Material Name (Product Name): SILICONE OIL; File: pd1326482.pdf; Product URL: http://full.chemwatch.net/msdscoll/showDoc?filename=pd998602.pdf
Folder Name : Supplier MSDS'; Document Id : 1326482; Product Id : 64365
Update of Id (Changed Document Id) : 998602
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Changed: OLD Line 0 : Revised 2/26/04 SILICONE OIL
NEW Line 0 : Revised 8/11/03 SILICONE OIL
Changed: OLD Line 0 : SILICONE OIL Replaces 11/17/03 INVITROGEN CORPORATION
NEW Line 0 : SILICONE OIL Replaces (None) INVITROGEN CORPORATION
Changed: OLD Line 0 : INVITROGEN CORPORATION Printed 2/26/04 MSDS ID: 10890
NEW Line 0 : INVITROGEN CORPORATION Printed 8/11/03 MSDS ID: 10890
Changed: OLD Line 0 : INVITROGEN CORPORATION INVITROGEN AUSTRALIA PTY LIMITED
NEW Line 0 : INVITROGEN CORPORATION
Changed: OLD Line 0 : 2270 INDUSTRIAL ST. 2A/14 LIONEL ROAD BURLINGTON, ONT MOUNT WAVERLY VIC 3149
NEW Line 0 : 2270 INDUSTRIAL ST. BURLINGTON, ONT
Changed: OLD Line 0 : CANADA L7P 1A1 AUSTRALIA 905/335-2255 1-800-331-627
NEW Line 0 : CANADA L7P 1A1 905/335-2255
Changed: OLD Line 0 : human or animal diagnostics, therapeutic, or other clinical uses.
NEW Line 0 : human or animal diagnostics, therpeutic, or other clinical uses.
Changed: OLD Line 0 : Revised 2/26/04 SILICONE OIL
NEW Line 0 : Revised 8/11/03 SILICONE OIL
Changed: OLD Line 0 : SILICONE OIL Replaces 11/17/03 INVITROGEN CORPORATION
NEW Line 0 : SILICONE OIL Replaces (None) INVITROGEN CORPORATION
Changed: OLD Line 0 : INVITROGEN CORPORATION Printed 2/26/04 MSDS ID: 10890
NEW Line 0 : INVITROGEN CORPORATION Printed 8/11/03 MSDS ID: 10890
Changed: OLD Line 0 : Ingestion: Mildly irritating to mouth, throat, and stomach. Can cause abdominal
NEW Line 0 : Ingestion: May cause nausea or vomiting.
Changed: OLD Line 0 : discomfort.
NEW Line 0 : Chronic:
Changed: OLD Line 0 : Chronic: No data on cancer.
NEW Line 0 : No data on cancer.
NEW Line 0 : ______________________________________________________________________________ 4. FIRST AID MEASURES
Deleted: OLD Line 0 : 4. FIRST AID MEASURES
Changed: OLD Line 0 : Revised 2/26/04 SILICONE OIL
NEW Line 0 : Revised 8/11/03 SILICONE OIL
Changed: OLD Line 0 : SILICONE OIL Replaces 11/17/03 INVITROGEN CORPORATION
NEW Line 0 : SILICONE OIL Replaces (None) INVITROGEN CORPORATION
Changed: OLD Line 0 : INVITROGEN CORPORATION Printed 2/26/04 MSDS ID: 10890
NEW Line 0 : INVITROGEN CORPORATION Printed 8/11/03 MSDS ID: 10890
Changed: OLD Line 0 : Revised 2/26/04 SILICONE OIL
NEW Line 0 : Revised 8/11/03 SILICONE OIL
Changed: OLD Line 0 : SILICONE OIL Replaces 11/17/03 INVITROGEN CORPORATION
NEW Line 0 : SILICONE OIL Replaces (None) INVITROGEN CORPORATION
Changed: OLD Line 0 : INVITROGEN CORPORATION Printed 2/26/04 MSDS ID: 10890
NEW Line 0 : INVITROGEN CORPORATION Printed 8/11/03 MSDS ID: 10890
Changed: OLD Line 0 : Not established. Octanol/water Partition Coeff: Not established.
NEW Line 0 : Specific Gravity/Density: Not established. Octanol/water Partition Coeff: Not established.
Changed: OLD Line 0 : Volatiles: Not established. Not established.
NEW Line 0 : Volatiles: Not established. Evaporation Rate: Not established.
Changed: OLD Line 0 : Not established.
NEW Line 0 : Viscosity: Not established.
Changed: OLD Line 0 : Revised 2/26/04 SILICONE OIL
NEW Line 0 : Revised 8/11/03 SILICONE OIL
Changed: OLD Line 0 : SILICONE OIL Replaces 11/17/03 INVITROGEN CORPORATION
NEW Line 0 : SILICONE OIL Replaces (None) INVITROGEN CORPORATION
Changed: OLD Line 0 : INVITROGEN CORPORATION Printed 2/26/04 MSDS ID: 10890
NEW Line 0 : INVITROGEN CORPORATION Printed 8/11/03 MSDS ID: 10890
Changed: OLD Line 0 : Revised 2/26/04 SILICONE OIL
NEW Line 0 : Revised 8/11/03 SILICONE OIL
Changed: OLD Line 0 : SILICONE OIL Replaces 11/17/03 INVITROGEN CORPORATION
NEW Line 0 : SILICONE OIL Replaces (None) INVITROGEN CORPORATION
Changed: OLD Line 0 : INVITROGEN CORPORATION Printed 2/26/04 MSDS ID: 10890
NEW Line 0 : INVITROGEN CORPORATION Printed 8/11/03 MSDS ID: 10890
Changed: OLD Line 0 : Revised 2/26/04 SILICONE OIL
NEW Line 0 : Revised 8/11/03 SILICONE OIL
Changed: OLD Line 0 : SILICONE OIL Replaces 11/17/03 INVITROGEN CORPORATION
NEW Line 0 : SILICONE OIL Replaces (None) INVITROGEN CORPORATION
Changed: OLD Line 0 : INVITROGEN CORPORATION Printed 2/26/04 MSDS ID: 10890
NEW Line 0 : INVITROGEN CORPORATION Printed 8/11/03 MSDS ID: 10890
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Material Name (Product Name): ROCOL OPEN GEAR SPRAY; File: pd1947391.pdf; Product URL: http://full.chemwatch.net/msdscoll/showDoc?filename=pd1432246.pdf
Folder Name : Supplier MSDS'; Document Id : 1947391; Product Id : 21448
Update of Id (Changed Document Id) : 1432246
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Changed: OLD Line 0 : ChemWatch Material Safety Data Sheet CHEMWATCH 21448
NEW Line 0 : ChemWatch Material Safety Data Sheet (REVIEW) CHEMWATCH 21448
Changed: OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 1 of 15
NEW Line 0 : Issue Date: Thu 15-Nov-2001 CD 2002/3 Page 1 of 10
Changed: OLD Line 0 : Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
NEW Line 0 : IDENTIFICATION
Changed: OLD Line 0 : PRODUCT NAME
NEW Line 0 : STATEMENT OF HAZARDOUS NATURE
Changed: OLD Line 0 : ROCOL OPEN GEAR SPRAY
OLD Line 0 : SYNONYMS
OLD Line 0 : bitumen spray
OLD Line 0 : PROPER SHIPPING NAME
OLD Line 0 : AEROSOLS
OLD Line 0 : PRODUCT USE
OLD Line 0 : Open gear lubricant. Application is by spray atomisation from a hand held aerosol pack
NEW Line 0 : HAZARDOUS ACCORDING TO WORKSAFE AUSTRALIA CRITERIA.
Changed: OLD Line 0 : Company: ITW Polymers And Fluids Pty Ltd
NEW Line 0 : Company: ITW Polymers and Fluids Pty Ltd Company: ITW Polymers and Fluids Pty Ltd
Changed: OLD Line 0 : Address:
NEW Line 0 : Address: Address:
Changed: OLD Line 0 : 100 Hassall Street
NEW Line 0 : 100 Hassall Street Private Bag 35
Changed: OLD Line 0 : Wetherill Park
NEW Line 0 : Wetherill Park Wetherill Park
Changed: OLD Line 0 : NSW, 2164
NEW Line 0 : NSW NSW
Changed: OLD Line 0 : AUSTRALIA
NEW Line 0 : Australia Australia
Changed: OLD Line 0 : Fax: 02 9757 3855
NEW Line 0 : Fax: (+61 2) 9757 3855
Changed: OLD Line 0 : HAZARD RATINGS
NEW Line 0 : CHEMWATCH HAZARD RATINGS
Changed: OLD Line 0 : Flammability
NEW Line 0 : Flammability:
Changed: OLD Line 0 : Toxicity
NEW Line 0 : Toxicity:
Changed: OLD Line 0 : Body Contact
NEW Line 0 : Body Contact:
Changed: OLD Line 0 : Reactivity
NEW Line 0 : Reactivity:
Changed: OLD Line 0 : Chronic
NEW Line 0 : Chronic:
Changed: OLD Line 0 : Section 2 - HAZARDS IDENTIFICATION
NEW Line 0 : PERSONAL PROTECTIVE EQUIPMENT FOR INDUSTRIAL/COMMERCIAL ENVIRONMENTS
Changed: OLD Line 0 : STATEMENT OF HAZARDOUS NATURE
NEW Line 0 : Product Name: Rocol Open Gear Spray
Changed: OLD Line 0 : HAZARDOUS SUBSTANCE. DANGEROUS GOODS.
NEW Line 0 : CAS RN No(s): None
Changed: OLD Line 0 : According to the Criteria of NOHSC, and the ADG Code.
NEW Line 0 : UN Number: 1950
Changed: OLD Line 0 : POISONS SCHEDULE
NEW Line 0 : Packing Group: None
Changed: OLD Line 0 : None
NEW Line 0 : Dangerous Goods Class: 2.1
Changed: OLD Line 0 : RISK
NEW Line 0 : Subsidiary Risk: None
Changed: OLD Line 0 : Extremely flammable.
NEW Line 0 : Hazchem Code: 2Y
Changed: OLD Line 0 : Danger of cumulative effects.
OLD Line 0 : Irritating to skin.
OLD Line 0 : Risk of explosion if heated under confinement.
OLD Line 0 : Harmful: danger of serious damage to health by prolonged exposure through
OLD Line 0 : inhalation.
OLD Line 0 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
OLD Line 0 : environment.
OLD Line 0 : Possible risk of impaired fertility.
NEW Line 0 : Poisons Schedule Number: None
Changed: OLD Line 0 : ChemWatch Material Safety Data Sheet CHEMWATCH 21448
NEW Line 0 : ChemWatch Material Safety Data Sheet (REVIEW) CHEMWATCH 21448
Changed: OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 2 of 15
NEW Line 0 : Issue Date: Thu 15-Nov-2001 CD 2002/3 Page 2 of 10
Changed: OLD Line 0 : Section 2 - HAZARDS IDENTIFICATION
NEW Line 0 : IDENTIFICATION ...
Changed: OLD Line 0 : SAFETY
NEW Line 0 : USE
Changed: OLD Line 0 : Keep container in a well ventilated place.
NEW Line 0 : Open gear lubricant.
Changed: OLD Line 0 : Avoid exposure - obtain special instructions before use.
NEW Line 0 : Application is by spray atomisation from a hand held aerosol pack
Changed: OLD Line 0 : To clean the floor and all objects contaminated by this material, use water and
NEW Line 0 : PHYSICAL DESCRIPTION/PROPERTIES
Changed: OLD Line 0 : detergent.
NEW Line 0 : APPEARANCE
Changed: OLD Line 0 : Keep container tightly closed.
NEW Line 0 : Dark bitumastic material with solvent odour; does not mix with water.
Changed: OLD Line 0 : Keep away from food, drink and animal feeding stuffs.
NEW Line 0 : Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable
Changed: OLD Line 0 : Take off immediately all contaminated clothing.
NEW Line 0 : hydrocarbon propellant.
Changed: OLD Line 0 : In case of contact with eyes, rinse with plenty of water and contact Doctor or
NEW Line 0 : Boiling Point (癈): Not available.
Changed: OLD Line 0 : Poisons Information Centre.
NEW Line 0 : Melting Point (癈): Not available.
Changed: OLD Line 0 : If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (show
NEW Line 0 : Vapour Pressure (kPa): Not available.
Changed: OLD Line 0 : this container or label).
NEW Line 0 : Specific Gravity: Not available.
Changed: OLD Line 0 : If you feel unwell contact Doctor or Poisons Information Centre. (Show the label
NEW Line 0 : Flash Point (癈): -81 propellant
Changed: OLD Line 0 : if possible).
NEW Line 0 : Lower Explosive Limit (%): Not available
Changed: OLD Line 0 : Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NEW Line 0 : Upper Explosive Limit (%): Not available
NEW Line 0 : Solubility in Water (g/L): Immiscible
NEW Line 0 : INGREDIENTS
Changed: OLD Line 0 : Section 4 - FIRST AID MEASURES
NEW Line 0 : HEALTH HAZARD
NEW Line 0 : ACUTE HEALTH EFFECTS
Changed: OLD Line 0 : Not considered a normal route of entry.
NEW Line 0 : The liquid is discomforting to the gastro-intestinal tract and may be harmful
Changed: OLD Line 0 : If spontaneous vomiting appears imminent or occurs, hold patient's head down,
NEW Line 0 : if swallowed
Changed: OLD Line 0 : lower than their hips to help avoid possible aspiration of vomitus.
NEW Line 0 : Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by
Changed: OLD Line 0 : x If swallowed do NOT induce vomiting.
NEW Line 0 : aspiration may cause potentially lethal chemical pneumonitis.
Changed: OLD Line 0 : x x If vomiting occurs, lean patient forward or place on left side (head-down
OLD Line 0 : position, if possible) to maintain open airway and prevent aspiration.
OLD Line 0 : x x Observe the patient carefully.
OLD Line 0 : x x Never give liquid to a person showing signs of being sleepy or with reduced
OLD Line 0 : awareness; i.e. becoming unconscious.
OLD Line 0 : x x Give water to rinse out mouth, then provide liquid slowly and as much as
OLD Line 0 : casualty can comfortably drink.
OLD Line 0 : x x Seek medical advice.
OLD Line 0 : Avoid giving milk or oils.
OLD Line 0 : Avoid giving alcohol.
NEW Line 0 : Considered an unlikely route of entry in commercial/industrial environments
Changed: OLD Line 0 : If aerosols come in contact with the eyes:
NEW Line 0 : The mist is discomforting to the eyes
Changed: OLD Line 0 : x x Immediately hold the eyelids apart and flush the eye continuously for at least
NEW Line 0 : The material may be irritating to the eye, with prolonged contact causing
Changed: OLD Line 0 : 15 minutes with fresh running water.
NEW Line 0 : inflammation. Repeated or prolonged exposure to irritants may produce
Changed: OLD Line 0 : x x Ensure complete irrigation of the eye by keeping eyelids apart and away from
OLD Line 0 : eye and moving the eyelids by occasionally lifting the upper and lower lids.
OLD Line 0 : x x Transport to hospital or doctor without delay.
OLD Line 0 : x x Removal of contact lenses after an eye injury should only be undertaken by
OLD Line 0 : skilled personnel.
NEW Line 0 : conjunctivitis.
Changed: OLD Line 0 : If solids or aerosol mists are deposited upon the skin:
NEW Line 0 : The liquid is discomforting to the skin if exposure is prolonged and may cause
Changed: OLD Line 0 : x x Flush skin and hair with running water (and soap if available).
NEW Line 0 : drying of the skin, which may lead to dermatitis
Changed: OLD Line 0 : x x Remove any adhering solids with industrial skin cleansing cream.
NEW Line 0 : Toxic effects may result from skin absorption
NEW Line 0 : The material may accentuate any pre-existing skin condition
Changed: OLD Line 0 : ChemWatch Material Safety Data Sheet CHEMWATCH 21448
NEW Line 0 : ChemWatch Material Safety Data Sheet (REVIEW) CHEMWATCH 21448
Changed: OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 3 of 15
NEW Line 0 : Issue Date: Thu 15-Nov-2001 CD 2002/3 Page 3 of 10
Changed: OLD Line 0 : Section 4 - FIRST AID MEASURES
OLD Line 0 : x DO NOT use solvents.
OLD Line 0 : x x Seek medical attention in the event of irritation.
NEW Line 0 : HEALTH HAZARD ...
Changed: OLD Line 0 : If aerosols, fumes or combustion products are inhaled:
NEW Line 0 : The vapour/mist is discomforting to the upper respiratory tract
Changed: OLD Line 0 : x x Remove to fresh air.
NEW Line 0 : Inhalation hazard is increased at higher temperatures.
Changed: OLD Line 0 : x x Lay patient down. Keep warm and rested.
NEW Line 0 : Inhalation of high concentrations of gas/vapour causes lung irritation with
Changed: OLD Line 0 : x x Prostheses such as false teeth, which may block airway, should be removed,
NEW Line 0 : coughing and nausea, central nervous depression with headache and dizziness,
Changed: OLD Line 0 : where possible, prior to initiating first aid procedures.
NEW Line 0 : slowing of reflexes, fatigue and inco-ordination.
Changed: OLD Line 0 : x x If breathing is shallow or has stopped, ensure clear airway and apply
NEW Line 0 : WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
NEW Line 0 : CHRONIC HEALTH EFFECTS
NEW Line 0 : Principal routes of exposure are by skin contact/absorption and inhalation
NEW Line 0 : of mist/vapours.
NEW Line 0 : Chronic solvent inhalation exposures may result in nervous system impairment
NEW Line 0 : and liver and blood changes. [PATTYS]
NEW Line 0 : Chronic inhalation exposures may show indications of peripheral neuropathy, a
NEW Line 0 : progressive nerve disorder of extremities.
NEW Line 0 : Prolonged or continuous skin contact with the liquid may cause defatting with
NEW Line 0 : drying, cracking, irritation and dermatitis following.
NEW Line 0 : Prolonged contact may cause skin photosensitisation reaction.
NEW Line 0 : WARNING: Aerosol containers may present pressure related hazards.
NEW Line 0 : FIRST AID
NEW Line 0 : SWALLOWED
NEW Line 0 : If poisoning occurs, contact a doctor or Poisons Information Centre.
NEW Line 0 : If swallowed, DO NOT induce vomiting. Give a glass of water.
NEW Line 0 : EYE
NEW Line 0 : If this product comes in contact with the eyes:
NEW Line 0 : Immediately hold the eyes open and wash continuously for at least 15 minutes
NEW Line 0 : with fresh running water.
NEW Line 0 : Ensure complete irrigation of the eye by keeping eyelids apart and away from
NEW Line 0 : eye and moving the eyelids by occasionally lifting the upper and lower lids.
NEW Line 0 : Transport to hospital or doctor without delay.
NEW Line 0 : Removal of contact lenses after an eye injury should only be undertaken by
NEW Line 0 : skilled personnel.
NEW Line 0 : SKIN
NEW Line 0 : If product comes in contact with the skin:
NEW Line 0 : Immediately remove all contaminated clothing, including footwear
NEW Line 0 : Wash affected areas thoroughly with water (and soap if available).
NEW Line 0 : Seek medical attention in event of irritation.
NEW Line 0 : INHALED
NEW Line 0 : If fumes or combustion products are inhaled: Remove to fresh air.
NEW Line 0 : Lay patient down. Keep warm and rested.
NEW Line 0 : Prostheses such as false teeth, which may block airway, should be removed,
NEW Line 0 : where possible, prior to initiating first aid procedures
NEW Line 0 : If breathing is shallow or has stopped, ensure clear airway and apply
Deleted: OLD Line 0 : x x Transport to hospital, or doctor.
Deleted: OLD Line 0 : NOTES TO PHYSICIAN
Deleted: OLD Line 0 : Treat symptomatically.
Deleted: OLD Line 0 : Following acute or short term repeated exposures to n-hexane:
Deleted: OLD Line 0 : x x Large quantities of n-hexane are expired by the lungs after vapour exposure
Deleted: OLD Line 0 : (50-60%). Humans exposed to 100 ppm demonstrate an n-hexane biological half life
Deleted: OLD Line 0 : of 2 hours.
Deleted: OLD Line 0 : x x Initial attention should be directed towards evaluation and support of
Deleted: OLD Line 0 : respiration. Cardiac dysrhythmias are a potential complication.
Deleted: OLD Line 0 : INGESTION:
Deleted: OLD Line 0 : x x Ipecac syrup should be considered for ingestion of pure hexane exceeding
Deleted: OLD Line 0 : 2-3ml/kg. Extreme caution must be taken to avoid aspiration since small amounts
Deleted: OLD Line 0 : of n-hexane intratracheally, produce a severe chemical pneumonitis.
Deleted: OLD Line 0 : [Ellenhorn and Barceloux: Medical Toxicology]
Deleted: OLD Line 0 : BIOLOGICAL EXPOSURE INDEX - BEI
Deleted: OLD Line 0 : BEIs represent the levels of determinants which are most likely to be observed
Deleted: OLD Line 0 : in specimens collected in a healthy worker who has been exposed to chemicals to
Deleted: OLD Line 0 : the same extent as a worker with inhalation exposure to the Exposure Standard
Deleted: OLD Line 0 : (ES or TLV).
Deleted: OLD Line 0 : Determinant Index Sampling Time Comments
Deleted: OLD Line 0 : 1. 2,5-hexanedione 5 mg/gm creatinine End of shift NS
Deleted: OLD Line 0 : in urine
Deleted: OLD Line 0 : 2. n-Hexane in SQ
Deleted: OLD Line 0 : end-exhaled air
Deleted: OLD Line 0 : NS: Non-specific determinant; Metabolite observed following exposure to other
Deleted: OLD Line 0 : materials.
Deleted: OLD Line 0 : SQ: Semi-quantitative determinant; Interpretation may be ambiguous - should be
Deleted: OLD Line 0 : used as a screening test or confirmatory test.
Deleted: OLD Line 0 : Section 5 - FIRE FIGHTING MEASURES
Deleted: OLD Line 0 : EXTINGUISHING MEDIA
Deleted: OLD Line 0 : SMALL FIRE:
Deleted: OLD Line 0 : x x Water spray, dry chemical or CO2
Deleted: OLD Line 0 : LARGE FIRE:
Deleted: OLD Line 0 : x x Water spray or fog.
Deleted: OLD Line 0 : FIRE FIGHTING
Deleted: OLD Line 0 : x x Alert Fire Brigade and tell them location and nature of hazard.
Deleted: OLD Line 0 : x x May be violently or explosively reactive.
Deleted: OLD Line 0 : x x Wear breathing apparatus plus protective gloves.
Deleted: OLD Line 0 : continued...
Deleted: OLD Line 0 : ROCOL OPEN GEAR SPRAY
Deleted: OLD Line 0 : ChemWatch Material Safety Data Sheet CHEMWATCH 21448
Deleted: OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 4 of 15
Deleted: OLD Line 0 : Section 5 - FIRE FIGHTING MEASURES
Deleted: OLD Line 0 : x Prevent, by any means available, spillage from entering drains or water
Deleted: OLD Line 0 : course.
Deleted: OLD Line 0 : x x If safe, switch off electrical equipment until vapour fire hazard removed.
Deleted: OLD Line 0 : x x Use water delivered as a fine spray to control fire and cool adjacent area.
Deleted: OLD Line 0 : x x DO NOT approach containers suspected to be hot.
Deleted: OLD Line 0 : x x Cool fire exposed containers with water spray from a protected location.
Deleted: OLD Line 0 : x x If safe to do so, remove containers from path of fire.
Deleted: OLD Line 0 : x x Equipment should be thoroughly decontaminated after use.
Deleted: OLD Line 0 : When any large container (including road and rail tankers) is involved in a fire,
Deleted: OLD Line 0 : consider evacuation by 100 metres in all directions.
Deleted: OLD Line 0 : FIRE/EXPLOSION HAZARD
Deleted: OLD Line 0 : x x Liquid and vapour are flammable.
Deleted: OLD Line 0 : x x Moderate fire hazard when exposed to heat or flame.
Deleted: OLD Line 0 : x x Vapour forms an explosive mixture with air.
Deleted: OLD Line 0 : x x Moderate explosion hazard when exposed to heat or flame.
Deleted: OLD Line 0 : x x Vapour may travel a considerable distance to source of ignition.
Deleted: OLD Line 0 : x x Heating may cause expansion or decomposition leading to violent rupture of
Deleted: OLD Line 0 : containers.
Deleted: OLD Line 0 : x x Aerosol cans may explode on exposure to naked flame.
Deleted: OLD Line 0 : x x Rupturing containers may rocket and scatter burning materials.
Deleted: OLD Line 0 : x x Hazards may not be restricted to pressure effects.
Deleted: OLD Line 0 : x x May emit acrid, poisonous or corrosive fumes.
Deleted: OLD Line 0 : x x On combustion, may emit toxic fumes of carbon monoxide (CO).
Deleted: OLD Line 0 : Combustion products include , carbon dioxide (CO2) , other pyrolysis products
Deleted: OLD Line 0 : typical of burning organic material
Deleted: OLD Line 0 : FIRE INCOMPATIBILITY
Deleted: OLD Line 0 : Avoid contamination with oxidising agents i.e. nitrates, oxidising acids,
Deleted: OLD Line 0 : chlorine bleaches, pool chlorine etc. as ignition may result
Deleted: OLD Line 0 : HAZCHEM
Deleted: OLD Line 0 : 2Y
Deleted: OLD Line 0 : Personal Protective Equipment
Deleted: OLD Line 0 : PERSONAL PROTECTION EQUIPMENT
Deleted: OLD Line 0 : Breathing apparatus.
Deleted: OLD Line 0 : Gas tight chemical resistant suit.
Deleted: OLD Line 0 : Limit exposure duration to 1 BA set - 30 mins.
Deleted: OLD Line 0 : Section 6 - ACCIDENTAL RELEASE MEASURES
Deleted: OLD Line 0 : EMERGENCY PROCEDURES
Deleted: OLD Line 0 : MINOR SPILLS
Deleted: OLD Line 0 : x x Clean up all spills immediately.
Deleted: OLD Line 0 : x x Avoid breathing vapours and contact with skin and eyes.
Deleted: OLD Line 0 : x x Wear protective clothing, impervious gloves and safety glasses.
Deleted: OLD Line 0 : x x Shut off all possible sources of ignition and increase ventilation.
Deleted: OLD Line 0 : x x Wipe up.
Deleted: OLD Line 0 : x x If safe, damaged cans should be placed in a container outdoors, away from all
Deleted: OLD Line 0 : ignition sources, until pressure has dissipated.
Deleted: OLD Line 0 : x x Undamaged cans should be gathered and stowed safely.
Deleted: OLD Line 0 : x x Clean up all spills immediately.
Deleted: OLD Line 0 : x x Avoid breathing vapours and contact with skin and eyes.
Deleted: OLD Line 0 : x x Control personal contact by using protective equipment.
Deleted: OLD Line 0 : x x Contain and absorb spill with sand, earth, inert material or vermiculite.
Deleted: OLD Line 0 : x x Wipe up.
Deleted: OLD Line 0 : continued...
Deleted: OLD Line 0 : ROCOL OPEN GEAR SPRAY
Deleted: OLD Line 0 : ChemWatch Material Safety Data Sheet CHEMWATCH 21448
Deleted: OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 5 of 15
Deleted: OLD Line 0 : Section 6 - ACCIDENTAL RELEASE MEASURES
Deleted: OLD Line 0 : x Place in a suitable labelled container for waste disposal.
Deleted: OLD Line 0 : MAJOR SPILLS
Deleted: OLD Line 0 : x x Clear area of personnel and move upwind.
Deleted: OLD Line 0 : x x Alert Fire Brigade and tell them location and nature of hazard.
Deleted: OLD Line 0 : x x May be violently or explosively reactive.
Deleted: OLD Line 0 : x x Wear breathing apparatus plus protective gloves.
Deleted: OLD Line 0 : x x Prevent, by any means available, spillage from entering drains or water
Deleted: OLD Line 0 : courses
Deleted: OLD Line 0 : x x No smoking, naked lights or ignition sources.
Deleted: OLD Line 0 : x x Increase ventilation.
Deleted: OLD Line 0 : x x Stop leak if safe to do so.
Deleted: OLD Line 0 : x x Water spray or fog may be used to disperse / absorb vapour.
Deleted: OLD Line 0 : x x Absorb or cover spill with sand, earth, inert materials or vermiculite.
Deleted: OLD Line 0 : x x If safe, damaged cans should be placed in a container outdoors, away from
Deleted: OLD Line 0 : ignition sources, until pressure has dissipated.
Deleted: OLD Line 0 : x x Undamaged cans should be gathered and stowed safely.
Deleted: OLD Line 0 : x x Collect residues and seal in labelled drums for disposal.
Deleted: OLD Line 0 : PROTECTIVE ACTIONS FOR SPILL
Deleted: OLD Line 0 : down wind distanceisolation
Deleted: OLD Line 0 : distance
Deleted: OLD Line 0 : PROTECTIVE ACTION ZONE
Deleted: OLD Line 0 : evacuation
Deleted: OLD Line 0 : direction
Deleted: OLD Line 0 : evacuation
Deleted: OLD Line 0 : direction
Deleted: OLD Line 0 : half
Deleted: OLD Line 0 : downwind
Deleted: OLD Line 0 : distance
Deleted: OLD Line 0 : half
Deleted: OLD Line 0 : downwind
Deleted: OLD Line 0 : distanceINITIALISOLATION
Deleted: OLD Line 0 : ZONE
Deleted: OLD Line 0 : wind
Deleted: OLD Line 0 : direction
Deleted: OLD Line 0 : From IERG (Canada/Australia)
Deleted: OLD Line 0 : Isolation Distance -
Deleted: OLD Line 0 : Downwind Protection Distance 8 metres
Deleted: OLD Line 0 : IERG Number 49
Deleted: OLD Line 0 : FOOTNOTES
Deleted: OLD Line 0 : 1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk
Deleted: OLD Line 0 : of harmful exposure. This zone assumes that random changes in wind direction
Deleted: OLD Line 0 : confines the vapour plume to an area within 30 degrees on either side of the
Deleted: OLD Line 0 : predominant wind direction, resulting in a crosswind protective action distance
Deleted: OLD Line 0 : equal to the downwind protective action distance.
Deleted: OLD Line 0 : 2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with
Deleted: OLD Line 0 : those closest to the spill and working away from the site in the downwind
Deleted: OLD Line 0 : direction. Within the protective action zone a level of vapour concentration
Deleted: OLD Line 0 : may exist resulting in nearly all unprotected persons becoming incapacitated
Deleted: OLD Line 0 : and unable to take protective action and/or incurring serious or irreversible
Deleted: OLD Line 0 : health effects.
Deleted: OLD Line 0 : 3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the
Deleted: OLD Line 0 : incident, within which a high probability of localised wind reversal may
Deleted: OLD Line 0 : expose nearly all persons without appropriate protection to life-threatening
Deleted: OLD Line 0 : concentrations of the material.
Deleted: OLD Line 0 : 4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less,
Deleted: OLD Line 0 : such as a drum (jerrican or box with inner containers). Larger packages leaking
Deleted: OLD Line 0 : less than 200 litres and compressed gas leaking from a small cylinder are also
Deleted: OLD Line 0 : considered "small spills".
Deleted: OLD Line 0 : LARGE SPILLS involve many small leaking packages or a leaking package of
Deleted: OLD Line 0 : continued...
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Deleted: OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 6 of 15
Deleted: OLD Line 0 : Section 6 - ACCIDENTAL RELEASE MEASURES
Deleted: OLD Line 0 : greater than 200 litres, such as a cargo tank, portable tank or a "one-tonne"
Deleted: OLD Line 0 : compressed gas cylinder.
Deleted: OLD Line 0 : 5 Guide 126 is taken from the US DOT emergency response guide book.
Deleted: OLD Line 0 : 6 IERG information is derived from CANUTEC - Transport Canada.
Deleted: OLD Line 0 : Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Deleted: OLD Line 0 : Section 7 - HANDLING AND STORAGE
Deleted: OLD Line 0 : PROCEDURE FOR HANDLING
Deleted: OLD Line 0 : x Avoid all personal contact, including inhalation.
Deleted: OLD Line 0 : x x Wear protective clothing when risk of exposure occurs.
Deleted: OLD Line 0 : x x Use in a well-ventilated area.
Deleted: OLD Line 0 : x x Prevent concentration in hollows and sumps.
Deleted: OLD Line 0 : x x DO NOT enter confined spaces until atmosphere has been checked.
Deleted: OLD Line 0 : x x Avoid smoking, naked lights or ignition sources.
Deleted: OLD Line 0 : x x Avoid contact with incompatible materials.
Deleted: OLD Line 0 : x x When handling, DO NOT eat, drink or smoke.
Deleted: OLD Line 0 : x x DO NOT incinerate or puncture aerosol cans.
Deleted: OLD Line 0 : x x DO NOT spray directly on humans, exposed food or food utensils.
Deleted: OLD Line 0 : x x Avoid physical damage to containers.
Deleted: OLD Line 0 : x x Always wash hands with soap and water after handling.
Deleted: OLD Line 0 : x x Work clothes should be laundered separately.
Deleted: OLD Line 0 : x x Use good occupational work practice.
Deleted: OLD Line 0 : x x Observe manufacturer's storing and handling recommendations.
Deleted: OLD Line 0 : x x Atmosphere should be regularly checked against established exposure standards
Deleted: OLD Line 0 : to ensure safe working conditions are maintained.
Deleted: OLD Line 0 : DO NOT allow clothing wet with material to stay in contact with skin
Deleted: OLD Line 0 : SUITABLE CONTAINER
Deleted: OLD Line 0 : x x Aerosol dispenser.
Deleted: OLD Line 0 : x x Check that containers are clearly labelled.
Deleted: OLD Line 0 : STORAGE INCOMPATIBILITY
Deleted: OLD Line 0 : Avoid reaction with oxidising agents
Deleted: OLD Line 0 : STORAGE REQUIREMENTS
Deleted: OLD Line 0 : Store in an upright position.
Deleted: OLD Line 0 : Outside or detached storage is preferred.
Deleted: OLD Line 0 : Store below 38 deg. C.
Deleted: OLD Line 0 : Keep dry to avoid corrosion of cans. Corrosion may result in container
Deleted: OLD Line 0 : perforation and internal pressure may eject contents of can.
Deleted: OLD Line 0 : x x Store in original containers in approved flammable liquid storage area.
Deleted: OLD Line 0 : x x DO NOT store in pits, depressions, basements or areas where vapours may be
Deleted: OLD Line 0 : trapped.
Deleted: OLD Line 0 : x x No smoking, naked lights, heat or ignition sources.
Deleted: OLD Line 0 : x x Keep containers securely sealed. Contents under pressure.
Deleted: OLD Line 0 : x x Store away from incompatible materials.
Deleted: OLD Line 0 : x x Store in a cool, dry, well ventilated area.
Deleted: OLD Line 0 : x x Avoid storage at temperatures higher than 40 deg C.
Deleted: OLD Line 0 : x x Store in an upright position.
Deleted: OLD Line 0 : x x Protect containers against physical damage.
Deleted: OLD Line 0 : x x Check regularly for spills and leaks.
Deleted: OLD Line 0 : x x Observe manufacturer's storing and handling recommendations.
Changed: OLD Line 0 : ChemWatch Material Safety Data Sheet CHEMWATCH 21448
NEW Line 0 : ChemWatch Material Safety Data Sheet (REVIEW) CHEMWATCH 21448
Changed: OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 7 of 15
NEW Line 0 : Issue Date: Thu 15-Nov-2001 CD 2002/3 Page 4 of 10
Changed: OLD Line 0 : Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
NEW Line 0 : HEALTH HAZARD ...
Changed: OLD Line 0 : EXPOSURE CONTROLS
NEW Line 0 : Transport to hospital, or doctor.
Changed: OLD Line 0 : No data available for n-hexane as (CAS: 110-54-3) / (CAS: 68476-85-7) / (CAS: 68476-86-8)
NEW Line 0 : ADVICE TO DOCTOR
NEW Line 0 : For acute or short term repeated exposures to petroleum distillates or related
NEW Line 0 : hydrocarbons:
NEW Line 0 : Primary threat to life, from pure petroleum distillate ingestion and/or
NEW Line 0 : inhalation, is respiratory failure.
NEW Line 0 : Patients should be quickly evaluated for signs of respiratory distress (e.g.
NEW Line 0 : cyanosis, tachypnoea, intercostal retraction, obtundation) and given oxygen.
NEW Line 0 : Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm
NEW Line 0 : Hg) should be intubated.
NEW Line 0 : Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
NEW Line 0 : electrocardiographic evidence of myocardial injury has been reported;
NEW Line 0 : intravenous lines and cardiac monitors should be established in obviously
NEW Line 0 : symptomatic patients. The lungs excrete inhaled solvents, so that
NEW Line 0 : hyperventilation improves clearance
NEW Line 0 : A chest x-ray should be taken immediately after stabilisation of breathing and
NEW Line 0 : circulation to document aspiration and detect the presence of pneumothorax.
NEW Line 0 : Epinephrine (adrenalin) is not recommended for treatment of bronchospasm
NEW Line 0 : because of potential myocardial sensitisation to catecholamines. Inhaled
NEW Line 0 : cardioselective bronchodilators (e.g. Alupent, Salbutamol) are the preferred
NEW Line 0 : agents, with aminophylline a second choice.
NEW Line 0 : Lavage is indicated in patients who require decontamination; ensure use of
NEW Line 0 : cuffed endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical
NEW Line 0 : Toxicology]
NEW Line 0 : PRECAUTIONS FOR USE
NEW Line 0 : EXPOSURE STANDARDS
Deleted: OLD Line 0 : ODOUR SAFETY FACTOR (OSF)
Deleted: OLD Line 0 : OSF=0.15 (n-HEXANE)
Deleted: OLD Line 0 : Exposed individuals are NOT reasonably expected to be warned, by smell, that the
Deleted: OLD Line 0 : Exposure Standard is being exceeded.
Deleted: OLD Line 0 : Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
Deleted: OLD Line 0 : The Odour Safety Factor (OSF) is defined as:
Deleted: OLD Line 0 : OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Deleted: OLD Line 0 : Classification into classes follows:
Deleted: OLD Line 0 : Class OSF Description
Deleted: OLD Line 0 : A 550 Over 90% of exposed
Deleted: OLD Line 0 : individuals are aware by
Deleted: OLD Line 0 : smell that the Exposure
Deleted: OLD Line 0 : Standard (TLV-TWA for
Deleted: OLD Line 0 : example) is being
Deleted: OLD Line 0 : reached, even when
Deleted: OLD Line 0 : distracted by working
Deleted: OLD Line 0 : activities
Deleted: OLD Line 0 : B 26-550 As "A" for 50-90% of
Deleted: OLD Line 0 : persons being distracted
Deleted: OLD Line 0 : C 1-26 As "A" for less than 50%
Deleted: OLD Line 0 : of persons being
Deleted: OLD Line 0 : distracted
Deleted: OLD Line 0 : D 0.18-1 10-50% of persons aware
Deleted: OLD Line 0 : of being tested perceive
Deleted: OLD Line 0 : by smell that the
Deleted: OLD Line 0 : Exposure Standard is
Deleted: OLD Line 0 : being reached
Deleted: OLD Line 0 : E <0.18 As "D" for less than 10%
Deleted: OLD Line 0 : of persons aware of being
Deleted: OLD Line 0 : tested
Deleted: OLD Line 0 : EXPOSURE STANDARDS FOR MIXTURE
Deleted: OLD Line 0 : "Worst Case" computer-aided prediction of vapour components/concentrations:
Deleted: OLD Line 0 : Composite Exposure Standard for Mixture (TWA) (mg/m?: 105.8824 mg/m?br>
Deleted: OLD Line 0 : If the breathing zone concentration of ANY of the components listed below is
Deleted: OLD Line 0 : exceeded, "Worst Case" considerations deem the individual to be overexposed.
Deleted: OLD Line 0 : Component Breathing Zone ppm Breathing Zone mg/m?Mixture Conc: (%)
Deleted: OLD Line 0 : Component Breathing zone Breathing Zone Mixture Conc
Deleted: OLD Line 0 : (ppm) (mg/m? (%)
Deleted: OLD Line 0 : n-hexane 19.61 70.5882 60.0
Deleted: OLD Line 0 : hydrocarbon propellant 19.61 35.2941 30.0
Deleted: OLD Line 0 : Operations which produce a spray/mist or fume/dust, introduce particulates to
Deleted: OLD Line 0 : the breathing zone.
Deleted: OLD Line 0 : If the breathing zone concentration of ANY of the components listed below is
Deleted: OLD Line 0 : exceeded, "Worst Case" considerations deem the individual to be overexposed.
Deleted: OLD Line 0 : At the "Composite Exposure Standard for Mixture" (TWA) (mg/m?: 90 mg/m?br>
Deleted: OLD Line 0 : continued...
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Deleted: OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 8 of 15
Deleted: OLD Line 0 : Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Changed: OLD Line 0 : literature search for the reproductive no-observed-adverse effect-level (NOAEL)
NEW Line 0 : literature search for reproductive no-observed-adverse effect-level (NOEL) and
Changed: OLD Line 0 : and the lowest-observed-adverse-effect-level(LOAEL). In addition the US EPA's
NEW Line 0 : the lowest-observed-adverse-effect-level (LOAEL). In addition the US EPA's
Changed: OLD Line 0 : Ingredient ORG UF Endpoint CR Adeq
NEW Line 0 : Ingredient ORG UF Endpoint CR Adequate
Added: NEW Line 0 : continued...
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Added: NEW Line 0 : Issue Date: Thu 15-Nov-2001 CD 2002/3 Page 5 of 10
Added: NEW Line 0 : PRECAUTIONS FOR USE ...
Added: NEW Line 0 : TLV TWA: 50 ppm Skin;BEI [ACGIH]
Deleted: OLD Line 0 : TLV TWA: 50 ppm Skin;BEI [ACGIH]
Changed: OLD Line 0 : MAK Category II Peak Limitation: For substances with systemic effects and with a
NEW Line 0 : MAK Category II Peak Limitation: For substances with systemic effects and with
Changed: OLD Line 0 : half-life in humans of less than two hours.
NEW Line 0 : a half-life in humans of less than two hours.
Changed: OLD Line 0 : Federal Republic of Germany.
NEW Line 0 : Federal Republic of Germany
Deleted: OLD Line 0 : continued...
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Deleted: OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 9 of 15
Deleted: OLD Line 0 : Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Deleted: OLD Line 0 : PEL TWA: 1000 ppm, 1800 mg/m?[OSHA Z1]
Added: NEW Line 0 : ENGINEERING CONTROLS
Added: NEW Line 0 : Use in a well-ventilated area
Added: NEW Line 0 : continued...
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Added: NEW Line 0 : Issue Date: Thu 15-Nov-2001 CD 2002/3 Page 6 of 10
Added: NEW Line 0 : PRECAUTIONS FOR USE ...
Added: NEW Line 0 : General exhaust is adequate under normal operating conditions. If risk of
Added: NEW Line 0 : overexposure exists, wear SAA approved respirator. Correct fit is essential to
Added: NEW Line 0 : obtain adequate protection. Provide adequate ventilation in warehouse or closed
Added: NEW Line 0 : storage areas. Air contaminants generated in the workplace possess varying
Added: NEW Line 0 : "escape" velocities which, in turn, determine the "capture velocities" of fresh
Added: NEW Line 0 : circulating air required to effectively remove the contaminant.
Added: NEW Line 0 : Type of Contaminant: Air Speed:
Added: NEW Line 0 : solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min)
Added: NEW Line 0 : evaporating from tank (in still air)
Added: NEW Line 0 : aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
Added: NEW Line 0 : operations, intermittent container
Added: NEW Line 0 : filling, low speed conveyer transfers,
Added: NEW Line 0 : welding, spray drift, plating acid
Added: NEW Line 0 : fumes, pickling (released at low
Added: NEW Line 0 : velocity into zone of active
Added: NEW Line 0 : generation)
Added: NEW Line 0 : direct spray, spray painting in 1-2.5 m/s (200-500 f/min)
Added: NEW Line 0 : shallow booths, drum filling, conveyer
Added: NEW Line 0 : loading, crusher dusts, gas discharge
Added: NEW Line 0 : (active generation into zone of rapid
Added: NEW Line 0 : air motion)
Added: NEW Line 0 : grinding, abrasive blasting, tumbling, 2.5-10 m/s (500-2000 f/min.)
Added: NEW Line 0 : high speed wheel generated dusts
Added: NEW Line 0 : (released at high initial velocity
Added: NEW Line 0 : into zone of very high rapid air
Added: NEW Line 0 : motion).
Added: NEW Line 0 : Within each range the appropriate value depends on:
Added: NEW Line 0 : Lower end of the range Upper end of the range
Added: NEW Line 0 : 1: Room air currents minimal or 1: Disturbing room air currents
Added: NEW Line 0 : favourable to capture
Added: NEW Line 0 : 2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
Added: NEW Line 0 : nuisance value only
Added: NEW Line 0 : 3: Intermittent, low production. 3: High production, heavy use
Added: NEW Line 0 : 4: Large hood or large air mass in 4: Small hood - local control only
Added: NEW Line 0 : motion
Added: NEW Line 0 : Simple theory shows that air velocity falls rapidly with distance away from the
Added: NEW Line 0 : opening of a simple extraction pipe. Velocity generally decreases with the
Added: NEW Line 0 : square of distance from the extraction point (in simple cases). Therefore the
Added: NEW Line 0 : air speed at the extraction point should be adjusted, accordingly, after
Added: NEW Line 0 : reference to distance from the contaminating source. The air velocity at the
Added: NEW Line 0 : extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.)
Added: NEW Line 0 : for extraction of solvents generated in a tank 2 meters distant from the
Added: NEW Line 0 : extraction point. Other mechanical considerations, producing performance
Added: NEW Line 0 : deficits within the extraction apparatus, make it essential that theoretical
Added: NEW Line 0 : air velocities are multiplied by factors of 10 or more when extraction systems
Added: NEW Line 0 : are installed or used.
Changed: OLD Line 0 : No special equipment for minor exposure i.e. when handling small quantities.
NEW Line 0 : Safety glasses with side shields; or as required, Chemical goggles. Contact
Changed: OLD Line 0 : OTHERWISE: For potentially moderate or heavy exposures:
NEW Line 0 : lenses pose a special hazard; soft lenses may absorb irritants and all lenses
Changed: OLD Line 0 : x Safety glasses with side shields.
NEW Line 0 : continued...
Changed: OLD Line 0 : x x NOTE: Contact lenses pose a special hazard; soft lenses may absorb irritants
NEW Line 0 : ROCOL OPEN GEAR SPRAY
Changed: OLD Line 0 : and ALL lenses concentrate them.
NEW Line 0 : ChemWatch Material Safety Data Sheet (REVIEW) CHEMWATCH 21448
NEW Line 0 : Issue Date: Thu 15-Nov-2001 CD 2002/3 Page 7 of 10
NEW Line 0 : PRECAUTIONS FOR USE ...
NEW Line 0 : concentrate them.
Changed: OLD Line 0 : OTHERWISE:
NEW Line 0 : OTHERWISE: Wear general protective gloves, eg. light weight rubber gloves. Or
Changed: OLD Line 0 : For potentially moderate exposures:
OLD Line 0 : Wear general protective gloves, eg. light weight rubber gloves.
OLD Line 0 : For potentially heavy exposures:
OLD Line 0 : Wear chemical protective gloves, eg. PVC. and safety footwear.
NEW Line 0 : as required: Wear chemical protective gloves, eg. PVC. Wear safety footwear.
Changed: OLD Line 0 : x x Overalls.
NEW Line 0 : Overalls.
Changed: OLD Line 0 : x x Skin cleansing cream.
NEW Line 0 : Skin cleansing cream.
Changed: OLD Line 0 : x x Eyewash unit.
NEW Line 0 : Eyewash unit.
Changed: OLD Line 0 : x x Do not spray on hot surfaces.
OLD Line 0 : GLOVE SELECTION INDEX
OLD Line 0 : Glove selection is based on a modified presentation of the:
OLD Line 0 : "Forsberg Clothing Performance Index".
OLD Line 0 : The effect(s) of the following substance(s) are taken into account in the
OLD Line 0 : computer-generated selection:
OLD Line 0 : Substance
OLD Line 0 : ________________________________________
OLD Line 0 : n-hexane
OLD Line 0 : PE/EVAL/PE A
OLD Line 0 : PVA A
OLD Line 0 : SARANEX-23 2-PLY A
OLD Line 0 : VITON A
OLD Line 0 : VITON/CHLOROBUTYL A
OLD Line 0 : TEFLON B
OLD Line 0 : NITRILE B
OLD Line 0 : NEOPRENE C
OLD Line 0 : NEOPRENE/NATURAL C
OLD Line 0 : NITRILE+PVC C
OLD Line 0 : PVC C
OLD Line 0 : BUTYL C
OLD Line 0 : * CPI - Chemwatch Performance Index
OLD Line 0 : A: Best Selection
OLD Line 0 : B: Satisfactory; may degrade after 4 hours continuous immersion
OLD Line 0 : C: Poor to Dangerous Choice for other than short term immersion
OLD Line 0 : NOTE: As a series of factors will influence the actual performance of the glove,
OLD Line 0 : continued...
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OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 10 of 15
OLD Line 0 : Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
OLD Line 0 : a final selection must be based on detailed observation. -
OLD Line 0 : * Where the glove is to be used on a short term, casual or infrequent basis,
OLD Line 0 : factors such as "feel" or convenience (e.g. disposability), may dictate a choice
OLD Line 0 : of gloves which might otherwise be unsuitable following long-term or frequent
OLD Line 0 : use. A qualified practitioner should be consulted.
NEW Line 0 : Do not spray on hot surfaces.
Changed: OLD Line 0 : ENGINEERING CONTROLS
NEW Line 0 : SAFE HANDLING
Changed: OLD Line 0 : General exhaust is adequate under normal conditions. If risk of overexposure
NEW Line 0 : STORAGE AND TRANSPORT
Changed: OLD Line 0 : exists, wear SAA approved respirator. Correct fit is essential to obtain
NEW Line 0 : SUITABLE CONTAINER
Changed: OLD Line 0 : adequate protection.
NEW Line 0 : Aerosol dispenser. Check that containers are clearly labelled.
Changed: OLD Line 0 : Provide adequate ventilation in warehouse or closed storage areas.
NEW Line 0 : STORAGE INCOMPATIBILITY
Changed: OLD Line 0 : Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
NEW Line 0 : Avoid storage with oxidisers
Changed: OLD Line 0 : APPEARANCE
NEW Line 0 : STORAGE REQUIREMENTS
Changed: OLD Line 0 : Dark bitumastic material with solvent odour; does not mix with water.
NEW Line 0 : Store in original containers in approved flame-proof area.
Changed: OLD Line 0 : Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable
NEW Line 0 : DO NOT store in pits, depressions, basements or areas where vapours may be
Changed: OLD Line 0 : hydrocarbon propellant.
OLD Line 0 : PHYSICAL PROPERTIES
OLD Line 0 : Liquid.
OLD Line 0 : Gas.
OLD Line 0 : Does not mix with water.
OLD Line 0 : Molecular Weight: Not applicable. Boiling Range (癈): Not available.
OLD Line 0 : Melting Range (癈): Not available. Specific Gravity (water=1): Not available.
OLD Line 0 : Solubility in water (g/L): Immiscible pH (as supplied): Not applicable
OLD Line 0 : pH (1% solution): Not applicable Vapour Pressure (kPa): Not available.
OLD Line 0 : Volatile Component (%vol): Not available. Evaporation Rate: Not available
OLD Line 0 : Relative Vapour Density (air=1): >1 Flash Point (癈): -81 propellant
OLD Line 0 : Lower Explosive Limit (%): Not available Upper Explosive Limit (%): Not available
OLD Line 0 : Autoignition Temp (癈): Not available. Decomposition Temp (癈):
OLD Line 0 : State: Liquid
OLD Line 0 : continued...
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OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 11 of 15
OLD Line 0 : Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
OLD Line 0 : CONDITIONS CONTRIBUTING TO INSTABILITY
OLD Line 0 : x Elevated temperatures.
OLD Line 0 : x x Presence of open flame.
OLD Line 0 : x x Product is considered stable.
OLD Line 0 : x x Hazardous polymerisation will not occur.
OLD Line 0 : Section 11 - TOXICOLOGICAL INFORMATION
OLD Line 0 : POTENTIAL HEALTH EFFECTS
OLD Line 0 : ACUTE HEALTH EFFECTS
OLD Line 0 : SWALLOWED
OLD Line 0 : Not normally a hazard due to physical form of product.
OLD Line 0 : Considered an unlikely route of entry in commercial/industrial environments.
OLD Line 0 : Accidental ingestion of the material may be damaging to the health of the
OLD Line 0 : individual.
OLD Line 0 : Swallowing of the liquid may cause aspiration into the lungs with the risk of
OLD Line 0 : chemical pneumonitis; serious consequences may result.
OLD Line 0 : (ICSC13733).
OLD Line 0 : Ingestion of sulfide salts may result in their decomposition by stomach gastric
OLD Line 0 : acid to hydrogen sulfide with systemic poisoning. Symptoms may include headache,
OLD Line 0 : respiratory depression, cyanosis, fall of blood pressure, loss of consciousness,
OLD Line 0 : tremors and convulsions.
OLD Line 0 : EYE
OLD Line 0 : Limited evidence or practical experience suggests, that the material may cause
OLD Line 0 : eye irritation in a substantial number of individuals. Repeated or prolonged eye
OLD Line 0 : contact may cause inflammation characterised by temporary redness (similar to
OLD Line 0 : windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision
OLD Line 0 : and/or other transient eye damage/ulceration may occur.
OLD Line 0 : SKIN
OLD Line 0 : Skin contact with the material may damage the health of the individual; systemic
OLD Line 0 : effects may result following absorption.
OLD Line 0 : Evidence exists, or practical experience predicts, that the material either
OLD Line 0 : produces inflammation of the skin in a substantial number of individuals
OLD Line 0 : following direct contact, and/or produces significant inflammation when applied
OLD Line 0 : to the healthy intact skin of animals, for up to four hours, such inflammation
OLD Line 0 : being present twenty-four hours or more after the end of the exposure period.
OLD Line 0 : Skin irritation may also be present after prolonged or repeated exposure; this
OLD Line 0 : may result in a form of contact dermatitis (nonallergic). The dermatitis is
OLD Line 0 : often characterised by skin redness (erythema) and swelling (oedema) which may
OLD Line 0 : progress to blistering (vesiculation), scaling and thickening of the epidermis.
OLD Line 0 : At the microscopic level there may be intercellular oedema of the spongy layer
OLD Line 0 : of the skin (spongiosis) and intracellular oedema of the epidermis.
OLD Line 0 : The material may accentuate any pre-existing dermatitis condition.
OLD Line 0 : Spray mist may produce discomfort.
OLD Line 0 : Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
OLD Line 0 : may produce systemic injury with harmful effects. Examine the skin prior to the
OLD Line 0 : use of the material and ensure that any external damage is suitably protected.
OLD Line 0 : INHALED
OLD Line 0 : Inhalation of aerosols (mists, fumes), generated by the material during the
OLD Line 0 : course of normal handling, may be damaging to the health of the individual.
OLD Line 0 : continued...
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OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 12 of 15
OLD Line 0 : Section 11 - TOXICOLOGICAL INFORMATION
OLD Line 0 : Limited evidence or practical experience suggests that the material may produce
OLD Line 0 : irritation of the respiratory system, in a significant number of individuals,
OLD Line 0 : following inhalation. In contrast to most organs, the lung is able to respond to
OLD Line 0 : a chemical insult by first removing or neutralising the irritant and then
OLD Line 0 : repairing the damage. The repair process, which initially evolved to protect
OLD Line 0 : mammalian lungs from foreign matter and antigens, may however, produce further
OLD Line 0 : lung damage resulting in the impairment of gas exchange, the primary function of
OLD Line 0 : the lungs. Respiratory tract irritation often results in an inflammatory
OLD Line 0 : response involving the recruitment and activation of many cell types, mainly
OLD Line 0 : derived from the vascular system.
OLD Line 0 : Inhalation of vapours may cause drowsiness and dizziness. This may be
OLD Line 0 : accompanied by narcosis, drowsiness, reduced alertness, loss of reflexes, lack
OLD Line 0 : of coordination and vertigo.
OLD Line 0 : Acute effects from inhalation of high concentrations of vapour are pulmonary
OLD Line 0 : irritation, including coughing, with nausea; central nervous system depression -
OLD Line 0 : characterised by headache and dizziness, increased reaction time, fatigue and
OLD Line 0 : loss of co-ordination.
OLD Line 0 : Central nervous system (CNS) depression may include nonspecific discomfort,
OLD Line 0 : symptoms of giddiness, headache, dizziness, nausea, anaesthetic effects, slowed
OLD Line 0 : reaction time, slurred speech and may progress to unconsciousness. Serious
OLD Line 0 : poisonings may result in respiratory depression and may be fatal.
OLD Line 0 : Material is highly volatile and may quickly form a concentrated atmosphere in
OLD Line 0 : confined or unventilated areas. Vapour is heavier than air and may displace and
OLD Line 0 : replace air in breathing zone, acting as a simple asphyxiant. This may happen
OLD Line 0 : with little warning of overexposure.
OLD Line 0 : Symptoms of asphyxia (suffocation) may include headache, dizziness, shortness of
OLD Line 0 : breath, muscular weakness, drowsiness and ringing in the ears. If the asphyxia
OLD Line 0 : is allowed to progress, there may be nausea and vomiting, further physical
OLD Line 0 : weakness and unconsciousness and, finally, convulsions, coma and death.
OLD Line 0 : Significant concentrations of the non-toxic gas reduce the oxygen level in the
OLD Line 0 : air. As the amount of oxygen is reduced from 21 to 14 volume %, the pulse rate
OLD Line 0 : accelerates and the rate and volume of breathing increase. The ability to
OLD Line 0 : maintain attention and think clearly is diminished and muscular coordination is
OLD Line 0 : somewhat disturbed. As oxygen decreases from 14-10% judgement becomes faulty;
OLD Line 0 : severe injuries may cause no pain. Muscular exertion leads to rapid fatigue.
OLD Line 0 : Further reduction to 6% may produce nausea and vomiting and the ability to move
OLD Line 0 : may be lost. Permanent brain damage may result even after resuscitation at
OLD Line 0 : exposures to this lower oxygen level. Below 6% breathing is in gasps and
OLD Line 0 : convulsions may occur. Inhalation of a mixture containing no oxygen may result
OLD Line 0 : in unconsciousness from the first breath and death will follow in a few minutes.
OLD Line 0 : WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
OLD Line 0 : If exposure to highly concentrated solvent atmosphere is prolonged this may lead
OLD Line 0 : to narcosis, unconsciousness, even coma and possible death.
OLD Line 0 : Effects on lungs are significantly enhanced in the presence of respirable
OLD Line 0 : particles. Overexposure to respirable dust may produce wheezing, coughing and
OLD Line 0 : breathing difficulties leading to or symptomatic of impaired respiratory
OLD Line 0 : function.
OLD Line 0 : Hydrocarbons may sensitise the heart to adrenalin and other circulatory
OLD Line 0 : catecholamines; as a result cardiac arrhythmias and ventricular fibrillation may
OLD Line 0 : occur. Abrupt collapse may produce traumatic injury. Central nervous system
OLD Line 0 : (CNS) depression may be evident early. Symptoms of moderate poisoning may
OLD Line 0 : include giddiness, headache, dizziness and nausea. Serious poisonings may result
OLD Line 0 : in respiratory depression and may be fatal.
OLD Line 0 : The paraffin gases C1-4 are practically non-toxic below their lower flammability
OLD Line 0 : limits (18000-50000 ppm). Above this level, incidental effects include CNS
OLD Line 0 : depression and irritation but these are reversible upon cessation of the
OLD Line 0 : exposure. The C3 and iso-C5 hydrocarbons show increasing narcotic properties;
OLD Line 0 : branching of the chain also enhances the effect. The C4 hydrocarbons appear to
OLD Line 0 : be more highly neurotoxic than the C3 and C5 members. Several fatalities due to
OLD Line 0 : continued...
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OLD Line 0 : ChemWatch Material Safety Data Sheet CHEMWATCH 21448
OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 13 of 15
OLD Line 0 : Section 11 - TOXICOLOGICAL INFORMATION
OLD Line 0 : voluntary inhalation of butane have been reported, possibly due to central,
OLD Line 0 : respiratory and circulatory effects resulting from anaesthesia, laryngeal
OLD Line 0 : oedema, chemical pneumonia or the combined effects of cardiac toxicity and
OLD Line 0 : increased sympathomimetic effects.
OLD Line 0 : Inhalation of petroleum gases may produce narcosis, due in part to olefinic
OLD Line 0 : impurities. Displacement of oxygen in the air may cyanosis. If present in
OLD Line 0 : sufficient quantity these gases may reduce the oxygen level to below 18%
OLD Line 0 : producing asphyxiation. Symptoms include rapid respiration, mental dullness,
OLD Line 0 : lack of coordination, poor judgement, nausea and vomiting. The onset of cyanosis
OLD Line 0 : may lead to unconsciousness and death.
OLD Line 0 : CHRONIC HEALTH EFFECTS
OLD Line 0 : Principal route of occupational exposure to the gas is by inhalation. Substance
OLD Line 0 : accumulation, in the human body, may occur and may cause some concern following repeated
OLD Line 0 : or long-term occupational exposure. Exposure to the material may cause concerns for human
OLD Line 0 : fertility, generally on the basis that results in animal studies provide sufficient
OLD Line 0 : evidence to cause a strong suspicion of impaired fertility in the absence of toxic
OLD Line 0 : effects, or evidence of impaired fertility occurring at around the same dose levels as
OLD Line 0 : other toxic effects, but which are not a secondary non-specific consequence of other toxic
OLD Line 0 : effects. Chronic inhalation or skin exposure to n-hexane may cause peripheral neuropathy,
OLD Line 0 : which is damage to nerve ends in extremities, e.g. fingers, with loss of sensation and
OLD Line 0 : characteristic thickening. Nerve damage has been documented with chronic exposures of
OLD Line 0 : greater than 500 ppm. Improvement in condition does not immediately follow removal from
OLD Line 0 : exposure and symptoms may progress for two or three months. Recovery may take a year or
OLD Line 0 : more depending on severity of exposure, and may not always be complete. Exposure to
OLD Line 0 : n-hexane with methyl ethyl ketone (MEK) will accelerate the appearance of damage, but MEK
OLD Line 0 : alone will not cause the nerve damage. Other isomers of hexane do not cause nerve damage.
OLD Line 0 : [Source: Shell Co.]. Cattle, rabbits, and chicks on high dietary levels of molybdenum
OLD Line 0 : exhibited deformities of joints of the extremities. Chronic exposure of workers in Russian
OLD Line 0 : molybdenum-copper plant resulted in a fall in the albumin/globulin ratio owing to a rise
OLD Line 0 : in globulins (particularly alpha-globulins) which is interpreted as evidence of liver
OLD Line 0 : dysfunction with hyperbilirubinaemia. Hepatotoxic effects are also found in animals given
OLD Line 0 : molybdenum salts with a rise in alpha-globulin levels, hypoalbuminaemia and increased
OLD Line 0 : serum bilirubin reported. Other reported biochemical effects include an early depletive
OLD Line 0 : effect on tissue nicotinamide nucleotides, hyperaminoaciduria, reduction in red blood cell
OLD Line 0 : life-span and hyper-thyroidism. Industrial exposure to some insoluble molybdenum compounds
OLD Line 0 : is thought to have resulted in an increased incidence of weakness, fatigue, anorexia,
OLD Line 0 : headache and joint and muscular pain. Animals exposed to certain insoluble molybdenum
OLD Line 0 : compounds show anorexia, diarrhoea, weight loss, listlessness, and liver and kidney
OLD Line 0 : damage. Molybdenum disturbs bone metabolism, giving rise to lameness, bone joint
OLD Line 0 : abnormalities, osteoporosis and high serum phosphatase levels. Low molybdenum intake has
OLD Line 0 : been attributed to the high incidence of oesophageal cancer in South Africa among the
OLD Line 0 : Bantu of Transkei, in China and in Russia. Under the conditions of a 2-year inhalation
OLD Line 0 : study* there was equivocal evidence of carcinogenic activity of molybdenum trioxide in
OLD Line 0 : male rats, male mice and female mice based on a marginally significant positive trend of
OLD Line 0 : alveolar/bronchiolar adenoma or carcinoma. There was no evidence of carcinogenic activity
OLD Line 0 : in female rats exposed to 10, 30 and 100 mg/m3. Exposure of male and female rats to
OLD Line 0 : molybdenum trioxide by inhalation resulted in increased incidences of chronic alveolar
OLD Line 0 : inflammation, hyaline degeneration of the olfactory epithelium (females), hyaline
OLD Line 0 : degeneration of the respiratory epithelium and squamous metaplasia of the epiglottis.
OLD Line 0 : Exposure of female and male mice to molybdenum trioxide resulted in an increased incidence
OLD Line 0 : of metaplasia of the alveolar epithelium, histiocyte cellular inflammation (males),
OLD Line 0 : hyaline degeneration of the respiratory epithelium, hyaline degeneration of the olfactory
OLD Line 0 : epithelium (females), squamous metaplasia of the epiglottis, and hyperplasia of the
OLD Line 0 : larynx. Molybdenum trioxide was not mutagenic in any of five strains of Salmonella
OLD Line 0 : typhimurium and did not induce sister chromatid exchanges or chromosomal aberrations in
OLD Line 0 : cultured Chinese hamster ovary cells in vitro. All tests were conducted with or without S9
OLD Line 0 : metabolic activation enzymes. National Toxicology Program: Technical Report Series 462,
OLD Line 0 : April 1997. Repeated or prolonged exposure to mixed hydrocarbons may produce narcosis with
OLD Line 0 : continued...
OLD Line 0 : ROCOL OPEN GEAR SPRAY
OLD Line 0 : ChemWatch Material Safety Data Sheet CHEMWATCH 21448
OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 14 of 15
OLD Line 0 : Section 11 - TOXICOLOGICAL INFORMATION
OLD Line 0 : dizziness, weakness, irritability, concentration and/or memory loss, tremor in the fingers
OLD Line 0 : and tongue, vertigo, olfactory disorders, constriction of visual field, paraesthesias of
OLD Line 0 : the extremities, weight loss and anaemia and degenerative changes in the liver and kidney.
OLD Line 0 : Chronic exposure by petroleum workers, to the lighter hydrocarbons, has been associated
OLD Line 0 : with visual disturbances, damage to the central nervous system, peripheral neuropathies
OLD Line 0 : (including numbness and paraesthesias), psychological and neurophysiological deficits,
OLD Line 0 : bone marrow toxicities (including hypoplasia possibly due to benzene) and hepatic and
OLD Line 0 : renal involvement. Chronic dermal exposure to petroleum hydrocarbons may result in
OLD Line 0 : defatting which produces localised dermatoses. Surface cracking and erosion may also
OLD Line 0 : increase susceptibility to infection by microorganisms. One epidemiological study of
OLD Line 0 : petroleum refinery workers has reported elevations in standard mortality ratios for skin
OLD Line 0 : cancer along with a dose-response relationship indicating an association between routine
OLD Line 0 : workplace exposure to petroleum or one of its constituents and skin cancer, particularly
OLD Line 0 : melanoma. Other studies have been unable to confirm this finding.
OLD Line 0 : Rocol Open Gear Spray
OLD Line 0 : Not available. Refer to individual constituents.
OLD Line 0 : unless otherwise specified data extracted from RTECS - Register of Toxic Effects
OLD Line 0 : of Chemical Substances
OLD Line 0 : N-HEXANE:
OLD Line 0 : TOXICITY IRRITATION
OLD Line 0 : Eye(rabbit): 10 mg - mild Oral (rat) LD50: 28710 mg/kg
OLD Line 0 : Inhalation (human) TCLo: 190 ppm/8W
OLD Line 0 : Inhalation (rat) LD50: 48000 ppm/4h
OLD Line 0 : HYDROCARBON PROPELLANT:
OLD Line 0 : No significant acute toxicological data identified in literature search.
OLD Line 0 : Section 12 - ECOLOGICAL INFORMATION
OLD Line 0 : Drinking Water Standards:
OLD Line 0 : hydrocarbon total: 10 ug/l (UK max.).
OLD Line 0 : DO NOT discharge into sewer or waterways.
OLD Line 0 : Toxic to aquatic organisms.
OLD Line 0 : Do NOT allow product to come in contact with surface waters or to intertidal
OLD Line 0 : areas below the mean high water mark. Do not contaminate water when cleaning
OLD Line 0 : equipment or disposing of equipment wash-waters.
OLD Line 0 : Wastes resulting from use of the product must be disposed of on site or at
OLD Line 0 : approved waste sites.
OLD Line 0 : May cause long-term adverse effects in
OLD Line 0 : the aquatic environment.
OLD Line 0 : Section 13 - DISPOSAL CONSIDERATIONS
OLD Line 0 : x Consult State Land Waste Management Authority for disposal.
OLD Line 0 : x x Discharge contents of damaged aerosol cans at an approved site.
OLD Line 0 : x x Allow small quantities to evaporate.
OLD Line 0 : x x DO NOT incinerate or puncture aerosol cans.
OLD Line 0 : x x Bury residues and emptied aerosol cans at an approved site.
OLD Line 0 : Section 14 - TRANSPORTATION INFORMATION
OLD Line 0 : Shipping Name:
OLD Line 0 : AEROSOLS
OLD Line 0 : Dangerous Goods Class: 2.1
OLD Line 0 : UN/NA Number: 1950
NEW Line 0 : trapped.
Changed: OLD Line 0 : ChemWatch Material Safety Data Sheet CHEMWATCH 21448
NEW Line 0 : ChemWatch Material Safety Data Sheet (REVIEW) CHEMWATCH 21448
Changed: OLD Line 0 : Issue Date: Fri 14-Jan-2005 CD 2004/4 Page 15 of 15
NEW Line 0 : Issue Date: Thu 15-Nov-2001 CD 2002/3 Page 8 of 10
Changed: OLD Line 0 : Section 14 - TRANSPORTATION INFORMATION
NEW Line 0 : SAFE HANDLING ...
Changed: OLD Line 0 : ADR Number: None
NEW Line 0 : No smoking, naked lights, heat or ignition sources.
Changed: OLD Line 0 : Packing Group: None
NEW Line 0 : Keep containers securely sealed. Contents under pressure.
Changed: OLD Line 0 : Labels Required: flammable gas
NEW Line 0 : Store away from incompatible materials.
Changed: OLD Line 0 : Additional Shipping Information:
NEW Line 0 : Store in a cool, dry, well ventilated area in an upright position.
Changed: OLD Line 0 : International Transport Regulations:
NEW Line 0 : Avoid storage at temperatures higher than 40 deg C.
Changed: OLD Line 0 : IMO: 2102
NEW Line 0 : Protect containers against physical damage and check regularly for leaks.
NEW Line 0 : Observe manufacturer's storing and handling recommendations.
NEW Line 0 : TRANSPORTATION
NEW Line 0 : Class 2.1 - Flammable gases shall not be loaded in the same vehicle or packed
NEW Line 0 : in the same freight container with:
NEW Line 0 : Class 1 - Explosives;
NEW Line 0 : Class 3 - Flammable liquids (where both flammable liquids and flammable gases
NEW Line 0 : are in bulk);
NEW Line 0 : Class 4.1 - Flammable solids;
NEW Line 0 : Class 4.2 - Spontaneously combustible substances;
NEW Line 0 : Class 4.3 - Dangerous when wet substances;
NEW Line 0 : Class 5.1 - Oxidising agents;
NEW Line 0 : Class 5.2 - Organic peroxides;
NEW Line 0 : Class 7 - Radioactive substances.
NEW Line 0 : SPILLS AND DISPOSAL
NEW Line 0 : MINOR SPILLS
NEW Line 0 : Clean up all spills immediately.
NEW Line 0 : Avoid breathing vapours and contact with skin and eyes.
NEW Line 0 : Wear protective clothing, impervious gloves and safety glasses.
NEW Line 0 : Shut off all possible sources of ignition and increase ventilation.
NEW Line 0 : Wipe up.
NEW Line 0 : If safe, damaged cans should be placed in a container outdoors, away from all
NEW Line 0 : ignition sources, until pressure has dissipated.
NEW Line 0 : Undamaged cans should be gathered and stowed safely.
NEW Line 0 : MAJOR SPILLS
NEW Line 0 : Clear area of personnel and move upwind.
NEW Line 0 : Alert Fire Brigade and tell them location and nature of hazard.
NEW Line 0 : May be violently or explosively reactive.
NEW Line 0 : Wear breathing apparatus plus protective gloves.
NEW Line 0 : Prevent, by any means available, spillage from entering drains or
NEW Line 0 : No smoking, naked lights or ignition sources.
NEW Line 0 : Increase ventilation.
NEW Line 0 : Stop leak if safe to do so.
NEW Line 0 : Water spray or fog may be used to disperse / absorb vapour.
NEW Line 0 : Absorb or cover spill with sand, earth, inert materials or vermiculite.
NEW Line 0 : If safe, damaged cans should be placed in a container outdoors, away
NEW Line 0 : Undamaged cans should be gathered and stowed safely.
NEW Line 0 : Collect residues and seal in labelled drums for disposal.
NEW Line 0 : DISPOSAL
NEW Line 0 : Consult State Land Waste Management Authority for disposal.
NEW Line 0 : Discharge contents of damaged aerosol cans at an approved site.
NEW Line 0 : Allow small quantities to evaporate.
NEW Line 0 : DO NOT incinerate or puncture aerosol cans.
NEW Line 0 : Bury residues and emptied aerosol cans at an approved site.
NEW Line 0 : continued...
NEW Line 0 : ROCOL OPEN GEAR SPRAY
NEW Line 0 : ChemWatch Material Safety Data Sheet (REVIEW) CHEMWATCH 21448
NEW Line 0 : Issue Date: Thu 15-Nov-2001 CD 2002/3 Page 9 of 10
NEW Line 0 : SAFE HANDLING ...
NEW Line 0 : FIRE FIGHTERS' REPORT
NEW Line 0 : EXTINGUISHING MEDIA
NEW Line 0 : Water spray or fog.
NEW Line 0 : Foam.
NEW Line 0 : Dry chemical powder.
NEW Line 0 : BCF (where regulations permit).
NEW Line 0 : Carbon dioxide.
NEW Line 0 : FIRE FIGHTING
NEW Line 0 : Alert Fire Brigade and tell them location and nature of hazard.
NEW Line 0 : May be violently or explosively reactive.
NEW Line 0 : Wear breathing apparatus plus protective gloves.
NEW Line 0 : Prevent, by any means available, spillage from entering drains or water course.
NEW Line 0 : If safe, switch off electrical equipment until vapour fire hazard removed.
NEW Line 0 : Use water delivered as a fine spray to control fire and cool adjacent area.
NEW Line 0 : DO NOT approach containers suspected to be hot.
NEW Line 0 : Cool fire exposed containers with water spray from a protected location.
NEW Line 0 : If safe to do so, remove containers from path of fire.
NEW Line 0 : Equipment should be thoroughly decontaminated after use.
NEW Line 0 : When any large container (including road and rail tankers) is involved in a fire,
NEW Line 0 : consider evacuation by 100 metres in all directions.
NEW Line 0 : FIRE/EXPLOSION HAZARD
NEW Line 0 : Liquid and vapour are highly flammable.
NEW Line 0 : Severe fire hazard when exposed to heat or flame.
NEW Line 0 : Vapour forms an explosive mixture with air.
NEW Line 0 : Severe explosion hazard, in the form of vapour, when exposed to flame or spark.
NEW Line 0 : Vapour may travel a considerable distance to source of ignition.
NEW Line 0 : Heating may cause expansion or decomposition with violent container rupture.
NEW Line 0 : Aerosol cans may explode on exposure to naked flames.
NEW Line 0 : Rupturing containers may rocket and scatter burning materials.
NEW Line 0 : Hazards may not be restricted to pressure effects.
NEW Line 0 : May emit acrid, poisonous or corrosive fumes.
NEW Line 0 : On combustion, may emit toxic fumes of carbon monoxide (CO).
NEW Line 0 : Other combustion products include carbon dioxide (CO2) and sulfur oxides (SOx)
NEW Line 0 : FIRE INCOMPATIBILITY
NEW Line 0 : Avoid contamination with strong oxidising agents as ignition may result
Changed: OLD Line 0 : Section 15 - REGULATORY INFORMATION
NEW Line 0 : CONTACT POINT
Changed: OLD Line 0 : POISONS SCHEDULE
NEW Line 0 : COMPANY CONTACT
Changed: OLD Line 0 : None
NEW Line 0 : (+61 2) 9757 8800
Changed: OLD Line 0 : Section 16 - OTHER INFORMATION
NEW Line 0 : AUSTRALIAN POISONS INFORMATION CENTRE
NEW Line 0 : continued...
NEW Line 0 : ROCOL OPEN GEAR SPRAY
NEW Line 0 : ChemWatch Material Safety Data Sheet (REVIEW) CHEMWATCH 21448
NEW Line 0 : Issue Date: Thu 15-Nov-2001 CD 2002/3 Page 10 of 10
NEW Line 0 : CONTACT POINT ...
NEW Line 0 : 24 HOUR SERVICE: 13 11 26
NEW Line 0 : POLICE, FIRE BRIGADE OR AMBULANCE: 000
NEW Line 0 : NEW ZEALAND POISONS INFORMATION CENTRE
NEW Line 0 : 24 HOUR SERVICE: (03) 4747 000
NEW Line 0 : NZ EMERGENCY SERVICES: 111
NEW Line 0 : End of Report
NEW Line 0 : Issue Date: Thu 15-Nov-2001
NEW Line 0 : Print Date: Tue 10-Sep-2002
Deleted: OLD Line 0 : Issue Date: Fri 14-Jan-2005
Deleted: OLD Line 0 : Print Date: Fri 25-Feb-2005
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Material Name (Product Name): ACETIC ACID GLACIAL; File: pd2366528.htm.gz; Product URL: http://full.chemwatch.net/msdscoll/showDoc?filename=pd13955.htm.gz
Folder Name : Supplier MSDS'; Document Id : 2366528; Product Id : 2789-3
Update of Id (Changed Document Id) : 13955
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The document at URL http://full.chemwatch.net/msdscoll/showDoc?filename=pd2366528.htm.gz is not available or has been moved or search for the document produces no result.
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Material Name (Product Name): L-Cystine, 96% (titr.); File: pd2369571.htm.gz; Product URL: http://full.chemwatch.net/msdscoll/showDoc?filename=pd365317.htm.gz
Folder Name : Supplier MSDS'; Document Id : 2369571; Product Id : 35883
Update of Id (Changed Document Id) : 365317
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Added: NEW Line 0 : Hazard Symbols: None listed.
Added: NEW Line 0 : Risk Phrases: None listed.
Changed: OLD Line 0 : Appearance: White Powder.
OLD Line 0 : Caution! May cause eye irritation and transient injury. May cause adverse reproductive effects based upon animal studies. The toxicological properties of this material have not been fully investigated. This is expected to be a low hazard for usual industrial handling.
NEW Line 0 : Appearance: White Powder. Caution! May cause eye irritation and transient injury. May cause adverse reproductive effects based upon animal studies. The toxicological properties of this material have not been fully investigated. This is expected to be a low hazard for usual industrial handling.
Changed: OLD Line 0 : Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
NEW Line 0 : Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Changed: OLD Line 0 : Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
NEW Line 0 : Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Changed: OLD Line 0 : Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
NEW Line 0 : Respirators: A respiratory protection program that meets OSHA's 29 CFR ?910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Changed: OLD Line 0 : CAS# 56-89-3:
OLD Line 0 : Oral, mouse: LD50 = 156 mg/kg;
OLD Line 0 : Oral, rat LDLo = 25 g/kg rat TDLo = 279
NEW Line 0 : Not available.
Changed: OLD Line 0 : CAS# 56-89-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
NEW Line 0 : CAS# 56-89-3: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Deleted: OLD Line 0 : Mutagenicity: No information available.
Changed: OLD Line 0 : Other Studies:
NEW Line 0 : Mutagenicity: No information available.
NEW Line 0 : Other Studies: None.
Added: NEW Line 0 : IATA
Added: NEW Line 0 : RID/ADR
Added: NEW Line 0 : IMO
Deleted: OLD Line 0 : Please contact Fisher Scientific for shipping information
Added: NEW Line 0 : No information available.
Changed: OLD Line 0 : CERCLA Hazardous Substances and corresponding RQs
NEW Line 0 : SARA
NEW Line 0 : Section 302 (RQ)
Changed: OLD Line 0 : SARA Section 302 Extremely Hazardous Substances
NEW Line 0 : Section 302 (TPQ)
Changed: OLD Line 0 : Section 313 No chemicals are reportable under Section 313.
NEW Line 0 : Section 313
NEW Line 0 : No chemicals are reportable under Section 313.
Changed: OLD Line 0 : This material does not contain any hazardous air pollutants.
OLD Line 0 : This material does not contain any Class 1 Ozone depletors.
OLD Line 0 : This material does not contain any Class 2 Ozone depletors.
NEW Line 0 : This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Changed: OLD Line 0 : None of the chemicals in this product are listed as Hazardous Substances under the CWA.
OLD Line 0 : None of the chemicals in this product are listed as Priority Pollutants under the CWA.
OLD Line 0 : None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
NEW Line 0 : None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
Deleted: OLD Line 0 : California Prop 65
Changed: OLD Line 0 : WHMIS: Not available.
NEW Line 0 : This product has a WHMIS classification of D2A.
Added: NEW Line 0 : Exposure Limits
Changed: OLD Line 0 : Revision #2 Date: 3/18/2003
NEW Line 0 : Revision #1 Date: 8/02/2000
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Material Name (Product Name): SODIUM HYDROXIDE 25% 1275KG IBC; File: pd2384352.pdf; Product URL: http://full.chemwatch.net/msdscoll/showDoc?filename=pd1621312.pdf
Folder Name : Supplier MSDS'; Document Id : 2384352; Product Id : 1824
Update of Id (Changed Document Id) : 1621312
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Changed: OLD Line 0 : SODIUM HYDROXIDE 25% 1275KG IBC Version: 1.3 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : SODIUM HYDROXIDE 25% 1275KG IBC Version: 1.1 Current Issue: 11/20/2003 Printed:
NEW Line 0 : 11/21/2003
Changed: OLD Line 0 : 1. Chemical Product and Company Identification
NEW Line 0 : 1. Chemical Product and Company Identification
Changed: OLD Line 0 : Hexion Specialty Chemicals, Inc.
NEW Line 0 : BORDEN CHEMICAL, INC.
Changed: OLD Line 0 : 2. Composition, Information on Ingredients
NEW Line 0 : 2. Composition, Information on Ingredients
Changed: OLD Line 0 : The ingredients listed below have been associated with one or more immediate and/or
NEW Line 0 : The ingredients listed below have been associated with one or more immediate and/or delayed(*) health
Changed: OLD Line 0 : delayed(*) health hazards. Risk of damage and effects depends upon duration and level of
NEW Line 0 : hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING,
Changed: OLD Line 0 : exposure. BEFORE USING, HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ
NEW Line 0 : HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE
Changed: OLD Line 0 : AND UNDERSTAND THE MSDS.
NEW Line 0 : MSDS.
Changed: OLD Line 0 : 1310-73-2
NEW Line 0 : 1310-73-2 Sodium Hydroxide 10.0 - 30.0
Changed: OLD Line 0 : Sodium Hydroxide 10.0 - 30.0
NEW Line 0 : 3. Hazards Identification
Changed: OLD Line 0 : Any applicable Canadian trade secret numbers will be listed in Section 15.2.
OLD Line 0 : 3. Hazards Identification
OLD Line 0 : 3.1 Emergency Overview
NEW Line 0 : 3.1 Emergency Overview
Deleted: OLD Line 0 : HMIS Rating
Changed: OLD Line 0 : SODIUM HYDROXIDE 25% 1275KG IBC Version: 1.3 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : SODIUM HYDROXIDE 25% 1275KG IBC Version: 1.1 Current Issue: 11/20/2003 Printed:
NEW Line 0 : 11/21/2003
Added: NEW Line 0 : HMIS Rating
Changed: OLD Line 0 : 3.2 Potential Health Effects
NEW Line 0 : 3.2 Potential Health Effects
Changed: OLD Line 0 : If accidentally swallowed, burns or irritation to mucous membranes,
NEW Line 0 : If accidentally swallowed, burns or irritation to mucous membranes, esophagus
Changed: OLD Line 0 : esophagus or GI tract can result.
NEW Line 0 : or GI tract can result.
Changed: OLD Line 0 : None of the components present in this product at concentrations equal to or greater than
NEW Line 0 : None of the components present in this product at concentrations equal to or greater than 0.1% have
Changed: OLD Line 0 : 0.1% have been listed by NTP, classified by IARC, nor regulated by OSHA as a carcinogen.
NEW Line 0 : been listed by NTP, classified by IARC, nor regulated by OSHA as a carcinogen.
Changed: OLD Line 0 : 4. First Aid Measures
NEW Line 0 : 4. First Aid Measures
Changed: OLD Line 0 : INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. If
NEW Line 0 : INGESTION: If accidentally swallowed, dilute by drinking large quantities of water.
Changed: OLD Line 0 : the individual is drowsy or unconscious, do not give anything by mouth.
NEW Line 0 : Immediately contact poison control center or hospital emergency room for any
Changed: OLD Line 0 : Immediately contact poison control center or hospital emergency room
OLD Line 0 : for advice on whether to induce vomiting or for any other additional
OLD Line 0 : treatment directions.
NEW Line 0 : other additional treatment directions.
Changed: OLD Line 0 : SKIN: Immediately flush with plenty of water for at least 15 minutes while
NEW Line 0 : SKIN: Immediately flush with plenty of water for at least 15 minutes while removing
Changed: OLD Line 0 : removing contaminated clothing. Call a physician. Wash clothing before
NEW Line 0 : contaminated clothing. Call a physician. Wash clothing before reuse.
Changed: OLD Line 0 : reuse.
NEW Line 0 : EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Eyelids
Changed: OLD Line 0 : EYES: Immediately flush eyes with plenty of water for at least 15 minutes.
NEW Line 0 : should be held apart during irrigation to insure water contact with entire
Changed: OLD Line 0 : Eyelids should be held apart during irrigation to ensure water contact
NEW Line 0 : surface of eyes and lids. Call a physician.
Changed: OLD Line 0 : with entire surface of eyes and lids. Call a physician.
OLD Line 0 : 5. Fire Fighting Measures
NEW Line 0 : 5. Fire Fighting Measures
Changed: OLD Line 0 : 6. Accidental Release Measures
NEW Line 0 : 6. Accidental Release Measures
Changed: OLD Line 0 : SODIUM HYDROXIDE 25% 1275KG IBC Version: 1.3 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : SODIUM HYDROXIDE 25% 1275KG IBC Version: 1.1 Current Issue: 11/20/2003 Printed:
NEW Line 0 : 11/21/2003
Changed: OLD Line 0 : container. For large spills, use water spray to disperse vapors and flush spill area. Prevent
NEW Line 0 : container. For large spills, use water spray to disperse vapors and flush spill area. Prevent runoff from
Changed: OLD Line 0 : runoff from entering waterways or sewers. Use appropriate Personal Protective Equipment
NEW Line 0 : entering waterways or sewers. Use appropriate Personal Protective Equipment (PPE).
Changed: OLD Line 0 : (PPE).
NEW Line 0 : 7. Handling and Storage
Changed: OLD Line 0 : 7. Handling and Storage
NEW Line 0 : 7.1 Handling
Changed: OLD Line 0 : 7.1 Handling
NEW Line 0 : Handle in accordance with good industrial hygiene and safety practices. These practices include
Changed: OLD Line 0 : Handle in accordance with good industrial hygiene and safety practices. These practices
NEW Line 0 : avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash
Changed: OLD Line 0 : include avoiding unnecessary exposure and removal of the material from eyes, skin and
OLD Line 0 : clothing. Wash thoroughly after handling. Always use appropriate Personal Protective
OLD Line 0 : Equipment (PPE).
NEW Line 0 : thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE).
Changed: OLD Line 0 : 7.2 Storage
NEW Line 0 : 7.2 Storage
Changed: OLD Line 0 : 8. Exposure Controls/Personal Protection
NEW Line 0 : 8. Exposure Controls/Personal Protection
Changed: OLD Line 0 : 8.1 Exposure Controls
NEW Line 0 : 8.1 Exposure Controls
Changed: OLD Line 0 : ENGINEERING CONTROLS: The following exposure control techniques may be used to
NEW Line 0 : ENGINEERING CONTROLS: The following exposure control techniques may be used to effectively
Changed: OLD Line 0 : effectively minimize employee exposure: local exhaust ventilation, enclosed system design,
NEW Line 0 : minimize employee exposure: local exhaust ventilation, enclosed system design, process isolation and
Changed: OLD Line 0 : process isolation and remote control in combination with appropriate use of personal
NEW Line 0 : remote control in combination with appropriate use of personal protective equipment and prudent work
Changed: OLD Line 0 : protective equipment and prudent work practices. These techniques may not necessarily
NEW Line 0 : practices. These techniques may not necessarily address all issues pertaining to your operations. We,
Changed: OLD Line 0 : address all issues pertaining to your operations. We, therefore, recommend that you consult
NEW Line 0 : therefore, recommend that you consult with experts of your choice to determine whether or not your
Changed: OLD Line 0 : with experts of your choice to determine whether or not your programs are adequate.
NEW Line 0 : programs are adequate.
Changed: OLD Line 0 : If airborne contaminants are generated when the material is heated or handled, sufficient
NEW Line 0 : If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in
Changed: OLD Line 0 : ventilation in volume and air flow patterns should be provided to keep air contaminant
NEW Line 0 : volume and air flow patterns should be provided to keep air contaminant concentration levels below
Changed: OLD Line 0 : concentration levels below acceptable criteria.
NEW Line 0 : acceptable criteria.
Changed: OLD Line 0 : 8.2 Personal Protection
NEW Line 0 : 8.2 Personal Protection
Changed: OLD Line 0 : Wear synthetic apron and boots if contact is likely. Use goggles and face shield if contact is
NEW Line 0 : Wear synthetic apron and boots if contact is likely. Use goggles and face shield if contact is likely.
Changed: OLD Line 0 : likely. Wear impervious gloves as required to prevent skin contact.
NEW Line 0 : Wear impervious gloves as required to prevent skin contact.
Changed: OLD Line 0 : 8.3 Exposure Guidelines
NEW Line 0 : 8.3 Exposure Guidelines
Changed: OLD Line 0 : Remanded 2 mg/m3 1989 PEL remanded, but in
NEW Line 0 : Remanded Ceiling
NEW Line 0 : 2 mg/m3 1989 PEL remanded, but in
NEW Line 0 : effect in some states
Changed: OLD Line 0 : SODIUM HYDROXIDE 25% 1275KG IBC Version: 1.3 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : SODIUM HYDROXIDE 25% 1275KG IBC Version: 1.1 Current Issue: 11/20/2003 Printed:
NEW Line 0 : 11/21/2003
Changed: OLD Line 0 : Ceiling effect in some states
OLD Line 0 : 9. Physical and Chemical Properties
NEW Line 0 : 9. Physical and Chemical Properties
Changed: OLD Line 0 : 10. Stability and Reactivity
NEW Line 0 : 10. Stability and Reactivity
Changed: OLD Line 0 : 11. Toxicological Information
NEW Line 0 : 11. Toxicological Information
Changed: OLD Line 0 : 12. Ecological Information
NEW Line 0 : 12. Ecological Information
Changed: OLD Line 0 : 13. Disposal Considerations
NEW Line 0 : 13. Disposal Considerations
Changed: OLD Line 0 : Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and
NEW Line 0 : Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and federal
Changed: OLD Line 0 : federal requirements.
NEW Line 0 : requirements.
Changed: OLD Line 0 : 14. Transport Information
NEW Line 0 : 14. Transport Information
Changed: OLD Line 0 : 14.1 U.S. Department of Transportation (DOT)
NEW Line 0 : 14.1 U.S. Department of Transportation (DOT)
Changed: OLD Line 0 : The data provided in this section is for information only and may not be specific to your
NEW Line 0 : The data provided in this section is for information only and may not be specific to your package size.
Changed: OLD Line 0 : package size. You will need to apply the appropriate regulations to properly classify your
OLD Line 0 : shipment for transportation.
NEW Line 0 : You will need to apply the appropriate regulations to properly classify your shipment for transportation.
Added: NEW Line 0 : 14.2 Canadian Transportation of Dangerous Goods (TDG)
Changed: OLD Line 0 : SODIUM HYDROXIDE 25% 1275KG IBC Version: 1.3 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : SODIUM HYDROXIDE 25% 1275KG IBC Version: 1.1 Current Issue: 11/20/2003 Printed:
NEW Line 0 : 11/21/2003
Deleted: OLD Line 0 : 14.2 Canadian Transportation of Dangerous Goods (TDG)
Changed: OLD Line 0 : UN number: 1824
NEW Line 0 : UN number 1824
Changed: OLD Line 0 : 15. Regulatory Information (Selected Regulations)
NEW Line 0 : 15. Regulatory Information (Selected Regulations)
Changed: OLD Line 0 : 15.1 U.S. Federal Regulations
NEW Line 0 : 15.1 U.S. Federal Regulations
Changed: OLD Line 0 : This material is a "health hazard" and/or a "physical hazard" as determined when reviewed
NEW Line 0 : This material is a "health hazard" and/or a "physical hazard" as determined when reviewed according to
Changed: OLD Line 0 : according to the requirements of the Occupational Safety and Health Administration 29 CFR
NEW Line 0 : the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200
Changed: OLD Line 0 : Part 1910.1200 "Hazard Communication" Standard.
NEW Line 0 : "Hazard Communication" Standard.
Changed: OLD Line 0 : This product contains the following toxic chemical(s) subject to the reporting requirements of
NEW Line 0 : This product contains the following toxic chemical(s) subject to the reporting requirements of Section
Changed: OLD Line 0 : Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and
NEW Line 0 : 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C-
Changed: OLD Line 0 : Subpart C-Supplier Notification Requirement of 40 CFR Part 372.
NEW Line 0 : Supplier Notification Requirement of 40 CFR Part 372.
Changed: OLD Line 0 : All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications
NEW Line 0 : All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of
Changed: OLD Line 0 : of compliance from our suppliers for chemical substances not manufactured by us.
NEW Line 0 : compliance from our suppliers for chemical substances not manufactured by us.
Changed: OLD Line 0 : 15.2 Canadian Regulations
NEW Line 0 : 15.2 Canadian Regulations
Changed: OLD Line 0 : This product has been classified in accordance with the hazard criteria of the Controlled
NEW Line 0 : This product has been classified in accordance with the hazard criteria of the Controlled Products
Changed: OLD Line 0 : Products Regulation (CPR) and the MSDS contains all the information required by the CPR.
NEW Line 0 : Regulation (CPR) and the MSDS contains all the information required by the CPR.
Changed: OLD Line 0 : All reportable chemical substances are listed on the Domestic Substances List (DSL) or
NEW Line 0 : All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise
Changed: OLD Line 0 : otherwise comply with CEPA new substance notification requirements.
NEW Line 0 : comply with CEPA new substance notification requirements.
Added: NEW Line 0 : This product contains the following chemical(s) subject to the reporting requirements of the Canadian
Added: NEW Line 0 : Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory.
Changed: OLD Line 0 : SODIUM HYDROXIDE 25% 1275KG IBC Version: 1.3 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : SODIUM HYDROXIDE 25% 1275KG IBC Version: 1.1 Current Issue: 11/20/2003 Printed:
NEW Line 0 : 11/21/2003
Deleted: OLD Line 0 : This product contains the following chemical(s) subject to the reporting requirements of the
Deleted: OLD Line 0 : Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release
Deleted: OLD Line 0 : Inventory.
Changed: OLD Line 0 : 16. Other Information
NEW Line 0 : 16. Other Information
Changed: OLD Line 0 : The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace
NEW Line 0 : The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous
Changed: OLD Line 0 : Hazardous Materials Information System (WHMIS) require that the information contained on
NEW Line 0 : Materials Information System (WHMIS) require that the information contained on these sheets be made
Changed: OLD Line 0 : these sheets be made available to your workers. Educate and train your workers regarding
NEW Line 0 : available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions.
Changed: OLD Line 0 : OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult
NEW Line 0 : Instruct your workers to handle this product properly. Consult with appropriate experts to guard against
Changed: OLD Line 0 : with appropriate experts to guard against hazards associated with use of this product and its
OLD Line 0 : ingredients.
NEW Line 0 : hazards associated with use of this product and its ingredients.
Changed: OLD Line 0 : SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT
NEW Line 0 : SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR
Changed: OLD Line 0 : OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that
NEW Line 0 : THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product
Changed: OLD Line 0 : the product shall conform to contracted specifications, and that the product does not infringe
NEW Line 0 : shall conform to contracted specifications, and that the product does not infringe any valid United
Changed: OLD Line 0 : any valid United States or Canadian patent. No claim of any kind shall be greater in amount
NEW Line 0 : States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of
Changed: OLD Line 0 : than the purchase price of the quantity of product in respect of which damages are claimed. In
NEW Line 0 : the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for
Changed: OLD Line 0 : no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim
NEW Line 0 : incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty,
Changed: OLD Line 0 : is based on contract, breach of warranty, negligence or otherwise.
NEW Line 0 : negligence or otherwise.
----------***------------------***-------------------***-----------------***----------
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Material Name (Product Name): Sodium Hydroxide 3%; File: pd2385305.pdf; Product URL: http://full.chemwatch.net/msdscoll/showDoc?filename=pd1623680.pdf
Folder Name : Supplier MSDS'; Document Id : 2385305; Product Id : 1824
Update of Id (Changed Document Id) : 1623680
----------------------------------------------------------------------------------------------------------------------------
Changed: OLD Line 0 : Sodium Hydroxide 3% Version: 2.2 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : Sodium Hydroxide 3% Version: 2 Printed: 10/24/2003
Changed: OLD Line 0 : 1. Chemical Product and Company Identification
NEW Line 0 : 1. Chemical Product and Company Identification
Changed: OLD Line 0 : Hexion Specialty Chemicals, Inc.
NEW Line 0 : BORDEN CHEMICAL, INC.
Changed: OLD Line 0 : 2. Composition, Information on Ingredients
NEW Line 0 : 2. Composition, Information on Ingredients
Changed: OLD Line 0 : The ingredients listed below have been associated with one or more immediate and/or
NEW Line 0 : The ingredients listed below have been associated with one or more immediate and/or delayed(*) health
Changed: OLD Line 0 : delayed(*) health hazards. Risk of damage and effects depends upon duration and level of
NEW Line 0 : hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING,
Changed: OLD Line 0 : exposure. BEFORE USING, HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ
NEW Line 0 : HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE
Changed: OLD Line 0 : AND UNDERSTAND THE MSDS.
NEW Line 0 : MSDS.
Changed: OLD Line 0 : 1310-73-2
NEW Line 0 : 1310-73-2 Sodium Hydroxide 1.0 - 5.0
Changed: OLD Line 0 : Sodium Hydroxide 1.0 - 5.0
NEW Line 0 : 3. Hazards Identification
Changed: OLD Line 0 : Any applicable Canadian trade secret numbers will be listed in Section 15.2.
OLD Line 0 : 3. Hazards Identification
OLD Line 0 : 3.1 Emergency Overview
NEW Line 0 : 3.1 Emergency Overview
Deleted: OLD Line 0 : Page
Deleted: OLD Line 0 : Sodium Hydroxide 3% Version: 2.2 Current Issue: 08/02/2005 Printed: 08/03/2005
Deleted: OLD Line 0 : 2/6
Changed: OLD Line 0 : 3.2 Potential Health Effects
NEW Line 0 : Page
NEW Line 0 : Sodium Hydroxide 3% Version: 2 Printed: 10/24/2003
NEW Line 0 : 2/6
NEW Line 0 : 3.2 Potential Health Effects
Changed: OLD Line 0 : If accidentally swallowed, burns or irritation to mucous membranes,
NEW Line 0 : If accidentally swallowed, burns or irritation to mucous membranes, esophagus
Changed: OLD Line 0 : esophagus or GI tract can result.
NEW Line 0 : or GI tract can result.
Changed: OLD Line 0 : None of the components present in this product at concentrations equal to or greater than
NEW Line 0 : None of the components present in this product at concentrations equal to or greater than 0.1% have
Changed: OLD Line 0 : 0.1% have been listed by NTP, classified by IARC, nor regulated by OSHA as a carcinogen.
NEW Line 0 : been listed by NTP, classified by IARC, nor regulated by OSHA as a carcinogen.
Changed: OLD Line 0 : 4. First Aid Measures
NEW Line 0 : 4. First Aid Measures
Changed: OLD Line 0 : INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. If
NEW Line 0 : INGESTION: If accidentally swallowed, dilute by drinking large quantities of water.
Changed: OLD Line 0 : the individual is drowsy or unconscious, do not give anything by mouth.
NEW Line 0 : Immediately contact poison control center or hospital emergency room for any
Changed: OLD Line 0 : Immediately contact poison control center or hospital emergency room
OLD Line 0 : for advice on whether to induce vomiting or for any other additional
OLD Line 0 : treatment directions.
NEW Line 0 : other additional treatment directions.
Changed: OLD Line 0 : SKIN: Immediately flush with plenty of water for at least 15 minutes while
NEW Line 0 : SKIN: Immediately flush with plenty of water for at least 15 minutes while removing
Changed: OLD Line 0 : removing contaminated clothing. Call a physician. Wash clothing before
NEW Line 0 : contaminated clothing. Call a physician. Wash clothing before reuse.
Changed: OLD Line 0 : reuse.
NEW Line 0 : EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Eyelids
Changed: OLD Line 0 : EYES: Immediately flush eyes with plenty of water for at least 15 minutes.
NEW Line 0 : should be held apart during irrigation to insure water contact with entire
Changed: OLD Line 0 : Eyelids should be held apart during irrigation to ensure water contact
NEW Line 0 : surface of eyes and lids. Call a physician.
Changed: OLD Line 0 : with entire surface of eyes and lids. Call a physician.
OLD Line 0 : 5. Fire Fighting Measures
NEW Line 0 : 5. Fire Fighting Measures
Changed: OLD Line 0 : 6. Accidental Release Measures
NEW Line 0 : 6. Accidental Release Measures
NEW Line 0 : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable
NEW Line 0 : container. For large spills, use water spray to disperse vapors and flush spill area. Prevent runoff from
NEW Line 0 : entering waterways or sewers. Use appropriate Personal Protective Equipment (PPE).
NEW Line 0 : 7. Handling and Storage
Changed: OLD Line 0 : Sodium Hydroxide 3% Version: 2.2 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : Sodium Hydroxide 3% Version: 2 Printed: 10/24/2003
Changed: OLD Line 0 : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable
NEW Line 0 : 7.1 Handling
Changed: OLD Line 0 : container. For large spills, use water spray to disperse vapors and flush spill area. Prevent
NEW Line 0 : Handle in accordance with good industrial hygiene and safety practices. These practices include
Changed: OLD Line 0 : runoff from entering waterways or sewers. Use appropriate Personal Protective Equipment
NEW Line 0 : avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash
Changed: OLD Line 0 : (PPE).
OLD Line 0 : 7. Handling and Storage
OLD Line 0 : 7.1 Handling
OLD Line 0 : Handle in accordance with good industrial hygiene and safety practices. These practices
OLD Line 0 : include avoiding unnecessary exposure and removal of the material from eyes, skin and
OLD Line 0 : clothing. Wash thoroughly after handling. Always use appropriate Personal Protective
OLD Line 0 : Equipment (PPE).
NEW Line 0 : thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE).
Changed: OLD Line 0 : 7.2 Storage
NEW Line 0 : 7.2 Storage
Changed: OLD Line 0 : 8. Exposure Controls/Personal Protection
NEW Line 0 : 8. Exposure Controls/Personal Protection
Changed: OLD Line 0 : 8.1 Exposure Controls
NEW Line 0 : 8.1 Exposure Controls
Changed: OLD Line 0 : ENGINEERING CONTROLS: The following exposure control techniques may be used to
NEW Line 0 : ENGINEERING CONTROLS: The following exposure control techniques may be used to effectively
Changed: OLD Line 0 : effectively minimize employee exposure: local exhaust ventilation, enclosed system design,
NEW Line 0 : minimize employee exposure: local exhaust ventilation, enclosed system design, process isolation and
Changed: OLD Line 0 : process isolation and remote control in combination with appropriate use of personal
NEW Line 0 : remote control in combination with appropriate use of personal protective equipment and prudent work
Changed: OLD Line 0 : protective equipment and prudent work practices. These techniques may not necessarily
NEW Line 0 : practices. These techniques may not necessarily address all issues pertaining to your operations. We,
Changed: OLD Line 0 : address all issues pertaining to your operations. We, therefore, recommend that you consult
NEW Line 0 : therefore, recommend that you consult with experts of your choice to determine whether or not your
Changed: OLD Line 0 : with experts of your choice to determine whether or not your programs are adequate.
NEW Line 0 : programs are adequate.
Changed: OLD Line 0 : If airborne contaminants are generated when the material is heated or handled, sufficient
NEW Line 0 : If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in
Changed: OLD Line 0 : ventilation in volume and air flow patterns should be provided to keep air contaminant
NEW Line 0 : volume and air flow patterns should be provided to keep air contaminant concentration levels below
Changed: OLD Line 0 : concentration levels below acceptable criteria.
NEW Line 0 : acceptable criteria.
Changed: OLD Line 0 : 8.2 Personal Protection
NEW Line 0 : 8.2 Personal Protection
Changed: OLD Line 0 : Wear synthetic apron and boots if contact is likely. Use goggles and face shield if contact is
NEW Line 0 : Wear synthetic apron and boots if contact is likely. Use goggles and face shield if contact is likely.
Changed: OLD Line 0 : likely. Wear impervious gloves as required to prevent skin contact.
NEW Line 0 : Wear impervious gloves as required to prevent skin contact.
Changed: OLD Line 0 : 8.3 Exposure Guidelines
NEW Line 0 : 8.3 Exposure Guidelines
Changed: OLD Line 0 : Remanded
OLD Line 0 : Ceiling
NEW Line 0 : Remanded Ceiling
Changed: OLD Line 0 : Page
OLD Line 0 : Sodium Hydroxide 3% Version: 2.2 Current Issue: 08/02/2005 Printed: 08/03/2005
OLD Line 0 : 4/6
OLD Line 0 : 9. Physical and Chemical Properties
NEW Line 0 : 9. Physical and Chemical Properties
Added: NEW Line 0 : Freezing point Less than 0 癈 (32 癋)
Added: NEW Line 0 : Page
Added: NEW Line 0 : Sodium Hydroxide 3% Version: 2 Printed: 10/24/2003
Added: NEW Line 0 : 4/6
Changed: OLD Line 0 : 10. Stability and Reactivity
NEW Line 0 : 10. Stability and Reactivity
Changed: OLD Line 0 : 11. Toxicological Information
NEW Line 0 : 11. Toxicological Information
Changed: OLD Line 0 : 12. Ecological Information
NEW Line 0 : 12. Ecological Information
Changed: OLD Line 0 : 13. Disposal Considerations
NEW Line 0 : 13. Disposal Considerations
Changed: OLD Line 0 : Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and
NEW Line 0 : Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and federal
Changed: OLD Line 0 : federal requirements.
NEW Line 0 : requirements.
Changed: OLD Line 0 : 14. Transport Information
NEW Line 0 : 14. Transport Information
Changed: OLD Line 0 : 14.1 U.S. Department of Transportation (DOT)
NEW Line 0 : 14.1 U.S. Department of Transportation (DOT)
Changed: OLD Line 0 : The data provided in this section is for information only and may not be specific to your
NEW Line 0 : The data provided in this section is for information only and may not be specific to your package size.
Changed: OLD Line 0 : package size. You will need to apply the appropriate regulations to properly classify your
OLD Line 0 : shipment for transportation.
NEW Line 0 : You will need to apply the appropriate regulations to properly classify your shipment for transportation.
Changed: OLD Line 0 : 14.2 Canadian Transportation of Dangerous Goods (TDG)
NEW Line 0 : 14.2 Canadian Transportation of Dangerous Goods (TDG)
Added: NEW Line 0 : 15. Regulatory Information (Selected Regulations)
Added: NEW Line 0 : 15.1 U.S. Federal Regulations
Added: NEW Line 0 : OSHA Hazards Communication Standard 29CFR1910.1200
Changed: OLD Line 0 : Sodium Hydroxide 3% Version: 2.2 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : Sodium Hydroxide 3% Version: 2 Printed: 10/24/2003
Changed: OLD Line 0 : 15. Regulatory Information (Selected Regulations)
NEW Line 0 : This material is a "health hazard" and/or a "physical hazard" as determined when reviewed according to
Changed: OLD Line 0 : 15.1 U.S. Federal Regulations
NEW Line 0 : the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200
Changed: OLD Line 0 : OSHA Hazards Communication Standard 29CFR1910.1200
OLD Line 0 : This material is a "health hazard" and/or a "physical hazard" as determined when reviewed
OLD Line 0 : according to the requirements of the Occupational Safety and Health Administration 29 CFR
OLD Line 0 : Part 1910.1200 "Hazard Communication" Standard.
NEW Line 0 : "Hazard Communication" Standard.
Changed: OLD Line 0 : This product contains the following toxic chemical(s) subject to the reporting requirements of
NEW Line 0 : This product contains the following toxic chemical(s) subject to the reporting requirements of Section
Changed: OLD Line 0 : Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and
NEW Line 0 : 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C-
Changed: OLD Line 0 : Subpart C-Supplier Notification Requirement of 40 CFR Part 372.
NEW Line 0 : Supplier Notification Requirement of 40 CFR Part 372.
Changed: OLD Line 0 : All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications
NEW Line 0 : All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of
Changed: OLD Line 0 : of compliance from our suppliers for chemical substances not manufactured by us.
NEW Line 0 : compliance from our suppliers for chemical substances not manufactured by us.
Changed: OLD Line 0 : 15.2 Canadian Regulations
NEW Line 0 : 15.2 Canadian Regulations
Changed: OLD Line 0 : This product has been classified in accordance with the hazard criteria of the Controlled
NEW Line 0 : This product has been classified in accordance with the hazard criteria of the Controlled Products
Changed: OLD Line 0 : Products Regulation (CPR) and the MSDS contains all the information required by the CPR.
NEW Line 0 : Regulation (CPR) and the MSDS contains all the information required by the CPR.
Changed: OLD Line 0 : All reportable chemical substances are listed on the Domestic Substances List (DSL) or
NEW Line 0 : All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise
Changed: OLD Line 0 : otherwise comply with CEPA new substance notification requirements.
NEW Line 0 : comply with CEPA new substance notification requirements.
Changed: OLD Line 0 : This product contains the following chemical(s) subject to the reporting requirements of the
NEW Line 0 : This product contains the following chemical(s) subject to the reporting requirements of the Canadian
Changed: OLD Line 0 : Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release
OLD Line 0 : Inventory.
NEW Line 0 : Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory.
Changed: OLD Line 0 : 16. Other Information
NEW Line 0 : 16. Other Information
NEW Line 0 : User's Responsibility
NEW Line 0 : The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous
NEW Line 0 : Materials Information System (WHMIS) require that the information contained on these sheets be made
NEW Line 0 : available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions.
NEW Line 0 : Instruct your workers to handle this product properly. Consult with appropriate experts to guard against
NEW Line 0 : hazards associated with use of this product and its ingredients.
Changed: OLD Line 0 : Sodium Hydroxide 3% Version: 2.2 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : Sodium Hydroxide 3% Version: 2 Printed: 10/24/2003
Deleted: OLD Line 0 : User's Responsibility
Deleted: OLD Line 0 : The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace
Deleted: OLD Line 0 : Hazardous Materials Information System (WHMIS) require that the information contained on
Deleted: OLD Line 0 : these sheets be made available to your workers. Educate and train your workers regarding
Deleted: OLD Line 0 : OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult
Deleted: OLD Line 0 : with appropriate experts to guard against hazards associated with use of this product and its
Deleted: OLD Line 0 : ingredients.
Changed: OLD Line 0 : SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT
NEW Line 0 : SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR
Changed: OLD Line 0 : OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that
NEW Line 0 : THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product
Changed: OLD Line 0 : the product shall conform to contracted specifications, and that the product does not infringe
NEW Line 0 : shall conform to contracted specifications, and that the product does not infringe any valid United
Changed: OLD Line 0 : any valid United States or Canadian patent. No claim of any kind shall be greater in amount
NEW Line 0 : States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of
Changed: OLD Line 0 : than the purchase price of the quantity of product in respect of which damages are claimed. In
NEW Line 0 : the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for
Changed: OLD Line 0 : no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim
NEW Line 0 : incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty,
Changed: OLD Line 0 : is based on contract, breach of warranty, negligence or otherwise.
NEW Line 0 : negligence or otherwise.
----------***------------------***-------------------***-----------------***----------
----------***------------------***-------------------***-----------------***----------
Material Name (Product Name): Sodium Hydroxide 3%; File: pd2385390.pdf; Product URL: http://full.chemwatch.net/msdscoll/showDoc?filename=pd1623834.pdf
Folder Name : Supplier MSDS'; Document Id : 2385390; Product Id : 1824
Update of Id (Changed Document Id) : 1623834
----------------------------------------------------------------------------------------------------------------------------
Changed: OLD Line 0 : Sodium Hydroxide 3% Version: 2.2 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : Sodium Hydroxide 3% Version: 2 Printed: 10/24/2003
Changed: OLD Line 0 : 1. Chemical Product and Company Identification
NEW Line 0 : 1. Chemical Product and Company Identification
Changed: OLD Line 0 : Hexion Specialty Chemicals, Inc.
NEW Line 0 : BORDEN CHEMICAL, INC.
Changed: OLD Line 0 : 2. Composition, Information on Ingredients
NEW Line 0 : 2. Composition, Information on Ingredients
Changed: OLD Line 0 : The ingredients listed below have been associated with one or more immediate and/or
NEW Line 0 : The ingredients listed below have been associated with one or more immediate and/or delayed(*) health
Changed: OLD Line 0 : delayed(*) health hazards. Risk of damage and effects depends upon duration and level of
NEW Line 0 : hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING,
Changed: OLD Line 0 : exposure. BEFORE USING, HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ
NEW Line 0 : HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE
Changed: OLD Line 0 : AND UNDERSTAND THE MSDS.
NEW Line 0 : MSDS.
Changed: OLD Line 0 : 1310-73-2
NEW Line 0 : 1310-73-2 Sodium Hydroxide 1.0 - 5.0
Changed: OLD Line 0 : Sodium Hydroxide 1.0 - 5.0
NEW Line 0 : 3. Hazards Identification
Changed: OLD Line 0 : Any applicable Canadian trade secret numbers will be listed in Section 15.2.
OLD Line 0 : 3. Hazards Identification
OLD Line 0 : 3.1 Emergency Overview
NEW Line 0 : 3.1 Emergency Overview
Deleted: OLD Line 0 : Page
Deleted: OLD Line 0 : Sodium Hydroxide 3% Version: 2.2 Current Issue: 08/02/2005 Printed: 08/03/2005
Deleted: OLD Line 0 : 2/6
Changed: OLD Line 0 : 3.2 Potential Health Effects
NEW Line 0 : Page
NEW Line 0 : Sodium Hydroxide 3% Version: 2 Printed: 10/24/2003
NEW Line 0 : 2/6
NEW Line 0 : 3.2 Potential Health Effects
Changed: OLD Line 0 : If accidentally swallowed, burns or irritation to mucous membranes,
NEW Line 0 : If accidentally swallowed, burns or irritation to mucous membranes, esophagus
Changed: OLD Line 0 : esophagus or GI tract can result.
NEW Line 0 : or GI tract can result.
Changed: OLD Line 0 : None of the components present in this product at concentrations equal to or greater than
NEW Line 0 : None of the components present in this product at concentrations equal to or greater than 0.1% have
Changed: OLD Line 0 : 0.1% have been listed by NTP, classified by IARC, nor regulated by OSHA as a carcinogen.
NEW Line 0 : been listed by NTP, classified by IARC, nor regulated by OSHA as a carcinogen.
Changed: OLD Line 0 : 4. First Aid Measures
NEW Line 0 : 4. First Aid Measures
Changed: OLD Line 0 : INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. If
NEW Line 0 : INGESTION: If accidentally swallowed, dilute by drinking large quantities of water.
Changed: OLD Line 0 : the individual is drowsy or unconscious, do not give anything by mouth.
NEW Line 0 : Immediately contact poison control center or hospital emergency room for any
Changed: OLD Line 0 : Immediately contact poison control center or hospital emergency room
OLD Line 0 : for advice on whether to induce vomiting or for any other additional
OLD Line 0 : treatment directions.
NEW Line 0 : other additional treatment directions.
Changed: OLD Line 0 : SKIN: Immediately flush with plenty of water for at least 15 minutes while
NEW Line 0 : SKIN: Immediately flush with plenty of water for at least 15 minutes while removing
Changed: OLD Line 0 : removing contaminated clothing. Call a physician. Wash clothing before
NEW Line 0 : contaminated clothing. Call a physician. Wash clothing before reuse.
Changed: OLD Line 0 : reuse.
NEW Line 0 : EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Eyelids
Changed: OLD Line 0 : EYES: Immediately flush eyes with plenty of water for at least 15 minutes.
NEW Line 0 : should be held apart during irrigation to insure water contact with entire
Changed: OLD Line 0 : Eyelids should be held apart during irrigation to ensure water contact
NEW Line 0 : surface of eyes and lids. Call a physician.
Changed: OLD Line 0 : with entire surface of eyes and lids. Call a physician.
OLD Line 0 : 5. Fire Fighting Measures
NEW Line 0 : 5. Fire Fighting Measures
Changed: OLD Line 0 : 6. Accidental Release Measures
NEW Line 0 : 6. Accidental Release Measures
NEW Line 0 : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable
NEW Line 0 : container. For large spills, use water spray to disperse vapors and flush spill area. Prevent runoff from
NEW Line 0 : entering waterways or sewers. Use appropriate Personal Protective Equipment (PPE).
NEW Line 0 : 7. Handling and Storage
Changed: OLD Line 0 : Sodium Hydroxide 3% Version: 2.2 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : Sodium Hydroxide 3% Version: 2 Printed: 10/24/2003
Changed: OLD Line 0 : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable
NEW Line 0 : 7.1 Handling
Changed: OLD Line 0 : container. For large spills, use water spray to disperse vapors and flush spill area. Prevent
NEW Line 0 : Handle in accordance with good industrial hygiene and safety practices. These practices include
Changed: OLD Line 0 : runoff from entering waterways or sewers. Use appropriate Personal Protective Equipment
NEW Line 0 : avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash
Changed: OLD Line 0 : (PPE).
OLD Line 0 : 7. Handling and Storage
OLD Line 0 : 7.1 Handling
OLD Line 0 : Handle in accordance with good industrial hygiene and safety practices. These practices
OLD Line 0 : include avoiding unnecessary exposure and removal of the material from eyes, skin and
OLD Line 0 : clothing. Wash thoroughly after handling. Always use appropriate Personal Protective
OLD Line 0 : Equipment (PPE).
NEW Line 0 : thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE).
Changed: OLD Line 0 : 7.2 Storage
NEW Line 0 : 7.2 Storage
Changed: OLD Line 0 : 8. Exposure Controls/Personal Protection
NEW Line 0 : 8. Exposure Controls/Personal Protection
Changed: OLD Line 0 : 8.1 Exposure Controls
NEW Line 0 : 8.1 Exposure Controls
Changed: OLD Line 0 : ENGINEERING CONTROLS: The following exposure control techniques may be used to
NEW Line 0 : ENGINEERING CONTROLS: The following exposure control techniques may be used to effectively
Changed: OLD Line 0 : effectively minimize employee exposure: local exhaust ventilation, enclosed system design,
NEW Line 0 : minimize employee exposure: local exhaust ventilation, enclosed system design, process isolation and
Changed: OLD Line 0 : process isolation and remote control in combination with appropriate use of personal
NEW Line 0 : remote control in combination with appropriate use of personal protective equipment and prudent work
Changed: OLD Line 0 : protective equipment and prudent work practices. These techniques may not necessarily
NEW Line 0 : practices. These techniques may not necessarily address all issues pertaining to your operations. We,
Changed: OLD Line 0 : address all issues pertaining to your operations. We, therefore, recommend that you consult
NEW Line 0 : therefore, recommend that you consult with experts of your choice to determine whether or not your
Changed: OLD Line 0 : with experts of your choice to determine whether or not your programs are adequate.
NEW Line 0 : programs are adequate.
Changed: OLD Line 0 : If airborne contaminants are generated when the material is heated or handled, sufficient
NEW Line 0 : If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in
Changed: OLD Line 0 : ventilation in volume and air flow patterns should be provided to keep air contaminant
NEW Line 0 : volume and air flow patterns should be provided to keep air contaminant concentration levels below
Changed: OLD Line 0 : concentration levels below acceptable criteria.
NEW Line 0 : acceptable criteria.
Changed: OLD Line 0 : 8.2 Personal Protection
NEW Line 0 : 8.2 Personal Protection
Changed: OLD Line 0 : Wear synthetic apron and boots if contact is likely. Use goggles and face shield if contact is
NEW Line 0 : Wear synthetic apron and boots if contact is likely. Use goggles and face shield if contact is likely.
Changed: OLD Line 0 : likely. Wear impervious gloves as required to prevent skin contact.
NEW Line 0 : Wear impervious gloves as required to prevent skin contact.
Changed: OLD Line 0 : 8.3 Exposure Guidelines
NEW Line 0 : 8.3 Exposure Guidelines
Changed: OLD Line 0 : Remanded
OLD Line 0 : Ceiling
NEW Line 0 : Remanded Ceiling
Changed: OLD Line 0 : Page
OLD Line 0 : Sodium Hydroxide 3% Version: 2.2 Current Issue: 08/02/2005 Printed: 08/03/2005
OLD Line 0 : 4/6
OLD Line 0 : 9. Physical and Chemical Properties
NEW Line 0 : 9. Physical and Chemical Properties
Added: NEW Line 0 : Freezing point Less than 0 癈 (32 癋)
Added: NEW Line 0 : Page
Added: NEW Line 0 : Sodium Hydroxide 3% Version: 2 Printed: 10/24/2003
Added: NEW Line 0 : 4/6
Changed: OLD Line 0 : 10. Stability and Reactivity
NEW Line 0 : 10. Stability and Reactivity
Changed: OLD Line 0 : 11. Toxicological Information
NEW Line 0 : 11. Toxicological Information
Changed: OLD Line 0 : 12. Ecological Information
NEW Line 0 : 12. Ecological Information
Changed: OLD Line 0 : 13. Disposal Considerations
NEW Line 0 : 13. Disposal Considerations
Changed: OLD Line 0 : Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and
NEW Line 0 : Recover free liquid. Absorb residue and dispose of according to local, state/provincial, and federal
Changed: OLD Line 0 : federal requirements.
NEW Line 0 : requirements.
Changed: OLD Line 0 : 14. Transport Information
NEW Line 0 : 14. Transport Information
Changed: OLD Line 0 : 14.1 U.S. Department of Transportation (DOT)
NEW Line 0 : 14.1 U.S. Department of Transportation (DOT)
Changed: OLD Line 0 : The data provided in this section is for information only and may not be specific to your
NEW Line 0 : The data provided in this section is for information only and may not be specific to your package size.
Changed: OLD Line 0 : package size. You will need to apply the appropriate regulations to properly classify your
OLD Line 0 : shipment for transportation.
NEW Line 0 : You will need to apply the appropriate regulations to properly classify your shipment for transportation.
Changed: OLD Line 0 : 14.2 Canadian Transportation of Dangerous Goods (TDG)
NEW Line 0 : 14.2 Canadian Transportation of Dangerous Goods (TDG)
Added: NEW Line 0 : 15. Regulatory Information (Selected Regulations)
Added: NEW Line 0 : 15.1 U.S. Federal Regulations
Added: NEW Line 0 : OSHA Hazards Communication Standard 29CFR1910.1200
Changed: OLD Line 0 : Sodium Hydroxide 3% Version: 2.2 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : Sodium Hydroxide 3% Version: 2 Printed: 10/24/2003
Changed: OLD Line 0 : 15. Regulatory Information (Selected Regulations)
NEW Line 0 : This material is a "health hazard" and/or a "physical hazard" as determined when reviewed according to
Changed: OLD Line 0 : 15.1 U.S. Federal Regulations
NEW Line 0 : the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200
Changed: OLD Line 0 : OSHA Hazards Communication Standard 29CFR1910.1200
OLD Line 0 : This material is a "health hazard" and/or a "physical hazard" as determined when reviewed
OLD Line 0 : according to the requirements of the Occupational Safety and Health Administration 29 CFR
OLD Line 0 : Part 1910.1200 "Hazard Communication" Standard.
NEW Line 0 : "Hazard Communication" Standard.
Changed: OLD Line 0 : This product contains the following toxic chemical(s) subject to the reporting requirements of
NEW Line 0 : This product contains the following toxic chemical(s) subject to the reporting requirements of Section
Changed: OLD Line 0 : Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and
NEW Line 0 : 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C-
Changed: OLD Line 0 : Subpart C-Supplier Notification Requirement of 40 CFR Part 372.
NEW Line 0 : Supplier Notification Requirement of 40 CFR Part 372.
Changed: OLD Line 0 : All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications
NEW Line 0 : All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of
Changed: OLD Line 0 : of compliance from our suppliers for chemical substances not manufactured by us.
NEW Line 0 : compliance from our suppliers for chemical substances not manufactured by us.
Changed: OLD Line 0 : 15.2 Canadian Regulations
NEW Line 0 : 15.2 Canadian Regulations
Changed: OLD Line 0 : This product has been classified in accordance with the hazard criteria of the Controlled
NEW Line 0 : This product has been classified in accordance with the hazard criteria of the Controlled Products
Changed: OLD Line 0 : Products Regulation (CPR) and the MSDS contains all the information required by the CPR.
NEW Line 0 : Regulation (CPR) and the MSDS contains all the information required by the CPR.
Changed: OLD Line 0 : All reportable chemical substances are listed on the Domestic Substances List (DSL) or
NEW Line 0 : All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise
Changed: OLD Line 0 : otherwise comply with CEPA new substance notification requirements.
NEW Line 0 : comply with CEPA new substance notification requirements.
Changed: OLD Line 0 : This product contains the following chemical(s) subject to the reporting requirements of the
NEW Line 0 : This product contains the following chemical(s) subject to the reporting requirements of the Canadian
Changed: OLD Line 0 : Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release
OLD Line 0 : Inventory.
NEW Line 0 : Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory.
Changed: OLD Line 0 : 16. Other Information
NEW Line 0 : 16. Other Information
NEW Line 0 : User's Responsibility
NEW Line 0 : The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous
NEW Line 0 : Materials Information System (WHMIS) require that the information contained on these sheets be made
NEW Line 0 : available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions.
NEW Line 0 : Instruct your workers to handle this product properly. Consult with appropriate experts to guard against
NEW Line 0 : hazards associated with use of this product and its ingredients.
Changed: OLD Line 0 : Sodium Hydroxide 3% Version: 2.2 Current Issue: 08/02/2005 Printed: 08/03/2005
NEW Line 0 : Sodium Hydroxide 3% Version: 2 Printed: 10/24/2003
Deleted: OLD Line 0 : User's Responsibility
Deleted: OLD Line 0 : The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace
Deleted: OLD Line 0 : Hazardous Materials Information System (WHMIS) require that the information contained on
Deleted: OLD Line 0 : these sheets be made available to your workers. Educate and train your workers regarding
Deleted: OLD Line 0 : OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult
Deleted: OLD Line 0 : with appropriate experts to guard against hazards associated with use of this product and its
Deleted: OLD Line 0 : ingredients.
Changed: OLD Line 0 : SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT
NEW Line 0 : SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR
Changed: OLD Line 0 : OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that
NEW Line 0 : THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product
Changed: OLD Line 0 : the product shall conform to contracted specifications, and that the product does not infringe
NEW Line 0 : shall conform to contracted specifications, and that the product does not infringe any valid United
Changed: OLD Line 0 : any valid United States or Canadian patent. No claim of any kind shall be greater in amount
NEW Line 0 : States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of
Changed: OLD Line 0 : than the purchase price of the quantity of product in respect of which damages are claimed. In
NEW Line 0 : the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for
Changed: OLD Line 0 : no event shall Seller be liable for incidental or consequential damages, whether Buyer's claim
NEW Line 0 : incidental or consequential damages, whether Buyer's claim is based on contract, breach of warranty,
Changed: OLD Line 0 : is based on contract, breach of warranty, negligence or otherwise.
NEW Line 0 : negligence or otherwise.
----------***------------------***-------------------***-----------------***----------
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Material Name (Product Name): Open Gear Spray; File: pd749447.htm.gz; Product URL: http://full.chemwatch.net/msdscoll/showDoc?filename=pd0.txt.gz
Folder Name : Supplier MSDS'; Document Id : 749447; Product Id : 7382975
Update of Id (Changed Document Id) : 0
----------------------------------------------------------------------------------------------------------------------------
Changed: OLD Line 0 : HMIS BCPHP : OPEN GEAR SPRAY
OLD Line 0 : /HMIS_Msds/HMIS/086/BCPHP.HTM (1 hits)
OLD Line 0 : OPEN GEAR SPRAY
OLD Line 0 : Product and Company Identification
OLD Line 0 : Composition/Information on Ingredients
OLD Line 0 : Hazards Identification
OLD Line 0 : First Aid Measures
OLD Line 0 : Fire Fighting Measures
OLD Line 0 : Accidental Release Measures
OLD Line 0 : Handling and Storage
OLD Line 0 : Exposure Controls/Personal Protection
OLD Line 0 : Physical and Chemical Properties
OLD Line 0 : Stability and Reactivity
OLD Line 0 : Toxicological Information
OLD Line 0 : Ecological Information
OLD Line 0 : Disposal Considerations
OLD Line 0 : Transport Information
OLD Line 0 : Regulatory Information
OLD Line 0 : Other Information / Hazmat Info / Hazcom Label
OLD Line 0 : !! This is an ARCHIVE Record !!
OLD Line 0 : MSDS Safety Information
OLD Line 0 : TOP
OLD Line 0 : FSC:
OLD Line 0 : 6850
OLD Line 0 : MSDS Date:
OLD Line 0 : 01/01/1987
OLD Line 0 : MSDS Num:
OLD Line 0 : BCPHP
OLD Line 0 : Submitter:
OLD Line 0 : N EN
OLD Line 0 : LIIN:
OLD Line 0 : 00N008065
OLD Line 0 : Tech Review:
OLD Line 0 : 07/13/1986
OLD Line 0 : Status CD:
OLD Line 0 : C
OLD Line 0 : Product ID:
OLD Line 0 : OPEN GEAR SPRAY
OLD Line 0 : MFN:
OLD Line 0 : 01
OLD Line 0 : Article:
OLD Line 0 : N
OLD Line 0 : Kit Part:
OLD Line 0 : N
OLD Line 0 : Responsible Party
OLD Line 0 : Cage:
OLD Line 0 : DRYDE
OLD Line 0 : Name:
OLD Line 0 : DRYDEN OIL COMPANY,INC.
OLD Line 0 : City:
OLD Line 0 : N/P
OLD Line 0 : State:
OLD Line 0 : NK
OLD Line 0 : Zip:
OLD Line 0 : 00000
OLD Line 0 : Country:
OLD Line 0 : NK
OLD Line 0 : Emergency Phone Number:
OLD Line 0 : 301-574-5000
OLD Line 0 : Preparer's Name:
OLD Line 0 : N/P
OLD Line 0 : Proprietary Ind:
OLD Line 0 : Y
OLD Line 0 : Review Ind:
OLD Line 0 : Y
OLD Line 0 : Published:
OLD Line 0 : Y
OLD Line 0 : Special Project CD:
OLD Line 0 : N
OLD Line 0 : Contractor Summary
OLD Line 0 : TOP
OLD Line 0 : Cage:
OLD Line 0 : 40310
OLD Line 0 : Name:
OLD Line 0 : DRYDEN OIL CO INC
OLD Line 0 : Address:
OLD Line 0 : 9300 PULASKI HWY
OLD Line 0 : City:
OLD Line 0 : BALTIMORE
OLD Line 0 : State:
OLD Line 0 : MD
OLD Line 0 : Zip:
OLD Line 0 : 21220
OLD Line 0 : Country:
OLD Line 0 : US
OLD Line 0 : Phone:
OLD Line 0 : UNKNOWN
OLD Line 0 : Cage:
OLD Line 0 : DRYDE
OLD Line 0 : Name:
OLD Line 0 : DRYDEN OIL COMPANY, INC
OLD Line 0 : Address:
OLD Line 0 : 9300 PULASKI HIGHWAY
OLD Line 0 : Box:
OLD Line 0 : N/K
OLD Line 0 : City:
OLD Line 0 : BALTIMORE
OLD Line 0 : State:
OLD Line 0 : MD
OLD Line 0 : Zip:
OLD Line 0 : 21220
OLD Line 0 : Country:
OLD Line 0 : US
OLD Line 0 : Phone:
OLD Line 0 : 410-574-500
OLD Line 0 : Ingredients
OLD Line 0 : TOP
OLD Line 0 : Cas:
OLD Line 0 : Code:
OLD Line 0 : RTECS #:
OLD Line 0 : Code:
OLD Line 0 : Name:
OLD Line 0 : *** PROPRIETARY HMIS ***
OLD Line 0 : Environmental Wt:
OLD Line 0 : Other REC Limits:
OLD Line 0 : OSHA PEL:
OLD Line 0 : Code:
OLD Line 0 : OSHA STEL:
OLD Line 0 : Code:
OLD Line 0 : ACGIH TLV:
OLD Line 0 : Code:
OLD Line 0 : ACGIH STEL:
OLD Line 0 : Code:
OLD Line 0 : EPA Rpt Qty:
OLD Line 0 : DOT Rpt Qty:
OLD Line 0 : Ozone Depleting Chemical:
OLD Line 0 : Cas:
OLD Line 0 : Code:
OLD Line 0 : RTECS #:
OLD Line 0 : Code:
OLD Line 0 : Name:
OLD Line 0 : Environmental Wt:
OLD Line 0 : Other REC Limits:
OLD Line 0 : OSHA PEL:
OLD Line 0 : Code:
OLD Line 0 : OSHA STEL:
OLD Line 0 : Code:
OLD Line 0 : ACGIH TLV:
OLD Line 0 : Code:
OLD Line 0 : ACGIH STEL:
OLD Line 0 : Code:
OLD Line 0 : EPA Rpt Qty:
OLD Line 0 : DOT Rpt Qty:
OLD Line 0 : Ozone Depleting Chemical:
OLD Line 0 : Health Hazards Data
OLD Line 0 : TOP
OLD Line 0 : LD50 LC50 Mixture
OLD Line 0 : N/P
OLD Line 0 : Route Of Entry Inds - Inhalation:
OLD Line 0 : N/P
OLD Line 0 : Skin:
OLD Line 0 : N/P
OLD Line 0 : Ingestion:
OLD Line 0 : N/P
OLD Line 0 : Carcinogenicity Inds - NTP:
OLD Line 0 : N/P
OLD Line 0 : IARC:
OLD Line 0 : N/P
OLD Line 0 : OSHA:
OLD Line 0 : N/P
OLD Line 0 : Health Hazards Acute And Chronic
OLD Line 0 : N/P
OLD Line 0 : Explanation Of Carcinogenicity
OLD Line 0 : N/P
OLD Line 0 : Signs And Symptions Of Overexposure
OLD Line 0 : SKIN & EYE IRRIT.HARMFUL/FATAL IF INGEST.INHALATION POSS HARMFUL,MAY CAUSE DIZZINESS,HEADACHE,NAUSEA
OLD Line 0 : Medical Cond Aggravated By Exposure
OLD Line 0 : N/P
OLD Line 0 : First Aid Information
OLD Line 0 : TOP
OLD Line 0 : EYE:FLUSH W/COPIOUS AMTS OF H*2O FOR @ LEAST 15 MIN.CALL PHYSICIAN.SKIN:WASH AFFECTED AREA W/SOAP & H*2O.INGEST:DO NOTINDUCE VOMITING.CALL PHYSICIAN IMMEDIATELY,INHAL:REMOVE TO FRESH AIR.IF BREATHING HAS STOPPED GIVE ARTIFICAL RESPIRATION.
OLD Line 0 : Spill Release Procedures
OLD Line 0 : TOP
OLD Line 0 : ELIMINATE SOURCES OF HEAT/IGNITION.VENTILATE AREA.APPLY ABSORBENT TO THE SPILL AREA.
OLD Line 0 : Neutralizing Agent
OLD Line 0 : N/P
OLD Line 0 : Waste Disposal Methods
OLD Line 0 : TOP
OLD Line 0 : ABSORBING MATERIAL/DEFECTIVE CONTAINERS SHOULD BE DISPOSED OF @ APPROVED WASTE SITE.DISPOSE OF IAW FEDERAL,STATE & LOCAL REGUALTIONS.
OLD Line 0 : Handling and Storage Precautions
OLD Line 0 : TOP
OLD Line 0 : EXTREMELY FLAM.STORE,USE AWAY FROM ALL HEAT,IGNITION SOURCES.USE ADEQ VENT.CONTENTS UNDER PRESSURE.DONT STORE ABOVE 120F.DONT PUNCTURE/INCINERATE.
OLD Line 0 : Other Precautions
OLD Line 0 : NO SMOKING IN AREA.DONT USE IN GENL VICINITY OF ARCWELDNG,OPEN FLM/HOT SURF.HEAT &/OR UV RADIATION MAY CAUSE HCL/PHOSGENEFORMATION.VAP PRESS:190-195 @ 100F(PROPANE).BOILING PT FOR PROPANE.
OLD Line 0 : Fire and Explosion Hazard Information
OLD Line 0 : TOP
OLD Line 0 : Flash Point Method:
OLD Line 0 : N/P
OLD Line 0 : Flash Point:
OLD Line 0 : Flash Point Text:
OLD Line 0 : -156F,TCC(PROPAN
OLD Line 0 : Autoignition Temp:
OLD Line 0 : Autoignition Temp Text:
OLD Line 0 : N/A
OLD Line 0 : Lower Limits:
OLD Line 0 : 2.2
OLD Line 0 : Upper Limits:
OLD Line 0 : 8.9
OLD Line 0 : Extinguishing Media
OLD Line 0 : FOAM,CO*2,DRY CHEMICALS
OLD Line 0 : Fire Fighting Procedures
OLD Line 0 : WEAR PRESS DEMAND SCBA,FULL PROT CLTHG.HANDLE AS FLAM LIQUID
OLD Line 0 : Unusual Fire/Explosion Hazard
OLD Line 0 : CONTENTS UNDER PRESSURE.COOL CNTNRS EXPOSED TO HEAT. THERMAL DECOMP PROD MAY INCLUDE HCL,PHOSGENE.
OLD Line 0 : Control Measures
OLD Line 0 : TOP
OLD Line 0 : Respiratory Protection
OLD Line 0 : NOT NORMALLY REQUIRED IF AREA IS PROPERLY VENTILATED(MFR).
OLD Line 0 : Ventilation
OLD Line 0 : LOCAL EXHAUST VENT & MECH VENTAS REQUIRED
OLD Line 0 : Protective Gloves
OLD Line 0 : AS REQUIRED
OLD Line 0 : Eye Protection
OLD Line 0 : SFTY GLASSES/GOGGLES.
OLD Line 0 : Other Protective Equipment
OLD Line 0 : N/P
OLD Line 0 : Work Hygienic Practices
OLD Line 0 : N/P
OLD Line 0 : Supplemental Safety and Health
OLD Line 0 : PRODUCT DOES NOT CONTAN COAL TAR PITCH(CAS# 8007-45-2) IN ASPHALT. DOP:6/25/86.
OLD Line 0 : Physical/Chemical Properties
OLD Line 0 : TOP
OLD Line 0 : HCC:
OLD Line 0 : NRC/State LIC No:
OLD Line 0 : N/A
OLD Line 0 : Net Prop WT For Ammo:
OLD Line 0 : N/A
OLD Line 0 : Boiling Point:
OLD Line 0 : B.P. Text:
OLD Line 0 : -43.7F
OLD Line 0 : Melt/Freeze Pt:
OLD Line 0 : M.P/F.P Text:
OLD Line 0 : N/A
OLD Line 0 : Decomp Temp:
OLD Line 0 : Decomp Text:
OLD Line 0 : N/A
OLD Line 0 : Vapor Pres:
OLD Line 0 : N/P
OLD Line 0 : Vapor Density:
OLD Line 0 : N/P
OLD Line 0 : Volatile Org Content %:
OLD Line 0 : Spec Gravity:
OLD Line 0 : 0.96
OLD Line 0 : VOC Pounds/Gallon:
OLD Line 0 : PH:
OLD Line 0 : N/P
OLD Line 0 : VOC Grams/Liter:
OLD Line 0 : Viscosity:
OLD Line 0 : N/A
OLD Line 0 : Evaporation Rate & Reference:
OLD Line 0 : FASTER THAN ETHER.
OLD Line 0 : Solubility in Water:
OLD Line 0 : MODERATE.
OLD Line 0 : Appearance and Odor:
OLD Line 0 : BLACK/CHLORINATED SOLVENT.
OLD Line 0 : Percent Volatiles by Volume:
OLD Line 0 : 71
OLD Line 0 : Corrosion Rate:
OLD Line 0 : N/P
OLD Line 0 : Seton Resource Center
OLD Line 0 : Allow access to non-virtual folders: 0
OLD Line 0 : Reactivity Data
OLD Line 0 : TOP
OLD Line 0 : Stability Indicator:
OLD Line 0 : YES
OLD Line 0 : Stability Condition To Avoid:
OLD Line 0 : HEAT,SPARKS/OPEN FLAME
OLD Line 0 : Materials To Avoid:
OLD Line 0 : STRONG OXIDANTS
OLD Line 0 : Hazardous Decomposition Products:
OLD Line 0 : HCL,PHOSENE
OLD Line 0 : Hazardous Polymerization Indicator:
OLD Line 0 : NO
OLD Line 0 : Conditions To Avoid Polymerization :
OLD Line 0 : N/P
OLD Line 0 : Toxicological Information
OLD Line 0 : TOP
OLD Line 0 : Toxicological Information:
OLD Line 0 : N/P
OLD Line 0 : Ecological Information
OLD Line 0 : TOP
OLD Line 0 : Ecological:
OLD Line 0 : N/P
OLD Line 0 : MSDS Transport Information
OLD Line 0 : TOP
OLD Line 0 : Transport Information:
OLD Line 0 : N/P
OLD Line 0 : Regulatory Information
OLD Line 0 : TOP
OLD Line 0 : Sara Title III Information:
OLD Line 0 : N/P
OLD Line 0 : Federal Regulatory Information:
OLD Line 0 : N/P
OLD Line 0 : State Regulatory Information:
OLD Line 0 : N/P
OLD Line 0 : Other Information
OLD Line 0 : TOP
OLD Line 0 : Other Information:
OLD Line 0 : N/P
OLD Line 0 : HMIS Transportation Information
OLD Line 0 : TOP
OLD Line 0 : Responsible Party Cage:
OLD Line 0 : DRYDE
OLD Line 0 : Trans ID NO:
OLD Line 0 : 14538
OLD Line 0 : Product ID:
OLD Line 0 : OPEN GEAR SPRAY
OLD Line 0 : MSDS Prepared Date:
OLD Line 0 : 01/01/1987
OLD Line 0 : Review Date:
OLD Line 0 : 09/24/1986
OLD Line 0 : MFN:
OLD Line 0 : 1
OLD Line 0 : Submitter:
OLD Line 0 : N TN
OLD Line 0 : Status CD:
OLD Line 0 : C
OLD Line 0 : Article W/O MSDS :
OLD Line 0 : N
OLD Line 0 : Tech Entry NOS Shipping Nm:
OLD Line 0 : PROPANE PROPELLANT
OLD Line 0 : Radioactivity:
OLD Line 0 : N/A
OLD Line 0 : Form:
OLD Line 0 : Net Explosive Weight:
OLD Line 0 : N/A
OLD Line 0 : Coast Guard AMMO Code:
OLD Line 0 : N/A
OLD Line 0 : Magnetism:
OLD Line 0 : N/P
OLD Line 0 : Net Unit Weight:
OLD Line 0 : N/K
OLD Line 0 : AF MMAC Code:
OLD Line 0 : DOD Exemption NUM:
OLD Line 0 : N/A
OLD Line 0 : Limited Quantity IND:
OLD Line 0 : Multiple KIT Number:
OLD Line 0 : 0
OLD Line 0 : Kit IND:
OLD Line 0 : N
OLD Line 0 : Kit Part IND:
OLD Line 0 : N
OLD Line 0 : Review IND:
OLD Line 0 : Y
OLD Line 0 : Unit Of Issue:
OLD Line 0 : NK
OLD Line 0 : Container QTY:
OLD Line 0 : NK
OLD Line 0 : Type Of Container:
OLD Line 0 : Additional Data:
OLD Line 0 : CONTENTS UNDER PRESSURE
OLD Line 0 : Detail DOT Information
OLD Line 0 : TOP
OLD Line 0 : DOT PSN Code:
OLD Line 0 : DQH
OLD Line 0 : Symbols:
OLD Line 0 : DOT Proper Shipping Name:
OLD Line 0 : COMPRESSED GASES, FLAMMABLE, N.O.S.
OLD Line 0 : DOT PSN Modifier:
OLD Line 0 : Hazard Class:
OLD Line 0 : 2.1
OLD Line 0 : UN ID Num:
OLD Line 0 : UN1954
OLD Line 0 : DOT Packaging Group:
OLD Line 0 : Label:
OLD Line 0 : FLAMMABLE GAS
OLD Line 0 : Special Provision:
OLD Line 0 : B13
OLD Line 0 : Packaging Exception:
OLD Line 0 : Non Bulk Pack:
OLD Line 0 : 302,305
OLD Line 0 : Bulk Pack:
OLD Line 0 : 314,315
OLD Line 0 : Max Qty Pass:
OLD Line 0 : FORBIDDEN
OLD Line 0 : Max Qty Cargo:
OLD Line 0 : 150 KG
OLD Line 0 : Vessel Stow Req:
OLD Line 0 : D
OLD Line 0 : Water/Ship/Other Req:
OLD Line 0 : 40
OLD Line 0 : Detail IMO Information
OLD Line 0 : TOP
OLD Line 0 : IMO PSN Code:
OLD Line 0 : EQB
OLD Line 0 : IMO Proper Shipping Name:
OLD Line 0 : COMPRESSED GAS, FLAMMABLE, N.O.S. o
OLD Line 0 : IMO PSN Modifier:
OLD Line 0 : IMDG Page Number:
OLD Line 0 : 2124
OLD Line 0 : UN Number:
OLD Line 0 : 1954
OLD Line 0 : UN Hazard Class:
OLD Line 0 : 2(2.1)
OLD Line 0 : IMO Packaging Group:
OLD Line 0 : -
OLD Line 0 : Subsidiary Risk Label:
OLD Line 0 : -
OLD Line 0 : EMS Number:
OLD Line 0 : 2-02
OLD Line 0 : MED First Aid Guide NUM:
OLD Line 0 : 620
OLD Line 0 : Detail IATA Information
OLD Line 0 : TOP
OLD Line 0 : IATA PSN Code:
OLD Line 0 : HDE
OLD Line 0 : IATA UN ID NUM:
OLD Line 0 : 1954
OLD Line 0 : IATA Proper Shipping Name:
OLD Line 0 : COMPRESSED GAS, FLAMMABLE, N.O.S. *
OLD Line 0 : IATA PSN Modifier:
OLD Line 0 : IATA UN Class:
OLD Line 0 : 2.1
OLD Line 0 : Subsidiary Risk Class:
OLD Line 0 : IATA Label:
OLD Line 0 : FLAMMABLE GAS
OLD Line 0 : UN Packing Group:
OLD Line 0 : Packing Note Passenger:
OLD Line 0 : FORB
OLD Line 0 : Max Quant Pass:
OLD Line 0 : FORB
OLD Line 0 : Max Quant Cargo:
OLD Line 0 : 150KG
OLD Line 0 : Packaging Note Cargo:
OLD Line 0 : 200
OLD Line 0 : Exceptions:
OLD Line 0 : A1
OLD Line 0 : Detail AFI Information
OLD Line 0 : TOP
OLD Line 0 : AFI PSN Code:
OLD Line 0 : HDE
OLD Line 0 : AFI Symbols:
OLD Line 0 : *
OLD Line 0 : AFI Proper Shipping Name:
OLD Line 0 : COMPRESSED GAS, FLAMMABLE, N.O.S.
OLD Line 0 : AFI PSN Modifier:
OLD Line 0 : AFI Hazard Class:
OLD Line 0 : 2.1
OLD Line 0 : AFI UN ID NUM:
OLD Line 0 : UN1954
OLD Line 0 : AFI Packing Group:
OLD Line 0 : N/A
OLD Line 0 : AFI Label:
OLD Line 0 : Special Provisions:
OLD Line 0 : P4
OLD Line 0 : Back Pack Reference:
OLD Line 0 : A6.3, A6.5
OLD Line 0 : HMIS HAZCOM Label
OLD Line 0 : TOP
OLD Line 0 : Product ID:
OLD Line 0 : OPEN GEAR SPRAY
OLD Line 0 : Cage:
OLD Line 0 : DRYDE
OLD Line 0 : Assigned IND:
OLD Line 0 : Y
OLD Line 0 : Company Name:
OLD Line 0 : DRYDEN OIL COMPANY, INC
OLD Line 0 : Street:
OLD Line 0 : 9300 PULASKI HIGHWAY
OLD Line 0 : PO Box:
OLD Line 0 : N/K
OLD Line 0 : City:
OLD Line 0 : BALTIMORE
OLD Line 0 : State:
OLD Line 0 : MD
OLD Line 0 : Zipcode:
OLD Line 0 : 21220
OLD Line 0 : Country:
OLD Line 0 : US
OLD Line 0 : Health Emergency Phone:
OLD Line 0 : 301-574-5000
OLD Line 0 : Label Required IND:
OLD Line 0 : Y
OLD Line 0 : Date Of Label Review:
OLD Line 0 : 12/16/1998
OLD Line 0 : Status Code:
OLD Line 0 : C
OLD Line 0 : MFG Label NO:
OLD Line 0 : Label Date:
OLD Line 0 : 12/16/1998
OLD Line 0 : Year Procured:
OLD Line 0 : N/K
OLD Line 0 : Origination Code:
OLD Line 0 : G
OLD Line 0 : Chronic Hazard IND:
OLD Line 0 : N/P
OLD Line 0 : Eye Protection IND:
OLD Line 0 : N/P
OLD Line 0 : Skin Protection IND:
OLD Line 0 : N/P
OLD Line 0 : Signal Word:
OLD Line 0 : N/P
OLD Line 0 : Respiratory Protection IND:
OLD Line 0 : N/P
OLD Line 0 : Health Hazard:
OLD Line 0 : Contact Hazard:
OLD Line 0 : Fire Hazard:
OLD Line 0 : Reactivity Hazard:
OLD Line 0 : Hazard And Precautions
OLD Line 0 : SKIN & EYE IRRIT.HARMFUL/FATAL IF INGEST.INHALATION POSS HARMFUL,MAY CAUSE DIZZINESS,HEADACHE,NAUSEA
OLD Line 0 : This information is derived from the Hazardous Material Information System which is utilized by the U.S. Department of Defense. IntraWEB, LLC and its Distributors in no manner whatsoever, expressly or implied warrants, states, or intends said information to have any application use or viability by or to any person or persons. Any person utilizing this information should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.
NEW Line 0 : ---------------- MATERIAL SAFETY DATA SHEET --------------- DURATROL HOUSEHOLD FLEA SPRAY - NO.1488T, 1488R 3M Canada ----------------------------------------------------------- MANUFACTURER: 3M CANADA INC. POST OFFICE BOX 5757 LONDON, ONTARIO N6A 4T1 MEDICAL EMERGENCY TELEPHONE: (519) 451-2500, EXT. 2222 DOCUMENT ID: 10-5506-0 VERSION: 7.00 ISSUE DATE: 05/14/95 SUPERSEDES DATE: 04/08/95 PREPARED BY: Corporate Loss Prevention Department, 3M Canada Inc. TELEPHONE: (519) 452-6102 FAX: (519) 452-6015 ----------------------------------------------------------- 1 PRODUCT IDENTIFICATION ----------------------------------------------------------- TRADENAME: Duratrol Household Flea Spray - NO.1488T, 1488R 3M PRODUCT ID: 70-2005-2331-7 70-2005-2332-5 70-2005-2333-3 70-2006-1369-6 70-2006-1370-4 70-2006-1371-2 70-2006-3338-9 70-2006-3339-7 70-2006-3340-5 CT-0607-1859-1 CT-0607-2277-5 CT-0607-3803-7 CH-0000-0045-5 CT-0607-3804-5 INTENDED USE OF PRODUCT: Household Flea Spray DIVISION: Animal Care Products Project ----------------------------------------------------------- 2 COMPOSITION/INFORMATION ON INGREDIENTS ----------------------------------------------------------- Ingredient Name CAS Number Percentage ----------------------------------------------------------- Water 7732-18-5 99.2 Chlorpyrifos 2921-88-2 0.5 Polymeric Shell Trade Secret 0.3 Wall Material NOTE: Polymeric shell wall material is a trade secret material. ----------------------------------------------------------- 3 HAZARDS IDENTIFICATION ----------------------------------------------------------- CRITICAL HAZARDS: Allergic Skin Reaction: Signs/symptoms can include redness, swelling, blistering, and itching. See Sections 7 and 11 for further information. ----------------------------------------------------------- 4 FIRST AID MEASURES ----------------------------------------------------------- INSTRUCTIONS FOR EYE CONTACT: Immediately flush eyes with large amounts of water. Get immediate medical attention. INSTRUCTIONS FOR SKIN CONTACT: Immediately wash skin with soap and large amounts of water. Remove contaminated clothing. If signs/symptoms occur, call a physician. Wash contaminated clothing before reuse and dispose of contaminated shoes. INSTRUCTIONS FOR INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. INSTRUCTIONS FOR INGESTION: If swallowed: If conscious, induce vomiting immediately as directed by medical personnel. SPECIAL INSTRUCTIONS: Atropine by intravenous administration is the preferable antidote. Suggest serum and/or RBC cholinesterase determination. Treatment based on judgement of the physician in response to reactions of the patient. ----------------------------------------------------------- 5 FIRE FIGHTING MEASURES ----------------------------------------------------------- FLASH POINT: Not applicable LOWER EXPLOSIVE LIMIT (%): Not applicable UPPER EXPLOSIVE LIMIT (%): Not applicable AUTOIGNITION TEMPERATURE: Unknown SUITABLE EXTINGUISHING MEDIA: Water; carbon dioxide; dry chemical; foam EXPOSURE HAZARDS DURING FIRE: No data available COMBUSTION PRODUCTS FROM FIRE: None known FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants , bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SPECIAL INSTRUCTIONS: Runoff must be contained, may contain product which is toxic to fish and other marine organisms. ----------------------------------------------------------- 6 ACCIDENTAL RELEASE MEASURES ----------------------------------------------------------- PERSONAL PRECAUTIONS: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. SPILL RESPONSE: Contain spill. Cover with absorbent material. Collect spilled material. Clean up residue with water. Place in an approved container and seal. METHODS OF DISPOSAL: Do not release to waterways or sewer. Incinerate in a permitted hazardous waste incinerator in the presence of a combustible material. Combustion products will include HCl. ----------------------------------------------------------- 7 HANDLING AND STORAGE ----------------------------------------------------------- STORAGE REQUIREMENTS: Keep container closed when not in use. INCOMPATIBLE MATERIALS: None known. USE INSTRUCTIONS: Keep container tightly closed. ----------------------------------------------------------- 8 EXPOSURE CONTROLS/PERSONAL PROTECTION ----------------------------------------------------------- PERSONAL PROTECTION: EYE PROTECTION: Avoid eye contact. Wear unvented goggles during operations in which exposure is likely. HAND PROTECTION: Wear appropriate gloves when handling this material. A pair of gloves from the following material(s) are recommended: Nitrile rubber; fluoroelastomer (Viton). SKIN PROTECTION: Avoid prolonged or repeated skin contact. RESPIRATORY PROTECTION: Avoid prolonged breathing of spray or mists. INGESTION (PREVENTION): Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep out of the reach of children. RECOMMENDED VENTILATION: Use in a well-ventilated area. Provide sufficient ventilation to maintain emissions below recommended exposure limits. INGREDIENT EXPOSURE DATA: WATER (7732-18-5) SPECIFIC INGREDIENT DATA: Not applicable CHLORPYRIFOS (2921-88-2) LD50 (rat, oral): 82 mg/kg LC50 (rat, inhalation/4 hours): 14 ppm PIN (Product Identification Number): NA 2693 ONTARIO TWAEV: 0.2 mg/m3 ONTARIO STEL: 0.6 mg/m3 ACGIH TLV-TWA: 0.2 mg/m3 SKIN NOTATION: Overall exposure for this substance will be influenced by cutaneous route exposure, including mucous membrane and eye, either by airborne or more particularly by direct contact with the substance. Vehicles can alter skin absorption. ----------------------------------------------------------- 9 PHYSICAL AND CHEMICAL PROPERTIES ----------------------------------------------------------- PHYSICAL FORM, COLOR, ODOUR: Liquid suspension of microcapsules in water; white ODOUR THRESHOLD: No data available pH: 7.50-8.50 BOILING POINT/BOILING RANGE: 100.0 deg C MELTING POINT/MELTING RANGE: Unknown VAPOUR PRESSURE: Unknown WATER SOLUBILITY: Complete PARTITION COEFFICIENT (K o/w): No data available SPECIFIC GRAVITY: 1.001 g/cc VAPOUR DENSITY: Unknown VOLATILE ORGANIC COMPOUNDS: Unknown EVAPORATION RATE: Unknown VISCOSITY: 1.0-5.0 centipoise at 20 deg C ----------------------------------------------------------- 10 STABILITY AND REACTIVITY ----------------------------------------------------------- CONDITIONS TO AVOID: None known. MATERIALS TO AVOID: Heat HAZARDOUS DECOMPOSITION: Carbon monoxide and carbon dioxide; hydrogen chloride; toxic vapours, gases or particulates. STABILITY AND REACTIVITY: Stable. Hazardous polymerization will not occur. ----------------------------------------------------------- 11 TOXICOLOGICAL INFORMATION ----------------------------------------------------------- EFFECTS FROM EYE CONTACT: MILD EYE IRRITATION: Signs/symptoms can include redness, swelling, pain and tearing. EFFECTS FROM SKIN CONTACT: ALLERGIC SKIN REACTION: Signs/symptoms can include redness, swelling, blistering and itching. MILD SKIN IRRITATION (after prolonged or repeated contact): Signs/symptoms can include redness, swelling, and itching. EFFECTS FROM INHALATION: IRRITATION (upper respiratory): Signs/symptoms can include soreness of the nose and throat, coughing and sneezing. EFFECTS FROM INGESTION: IRRITATION OF GASTROINTESTINAL TISSUES: Signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. SENSITIZATION INFORMATION: No data available. CARCINOGENICITY: No data available. MUTAGENICITY: No data available. REPRODUCTIVE EFFECTS: No data available. ----------------------------------------------------------- 12 ECOLOGICAL INFORMATION ----------------------------------------------------------- ECOTOXICITY DATA: No data available. OTHER EFFECTS AND INFORMATION: Product is toxic to fish and other marine organisms. Keep product out of lakes, streams and ponds. ----------------------------------------------------------- 13 DISPOSAL CONSIDERATIONS ----------------------------------------------------------- PRODUCT AS SOLD: No data available. PRODUCT PACKAGING: No data available. SPECIAL INSTRUCTIONS: Since regulations vary, consult applicable regulations or authorities before disposal. ----------------------------------------------------------- 14 TRANSPORTATION INFORMATION ----------------------------------------------------------- TRANSPORTATION OF DANGEROUS GOODS: TDG CLASSIFICATION: Non-regulated material. INTERNATIONAL DANGEROUS GOODS CLASSIFICATION: IMO CLASS: No data available. ICAO CLASS: No data available. ----------------------------------------------------------- 15 REGULATORY INFORMATION ----------------------------------------------------------- WHMIS CLASSIFICATION: Exempt (Registered under Pest Control Products Act.) NOTE: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. ----------------------------------------------------------- 16 OTHER INFORMATION ----------------------------------------------------------- REASON FOR REISSUE: Update tradename. ----------------------------------------------------------- The information on this data sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this data sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user. ----------------------------------------------------------- DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representation as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose(s). A request has been made to the manufacturer to approve the contents of this material safety data sheet. Upon receipt a new MSDS will be made available. ----------------------------------------------------------- COMPAS Code: 20100030 -----------------------------------------------------------
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