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CAS

68553-14-0 106-88-7 106-94-5 75-65-0

File Name: 68553-14-0_106-88-7_106-94-5_75-65.asp

                                    MATERIAL SAFETY
DATA SHEET
Prepared to U.S. Standards

1. PRODUCT IDENTIFICATION

CHEMICAL NAME; CLASS: TEMPILAQ GREEN LABEL
THINNER

PRODUCT : Tempilaq Green Label Thinner

SUPPLIER/MANUFACTURER'S NAME: TEMPIL INC.
ADDRESS: 2901 HAMILTON BLVD.
SOUTH PLAINFIELD, NJ 07080

EMERGENCY PHONE: CHEMTREC: 1-800-424-9300

BUSINESS PHONE: 1-908-757-8300




2. COMPOSITION and INFORMATION ON INGREDIENTS

CHEMICAL NAME CAS # % EXPOSURE LIMITS IN AIR
Hazardous
ACGIH OSHA
TLV STEL PEL STEL IDLH OTHER
ppm ppm Ppm ppm ppm



Hydrocarbon,c8-c11 68553-14-0 15-18 NE NA NE NA NA NA

1,2 Epoxybutane 106-88-7 1-2 NE NE NE NE NE NA

n-Propyl bromide 106-94-5 75-80 NE NE NE NE NE NA

t-Butanol 75-65-0 1-5 100ppm NE 100ppm NE NE NA

NA = Not Available, NE= Not Established




TEMPIL LAQ GREEN LABEL THINNER MSDS EFFECTIVE DATE: MAY 7, 2001
PAGE 1 OF 7
3. HAZARD IDENTIFICATION

EMERGENCY OVERVIEW: Fumes are released in fire situations. Harmful if inhaled. Wear full protected
equipment. Prevent contamination of soil surface ,water or ground water.

SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The most significant route of over-exposure
for this product is by contact with the skin.

INHALATION: In high concentrations produces irritation to upper respiratory tract , vapors can cause
unconsciousness .

CONTACT WITH THE SKIN AND EYES: May cause pain and slight eye irritation. Vapors may irritate eyes.
Prolonged or repeated exposure may cause skin irritation. May cause drying or flaking of skin. A single prolonged
exposure is not likely to result in the material being absorbed through skin in harmful amounts.


INGESTION: may result in irritation of mouth and gastro-intestinal tract.


HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms.

Persons having pre-existing diseases of the lungs, eyes or skin may have increased susceptibility to the hazards of
excessive exposure.




4. FIRST-AID MEASURES
SKIN EXPOSURE: If this product contaminates the skin, begin flushing with soap and water. Remove exposed or
contaminated clothing, taking care not to contaminate eyes. Contaminated individual must seek medical attention if
redness or irritation continues after area has been rinsed.

EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use
sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes.

INHALATION: Remove victim to fresh air. If necessary, use artificial respiration to support vital functions.
Remove or cover gross contamination to avoid exposure to rescuers. Call a physician and/or transport to
emergency facility immediately.




TEMPIL LAQ GREEN LABEL THINNER MSDS EFFECTIVE DATE: MAY 7, 2001
PAGE 2 OF 7
4. FIRST-AID MEASURES (Continued)
INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST
CURRENT INFORMATION

Contaminated individual must be taken for medical attention if adverse effects occur. Rescuers should be taken for
medical attention, if necessary. Take copy of label and MSDS to physician or other health professional with
contaminated individual.

5. FIRE-FIGHTING MEASURES
FLASH POINT, (method): None (CC)
NFPA RATING
FLAMMABILITY
AUTOIGNITION TEMPERATURE: NA
1
FLAMMABLE LIMITS (in air by volume, %):
0
2
HEALTH REACTIVITY
Lower (LFL): NE
Upper (UFL): NE

FIRE EXTINGUISHING MATERIALS:
OTHER

Water fog: YES Carbon Dioxide: YES
Foam: YES Dry Chemical: YES


UNUSUAL FIRE AND EXPLOSION HAZARDS: Avoid contact with flames, sparks or high intensity sources.
Product will decompose rapidly at temperature above 400 C releasing toxic fumes of carbon monoxide, carbon
dioxide, hydrogen halide and toxic fumes of bromides.

.

SPECIAL FIRE-FIGHTING PROCEDURES: Keep people away . Isolate fire area and deny unnecessary entry.
Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Stay
upwind. Wear positive-pressure self-contained breathing appratus (SCBA) and protective fire fighting clothing. If
possible, prevent run-off water from entering storm drains, bodies of water, or other environmentally sensitive areas.

6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Clear all personnel from area. Do not breathe vapors. Ventilate area of leak or spill.
Do not breathe vapors. Ventilate area of leak or spill. Wear protective equipment including positive pressure self
contained or air supplied breathing apparatus.

Contain liquid, prevent contamination of soil, surface water or ground water. Solvent material is heavier than water
and has limited water solubility. It will collect on the lowest surface.


Contain liquid, transfer to properly labeled closed containers. Place all spill in a suitable container and seal.
Dispose of in accordance with Federal, State and local hazardous waste disposal regulations (see Section 13,
Disposal Considerations).

7. HANDLING and USE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN
YOU. Do not eat or drink while handling chemicals.




TEMPIL LAQ GREEN LABEL THINNER MSDS EFFECTIVE DATE: MAY 7, 2001
PAGE 3 OF 7
7. HANDLING and USE (Continued)
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it
safely. Avoid breathing material of this product. Packages of this product must be properly labeled. Store
packages in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible.
Store away from incompatible materials (see Section 10, Stability and Reactivity). Inspect all incoming packages
before storage, to ensure they are properly labeled and not damaged.

PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices
indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-
out safely. Decontaminate equipment using soapy water before maintenance begins. Collect all rinsates and
dispose of according to applicable Federal, State, or local procedures.

8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Prudent practice is to ensure eyewash/safety shower stations
are available near where this product is used. Provide local exhaust ventilation to control airborne levels below the
exposure guidelines.

RESPIRATORY PROTECTION: Use an approved air-purifying or positive-pressure supplied-air respirator
depending on the potential concentration. Follow the requirements of the Federal OSHA Respiratory Protection
Standard (29 CFR 1910.134), or equivalent State standards.

EYE PROTECTION: Safety glasses.

HAND PROTECTION: Wear impervious gloves.



9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): NA. Odor: Irritating odor at high concentration.
SPECIFIC GRAVITY (water = 1): NA FREEZING/MELTING POINT: Not available.
SOLUBILITY IN WATER: NA BOILING POINT: NA
VAPOR PRESSURE: NA
pH: NA.
COEFFICIENT WATER/OIL DISTRIBUTION: Not applicable.

APPEARANCE AND COLOR: liquid with solvent odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance is a distinct property of this
product.

10. STABILITY and REACTIVITY
STABILITY: Stable.

DECOMPOSITION PRODUCTS: None known.

HAZARDOUS POLYMERIZATION: Will not occur.

CONDITIONS TO AVOID: Avoid open flames, direct sunlight or ultraviolet sources.




TEMPIL LAQ GREEN LABEL THINNER MSDS EFFECTIVE DATE: MAY 7, 2001
PAGE 4 OF 7
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: The following toxicological data are available for the components of this product:



Hydrocarbon c8-11:

Has central nervous system effects.

May cause irregular pulse

Vapors may cause irritation of the eyes, nose, and respiratory tract.


N-Propyl bromide LD50/Rat--oral --4260 mg/Kg
Lc50/Rat, inhalation--253000mg/m3/0.5 hr

1,2 Epoxybutane LD50/Rat, oral-1180 mg/Kg
LD50/Rabbit, dermal-1760 mg/kg

t-Butanol LD50/Rat, oral-3500mg/Kg




RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce or eliminate exposure.




12. ECOLOGICAL INFORMATION

ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION

ENVIRONMENTAL STABILITY:

No information available




TEMPIL LAQ GREEN LABEL THINNER MSDS EFFECTIVE DATE: MAY 7, 2001
PAGE 5 OF 7
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State,
and local regulations. This product if unaltered by use may be disposed of by treatment at a permitted facility or as
advised by your local hazardous waste regulatory authority.


14. TRANSPORTATION INFORMATION

PROPER SHIPPING NAME: Product not regulated
HAZARD CLASS NUMBER and DESCRIPTION: NA.
UN IDENTIFICATION NUMBER: NA
PACKING GROUP: NA.
DOT LABEL(S) REQUIRED: NA.

NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (1996): NA.
MARINE POLLUTANT: NA.

TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: NA

15. REGULATORY INFORMATION
SARA REPORTING REQUIREMENTS: This product is subject to the reporting requirements of Sections 311, 312
and 313 of Title III of the Superfund Amendments and Reauthorization Act., as follows:
COMPONENT SARA 311 SARA 312 SARA 313
1,2 Epoxybutane NA NA Yes
t-Butanol Yes




SARA THRESHOLD PLANNING QUANTITY: NA.
TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
CERCLA REPORTABLE QUANTITY (RQ): NA.
OTHER U.S. FEDERAL REGULATIONS: NA.
STATE REGULATORY INFORMATION: The components of this product are covered under specific State
regulations, as denoted below:
Alaska - Designated Toxic and Massachusetts - Substance List: NA. Pennsylvania - Hazardous Substance
Hazardous Substances: NA. Minnesota - List of Hazardous List: NA.
California - Permissible Exposure Substances: NA. Rhode Island - Hazardous Substance
Limits for Chemical Contaminants: Missouri - Employer Information/Toxic List: NA.
NA. Substance List: NA. Texas - Hazardous Substance List:
Florida - Substance List: NA. New Jersey - Right to Know Hazardous NA.
Illinois - Toxic Substance List: NA. Substance List: NA. West Virginia - Hazardous Substance
Kansas - Section 302/313 List: NA. North Dakota - List of Hazardous List: NA.
Chemicals, Reportable Quantities: Wisconsin - Toxic and Hazardous
NA. Substances: NA.




TEMPIL LAQ GREEN LABEL THINNER MSDS EFFECTIVE DATE: MAY 7, 2001
PAGE 6 OF 7
16. OTHER INFORMATION

CAUTION! MAY BE HARMFUL IF INGESTED. CONTACT WITH SKIN MAY CAUSE IRRITATION. Do not
taste or swallow. Avoid contact with skin. Use with adequate ventilation. Wash thoroughly after handling.
Wear gloves and safety goggles when using this product. FIRST-AID: In case of contact, immediately flush
skin or eyes with large amounts of water. If inhaled, move to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. IN CASE OF FIRE: Use fog, foam, dry chemical or CO2. IN
CASE OF SPILL: Pick-up material and rinse area with soap and water. Refer to MSDS for additional
information.


PREPARED BY: Tempil INC.
2901 Hamilton Boulevard, South Plainfield, NJ 07080
908/757/8300



This Material Safety Data Sheet is offered pursuant to OSHA's Hazard Communication Standard, 29 CFR, 1910.1200. Other government
regulations must be reviewed for applicability to this product. To the best of Tempil's knowledge, the information contained herein is reliable
and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed and no warranties of any type, either express
or implied, are provided. The information contained herein relates only to this specific product. If this product is combined with other
materials, all component properties must be considered. Data may be changed from time to time. Be sure to consult the latest edition.




TEMPIL LAQ GREEN LABEL THINNER MSDS EFFECTIVE DATE: MAY 7, 2001
PAGE 7 OF 7

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