Material Safety Data Sheet
TREMPRO/VULKEM 626 WHITE 30 CTG/CS
Version 1.6 Print Date 03/06/2007
REVISION DATE: 09/01/2006
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : TREMPRO/VULKEM 626 WHITE 30 CTG/CS
Product code : 686806 323
COMPANY : Tremco Incorporated
3735 Green Road
Cleveland, OH 44122
Telephone : (216) 292-5000 8:30 - 5:00 EST
Emergency Phone: : (216) 765-6727 8:30 - 5:00 EST
After Hours: Chemtrec 1-800-424-9300
Product use : Sealant
SECTION 2 - HAZARDS IDENTIFICATION
Emergency Overview
White. Non-sag gunnable paste. May cause slight irritation to the respiratory system. May cause nausea,
headaches, and dizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory
sensitization. Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical
attention. Move to fresh air. If required, artificial respiration or administration of oxygen can be performed by
trained personnel.
Acute Potential Health Effects/ Routes of Entry
Inhalation May cause slight irritation to the respiratory system. May cause nausea, headaches, and
:
dizziness. May cause drowsiness, weakness, and fatigue. May cause allergic respiratory
sensitization.
Eyes Direct contact may cause mild irritation.
:
Ingestion May cause gastrointestinal irritation, nausea, and vomiting.
:
Skin May cause sensitization resulting in irritation, itching and redness.
:
Aggravated Medical Conditions
Pre-existing eye, skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Overexposure may cause dermatitis, asthma, skin and respiratory sensitization and decreased lung function.
Prolonged or repeated contact/exposure to aromatic petroleum distillates may cause defatting, drying, and
irritation of the skin, dermatitis, and central nervous system (CNS) effects. Prolonged or repeated exposure to
butyl benzyl phthalate may cause reduced body weights and adverse effects on the liver, kidney, spleen,
pancreas, and reproductive organs. Inhalation of crystalline silica (quartz) can cause cancer based on animal
data, and IARC concludes sufficient evidence in humans (Group 1). Prolonged and repeated overexposure to
free crystalline silica dust above the TLV level may cause scarring of the lungs with cough and shortness of
breath. A delayed lung injury, silicosis may result from breathing free silica. A long-term NTP study showed that
oral exposure to toluene diisocyanate (TDI) caused cancer in rats and mice. A lifetime inhalation study
sponsored by the International Isocyanate Institute did not show carcinogenic activity in rats. May cause
allergic skin and respiratory sensitization. Fillers are encapsulated and not expected to be released from
product under normal conditions of use.
Target Organs: Skin, Eye, Ingestion, Lung
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Material Safety Data Sheet
TREMPRO/VULKEM 626 WHITE 30 CTG/CS
Version 1.6 Print Date 03/06/2007
REVISION DATE: 09/01/2006
SECTION 3 - PRODUCT COMPOSITION
Chemical Name CAS-No. Weight %
Aromatic Polyisocyanate Resin NJ TSRN# 51721300-5270P 30.0 - 60.0
Calcium Carbonate (Limestone) 1317-65-3 10.0 - 30.0
Diisodecyl phthalate 26761-40-0 7.0 - 13.0
Tackifier NJ TSRN# 51721300-5272P 5.0 - 10.0
Butyl benzyl phthalate 85-68-7 5.0 - 10.0
Aromatic petroleum distillates 64742-95-6 5.0 - 10.0
Titanium dioxide 13463-67-7 5.0 - 10.0
Trimethyl benzene (mixed isomers) 25551-13-7 3.0 - 7.0
Thickener NJ TSRN# 51721300-5300P 3.0 - 7.0
Inert filler NJ TSRN# 51721300-5128P 3.0 - 7.0
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 - <1.0
2,4-Toluene diisocyanate 584-84-9 - <1.0
SECTION 4 - FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get
medical attention.Move to fresh air. If required, artificial respiration or administration
of oxygen can be performed by trained personnel.
Eye contact : Flush with water for at least 15 minutes while holding eye lids apart. Get medical
attention immediately.
Skin contact : Clean area of contact thoroughly using soap and water. If irritation, rash or other
disorders develop, get medical attention immediately.
Ingestion : Do not induce vomiting unless advised by a physician. Call nearest Poison Control
Center or Physician immediately.
SECTION 5 - FIRE FIGHTING MEASURES
Flash point : Not available.
Method : Not available.
Burning rate : Non-flammable solid
Lower explosion limit : Not available.
Upper explosion limit : Not available.
Autoignition temperature : Not available.
Extinguishing media : If water fog is ineffective, use carbon dioxide, dry chemical or foam.
Hazardous combustion : Carbon monoxide and carbon dioxide can form.Hydrocyanic acid and
products nitrogen oxides can form.
Protective equipment for : Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing, including self-contained breathing apparatus (SCBA).
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Material Safety Data Sheet
TREMPRO/VULKEM 626 WHITE 30 CTG/CS
Version 1.6 Print Date 03/06/2007
REVISION DATE: 09/01/2006
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Use appropriate protective equipment. Avoid contact with material. Scrape up and transfer to appropriate
container for disposal.
SECTION 7 - HANDLING AND STORAGE
Prevent inhalation of vapor, ingestion and contact with skin, eyes and clothing. Preferably use entire contents
in one continuous work session. Do not smoke, weld, generate sparks, or use flame near container. Change
soiled work clothes frequently. Clean hands thoroughly after handling Do not store or use near food. Keep
container closed when not in use. Since emptied containers retain product residue and vapor, observe
precautions even after container is emptied. Store under dry warehouse conditions away from heat and all
ignition sources.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Wear appropriate, properly fitted NIOSH/MSHA approved organic vapor or
supplied air respirator when airborne contaminant level(s) are expected to
exceed exposure limits indicated on the MSDS. Follow manufacturer's
directions for respirator use.
Hand protection : Use suitable impervious nitrile or neoprene gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Use safety glasses if eye contact is likely.
Skin and body protection : Use disposable or impervious clothing if work clothing contamination is likely.
Remove and wash contaminated clothing before reuse.
Protective measures : Use professional judgment in the selection, care, and use.
Engineering measures : Use general ventilation and/ or local exhaust to reduce the airborne
contaminant concentration below the exposure limit listed in the MSDS
Exposure Limits
Chemical Name CAS Number Regulation Limit Form
Calcium Carbonate 1317-65-3 OSHA PEL: 5 mg/m3 Respirable fraction.
(Limestone) OSHA PEL: 15 mg/m3 Total dust.
ACGIH TWA: 3 mg/m3 Respirable particles.
ACGIH TWA: 10 mg/m3 Inhalable particles.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Titanium dioxide 13463-67-7 ACGIH TWA: 10 mg/m3
OSHA PEL: 15 mg/m3 Total dust.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Trimethyl benzene 25551-13-7 ACGIH TWA: 25 ppm
(mixed isomers)
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Material Safety Data Sheet
TREMPRO/VULKEM 626 WHITE 30 CTG/CS
Version 1.6 Print Date 03/06/2007
REVISION DATE: 09/01/2006
Chemical Name CAS Number Regulation Limit Form
Inert filler NJ TSRN# ACGIH TWA: 3 mg/m3 Respirable particles.
51721300-5128P ACGIH TWA: 10 mg/m3 Inhalable particles.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
OSHA TWA: 15 mg/m3 Total dust.
OSHA TWA: 5 mg/m3 Respirable fraction.
Crystalline Silica 14808-60-7 ACGIH TWA: 0.05 mg/m3 Respirable fraction.
(Quartz)/ Silica Sand OSHA TWA: 0.1 mg/m3 Respirable.
OSHA TWA: 0.3 mg/m3 Total dust.
OSHA PEL: 15 mg/m3 Total dust.
OSHA PEL: 5 mg/m3 Respirable fraction.
2,4-Toluene diisocyanate 584-84-9 ACGIH TWA: 0.005 ppm
ACGIH STEL: 0.02 ppm
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form : Non-sag gunnable paste
Color : White
Odor : PetroleumSolvent
pH : Not available.
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : Not available.
Water solubility : Insoluble
Specific Gravity : 1.3
% Volatile Weight : 12 %
SECTION 10 - REACTIVITY / STABILITY
Substances to avoid : Amines.Water or moisture and oxidizing agents.Alcohols.Strong
acids.Strong bases.
Stability : Material is stable under normal storage, handling, and use.
Hazardous polymerization : Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
Butyl benzyl phthalate, CAS-No.: 85-68-7
Acute oral toxicity (LD-50 oral) 13,500 mg/kg ( Rat )
Trimethyl benzene (mixed isomers), CAS-No.: 25551-13-7
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Material Safety Data Sheet
TREMPRO/VULKEM 626 WHITE 30 CTG/CS
Version 1.6 Print Date 03/06/2007
REVISION DATE: 09/01/2006
Acute oral toxicity (LD-50 oral) 8,970 mg/kg ( Rat )
2,4-Toluene diisocyanate, CAS-No.: 584-84-9
Acute oral toxicity (LD-50 oral) 5,800 mg/kg ( Rat )
Acute inhalation toxicity (LC-50) 14 mg/l ( Rat )
SECTION 12 - ECOLOGICAL INFORMATION
No Data Available
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method : Waste not regulated under RCRA. Incinerate at EPA approved facility or dispose of
waste in compliance with state and local regulations.
SECTION 14 - TRANSPORTATION / SHIPPING DATA
TDG / DOT Shipping Description:
NOT REGULATED
SECTION 15 - REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on, or exempt from the Canadian Domestic Substances List.
U.S. Federal Regulations:
SARA 313 Components : 2,4-Toluene diisocyanate 584-84-9
SARA 311/312 Hazards : Acute Health Hazard
Chronic Health Hazard
OSHA Hazardous Components :
Calcium Carbonate (Limestone) 1317-65-3
Titanium dioxide 13463-67-7
Trimethyl benzene (mixed isomers) 25551-13-7
Inert filler NJ TSRN# 51721300-5128P
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
2,4-Toluene diisocyanate 584-84-9
OSHA Status: Considered : Irritant
hazardous based on the Sensitizer
following criteria: Carcinogen
OSHA Flammability : Not Regulated
Regulatory VOC (less water and : 158 g/l
exempt solvent)
VOC Method 310 : 12 %
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Material Safety Data Sheet
TREMPRO/VULKEM 626 WHITE 30 CTG/CS
Version 1.6 Print Date 03/06/2007
REVISION DATE: 09/01/2006
Chemical is listed as an IARC, NTP, OSHA, or ACGIH Carcinogen:
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
U.S. State Regulations:
MASS RTK Components : Calcium Carbonate (Limestone) 1317-65-3
Butyl benzyl phthalate 85-68-7
Titanium dioxide 13463-67-7
Trimethyl benzene (mixed isomers) 25551-13-7
Penn RTK Components : Aromatic Polyisocyanate Resin NJ TSRN# 51721300-5270P
Calcium Carbonate (Limestone) 1317-65-3
Diisodecyl phthalate 26761-40-0
Tackifier NJ TSRN# 51721300-5272P
Butyl benzyl phthalate 85-68-7
Aromatic petroleum distillates 64742-95-6
Titanium dioxide 13463-67-7
Trimethyl benzene (mixed isomers) 25551-13-7
Thickener NJ TSRN# 51721300-5300P
Inert filler NJ TSRN# 51721300-5128P
NJ RTK Components : Aromatic Polyisocyanate Resin NJ TSRN# 51721300-5270P
Calcium Carbonate (Limestone) 1317-65-3
Diisodecyl phthalate 26761-40-0
Tackifier NJ TSRN# 51721300-5272P
Butyl benzyl phthalate 85-68-7
Crystalline Silica (Quartz)/ Silica Sand 14808-60-7
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
14808-60-7 Crystalline Silica (Quartz)/ Silica Sand
584-84-9 2,4-Toluene diisocyanate
91-08-7 Toluene-2,6-Diisocyanate
91-20-3 Naphthalene
SECTION 16 - OTHER INFORMATION
HMIS Rating :
Health 2 0 = Minimum
1 = Slight
Flammability 2
2 = Moderate
Reactivity 1
3 = Serious
PPE
4 = Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the
consideration of the user, subject to their own investigation of compliance with applicable regulations, including
the safe use of the product under every foreseeable condition.
Prepared by: Rich Mikol
Legend
ACGIH - American Conference of Governmental Hygienists PEL - Permissible Exposure Limit
CERCLA - Comprehensive Environmental Response, Compensation, and RCRA - Resource Conservation and Recovery Act
6/7 686806 323
Material Safety Data Sheet
TREMPRO/VULKEM 626 WHITE 30 CTG/CS
Version 1.6 Print Date 03/06/2007
REVISION DATE: 09/01/2006
Liability Act
DOT - Department of Transportation RTK - Right To Know
DSL - Domestic Substance List SARA - Superfund Amendments and Reauthorization Act
EPA - Environmental Protection Agency STEL - Short Term Exposure Limit
HMIS - Hazardous Materials Information System TLV - Threshold Limit Value
IARC - International Agency for Research on Cancer TSCA - Toxic Substances Control Act
MSHA - Mine Safety Health Administration TWA - Time Weighted Average
NDSL - Non-Domestic Substance List V - Volume
NIOSH - National Institute for Occupational Safety and Health VOC - Volatile Organic Compound
WHMIS - Workplace Hazardous Materials Information
NTP - National Toxicology Program
System
OSHA - Occupational Safety and Health Administration
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