Product Name: Duro(R) Liquid Steel(R) Filler Page 1 of 5
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
Duro(R) Liquid Steel(R) Filler
80222
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Item No.: 80222
Part No.: LS-1
Product Type: Sealer/Filler
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Barium sulfate 7727-43-7 45-50
Clay 1332-58-7 20-25
ACETONE 67-64-1 10-15
ISOBUTYL ACETATE 110-19-0 5-10
Synthetic resin 25086-48-0 5-10
BIS (2-ETHYLHEXYL) PHTHALATE* 117-81-7 0.1-1
CARBON BLACK 1333-86-4 0.1-1
PROPYLENE OXIDE* 75-56-9 0.1-1
SILICA, AMORPHOUS,
precipitated 112926-00-8 0.1-1
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
Barium sulfate 10 mg/m3 dust 10 mg/m3 dust None
5 mg/m3 respir.
Clay 2 mg/m3 dust 10 mg/m3 dust None
5 mg/m3 respir.
ACETONE 500 ppm TWA 750 ppm TWA None
1188 mg/m3 1800 mg/m3
ISOBUTYL ACETATE 150 ppm TWA 150 ppm TWA None
713mg/M3 700mg/M3
BIS (2-ETHYLHEXYL) PHTHALATE 5 mg/m3 TWA 5 mg/m3 TWA None
CARBON BLACK 3.5 mg/m3 TWA 3.5 mg/m3 TWA 5ppm
PROPYLENE OXIDE 20 ppm TWA 20 ppm TWA 5 ppm
48 mg/m3 50 mg/m3 6 ppm STEL
SILICA, AMORPHOUS,
precipitated 10 mg/m3 TWA 6 mg/m3 TWA None
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Item No.: 80222
2. COMPOSITION, INFORMATION ON INGREDIENTS (continued)
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Product Name: Duro(R) Liquid Steel(R) Filler Page 2 of 5
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
ACETONE 750 ppm 1000 ppm
1782 mg/m3 2400 mg/m3
BIS (2-ETHYLHEXYL) PHTHALATE 10 mg/m3 10 mg/m3
3. HAZARDS IDENTIFICATION
Toxicity: Irritating to eyes. May cause burning, redness, or
swelling. Ingestion may cause gastroenteric
irritation, narcosis, liver or kidney injury.
Irritating by inhalation. Inhalation of high
concentrations may cause headache, confusion,
drowsiness, convulsions, or coma. May irritate
skin. Prolonged contact may cause redness, burning
dryness, or cracking.
Primary Routes of Entry: Skin, ingestion, inhalation.
Signs and Symptoms
of Exposure: Irritation of eyes, nose, throat. Headache,
confusion, drowsiness, convulsions
Existing Conditions
Aggravated by Exposure: Skin conditions.
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Barium sulfate LUN NO NO NO
Clay AC4 NUI NO NO NO
ACETONE AC4 BLO CNS IRR NO NO NO
ISOBUTYL ACETATE CNS IRR NO NO NO
Synthetic resin No Data NO NO NO
BIS (2-ETHYLHEXYL) PHTHALATE AC3 DEV KID LIV REP YES 2B NO
CARBON BLACK AC4 RES NO 2B NO
PROPYLENE OXIDE AC3 COR IRR MUT NER YES 2A NO
SILICA, AMORPHOUS,
precipitated NUI NO NO NO
-------------------------------------------------------------------------------
Abbreviations
2A Probably carcinogenic to humans 2B Possibly carcinogenic to humans
AC3 ACGIH animal carcinogen. AC4 ACGIH-Unclassifiable as human carc.
BLO Blood CNS Central nervous system
COR Corrosive DEV Developmental
IRR Irritant KID Kidney
LIV Liver LUN Lung
MUT Mutagen NER Nervous System
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Item No.: 80222
3. HAZARDS IDENTIFICATION (continued)
NUI Nuisance dust REP Reproductive
RES Respiratory
4. FIRST AID MEASURES
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Product Name: Duro(R) Liquid Steel(R) Filler Page 3 of 5
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention.
Skin Contact: Wash with soap and water.
Eye Contact: Flush with water for at least 15 minutes. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: 0癋 Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Special Firefighting
Procedures: Not available
Hazardous Products formed
by Fire or Thermal Decomp Oxides of carbon; hydrogen chloride
Unusual Fire or
Explosion Hazards: Vapors may ignite explosively.
Explosive Limits:
(% by volume in air)Lower 2.4%
(% by volume in air)Upper 12.8%
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Remove sources of ignition. Maintains adequate
ventialtion. Take up with an inert absorbent.
Store in a closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Keep away from fire, heat, sparks.
(Contact Loctite Customer Service 1-800-243-4874 for shelf life information)
Handling: Keep away from eyes. Avoid prolonged breathing of
vapor and contact with skin. Close container after
use.
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Item No.: 80222
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Sufficient to maintain vapor concentration
below TLV.
Respiratory Not available
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Black liquid
Odor: Penetrating
Boiling Point: 130癋 to 245癋
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Product Name: Duro(R) Liquid Steel(R) Filler Page 4 of 5
pH: Does not apply
Solubility in Water: Partial
Specific Gravity 1.85
Volatile Organic Compound
(EPA Method 24) Not available
Vapor Pressure: 181 mm at 68癋
Vapor Density: More than 1
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Oxidizing agents, strong alkalies, strong mineral
acids, reducing agents.
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number D001/D005 - Hazardous waste per 40CFR 261.21 and
may be a TCLP waste per 40CFR.24/Barium
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Item No.: 80222
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer Commodity (Not more than one liter);
Adhesives (More than one liter)
Hazard Class or
Division: ORM-D (Not more than one liter);
Class 3, Packing Group II (More than one liter)
Identification Number: None (Not more than one liter);
UN 1133 (More than one liter)
Marine Pollutant: None
IATA
Proper Shipping Name: Consumer Commodity (Not more than 500 ml);
Adhesives (More than 500 ml)
Class or Division: Class 9 (Not more than 500 ml);
Class 3, Packing Group II (More than 500 ml)
UN or ID Number: ID 8000 (Not more than 500 ml);
UN 1133 (More than 500 ml)
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Product Name: Duro(R) Liquid Steel(R) Filler Page 5 of 5
15. REGULATORY INFORMATION
CA Proposition 65: WARNING: This product contains a chemical known to
the State of California to cause cancer.
Di(2-Ethylhexyl)Phthalate (DEHP)
Ethylene Oxide
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 3
Fire Hazard: 3
Reactivity Hazard: 0
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 3
Flammability Hazard: 3
Reactivity Hazards: 0
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist- Safety,Health&Regulatory Affairs
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: December 02, 1997 Revision: 0008
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