Page 1 of 7
Material
Safety
Data
Sheet
24 Hour Emergency Phone Numbers:
?Medical: 1-800-327-3874
1-513-558-5111
Transportation:
1-800-535-5053
1-352-323-3500
NOTE: National Response Center emergency numbers to be used
only in the event of chemical emergencies involving a spill, leak,
fire, exposure or accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or
disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been
prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section
16.
Section 1 -Chemical Product / Company Information
This Material Safety Data Sheet is available in軨anadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales est?disponible en franc萻 canadiense y en espa襬l a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: VOC Compliant Phenoseal Does It All White and Revision Date: 02/03/2006
Colors
Product UPC 5113600005, 5113600101, 5113600511, Supercedes: 07/13/2004
Number: 5113600521, 5113600524, 5113602101,
5113602102, 5113603102, 5113604102,
5113606102, 5113609102, 5113616102,
5113624117, 5113630101, 5113699012,
5113699013, 5113699014, 5113699016
Product Use/Class: Latex Caulk MSDS Number: 00061014001
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888 -327-8477 (non-emergency matters)
Exposure Notes:
Section 2 - Composition / Information On Ingredients
Chemical Name CASRN WT% ACGIH TWA ACGIH STEL ACGIH CEILOSHA TWA OSHA STEL OSHA CEILSkin
Talc, non-fibrous 14807-96 -6 20-25 2 MGM3 N.E. N.E. 20 mppcf N.E. N.E. No
2,2,4Trimethyl-
1,3-pentanediol monoisobutyrate25265-77 -4 0.51.5
N.E. N.E. N.E. N.E. N.E. N.E. No
Titanium dioxide 13463-67 -7 0.51.5
10 MGM3 N.E. N.E. 15 MGM3 N.E. N.E. No
Carbon Black 133386-
4 0.01.5
3.5 MGM3 N.E. N.E. 3.5 MGM3 N.E. N.E. No
Vinyl acetate 108-054
<0.07 10 PPM 15 PPM N.E. N.E. N.E. N.E. No
Acetaldehyde 7507-
0 <0.03 N.E. N.E. 25 PPM 200 PPM N.E. N.E. No
CASRN Exposure Note
14807-96 -6 The talc (CAS number 14807 -96-6) within this product naturally contains a non-fibrous tremolite (CAS number 14567-73-8),
non-fibrous serpentine (CAS number 12135-86 -3), and non-fibrous anthophyllite (CAS number 17068-78-9). Refer to 29
CFR 1910.1000 Table Z 3 for the permissible exposure limits associated with non -fibrous talc and these naturally occurring
incidental constituents.
Page 2 of 7
Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits
may vary between states.
Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the
extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment,
engineering controls or work practices
Section 3 - Hazards Identification
Emergency Overview: A white, off -white or colored paste with a?slight solvent odor.軼ARNING! Harmful if
swallowed or absorbed through the skin. May cause eye, skin, nose, throat and respiratory tract irritation.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation.軭armful if absorbed through the skin.
Prolonged or repeated contact with skin may cause irritation.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Inhalation of high vapor concentrations can cause
CNS-depression and narcosis. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous
membranes).
Effects Of Overexposure - Ingestion: Harmful if swallowed.
Effects Of Overexposure - Chronic Hazards: Prolonged and repeated skin contact may cause irritation and
possibly dermatitis. Repeated or prolonged exposure may cause respiratory system damage. Overexposure
may cause kidney, cardiovascular, skin and liver damage.
This product contains vinyl acetate which is classified as a class 2B carcinogen by IARC. Vinyl acetate was found
to cause cancer in the respiratory tract of laboratory animals. There is no evidence that vinyl acetate causes
cancer in humans. The IARC published a monograph on vinyl acetate (1995). In this monograph, IARC indicates
"there is inadequate evidence in humans for carcinogenicity of vinyl acetate. There is limited evidence in
experimental animals for the carcinogenicity of vinyl acetate." Normally, this lack of conclusive evidence would
place a substance in the IARC 3 classification (not classified as a human carcinogen). However, because vinyl
acetate is metabolized to acetaldehyde, which has an IARC 2B (possibly carcinogenic to humans) classification, it
also has been listed under Category 2B.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15
minutes until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated
clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately.
First Aid -Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Page 3 of 7
Note to Physician: No Information.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the
above routes of entry.
Section 5 - Fire Fighting Measures
Flash Point, F: Greater than 200 degrees Lower Explosive Limit, %: Not Established
Fahrenheit
Method: (Seta Closed Cup) Upper Explosive Limit, %: Not Established
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved
or equivalent) and full protective gear. Use water spray to cool exposed surfaces.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in
Section 8. Use absorbent material or scrape up dried material and place in container.
Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Use only with adequate
ventilation. Avoid breathing vapor and contact with eyes, skin and clothing. Wash thoroughly after handling. Open
all windows and doors or use other means to ensure cross-ventilation and fresh air entry during application and
drying. Odor is not an adequate warning for hazardous conditions.
Storage: Close container after each use. Store containers away from excessive heat and freezing. Do not store
at temperatures above 120 degrees F. Store away from caustics and oxidizers.
Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain
ambient concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-
approved air purifying respirator with an organic vapor cartridge or canister may be necessary under certain
circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory protection
program that meets the OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirator's use.
Skin Protection: Rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Page 4 of 7
Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated
clothing before re-use.
Section 9 - Physical And Chemical Properties
Boiling Range: Not Established Vapor Density: Heavier Than Air
Odor: Slight Solvent Odor Threshold: Not Established
Appearance: A white, off-white or colored Evaporation Rate: Slower Than n-Butyl Acetate
paste
Solubility in H2O: Not Established Specific Gravity: 1.285
Freeze Point: Not Established pH: Between 7.0 and 12.0
Vapor Pressure: Not Established Viscosity: Not Established
Physical State: Paste
When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined
experimentally.
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.
Section 11 - Toxicological Information
Product LD50: Not Established Product LC50: Not Established
CASRN Chemical Name LD50 LC50
108-054
Vinyl acetate -------------Rat:11400 mg/m3/4H
7507-
0 Acetaldehyde -------------Rat:13300 ppm/4H
Carcinogenicity:
CAS No. Chemical Name ACGIH OSHA IARC NTP
13463-67 -7 Titanium dioxide ----------
Classification not
possible from current
data.
-----
108-05-4 Vinyl acetate
Confirmed animal carcinogen
with unknown relevance to
humans.
-----Possible carcinogen. -----
75-07-0 Acetaldehyde
Confirmed animal carcinogen
with unknown relevance to
humans.
-----Possible carcinogen. Anticipated carcinogen.
Significant Data with Possible Relevance to Humans: None
Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.
Page 5 of 7
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and
Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste
disposal is with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): None
Section 14 - Transportation Information
DOT Proper Shipping None Packing Group: N.A.
Name:
DOT Technical Name: None Hazard Subclass: N.A.
DOT Hazard Class: N.A. DOT UN/NA Number: None
Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
None
U.S. State Regulations:
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name CAS Number
Non-Hazardous Polymer Proprietary
Water 7732-18-5
Non-Hazardous Plasticizer Proprietary
Page 6 of 7
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name CAS Number
Non-Hazardous Polymer Proprietary
Water 7732-185
Non-Hazardous Plasticizer Proprietary
California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:
Chemical Name CAS Number Definition Date Listed
Acetaldehyde 75-070
Carcinogenic. Listed: April 1, 1988
Warning: The following ingredients present in the product are known to the State of California to cause birth
defects or other reproductive harm.
None
Section 16 - Other Information
HMIS Ratings:
Health: 1 Flammability: 1 Reactivity: 0
VOLATILE ORGANIC COMPOUNDS, GR/LTR: 83.6 LB/GAL: 0.7 WT%: 3.893
REASON FOR REVISION:
Legend: N.A. ?Not Applicable ACGIH ?American Conference of Governmental Industrial Hygienists
N.E. ?Not Established SARA ?Superfund Amendments and Reauthorization Act of 1986
N.D. ?Not Determined NJRTK ?New Jersey Right-to-Know Law
VOC ?Volatile Organic Compound OSHA ?Occupational Safety and Health Administration
PEL ?Permissible Exposure Limit HMIS ?Hazardous Materials Identification System
TLV ?Threshold Limit Value軳TP ?National Toxicology Program
STEL ?Short Term Exposure Limit葺CEIL ?Ceiling Exposure Limit
LD50 ?Lethal Dose 50葺LC50 ?Lethal Concentration 50
F ?Degree Fahrenheit葺C ?Degree Celcius
MSDS ?Material Safety Data Sheet葺CASRN ?The Chemical Abstracts Service Registry Number
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as
typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS
MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE
INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary
Page 7 of 7
handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the
recommendations with due consideration for the specific context of the intended use and (ii) determine if they are
appropriate.
|