BASF Corporation
MATERIAL SAFETY DATA SHEET EMERGENCY TELEPHONE NUMBERS:
Agricultural Products Group
BASF Corporation: 1 (800) 832-HELP
P.O.Box 13528,
Research Triangle Park, NC 27709 CHEMTREC: 1 (800) 424-9300
(919) 547-2000
Product No.: 556161 Sanmite庐 75 WP Miticide/Insecticide
Date Prepared: 11/16/1994 Date Revised: 9/17/2004
SECTION I
Trade Name: Sanmite庐 75 WP Miticide/Insecticide
Chemical Name: See Section II - Ingredients
Synonyms: NC-129, NCI-129, BAS 300 11 I, BAS 9078 I, Formula: C(19) H(25) Cl N(2) O S
Pyridaben
Chemical Family: Pyridazinone Mol Wt: 364.9
SECTION II - INGREDIENTS
COMPONENT CAS NO. % PEL/TLV - SOURCE
2-tert-butyl-5-(4-tert-butylbenzylthio)-4- 96489-71-3 75 0.01 mg/m(3) BASF recommended
chloropyridazin-3(2H)-one*
Inerts None 25 Not established
*Common chemical name: Pyridaben
This formulation contains kaolin. Kaolin
contains small amounts of crystalline silica.
This formulation may contain more than 0.1%
crystalline silica.
SARA Title III Section 313: Not listed
SECTION III - PHYSICAL DATA
BOILING/MELTING POINT@760mm Hg: N/A pH: 8.7 - 8.8
VAPOR PRESSURE mmHg @ 20潞C: N/D
SPECIFIC GRAVITY OR BULK DENSITY: 15.6 lb/ft(3) packed 13.45 lb/ft(3) free fall
SOLUBILITY IN WATER: Dispersible
APPEARANCE: Light tan powder ODOR: Vanilla INTENSITY: Faint
SECTION IV - FIRE AND EXPLOSION DATA
FLASH POINT (TEST METHOD): N/D AUTOIGNITION TEMP: **See below
FLAMMABILITY LIMITS IN AIR (% BY VOL): LOWER: N/D UPPER: N/D
NFPA 704 HAZARD CODES
FLAMMABLE: 3 INSTABILITY: 1 OTHER:
HEALTH: 4
NFPA 30 STORAGE CLASSIFICATION: Non flamable solid
Page 1 of 6
Product No.: 556161 Sanmite庐 75 WP Miticide/Insecticide BASF Corporation
EXTINGUISHING Use water fog, foam, CO(2), or dry chemical extinguishing media.
MEDIUM
SPECIAL Firefighters should be equipped with self-contained breathing apparatus and turnout gear.
FIREFIGHTING Care should be taken to decontaminate firefighters and equipment.
PROCEDURES
UNUSUAL FIRE Explosive dust/air mixtures can form in atmospheres as low as 9% oxygen. Ignition energy
EXPLOSION required is as low as 15 millijoules. Typical dust/air mixtures capable of exploding contain
HAZARDS 40 g per cubic meter. **Exotherm initiation temperature (Grewer oven): 394潞 C
SELECT ACRONYM KEY
N/A - Not available; N/D - Not determined; N/R - Not rated; N/E - Not established
Page 2 of 6
Product No.: 556161 Sanmite庐 75 WP Miticide/Insecticide BASF Corporation
SECTION V - HEALTH DATA
TOXICOLOGICAL TEST DATA:
Rat, Acute Oral LD50 = 1930 mg/kg
Rat, Acute Dermal LD50 > 2000 mg/kg
Rat, Acute Inhalation LC50 (4 hour) = 0.09 mg/L
Rat, Acute Inhalation LC50 (1 hour) (calculated) = 0.36 mg/L
Rabbit, Eye Irritation - not irritating
Rabbit, Skin Irritation - Non irritating to skin
Guinea pig, Dermal Sensitizer - Not sensitizing
Pyridaben was found not to be teratogenic in two species tested, but at a maternally toxic dose the compound
did produce only slight non-specific developmental effects in one species.
EFFECTS OF OVEREXPOSURE:
See Product Label and Directions For Use for additional precautionary statements.
Hazards to Humans and Domestic Animals
WARNING
May be fatal if inhaled. Do not breathe dust or spray mist. For handling activities, use dust/mist filtering respirator
(MSHA/NIOSH approval numbers prefix TC-21C), or a NIOSH approved respirator with a NPR, or HE prefilter.
Wear long-sleeved shirt and long pants, socks and shoes and waterproof gloves. Harmful if swallowed or absorbed
through skin. Avoid contact with skin. Remove contaminated clothing and wash before reuse. Causes moderate
eye irritation. Do not get in eyes or on clothing. Wear goggles, face shield, or safety glasses. Wash thoroughly
with soap and water after handling.
For a minor component of the formulation:
Overexposure to crystalline silica results in silicosis, a lung disease characterized by coughing, difficult breathing, wheezing,
scarring of the lungs, and repeated, non-specific chest illnesses. The International Academy for Research on Cancer (IARC)
has classified crystalline silica in Group 1 (those agents with evidence of carcinogenicity to humans).
Existing medical conditions aggravated by exposure to this material: No information found for this mixture.
FIRST AID PROCEDURES
Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration,
If inhaled:
preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.
Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able
If swallowed:
to swallow. Do not induce vomiting unless told to by a poison control center or doctor. Do not give anything to
an unconscious person.
Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison
If on skin or clothing:
control center or doctor for treatment advice.
Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present,
If in eyes:
after first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
This compound does not cause any definitive symptoms that would be diagnostic. No specific antidote is
Note to physician:
available. Treat the patient symptomatically. In case of medical emergencies, call 1-800-832-HELP.
Page 3 of 6
Product No.: 556161 Sanmite庐 75 WP Miticide/Insecticide BASF Corporation
SECTION VI - REACTIVITY DATA
STABILITY: Stable under normal conditions; relatively unstable to light.
Do not store with food, beverages, or animal feed.
CONDITIONS TO AVOID:
Pyridaben is a reducing agent - AVOID OXIDIZERS
CHEMICAL INCOMPATIBILITY:
HCl, NOx, SOx, CO
HAZARDOUS DECOMPOSITION PRODUCTS:
Does not occur
HAZARDOUS POLYMERIZATION:
N/A
CONDITIONS TO AVOID:
No OXIDIZER: No
CORROSIVE TO METAL:
SECTION VII - PERSONAL PROTECTION
PESTICIDE APPLICATORS & WORKERS must refer to the Product Label and Directions For Use
attached to the product for Agricultural Use Requirements in accordance with the EPA Worker
Protection Standard 40 CFR part 170.
RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING
WORKERS:
Respiratory Protection:
Operators, maintenance, or any worker potentially exposed to dust/mist must wear supplied air respirators or
self-contained breathing apparatus.
Eye Protection:
Chemical goggles.
Protective Clothing:
Disposable hooded coveralls, such as tyvek, boots, and gloves.
Ventilation:
Dust collectors need to be designed to trap and hold the potentially explosive and toxic particles.
SECTION VIII - ENVIRONMENTAL DATA
ENVIRONMENTAL TOXICITY DATA
For the active ingredient:
Bobwhite Quail, Oral LD50 > 2250 mg/kg
Mallard Duck, Oral LD50 > 2500 mg/kg
This pesticide is toxic to fish and aquatic invertebrates.
Consult label and Directions For Use for additional environmental hazards.
SARA 311/312 REPORTING
FIRE:Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC:Yes TPQ(lbs): 10,000
SPILL AND LEAK PROCEDURES:
Emergency response workers should don SCBA with Level B protection if dusts will be generated. If possible, keep
spilled material dry and recover for use. Spilled material may be carefully swept up and returned to original
container.
HAZARDOUS SUBSTANCE SUPERFUND: No RQ(lbs): None
WASTE DISPOSAL METHOD:
All pesticide waste are considered acutely toxic. Dispose of in an approved manner (consult local authority) only as
a last resort. Otherwise, apply according to label instructions. Consult label and Directions For Use.
HAZARDOUS WASTE 40CFR261: No HAZARDOUS WASTE NUMBER:N/A
CONTAINER DISPOSAL:
Clean, uncontaminated, empty containers may be disposed of in a sanitary landfill or incinerated. Do not reuse
empty container.
Page 4 of 6
Product No.: 556161 Sanmite庐 75 WP Miticide/Insecticide BASF Corporation
SECTION IX - SHIPPING DATA - PACKAGE AND BULK
D.O.T. PROPER SHIPPING NAME (49CFR172.101-102): HAZARDOUS SUBSTANCE
(49CFR CERCLA LIST):
Pesticide, solid, toxic, NOS (contains pyridaben)
Not listed
RQ(lbs): None
D.O.T. HAZARD CLASSIFICATION (CFR 172.101-102):
PRIMARY SECONDARY
Poison
D.O.T. LABELS REQUIRED (49CFR172.101-102): D.O.T. PLACARDS POISON CONSTITUENT
REQUIRED (CFR172.504): (49CFR172.203(K)):
Poison Poison Pyridaben
BILL OF LADING DESCRIPTION
Pesticides, solid, toxic, NOS (contains pyridaben), 6.1, UN 2588, PG I, ERG 151
UN 2588
CC NO.: UN/NA CODE:
SECTION X - ADDITIONAL INFORMATION
Sanmite庐 75 WP Miticide/Insecticide
Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle.
(If you do not understand this label, find someone to explain it to you in detail.)
KEEP OUT OF REACH OF CHILDREN
WARNING/AVISO
Complete Label and Directions For Use are attached to the product.
Agricultural Use Requirements
Use this product only in accordance with its labeling and with the Worker Protection Standard,
40 CFR part 170. Refer to supplemental labeling under "Agricultural Use Requirements" in the
Directions for Use section for information about this standard.
BASF Corporation
Agricultural Products Group
P.O.Box 13528,
Research Triangle Park, NC 27709
(919) 547-2000
Page 5 of 6
Product No.: 556161 Sanmite庐 75 WP Miticide/Insecticide BASF Corporation
DISCLAIMER
IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE
PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE
ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND
THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR
PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESS OR IMPLIED, INCLUDING
WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING
PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS,
DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY
RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS
PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU
EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION
FURNISHED BY BASF HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR
LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED,
ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
Page 6 of 6
|