MATERIAL SAFETY DATA SHEET
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1. Product and Company Identification
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894
Product number
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Water Based Multi-Purpose Adhesive Remover
Product name Multi-Purpose Adhesive Remover
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30-Dec-2008
Effective date
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Sprayway, Inc.
Claire Manufacturing Co.
Company information
500 Vista Ave.
484
Addison, IL 60101 United States
United States
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General Assistance 630-543-7600
Company phone
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800-424-9300
Emergency telephone US
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703-527-3887
Emergency telephone outside US
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03
Version #
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13-Nov-2007
Supersedes date
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2. Hazards Identification
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FLAMMABLE
Emergency overview
CONTENTS UNDER PRESSURE. Aerosol. Pressurized container may explode when
exposed to heat or flame.
Cancer hazard. Irritating to eyes. Prolonged exposure may cause chronic effects.
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Potential health effects
Causes eye irritation.
Eyes
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Prolonged or repeated contact can result in defatting and drying of the skin which may
Skin
result in skin irritation and dermatitis (rash).
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Intentional misuse by concentrating and inhaling the product can be harmful or fatal.
Inhalation
Prolonged inhalation may be harmful.
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Exposure by ingestion of an aerosol is unlikely. Ingestion may cause gastrointestinal
Ingestion
irritation, nausea, vomiting and diarrhea. May cause delayed lung damage.
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Central nervous system.
Target organs
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May cause central nervous system disorder (e.g., narcosis involving a loss of
Chronic effects
coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage.
May cause delayed lung damage.
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3. Composition / Information on Ingredients
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Components CAS # Percent
d-Limonene 5989-27-5 15 - 20
Diethylene Glycol Monobutyl Ether 112-34-5 10 - 15
n-Methyl-2-Pyrrolidinone 872-50-4 5-8
Dimethyl Ether 115-10-6 5-8
Polyethylene Glycol Nonylphenol Ether 9016-45-9 5-8
Isobutane 75-28-5 5-8
Propane 74-98-6 1-3
Nitromethane 75-52-5 0.1 - 0.5
Non-hazardous and other components below reportable levels 40 - 60
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4. First Aid Measures
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First aid procedures
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact
Eye contact
lenses, if present and easy to do. Get medical attention if irritation develops or persists.
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Remove and isolate contaminated clothing and shoes. Wash off with warm water and
Skin contact
soap. Get medical attention if irritation develops or persists. For minor skin contact, avoid
spreading material on unaffected skin.
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Product #: 894 Water Based date: 30-DEC-2008 Print date: 30-DEC-2008
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Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth
Inhalation
method if victim inhaled the substance. Induce artificial respiration with the aid of a
pocket mask equipped with a one-way valve or other proper respiratory medical device.
Call a physician if symptoms develop or persist.
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Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally,
Ingestion
have victim lean forward to reduce risk of aspiration. Do not use mouth-to-mouth method
if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask
equipped with a one-way valve or other proper respiratory medical device.
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5. Fire Fighting Measures
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Containers may explode when heated. Vapor or gas may spread to distant ignition
Flammable properties
sources and flash back.
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Extinguishing media
Water fog. Alcohol foam. Dry chemical. Polymer foam. Dry chemical powder. Carbon
Suitable extinguishing media
dioxide (CO2).
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Protection of firefighters
Fire may produce irritating, corrosive and/or toxic gases.
Specific hazards arising from
the chemical
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In the event of fire and/or explosion do not breathe fumes. Wear full protective clothing,
Protective equipment and
including helmet, self-contained positive pressure or pressure demand breathing
precautions for firefighters
apparatus, protective clothing and face mask. Containers should be cooled with water to
prevent vapor pressure build up. For massive fire, use unmanned hose holders or
monitor nozzles; if this is impossible, withdraw from area and let fire burn.
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6. Accidental Release Measures
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Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Methods for containment
Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the
leak is irreparable.
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Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated
Methods for cleaning up
surface thoroughly.
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7. Handling and Storage
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Pressurized container: Do not pierce or burn, even after use. Do not handle or store near
Handling
an open flame, heat or other sources of ignition. Do not use if spray button is missing or
defective. Use only with adequate ventilation. Do not get this material in contact with
eyes. Do not breathe gas/fumes/vapor/spray. Avoid contact with skin. Wear personal
protective equipment. Avoid prolonged exposure.
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Level 2 Aerosol.
Storage
Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed
containers can increase under the influence of heat. Avoid exposure to long periods of
sunlight. Keep in an area equipped with sprinklers. Keep out of the reach of children.
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8. Exposure Controls / Personal Protection
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Exposure limits
ACGIH
Components CAS # TWA STEL Ceiling
Diethylene Glycol Monobutyl 112-34-5 20 ppm Not established Not established
Ether
Isobutane 75-28-5 1000 ppm Not established Not established
Propane 74-98-6 1000 ppm Not established Not established
Nitromethane 75-52-5 20 ppm Not established Not established
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OSHA
Components CAS # TWA STEL Ceiling
Diethylene Glycol Monobutyl 112-34-5 100 ppm Not established Not established
Ether
Propane 74-98-6 1000 ppm Not established Not established
Nitromethane 75-52-5 100 ppm Not established Not established
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Product #: 894 Water Based date: 30-DEC-2008 Print date: 30-DEC-2008
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Personal protective equipment
Wear chemical goggles.
Eye / face protection
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Protective gloves.
Skin protection
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When workers are facing concentrations above the exposure limit they must use
Respiratory protection
appropriate certified respirators.
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9. Physical & Chemical Properties
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Compressed liquefied gas.
Appearance
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176 癋 (80 癈) estimated
Boiling point
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Light yellow.
Color
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21.1363 kJ/g estimated
Flammability (HOC)
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No
Flash back
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-156 癋 (-104.4 癈) estimated
Flash point
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Aerosol.
Form
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Sweet.
Odor
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8.93 - 9.93
pH
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Liquid.
Physical state
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40 - 50 psig @ 70F
Pressure
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Partially
Solubility
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0.8905 estimated
Specific gravity
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10. Chemical Stability & Reactivity Information
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Risk of ignition.
Chemical stability
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Heat, flames and sparks.
Conditions to avoid
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Isocyanates.
Incompatible materials
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Hazardous decomposition products May include oxides of oxides of carbon.
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11. Toxicological Information
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Acute LD50: 5690 mg/kg estimated, Rat, Dermal
Acute effects
Acute LC50: 31 mg/l/4h estimated, Rat, Inhalation
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Not expected to be hazardous by OSHA criteria.
Sensitization
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Hazardous by OSHA criteria.
Carcinogenicity
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Not expected to be hazardous by OSHA criteria.
Reproductive effects
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Not expected to be hazardous by OSHA criteria.
Teratogenicity
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12. Ecological Information
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LC50 2195 mg/L estimated, Fish, 96.00 Hours,
Ecotoxicity
EC50 873 mg/L estimated, Daphnia, 48.00 Hours,
IC50 2119 mg/L estimated, Algae, 72.00 Hours,
Components of this product have been identified as having potential environmental
concerns.
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13. Disposal Considerations
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D001: Waste Flammable material with a flash point <140 F
Waste codes
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Contents under pressure. Do not allow this material to drain into sewers/water supplies. If
Disposal instructions
discarded, this product is considered a RCRA ignitable waste, D001. Dispose in
accordance with all applicable regulations.
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Product #: 894 Water Based date: 30-DEC-2008 Print date: 30-DEC-2008
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14. Transport Information
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Department of Transportation (DOT) Requirements
Basic shipping requirements:
Consumer commodity
Proper shipping name
ORM-D
Hazard class
None
Subsidiary hazard class
Additional information:
156, 306
Packaging exceptions
156, 306
Packaging non bulk
None
Packaging bulk
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IMDG
Basic shipping requirements:
AEROSOLS
Proper shipping name
2.1
Hazard class
1950
UN number
Additional information:
LTD QTY
Packaging exceptions
None
Labels required
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IATA
Basic shipping requirements:
Aerosols, flammable
Proper shipping name
2.1
Hazard class
1950
UN number
Additional information:
LTD QTY
Packaging exceptions
2.1
Labels required
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15. Regulatory Information
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This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
US federal regulations
Standard, 29 CFR 1910.1200.
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
Diethylene Glycol Monobutyl Ether 112-34-5 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3,
R=alkyl C7 or less, or R = phenyl or alkyl substituted phenyl, R' = H or alkyl C7 or
less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or
sulfonate, Chemical Category N230)
n-Methyl-2-Pyrrolidinone 872-50-4 1.0 % de minimis concentration
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Occupational Safety and Health Administration (OSHA)
Yes
29 CFR 1910.1200 hazardous
chemical
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CERCLA (Superfund) reportable quantity
None
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
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No
Section 302 extremely
hazardous substance
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Section 311 hazardous chemical Yes
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Product #: 894 Water Based date: 30-DEC-2008 Print date: 30-DEC-2008
Revision Multi-Purpose Adhesive Remover
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Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
China Inventory of Existing Chemical Substances in China (IECSC) No
Europe European Inventory of New and Existing Chemicals (EINECS) No
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
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WARNING: This product contains a chemical known to the State of California to cause
State regulations
birth defects or other reproductive harm.
U.S. - Pennsylvania - RTK (Right to Know) List
Diethylene Glycol Monobutyl Ether 112-34-5 Environmental hazard
Dimethyl Ether 115-10-6 Present
Isobutane 75-28-5 Present
Nitromethane 75-52-5 Present
n-Methyl-2-Pyrrolidinone 872-50-4 Present
Propane 74-98-6 Present
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16. Other Information
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Health: 1
HMIS?ratings
Flammability: 3
Physical hazard: 0
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The information provided in this Safety Data Sheet is correct to the best of our
Disclaimer
knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified
in the text.
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Hazards Identification: Emergency overview
MSDS sections updated
Handling and Storage: Storage
Physical & Chemical Properties: Physical & Chemical Properties
Transport Information: Product Shipping Name/Packing Group
Regulatory Information: United States
Regulatory Information: State regulations
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Product #: 894 Water Based date: 30-DEC-2008 Print date: 30-DEC-2008
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