tr\JLV).(^ dLJ
CI'fGO l)ctrolcurn
Corporation
P.O.Box 3758
Tulsa, Oklahoma 74102
Materiul SufetvDutu Sheet
,':". (ZfGa ,F7 dcfinla &*sao/L
alkldri
'frade
Namc:
0+001
Commodity Code:
Motor (iasolinc, Pctrol, Gas
.Synonyms: Datc: iVlay.7,1992
'l'cchnical
CAS No,: Mixture Contact:(918)495-5933
(l{eferto Scction l) Mcdical Erncrgency:(3lS) 491-6215.
ChemtrecEmergency: (800)424-9300
Citgo Index No.: 0083
Material HazardEvaluation
(l'cr OSI'lA l-lazardComrnunicatiorr
Standard CFR Part 1910.12001) (OIICS)
[29
-
I{calth: I)r\NGI,IR: Contains l}enzene canccrhanrd.
l'larmlul or fatal if srvallowcd. Vapors hazardous.
Prccaution:rrystatement: |)ANGI|B: Extrcmelyflammable liquid. Do not siphon by mouth. If slallowed,
-
clo not induccvomiting catilifiEiliLn imrnecliaicly.
LIillS Ratingt: Health I Flammability 3 Reactivity 0
1.0 Generic
Composition Components
/
Componcnts CAS # Flaz.ard
% Data
Pctrolcu l)istillatcs
m i\'lixture 85-98 Oral LDI-o(hurnan): 0.5-5.0g/kg
Ilcnzcne <5
7t-43-2 OSII;\ PEL:TWA I ppm
Oral LD50(ms):4700mg/kg.
I-owcr rUiphatic ;Ucohols 1.D50(rat):> S.Ogikg
r\lixture 0-lI Ora.l
DcrmalLD50(rat): > 5.0g.kg
Inlrn TClo(l{uman): -25 ppm
0-r5
Lolvcr ;\liphatic l]thers iVli.rture Oral LD50(rat):4 ml/kg
DermalLD50(rbt): > l0 ml/kg
Eyes: i\lild iritant
i\lcolrols. alkyletbersand sirnilar additives, not significantly
do altcr tfte toxicity of UnleadedGasoline.
Y t l-lazard Rating: lcast-0; slis.ht-l; nroderate-2;trigh-3; exrreme-4
__tlg9 "Ilg"rnent based 91 9ur evaluation pcr Nl:P.\ and NPCA guidclincs.
-
Nr\ ND - No Dau
Nor i\pplicable NE - Not Esbblishcd
CI1'GO Unlcarlcd - 87 Octanc (lasoline (0.1-001,
i\lav 7. l99Z CIN f,: 0{}tt3) Page I of?
2.0 PhvsicalData
Classification 29 CFIt I'art 1910.1200)
(l)cr
Flazard
I)hysical
No Pyrophoric
Ycs [;lammablc
Combustiblc
No
No Rcactivity
No No OrganicPcroxidc
CompresscdCas
Yes Stable
No Oxidizer
Explosive
No
3s(es)
Boiling Point, 760 mml-lg,"C('F):
(iravity (60i60'tr)(l-l,O= l): 0.75
Spccilic
Vapor Dcnsity(r\ir: l): 3-4
FIigh
7n Voletilcsby Volume:
Nr\
Ilclting I)oint,'C("F):
5 l0-760
mml"lg (25"C):
Vapor Prcssure,
Ncgligible
Solubilityin II,O, % by Wcight:
Rate (llutyl r\cctate= l):
Evaporation
ND
pll of Undilutcd Product:
Light ycllorvor clearliquid - gasoline
Appearanccand Odor: odor
3.0 Fire andExplosion
Data
(:OC,'C('F1 -43(-4s)
Fl:rshPoint,
FlashPoht, PiVlC,'C("F; N D
COC,"C("F) N D
Firc Point,
Nl;l'A llatin'f Ilcalth: I Flarnmability: 3 Rcactivity: 0
Limits (% ty volume in air)
lilarnmablc [.orvcr: 1.4 Upfrer:7.6
llxtintruislintr}lcdia CC,, clry chcrnical,
foain, rvatcrfog
War sclf-containedbrcathing apparatuswhcn in a
Sgrccial
l.'irc Figlrting Proccdurc
conlined area.
Nlatcrialis higlrly volatile and emits vaporsrvhich
Unusuall;irc or llxpl
may be ignitcd by other ignition sources.
4,0 R.eacfivitv
Data
Staltilit-v-:
Stable
CoruiitionsContributing to Instahility: I-ligh Tcmperaturc, flame.
Incompatihility: Strongo.ddants,strongacids,caustics.
IIuzanlous DecompositionI>roducts: CO,, (CO under incompletccombustion).
( thernml, unlessothcnvisespeciJied.)
Conditiorts Contrib utin.g to H uz.ardous
I'olymcrir.ation: None.
)
2 llazard llating: lcast-0;sligtrt-l: nrodcratc-Z; high-3; extrcnrc-J
Citgo assignmentbascd orr our evaluat-ionpcr NFI).,\ guidclines.
NA - Not Applicablc liD - No Data NE - Not Eslablished
Unlcadcd - 87 O c t a n e G : r s o l i n c ( 0 { - 0 0 1 , } l a v l'rgc 2 ot7
CITGO 7, 1992 CIN #: 0083)
'u!aJaq pals!l Jaqrxnu uoqdaIa1 3ua6Jaua
a f a q 1 [ [ P ] J o u o r ? P f , orI a ] t d d n s
+ s a s o l c; n o , {
'Ja!
l l p l u o ? _ 3 a r u p l s t s s p t e s o d s r p ^ l u a o J a u j aJ o tddns rno,f ol arE ur der- uoEiJioJd
l 0 1 a [ ? n oa ^ [ P ^ u p q l ! r y . p a l a q p [ ^ l r a d o J J a u l p l u o l 6 u r d d r q s
A I P A p U P P a J n f , a S S d P f ,J O
u s l P 0 1 ? d u J a l l Pl o u o 0 ooHl3t { tvsocsro
3lSvM
' u l a J a u D a l s t I J a q u n ua u o q d a 1 a 1
foua6Jaula ql
a Jo
uoL?ploI J
rsaBut*TT{Tl-i'H*?|tfl,l'x,i:11,:'.*:-r5:i'iy::p ] ,'srreda.,a ! l d d n s
[[
6ut1dura11
of utel"rai aq ):'! {r
5 :l ''1uj'rdinua-i;r-;; ;;t*;-;;j;
Y- ,1 *Sl':tf,'"*tsFrr3cAilfle,Utsq,Hllght[U*dtd".a6.rnd
'1y-auq,Lnb.a alerrdo.-rdd.g- .parp pal.f,atlp urorJ
an1Xcaio"r.d. aqn
JI
o snitt.s: up rvithnon-combustible
snutu Takc absorbanbruarr,as.fiilI*s*r,*t*i,r,liJal:;*?9,J,(P^ilJlt-PAj
s:tHno330Hd yv3] HO-I-ltds
for latcr disposal.
A tiie-tighting
lbam blanket top of spillruiffr"au". un;;; *
on
o l{eport spills as requircd to appropriatcauthoritics.
'lod
OtOnv 01 SNO|IIONOJ
isfiosal: NOIIVZtU3|'\r SnOOUvZVH
nsibiLi of the uscr to dctermineif the nraterialis a
Checkbcforedisposing bc sureyou arc in compliance
to with all applicable
f5*3hr{dlp$rftldlfJlltllPtJ-t tV
tSllvdwo3Nr
o Chcmtrcc/RCRA EmergcncyHotlineNum
Protcctivc i\Ic:usures
l)uring Rcpair and Nlaintcnancc contamirratc$
of
o llel'cr to SectionVII - SpecialProtection lnformation.
' u o r ? s n q u os,a l p J a
f
Removc soiledclothing.
a
I a ] 3 p , t 1 s n o . l o1
t6
Usc impcrviousglovesif cxtcnclcd,
a
dircct contact
]dX3 ONV SUIJ
5.0 FtrealthaF{,Rzwdr.,Danar qrrq^l
s.r. ua6/cxo no13 dols ,alqrssod
aql
Jo 31
330ud
9Nu.H9tJ
3utJ ]vtf,3ds
'rezrprxoaq? se uE6Txo
P M J 0 S at 1 uenb sno ! do3 vro:rr,r
gNrHsrngNs.x
'r3'r j
t Jl/crR v/N
1l;
''!rti'
*vv v9Y&Yn tt\rtlo\ .t+
No rvJ{
\-arclno!:cn LOtTOSIVe
Ycs r\nirnal Carcinoscn sp0 ssa llopo-z ssa r.ro ) 3
lrritant
Ycs
\r \I
L -.\.tol
I
/N
Lol 'fcratogcn
JoUL I
N
| | =lllvl r=llavlro ^rJr^lJc
F l i g h l y'ro xi.8 'B Ie -)
3d l argct urgan: HemardpdiEne|iESpim$m
J.B ' i99:
No Yes
system, skin
'r"o{ipu/64
g1e'T) ;ttqt
N
a q l a A o q V( 3 " I ' I z )
uJle J.01. A1lsN30sv9
Lv
J . 0 / p t3 u n s s 3 u d . r v n
uo
rcfftryq
r-roouct usrco asc"sqrqtrroEg4 r Dy:
D, ( 3 " 6 . 2 8 I _ ) ) " t , .1 6 T
orn .,f y(.a (AIa I thrd LNtod 9NI-IOB
vl.vo -lvctl
iAFd
Toxicity iummutl,: r\'lodcratcly
toxic: 0.3 trr 8 oz. may bea lethal
_ oraldose l50lb. human.
for
tVluiorRoute(s)uol'Entrv:
'f Vapors,inhalation,and stiin contact ,,
{o_ua6 f i x o . r n d u .rn { [1 .r^4! P u r a [ q P u . u P l J 0 u a J p q l l q l 4 s l e l J a l p u a u o s . p a p l o ^ p
a J 1 aq
l n o q ss l p r J a l p u a l q e u l e i S [ [ p q ? r M ? 3 e 1 u o ] ' u 0 ! l S n q u i o J
r
s a l p J a I a f , ] p , { 1 s n o " r O 6 lu a 6 , ( x g
n
\-/ s3svg uo ,sot-.ls ' s o t n o t - lu 3 H l (
o ) JO S3UnJ.XthlsnooHVZVH
Z a6ed NA.N"r6ffibf. ND - No Dara NE - Not Esrablishcd
lJnlelded - ll7 ()ct:rnc (lusolinc (01-001, Nl:rv 7, 1992CIN f: 0083)
CII'GO
l'age 3 ol'7
AcuteExposure
Symptonrs
Inhatatiort: IVloclcr:rtc
risk
fpaccs with poor
ventilation. Euphoria, lung irritation a.d cdcma, hcadache,a;ril-rr,
drorvsincss,corrvulsi.ns,coma, cyanosis,
gencralizcd deprcssion.
Dermal Contact: Defattingrvith drying of skin.
Eye Contact: Iritant.
Ingestion: Buming of mouth and upper GI tract, vomiting ancl diiLrrhea: Abovc
I oz.
or lcssthan I oz. rvith retcntion: gcneraldeprcsJion,
scdation,,".pir"tory J"-
pression,coma.
ChronicExposure
Skin: D.ying of skin (dermatitis)
Inhulation: Benzene has been classifiedas a lcukemogen,and
-may produce anemia,
leukemia from repcatedor prol,nged exposrire rrigh
io The
r\rncrican Pctrolcurn hrstitutc sponsored chronic inirdation studies
"onJ"nLtionr.
of uii-
Ieadcdgasoline vapors indicating unleadedgasolineis carcinogenicto rauora_
tory animals
Other SpecialEffects
Nonc
NledicalConditions
Aggravatedby Exposure
Prc-existing
dcrmatoses.
First Aid &nd Enrcrgetrcy
Procedur.es Aatte Effect
for
Inhulntion: Ilernove to l'rcshair. Ilespiratory support, if uccessary. Seekmedical aid.
Dermal: Wash rvith soap :utd water. Do not rvearheavily contaminaterlclothing bcfore
cleaning.
Eyes: I;lush rvith largevolumcsof rvatcr. Seckmeclical
aid.
In.gestion: Do not inducevomiting. Seekmedical
aid.
Nots to Phy-sician:This is a lorv viscositymatcrial with a Saybolt viscosityat 100"F
of less than 40 SUS.
Pulmonart' hi-uh.aspiration.ltuzard, possibly pror,Iucirrg lipoid-pncumonia if iwalloivcd u,ro uo-itirg';;;^.
use carefi:lgastriclavagervith tight firting, luiJ"a cndolraihealiube.
NA - Not Applicabtc ND - No Data NE - Not Estabtished
-
c t ' r ( ; o U n l c a d c d 8 7 o c t a n eG u s o r i n ( 0 4 - 0 0 r .l t a v 7 , l 9 9 z c r N
e i s:00g3) Page 4 of 7
9.0 Environrnental
Data
nrotluct Narne CITGO Unlcaded- 87 OctaneGasoliue
/] CornrnodityCode: 04-00t
S.\R,\'TI'I'I,I|III
'lbxic
313-
Scctiorr Chemicnfs
This product containstoxic chemicalsof .Scction313 of f itle III of supcrfund Amendmentsand Reauthori-
(SARA) and 40 Cl;l{ part 372.
zation r\ct of 1986
Comoonents CAS# o
Ilcnzcne 7t-43-2 0-5
'l
crtiary Ilutyl rUcohol 75-65-0 0-t0
Ethyl Bcnzcnc 100-4t-4 0-5
l\lcthyl-t-butyl ether t634-04-4 0 -l 5
'Ioluene
108-88-3 0-25
1,2,4Trimcthyl Benzenc 95-63-6 0-5
Xylene (mixcd isomers) 1330-20-7 0-25
Scctirin3ll - llv.ard Catcgoris
No Not Applicablc Yes Fire llazard
(lmmediatc l-lcalth Hazard)
Jcl'\cutc No Suddcn Pressurcllelease
Ycs Cluonic (Dclaycd l.lealth Flazardj No Reactivity l-lazard
(l]-O = Rcnortable()uantity)
(-fPq : Tlrrcshold Irlanningeuantity)
This product doesnot contain Extrcmely l-lazardous
Substances Scction302(A).
of
Cotntroncnt o/o
CAS# RO lbs. TPO lbs.
Nonc . :
Cfc:rn\\iatcr Act
Undcrscction3l I (b) (a) of the Cterur
watcr Act,
of-crude and pctroleum
oil products any kind
in
or lbr:n to surtacc
w{rtcrs
mustbc irnmcdiatcly rcportcd t;?--N;;;JR;;ffiC;"ter: 800-42.1-gg02.
.I"z"rauu"
C
Nonc
Pctrolcum and pctrolcum fractionsarc excludctlfrom the list of
cERct-A hazardoussubstances Section
by
l0l( l1) of CITRCLA.
NA - Nor Appticabtc
ND - No Dara
NE - Not Esrabl.ished
-
cl'l-(;o [Jnlc:rrlcd87 oct:rnc Gasorinc
(0.r-00t,i\Iey 7, r992 ctN #:00g3)
P:rge 6 of 7
Nuv .Icrscv \l"orl
Ilight-to-[irrorv Act
Gasoline CAS#: g006-61-9
Cafifirrrrial)rotxrsition 65
\
Wi\llNNG: TI'IIS PIIODUC]'CONI',\INS A DlilltCTABLE r\i\,IOUN'fOF A CI,IEi\IICAL
KNOWN
1'O TIIITS'l'A'l'tioF C;\LII"OIINIA'l'OCr\USIICANClill ;\NI)/OR npprrOilU-Ctlvtr io,{icliy.'
10.0 Labeling
DANG E R
Contuirts BENZENE - Cancer Hazarcl
Extrcnrcly flammable
Hurndiil or /htul if swullowed
Hanillins
Kecp ax,,tty
from heut, sparles,und flames.
I(ecp cort
tuincr closed.
Do not brcathc vepors.
Usc only n,ith adaquutcven.tilotiort.
. Do not siplrcn lty mouth.
This product contains bcnzcncanclcertainothcr hydrocarbonswhich are po-
tcntially toxic and carcinogcnic. r\void rcpc:rtccl prolongcclcontuct rvith
or
skin.
First Aid
IJ'sn,ullowed,do not intluce vomitirtl3.
Cull a pltysiciutt irnmetliately.
In caseoJ'contact,rctnoyacontuntinateel clothing
itrtmcdiutaly,and wush tlrcroughry with soap antl water.
r\I-I'STA'I'D;\'IEN-I'S,
INI'-ORi\{A'I'lON. .\ND l)Al'A PltO\TIDED fj\i ]'HIS NtAniRIAL
sHliltr AllE llIiLI[vED 'l'o Bli .\ccuR,\'ft] ,\ND nttLI.AI]t.t., SAFETY DAI'A
t]u'l' ,rna pircsENTED\ylt.HOUT
cuAllAN'I'liE, RltPRlil_ttN'tATnN,
:YAR3j\NTv, ort n[snoNsrnri.rri oF
PR[ssED oR IN|PLIED. ,tNv ;iNI) ;\LL RtititrtisbN't',\'r'roNs-ANulon ANy KIND, EX_ wARg.,\NTIEs
i\'IIIICHANTIBII.ITYOlt FIl]iliSS Folt A l'lAtt't'I(lUrin PURpoSIi Alitf SpECIFICALLy o!.
Drs.
CLAIi\tl'll).U.SERS SIIOtiLDr\'1.\I'Ii'l'FIl'-Ilt IN\TS1'tc.\'ftONS'r'iillU'rmli\tlNlt
OwN
Allll-rl'Y oF 'tHIl INI:olllIA'floN oll PRot)ucrs tfolt 'fIIIint l,riuucur,.rn Tr{E SUr.r- puRpostr.
NOI'HING CONI'AINUD HI|REIN IS IN'l'IjNl)liI) i\S I'I]R,\'IISSION,
IN-I)UCIINIENT.OIf RECOi]t-
il'lENDAl'loN 1'o vloL'\'fl, ANY L.-\\vsott T'o pR.\c'I'rcD.\Ny rNvltNi'roru covERItD
uy tix-
IS]ING PA'IIiNTS, COPYIUG}I]'S OIT INVEM-IONS-
Nn - Not Appticrble ND - No Dau NE - Not Established
C l l ' G O L n l c a d c d - l l 7 O c t a n c ( l : r s o l i r r c 0 J J ) 01 . : \ l l r
( 7. 1992CIN f : {X)lt3) I'l-ge 1 of 7
|