CERAMCO
MATERIAL SAFETY DATA SHEET
CERAMCO PFZ PORCELAN
Issued on January 21, 2004
========================================================================================
SECTION I - PRODUCT IDENTIFICATION
========================================================================================
PRODUCT NAME: Ceramco PFZ Die Sealer
MANUFACTURER/SUPPLIER: Ceramco
Six Terri Lane
Burlington, NJ 08016
USA
Phone number: (800) 487-0100
========================================================================================
SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS
========================================================================================
DESCRIPTION: Organic liquid mixture.
HAZARDOUS INGREDIENTS:
Component CAS No Weight % OSHA/PEL or TWA ACGIH/TLV or TWA HAZARDS
Acetone 67-64-1 ~ 60% 750 ppm 750 ppm Flammable/Irritant
Methylethylketone 78-93-3 <30% 200 ppm / 300 stel 200 ppm / 300 stel Flammable
Silikoneresin containing
Acetone 000067-64-1
========================================================================================
SECTION III - HAZARDS IDENTIFICATION
========================================================================================
NFPA HAZARD DESIGNATIONS: Health: 1 (Moderate)
Flammability: 3 (Serious)
Reactivity: 0 (Slight)
IMPORTANT HAZARD INFORMATION: Highly flammable. Harmful if swallowed, inhaled or absorbed through skin.
Intentional misuse by deliberately concentrating and inhaling fumes may be
harmful or fatal. High vapor concentration can cause narcotic conditions
========================================================================================
SECTION IV - FIRST-AID MEASURES
========================================================================================
GENERAL INFORMATION: Consult doctor in case of symptoms.
AFTER INHALATION: Supply fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Consult doctor in case of symptoms. Do not administer epinephrine or similar
drugs.
AFTER SKIN CONTACT: Immediately wash skin with copious amounts of water. Remove any contaminated
clothing. Consult doctor in case of symptoms.
AFTER EYE CONTACT: Rinse opened eye for 15 minutes under running water. Consult doctor in case of
symptoms.
AFTER SWALLOWING: Do not induce vomiting. Consult doctor immediately.
========================================================================================
SECTION V- FIRE-FIGHTING MEASURES
========================================================================================
FIRE EXTINGUISHING AGENTS: Use fire-fighting methods that suit the environment. Carbon dioxide, dry
chemical powder, alcohol foam, or polymer foam. (Water may be ineffective)
SPECIAL PROTECTIVE EQUIPMENT: Wear self-contained breathing apparatus and protective clothing to prevent contact
with skin and eyes.
UNUSUAL EXPLOSION HAZARDS: Vapors form flammable or explosive mixtures with air at room temperature. Vapor
or gas may spread to distant ignition source and flash back. Containers may
explode in heat of fire. Runoff to sewer may cause fire or explosion hazard.
Page 2 of 4
CERAMCO
MATERIAL SAFETY DATA SHEET
CERAMCO PFZ DIE SEALER (continued)
========================================================================================
SECTION VI - ACCIDENTAL RELEASE MEASURES
========================================================================================
PERSON-RELATED SAFETY PRECAUTIONS: Avoid skin and eye contact. Provide adequate ventilation.
ENVIRONMENTAL PROTECTION: Do not allow to enter drainage system, surface or ground water. Use
water spray to reduce vapors.
MEASURES FOR CLEANING/COLLECTING: Take up with sand or other non-combustible absorbent material and place
into container for later disposal.
ADDITIONAL INFORMATION: Remove source of heat or flame.
========================================================================================
SECTION VII - HANDLING AND STORAGE
========================================================================================
INFORMATION FOR SAFE HANDLING: Ensure good ventilation/exhaustion at workplace. Keep container closed
when not in use.
PROTECTION AGAINST EXPLOSIONS/FIRES: Store away from ignition sources. Protect from heat, sparks, and flame.
Use non-sparking tools. In large quantities, ensure that all drums, hoses,
pipes, and transfer vessels are grounded.
STORAGE: Store in cool location, out of direct sunlight or other heat sources.
COMMON STORAGE FACILITIES: Avoid storage near oxidizers, strong acids and bases, anhydrides,
potassium tert-butoxide, alkali or alkaline earth metals.
========================================================================================
SECTION VIII - EXPOSURE CONTROLS/ PERSONAL PROTECTION
========================================================================================
VENTILATION: Use general or local exhaust to meet ventilation requirements.
EYE PROTECTION: Safety glasses are recommended. Do not wear contact lenses. An eye bath and washing
facilities should be available.
SKIN PROTECTION: Neoprene and nitrile gloves are recommended.
RESPIRATORY PROTECTION: If TLV is exceeded, a full-face respirator with self-contained breathing apparatus is
recommended.
========================================================================================
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
========================================================================================
PHYSICAL STATE: Liquid
FORM: Fluid
COLOR: Colorless
ODOR: characteristics of a dissolver, aromatic
pH: Not Determined
MELTING POINT: 62掳C
BOILING POINT: 56掳C
FLASH POINT: -20掳C
VAPOR DENSITY: 2.0 (air =1)
AUTOIGNITION TEMPERATURE: Not available
DANGER OF EXPLOSION: Product is explosive when exposed to heat and flame.
FLAMMABILITY: Product is flammable.
VAPOR PRESSURE: 184 mm Hg for Acetone
DENSITY: 0.90 鈥? 0.95 gm/cc @ 20掳C
SOLUBILITY/ MISCIBILITY 100%
EXPLOSION LIMIT: lower: 1.2 Vol. %; Upper: 12.8 Vol. %
========================================================================================
SECTION X - STABILITY AND REACTIVITY
========================================================================================
STABILITY: Stable
HAZARDOUS POLYMERIZATION: Will not occur.
Page 3 of 4
CERAMCO
MATERIAL SAFETY DATA SHEET
CERAMCO PFZ DIE SEALER (continued)
CONDITIONS TO AVOID: Heat, sparks, open flames, electrostatic discharge.
MATERIALS TO AVOID: Strong acids and bases, oxidizing materials, chlorinated compounds fluorine,
and alikalis.
DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, acetic acid, and unidentified organic
compounds in black smoke
========================================================================================
SECTION XI - TOXICOLOGICAL INFORMATION
========================================================================================
ORAL RAT LD50 FOR ACETONE: 9750 mg/kg
CARCINOGENEITY: NTP: no IARC: no Z LIST: no OSHA REG: no
EFFECTS OF OVEREXPOSURE:
SKIN CONTACT: Brief contact may dry the skin. Prolonged exposure may cause systemic
toxicity.
EYE CONTACT: Irritant. May cause temporary corneal damage.
INHALATION: Excessive exposure can cause dizziness, nausea, headaches, drowsiness,
unconsciousness, narcosis, and other central nervous system effects.
INGESTION: May cause central nervous system damage, headaches, nausea, vomiting,
diarrhea, shock, kidney failure, coma, and death.
SENSITIZATION: No sensitizing effect known.
CHRONIC EFFECTS: Damage to liver, kidneys, and blood. Central nervous system damage,
deleria, convulsions, hallucinations, and sudden death are possible.
CONDITIONS AGGRAVATED BY EXPOSURE: Damaged skin, respiratory system disease. Alcoholic beverages may
enhance the toxic effects of this chemical.
THRESHOLD LIMIT VALUE (TLV/TWA): 750 ppm for Acetone; 200 ppm for Methylethylketone
SHORT-TERM EXPOSURE LIMIT (STEL): 1,000 ppm for Acetone; 300 ppm for Methylethylketone
PERMISSIBLE EXPOSURE LIMIT (PEL): 750 ppm for Acetone; 200 ppm for Methylethylketone
========================================================================================
SECTION XII - ECOLOGICAL INFORMATION
========================================================================================
Do not allow product to reach ground water, water bodies, or sewage system.
========================================================================================
SECTION XIII - DISPOSAL CONSIDERATION
========================================================================================
PRODUCT DISPOSAL: Do not dispose with household waste. Dispose according to official
regulations.
CONTAMINATED PACKAGING: Dispose according to official regulations.
ADDITIONAL DISPOSAL INFORMATION: Local disposal regulations may exist.
========================================================================================
SECTION XIV - TRANSPORT INFORMATION
========================================================================================
U.S. D.O.T.:
HAZARD CLASS: 3
PACKAGING GROUP: II
DOT CLASSIFICATION: Flammable liquid
UN/NA: Acetone - UN1090
REPORTABLE QUANTITY: Acetone 鈥?5000lbs
REGULATORY REFERENCE: 49 CFR 172.101
CANADIAN TRANSPORTATION OF DANGEROUS GOODS (T.D.G.):
CLASSIFICATION: 3 - Flammable liquid
SPECIAL PROVISIONS: 109
Page 4 of 4
CERAMCO
MATERIAL SAFETY DATA SHEET
CERAMCO PFZ DIE SEALER (continued)
REGULATED LIMIT: 230 lbs.
========================================================================================
SECTION XV - REGULATORY INFORMATION
========================================================================================
U.S.:
SARA/TITLE III HAZARD CATEGORIES AND LISTS
ACUTE: Yes CHRONIC: No FLAMMABILITY: Yes PRESSURE: No REACTIVITY: No
EXTREMELY HAZARDOUS SUBSTANCE: No
CERCLA HAZARDOUS SUBSTANCE: Yes (contains acetone)
SARA 313 TOXIC CHEMICALS: Yes (contains acetone)
TSCA INVENTORY: Yes
CLEAN WATER ACT: NA
CLEAN AIR ACT: NA
DEA : NA
STATE LISTS: Acetone (2-propanone) is present on Right-To-Know lists in California, New Jersey, Florida,
Pennsylvania, Minnesota, Massachusetts.
CANADA:
WHMIS CLASSIFICATIONS:
CLASS A - COMPRESSED GAS: Does not meet criteria.
CLASS B - FLAMMABLE & COMBUSTIBLE MATERIAL: Meets criteria for 鈥淔lammable liquid鈥?.
CLASS C - OXIDIZING MATERIAL: Does not meet criteria.
CLASS D - POISONOUS AND INFECTIOUS MATERIAL:
DIV. 1 - IMMEDIATE ANS SERIOUS TOXIC EFFECTS: Meets criteria for 鈥淎cute Toxicity鈥?.
DIV. 2 - OTHER TOXIC EFFECTS: Meets criteria for 鈥淰ery Toxic Material鈥?.
CLASS E - CORROSIVE MATERIAL: Does not meet criteria.
CLASS F - DANGEROUSLY REACTIVE MATERIAL: Does not meet criteria.
========================================================================================
SECTION XVI - OTHER INFORMATION
========================================================================================
INTERNATIONAL RISK PHRASES: 10, 11, 16, 23, 24, 25, 40.
INTERNATIONAL SAFETY PHRASES: 2, 3, 7, 9, 14, 16, 20, 21, 23, 24, 25, 26, 33, 37, 51.
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
|