATORY INFORMATION
Chemical Name Regulation CASRN %
Isopropyl alcohol SARA 313 Reportable: 67-63-0 12.26
sec-Butyl alcohol SARA 313 Reportable: 78-92-2 5.57
Methanol SARA 313 Reportable: 67-56-1 3.58
Toluene SARA 313 Reportable: 108-88-3 3.34
m-Xylene SARA 313 Reportable: 108-38-3 0.95
o-Xylene SARA 313 Reportable: 95-47-6 0.39
Ethyl benzene SARA 313 Reportable: 100-41-4 0.3
p-Xylene SARA 313 Reportable: 106-42-3 0.24
Formaldehyde SARA 313 Reportable: 50-00-0 0.05
tert-Butyl alcohol SARA 313 Reportable: 75-65-0 0.01
Phosphoric acid SARA 313 Reportable: 7664-38-2 0.00
Formaldehyde Extremely Haz. Substances: 50-00-0 0.05
TPQ = 500 pounds; RQ = 100 pounds SARA Threshold Planning Quantity: 50-00-0 0.05
(does not meet toxicity criteria but
because of high production volume and
recognized toxicity is considered a
chemical of concern)
108-88-3 3.34
Benzene, methyl- California Proposition 65 Cancer List:
100-41-4 0.3
Benzene, ethyl- California Proposition 65 Cancer List:
50-00-0 0.05
Formaldehyde (gas) California Proposition 65 Cancer List:
14808-60-7 0.00
Quartz California Proposition 65 Cancer List:
108-88-3 3.34
Toluene California Proposition 65
Developmental Toxicity:
67-64-1 20.66
acetone New Jersey Right To Know:
74-98-6 14.73
propane New Jersey Right To Know:
67-63-0 12.26
isopropanol New Jersey Right To Know:
540-88-5 7.19
t-butyl acetate New Jersey Right To Know:
123-86-4 7.19
n-butyl acetate New Jersey Right To Know:
75-28-5 6.67
Isobutane New Jersey Right To Know:
XVI. ADDITIONAL INFORMATION
IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION
Other Information:
CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE
ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY
FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND
THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A
PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES
OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA
OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS,
INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS
AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND
INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION
OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE
ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
MSDS glossary.
M102-0413 PRE-CATALYZED SANDING SEALER Page 7 of 7
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