Material Safety Data Sheet
SPOT FREE 2177A Flintstone Drive FOR CHEMICAL EMERGENCY
TUCKER, GA 30084 Call INFOTRAC
www.ecolink.com 800/535-5053 (24 HOURS)
Environmentally Preferred Spot Remover email: info@ecolink.com
800/886-8240 or
Rev. 06/06/2007
770/621-8240 (9? EST)
Section I: Product Identification Section II: Chemical or Hazardous Components
Product name: Spot Free Chemical Name n - Propyl Bromide
CAS No. 106-94-5
Synonym: Alkyl Bromide
Approx. wt.% >95%
Molecular Formula: See Section II
Exposure OSHA -PEL ?N/E
MREL ?100 PPM 8 hr. TWA*
The "Plain English" Section
(*) Manufacturer's recommended exposure limits.
Material Safety Data Sheets can be confusing. Federal law
Chemical Name 1,2 - Butylene Oxide
requires us to print a great deal of technical information,
which probably won't help the non-scientist. ECOLINK CAS No. 106-88-7
includes this "PLAIN ENGLISH" section, written to address
Approx. wt. % <1%
the questions and concerns of the average person. If you
Exposure ACGIH-TLV-TWA ?N/E
have additional health, safety or product questions, don't
OSHA-PEL-TWA ?N/E
hesitate to call us at 800/886-8240.
Chemical Name Dimethoxymethane
Health Hazards: SPOT FREE is an industrial chemical. We
call it "environmentally preferred" because it is intended to CAS No. 109-87-5
replace products that are more hazardous, Approx. wt. % <5%
(Trichloroethylene, Methylene Chloride, etc.). This does not
Exposure Y (Hazardous)
mean that it is harmless. It is strong enough to remove
OSHA-PEL-TWA - 1000 ppm
tough industrial soils, so it can irritate your skin. We suggest
ACGIH TLV TWA -1000 ppm
you wear gloves, and avoid extended exposure to
unprotected skin. Don't get it in your eyes, or breath large Chemical Name t - Butanol
amounts of the vapor, (it will dry out your nasal passages). CAS No. 75-65-0
Used on a rag or from a spray bottle, the product won't
Approx. wt. % <5%
produce fumes in any great quantity, (don't spray this
Exposure Y (Hazardous)
material under high pressure without adequate ventilation).
OSHA-PEL-TWA - 100 ppm
For more exposure and first aid information, please read
ACGIH TLV TWA -100 ppm
through this MSDS.
1,2-Butylene Oxide and t-Butanol are subject to the reporting
Flashpoint: SPOT FREE does not have a flashpoint. Under
requirements of Section 313. 1,3 Butylene Oxide is a CERCLA
virtually all industrial circumstances and conditions, this
regulated material, RQ 100 lbs.
material will not burn, (under exactly the right conditions, it
can be made to ignite). Combustion in ordinary use isn't a
n-Propyl Bromide is listed as a reproductive toxin under the
big concern but if you want to discuss a specific application,
California Safe Drinking Water Act (Proposition 65)
please call us. We do not recommend using this, or any
other industrial solvent, around welding or hot work areas.
ALL MATERIALS IN PRODUCT ARE TSCA LISTED
Disposal: SPOT FREE is a brominated solvent. Liquid
waste that is captured after the cleaning process must be DOT regulated: No
disposed of according to certain specific guidelines.
Additionally, once this material is contaminated with
Section III: Physical Data
whatever you are cleaning, the resulting mixture may fall
under a hazardous classification, depending on whether or Appearance & Odor: Clear, colorless liquid with
not the material you are cleaning is hazardous. If you aren't characteristic odor.
sure how to dispose of this material, give us a call and we Boiling Point: 160?F @ 760 mm Hg
will help you make the right decisions.
Evaporation Rate: 6.05
Percent Volatile: 100%
Solubility In Water: .25g 100 ml @ 20篊
Specific Gravity: 1.35
Vapor Density (AIR=1): 4.25
Vapor Pressure: 111 mm Hg @ 20癈
Material Safety Data Sheet ?Spot Free
Ecolink, Inc. Page 1 of 3
Long-term overexposure may cause effects of the lung, kidney,
Section IV: Fire and Explosion Hazard Data liver, urinary blood, bone marrow, heart, eye, nervous and
reproductive systems.
Flash Point (Method): None (TCC)
Notes: This material is a halogenated alkane. Long term
overexposure, (without adequate ventilation and/or protective
Flammable Limits:
equipment), may cause lung, kidney, liver, urinary, blood, bone
LEL ~ 3.8%
marrow, heart, eye, central nervous system, reproductive and
UEL ~ 7.5%
fertility effects. The minor ingredient, 1,2-butylene oxide is
Extinguishing Media:
classified by IARC as a Group 3 material, which exhibits limited
All conventional media are suitable.
evidence of carcinogenicity in experimental animals and no
Special Fire Fighting Procedures: human data.
Keep fire exposed containers cool with water. Fire fighters
First Aid:
should wear self-contained breathing apparatus with a full
face piece operated in the positive pressure demand mode Ingestion: Seek medical attention immediately. If
with appropriate gear and chemical resistant personal individual is drowsy or unconscious, do not
protective equipment. give anything by mouth; place individual on
Unusual Fire & Explosion Hazards: left side with head down. If unconscious,
Material forms a flammable mixture with air in a narrow give 1-2 glasses of water. Contact medical
flammability range (3.8% ?7.5%. by volume). Containers facility or poison control center for advice on
exposed to flame or high heat may explode. In fire, toxic whether to induce vomiting.
gases may be released. Use water to cool containers Inhalation: Remove to fresh air. If breathing is difficult,
exposed to fire. give oxygen. If breathing has stopped,
perform artificial respiration. Keep person
Section V: Reactivity Data warm and quiet. Seek medical attention.
Stability: Stable Eyes: Irrigate immediately with water for at least 15
minutes. Get medical attention if irritation
Conditions to Avoid:
persists.
Sources of ignition such as sparks, hot spots, welding,
Skin: Wash with soap and water. Thoroughly clean
flames and cigarettes. Ignition/flash may result if
contaminated clothes and shoes before re-use.
concentration of product is in the flammable range.
If symptoms persist, seek medical attention.
(See section IV for LEL and UEL values.)
Carcinogen: NTP ?Not Listed
Incompatibility (Materials to Avoid):
IARC Monographs ?None
Not compatible with certain plastics and rubber. Test all
OSHA REGS ?NOT REGULATED
non-metals prior to use. Avoid strong oxidizers, acids and
bases, acid chlorides, and anhydrides.
Section VII: Precautions for Safe Handling
Hazardous Decomposition: May form hydrogen bromide, and
oxides of carbon.
HMIS Information:
Hazardous Polymerization: Will not occur. Health ?2 / Reactivity ?0
Flammability ?1 Personal Protection ?X
HMIS Definition:
Section VI: Health Hazard Data 0 ?Minimal 1 ?Slight 2 ?Moderate 3 ?Serious 4 ?Extreme
Primary Routes of Exposure: "/" in the Health Category denotes material does not target
Oral, Inhalation, & Skin any major organs.
"*" in the Health Category denotes material may target certain
Ingestion:
organs.
Swallowing large amounts may be harmful by causing
Personal Protection "X" means "Ask your safety specialist for
gastrointestinal irritation.
handling instructions.
Inhalation:
Eye Protection
Breathing large amounts may be harmful by causing
Chemical safety glasses and splash protection required.
nose, throat, and respiratory tract irritation and affecting
Protective Gloves:
the central nervous system by causing drowsiness,
Viton or Norfoil are recommended (contact your local glove
dizziness, and/or possible unconsciousness. Chemical
supplier.) Nitrile or butyl rubber provide splash protection only.
burns are possible.
Respiratory Protection:
Eyes:
Not required under conditions of normal use when ventilation
Irritant. Liquid contact will irritate eyes and may cause
is adequate. If vapor mist is present, use NIOSH certified
stinging, tearing, and redness. Chemical burns are
organic vapor mask.
possible.
Ventilation: Local exhaust/hood or fan may be used; adequate
Skin or Contact:
ventilation is extremely important.
May cause mild irritation of redness and burning. Chemical
burns are possible. Other Protective Clothing: None required under normal use.
Work Practices: All equipment should be grounded. Proper
May aggravate pre-existing diseases of the skin, liver, kidney
ventilation is required. Avoid breathing concentrated
and respiratory system.
Material Safety Data Sheet ?Spot Free
Ecolink, Inc. Page 2 of 3
vapors/fumes. Treat this chemical with respect and follow
Section IX: Part Numbers & Packaging
all MSDS instructions.
Product Name Part No. Packaging
Section VIII: Control Measures SPOT FREE 004-55 52 Gal (In 55 Gal Drum)
Small Spill: Absorb liquid on vermiculite, floor absorbent, or SPOT FREE 004-5 5 Gal Pail
other inert absorbent material and place in suitable
SPOT FREE 004-1 4 x 1 Gal Case
labeled containers for disposal.
Large Spill: Ventilate contaminated area. Eliminate all
ignition sources, (flares, flames including pilot lights,
electrical sparks). Persons not wearing protective
equipment should be excluded from area of spill until DISCLAIMER: Ecolink, Inc. believes the information contained herein
clean up has been completed. Stop spill at source. is accurate. However, Ecolink makes no warranty, expressed or
Prevent from entering drains, sewers, streams, etc. If implied, regarding the accuracy of this data or the results to be
runoff occurs, notify authorities as required. Pump or obtained by the use thereof. Ecolink, Inc. assumes no responsibility for
vacuum transfer spilled product to clean containers for injury from the use of the product described herein.
recovery. Transfer contaminated absorbent, soil and
other materials to containers for disposal.
Waste Disposal Method: SPOT FREE may be disposed of
as an industrial waste in a manner acceptable to good END OF MSDS
waste management practices and in compliance with
applicable local, state and federal regulations.
Precautions To Be Taken In Handling & Storing: Material
should be stored in a cool, dry, well-ventilated area.
Since empty containers retain product residues, all
hazard precautions given in the data sheet must be
observed. All metal pails or drums should be grounded
and/or bonded when material is transferred. Any use of
this product in elevated temperature processes should be
thoroughly evaluated to establish and maintain safe
operating conditions. Sudden release of hot organic
chemical vapors or mists from process equipment
operating at elevated temperatures may result in ignition.
Keep containers tightly closed.
Other Precautions: Keep this and all chemicals out of the
reach of children.
Material Safety Data Sheet ?Spot Free
Ecolink, Inc. Page 3 of 3
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