MATERIAL SAFETY DATA SHEET
COATINGS AND RESINS GROUP
PPG Industries, Inc.
SECTION 1 - CHEMICAL, PRODUCT, AND COMPANY INFORMATION
PRODUCT CODE/IDENTITY: 90-474
REVISION DATE: 12/18/97 (000) 0814
CUSTOMER PART #/NAME: Not applicable
PRODUCT TRADE NAME: PITT-TECH SATIN ACRYLIC ENAMEL
CHEMICAL FAMILY: Acrylic
WHMIS HAZARD CLASS:
Class D, Division 2, Subdivision A Class D, Division 2, Subdivision B Class D,
Division 1, Subdivision B
EMERGENCY MEDICAL/SPILL INFO: (514) 645-1320 91-800-00-214 (MEXICO)
TECHNICAL INFORMATION: (404) 761-7771
PRODUCT SAFETY/MSDS INFORMATION: 4325 ROSANNA DRIVE, P.O. BOX 9 ALLISON PARK, PA
15101 (412) 492-5555
DATE OF MSDS PREPARATION: 01/16/98
PRIMARY HAZARD WARNING
May be harmful if swallowed. May cause slight skin irritation. Causes severe eye
irritation. Vapor and/or spray mist may be harmful if inhaled.
THIS MATERIAL SAFETY DATA SHEET HAS BEEN PREPARED IN ACCORDANCE WITH CANADA'S
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM.
SECTION 2 - HAZARDOUS INGREDIENTS
REF HAZARDOUS INGREDIENTS PERCENT CAS NUMBER CARCINOGEN*
--- ---------------------------------------- ------- --------------- -----------
01 TITANIUM DIOXIDE 10 - 30 13463-67-7
02 TALC 3 - 7 14807-96-6
03 DIETHYLENE GLYCOL MONOBUTYL ETHER 3 - 7 112-34-5
04 SILICA 1 - 5 7631-86-9
05 DIETHYLENE GLYCOL MONOMETHYL ETHER 1 - 5 111-77-3
06 ALUMINUM HYDROXIDE 0.5-1.5 21645-51-2
* Carcinogens: O=OSHA; A=ACGIH; N=NTP; I=IARC
OCCUPATIONAL EXPOSURE LIMITS HAVE BEEN ESTABLISHED FOR THE FOLLOWING MATERIALS:
ACGIH ONTARIO
REF TLV-TWA TLV-STEL PEL-TWA PEL-STEL
---- ---------------- ------------ ---------------- ------------
01 10 mg/m3 NOT ESTAB. 10 mg/m3 NOT ESTAB.
02 R- 2 mg/m3 NOT ESTAB. R- 2 mg/m3 NOT ESTAB.
03 NOT ESTAB. NOT ESTAB. NOT ESTAB. NOT ESTAB.
04 10 mg/m3 NOT ESTAB. C- 0.20 mg/m3 NOT ESTAB.
05 NOT ESTAB. NOT ESTAB. NOT ESTAB. NOT ESTAB.
05 IPEL-TWA: 25 ppm IPEL-STEL: 50 ppm
06 2 mg/m3 NOT ESTAB. NOT ESTAB. NOT ESTAB.
[C- Ceiling Limit; S- Potential Skin Absorption; R- Respirable Dust] [NOT ESTAB.
= NOT ESTABLISHED = NOT APPLICABLE]
Consult local authorities for acceptable provincial values.
SECTION 3 - TOXICOLOGICAL PROPERTIES
REF LD50 ORAL (rat) LD50 DERMAL (rabbit) LC50 INHALATION (rat)
---- ---------------- --------------------- -------------------------
01 Not available Not available Not available
02 Not available Not available Not available
03 6.56 g/kg 4.12 g/kg Not available
04 Not available Not available Not available
05 9.20 g/kg .65 g/kg Not available
06 Not available Not available Not available
THE FOLLOWING INFORMATION IS REQUIRED UNDER CANADA'S WORKPLACE HAZARDOUS
MATERIALS INFORMATION SYSTEM
REF ACUTE TOXICITY
---- ------------------------------------------------------------
01 NO SEVERE HAZARDS
02 NO SEVERE HAZARDS
03 EYE IRRITANT
04 NO SEVERE HAZARDS
05 Toxic via dermal exposure.
06 NO SEVERE HAZARDS
REF CHRONIC TOXICITY
---- ------------------------------------------------------------
01 CARCINOGEN/LUNG
02 CARCINOGEN/LUNG
03 KIDNEY/LIVER/SPLEEN
04 NO LONG-TERM EFFECTS IDENTIFIED
05 BONE MARROW/BLOOD/KIDNEY/LIVER
06 NO LONG-TERM EFFECTS IDENTIFIED
HAZARDS IDENTIFICATION
EFFECTS OF OVEREXPOSURE FROM:
INGESTION: May be harmful if swallowed.
EYE CONTACT: Causes severe eye irritation.
SKIN CONTACT: May cause slight skin irritation.
INHALATION: Vapor and/or spray mist may be harmful if inhaled.
CHRONIC OVEREXPOSURE: Avoid long-term and repeated contact. This product
contains an ethylene series glycol ether and/or acetate which has been shown to
cause adverse effects on the kidneys, liver, blood and/or blood-forming tissue.
This product contains titanium dioxide. Animals inhaling massive quantities of
titanium dioxide dust in a long-term study developed lung tumors. Studies with
humans involved in manufacture of this pigment indicate no increased risk of
cancer from exposure. Potential for inhalation of titanium dioxide dusts from
coatings is very limited. Since overexposures are not expected, there is no
significant hazard for man. This product contains diethylene glycol monobutyl
ether (DEGBE). DEGBE consumed in drinking water at low levels by rats for 30
days caused microscopic injury to either the liver, kidney, spleen, or testes.
Further studies on the reproductive effects of DEGBE have not produced evidence
of toxic effects in tissue culture or animal assays. This product contains talc.
In a lifetime inhalation study female rats exposed to an elevated respirable
concentration (9 times the Permissible Exposure Limit) of cosmetic grade talc
developed lung cancer. To date, no U.S. regulatory agency has classified talc as
a carcinogen based on this data.
SIGNS AND SYMPTOMS OF OVEREXPOSURE: Redness, itching, burning sensation and
visual disturbances may indicate excessive eye contact. Dryness, itching,
cracking, burning, redness, and swelling are conditions associated with
excessive skin contact.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not applicable.
TOXICOLOGICALLY SYNERGISTIC PRODUCTS: Not available
SECTION 4 - FIRST AID MEASURES
INGESTION: If swallowed, do not induce vomiting. Gently wipe out inside mouth to
remove any residual material.
EYE CONTACT: In case of eye contact, remove contact lenses and flush eyes
immediately with a gentle stream of luke warm water for at least 15 minutes.
SKIN CONTACT: In case of skin contact, flush immediately with plenty of water
for at least 15 minutes followed by washing with soap and water.
INHALATION: If affected by inhalation of vapor or spray mist, remove to fresh
air. Apply artificial respiration and other support measures as required.
OTHER: If ingestion, any type of overexposure or symptoms of overexposure occur
during or following the use of this product, contact a poison control center,
emergency room or physician immediately; have Material Safety Data Sheet
information available.
SECTION 5 - FIRE OR EXPLOSION DATA
FLASHPOINT: Not applicable
FLAMMABLE LIMITS: Lower explosion limit (LEL): Not available
Upper explosion limit (UEL): Not available
EXTINGUISHING MEDIA: Use extinguishers appropriate for surrounding fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep this product away from heat, sparks,
flame, and other sources of ignition (i.e., pilot lights, electric motors,
static electricity). Invisible vapors can travel to a source of ignition and
flash back. Do not smoke while using this product. Keep containers tightly
closed when not in use. Closed containers may explode when overheated. Do not
apply to hot surfaces. Toxic gases may form when this product comes in contact
with extreme heat.
SPECIAL FIRE FIGHTING PROCEDURES: Water spray may be ineffective. Water spray
may be used to cool closed containers to prevent pressure build-up and possible
autoignition or explosion when exposed to extreme heat. If water is used, fog
nozzles are preferable. Fire-fighters should wear self-contained breathing
apparatus and full protective clothing.
AUTOIGNITION TEMPERATURE: Not available
SECTION 6 - PREVENTIVE MEASURES
ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Provide maximum
ventilation. Only personnel equipped with proper respiratory, skin, and eye
protection should be permitted in the area. Remove all sources of ignition. Take
up spilled material with sand, vermiculite, or other noncombustible absorbent
material and place in clean, empty containers for disposal. Only the spilled
material and the absorbant should be placed in this container.
WASTE DISPOSAL METHOD: Waste material must be disposed of in accordance with
federal, state, provincial, and local environmental control regulations. Empty
containers should be recycled or disposed of through an approved waste
management facility.
HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS: Do not store above 120 degrees F. (48 degrees
C.).
OTHER PRECAUTIONS: Vapors may collect in low areas. If this material is part of
a multiple component system, read the Material Safety Data Sheet(s) for the
other component or components before blending as the resulting mixture may have
the hazards of all of its parts. Containers should be grounded when pouring.
Avoid free fall of liquids in excess of a few inches.
EXPOSURE CONTROLS AND PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT FOR:
EYE PROTECTION: Wear chemical-type splash goggles when possibility exists for
eye contact due to splashing or spraying liquid, airborne particles, or vapors.
SKIN PROTECTION: Wear protective clothing. Gloves should be constructed of:
impermeable material. No specific permeation/degradation testing have been done
on protective clothing for this product. Recommendations for skin protection are
based on infrequent contact with this product. For frequent contact or total
immersion, contact a manufacturer of protective clothing for appropriate
chemical impervious equipment.
RESPIRATORY PROTECTION: Where ventilation is inadequate, use a NIOSH- approved
air purifying respirator with the appropriate chemical cartridges or positive-
pressure, air-supplied respirator. Read the respirator manufacturer's
instructions and literature carefully to determine the type of airborne
contaminants against which the respirator is effective, its limitations, and how
it is to be properly fitted and used.
OTHER EQUIPMENT: Clean contaminated clothing and shoes.
VENTILATION REQUIREMENTS: Provide general dilution or local exhaust ventilation
in volume and pattern to keep the concentration of ingredients listed in Section
2 below the lowest suggested exposure limits, the LEL below the stated limit,
and to remove decomposition products during welding or flame cutting.
SECTION 7 - PHYSICAL AND CHEMICAL PROPERTIES
[FORMULA VALUES, NOT SALES SPECIFICATIONS]
BOILING RANGE: 212 - 475Degrees F
SOLUBILITY IN WATER: 69.8 %
VAPOR PRESSURE: 17.6 mmHg
WEIGHT/GALLON (LBS): 12.1 (IMPERIAL)
VAPOR DENSITY: Heavier than air
pH: Not applicable
% VOLATILE/VOLUME: 62.570
% SOLIDS BY WEIGHT: 48.66
SPECIFIC GRAVITY: 1.214
EVAPORATION RATE(BuOAc=100): 32
PHYSICAL STATE: LIQUID
FREEZING POINT: Not available
ODOR THRESHHOLD: Not available
COEFFICIENT OF OIL/WATER DISTRIBUTION: Not available
ODOR/APPEARANCE: Viscous liquid with an odor characteristic of the solvents
listed in Section 2.
SECTION 8 - STABILITY AND REACTIVITY DATA
This product is normally stable and will not undergo hazardous reactions.
INCOMPATIBILITY (MATERIALS AND CONDITIONS TO AVOID): Avoid contact with strong
alkalies, strong mineral acids, or strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: May produce the following hazardous
decomposition products when exposed to extreme heat: carbon monoxide ; carbon
dioxide ; oxides of aluminum ; lower molecular weight polymer fractions; Extreme
heat includes, but is not limited to, flame cutting, brazing, and welding.
SECTION 9 - PREPARATION INFORMATION PREPARED BY: Product Safety Department PHONE
NUMBER: (412)492-5555 DATE OF MSDS PREPARATION: 01/16/98
Hazardous Materials Identification System (HMIS) and National Fire Protection
Association (NFPA) Ratings:
HMIS Rating NFPA Rating
-------------------- --------------------
HEALTH 2* HEALTH 2
FLAMMABILITY 2 FLAMMABILITY 2
REACTIVITY 0 INSTABILITY 0
Rating System:0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe, *=Chronic
Effects.
Safe handling of this product requires that all of the information on the MSDS
be evaluated for specific work environments and conditions of use.
THIS IS THE END OF THE MSDS FOR: 90-474 (00097346.00190-474 )
Manufactured and Supplied by:
PPG INDUSTRIES, EAST POINT
1377 OAKLEIGH DRIVE
EAST POINT, GA 30304
A^
|