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Vapona Concentrate Insecticide
Material Safety Data Sheet
DOT HCS Risk Phrases Protective Clothing
RQ Organophosphorus pesticide, HCS Class: Poisonous if swallowed,
Liquid, Toxic, N.O.S. (Dichlorvos), 6.1, inhaled or absorbed through the skin and
UN3018, PGIII eyes. Insecticide Signal Word: Danger
Section 1: Product Identification and Uses
Common/Trade name 庐
Vapona Concentrate Insecticide
CI# Not available
EPA Reg. No.: 4691-130
Synonyms Not available TSCA No products found
Chemical name Not applicable CAS# Mixture
Chemical formula Not applicable Code MSDS ID#: E97DC130A
Chemical family Organophosphate ester Molecular weight Not available
Manufacturer Amvac
Supplier Boehringer Ingelheim Vetmedica, Inc. 4100 E Washington Blvd
2621 North Belt Hwy Los Angeles, CA 90023
St. Joseph MO 64506-2002
Material uses Controls flies, gnats and mosquitoes on cattle and around livestock and poultry premises
Section 2: Hazardous Ingredients
Name CAS# % by Weight TLV/PEL LC50 / LD 50
Not available
3
Dichlorvos: 2,2- 62-73-7 40.2 1 mg/m (skin)
dichlorovinyl dimethyl
phosphate
Not available
Petroleum 64742-94-5 50-55 PEL: 100 ppm TWA
hydrocarbons
Section 3: First Aid Measures
Eye contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present,
after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
Skin contact Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison
control center or doctor for treatment advice.
Hazardous Corrosive, can cause irreversible eye damage or skin burns.
skin/eye contact
Slight inhalation Harmful if inhaled. Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give
artificial respiration, preferably by mouth-to-mouth if possible. Call poison control center or doctor for further
treatment advice.
Hazardous
No additional information
inhalation
Hazardous Harmful if swallowed or absorbed through skin. If swallowed, call a poison control center or doctor immediately
ingestion for treatment advice. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not
give any liquid to the person. Do not give anything by mouth to an unconscious person. NOTE TO
PHYSICIAN: This product is a cholinesterase inhibitor. Atropine is the specific therapeutic antagonist of
choice against parasympathetic nervous stimulation. If there are signs of parasympathetic stimulation, Atropine
Sulfate should be injected at 10 minute intervals in doses of 1-2 milligrams until complete atropinization has
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Vapona Concentrate Insecticide
occurred. Pralidoxine chloride (2-PAM) may also be used as an effective antidote in addition to and while
maintaining full atropinization. In adults, an initial dose of 1 gram of 2-PAM should be injected preferably as an
infusion in 250 cc of saline over a 15-30 minute period. If this is not practical, 2-PAM may be administered
slowly by intravenous injection as a 5 percent solution in water over not less than two minutes. After about an
hour, a second dose of 1 gram of 2-PAM will be indicated if muscles weakness has not been relieved. For
infants and children, the dose of 2-PAM is 0.25 grams. Morphine is an improper treatment. Clear chest by
postural drainage. Oxygen administration may be necessary. Observe patient continuously for 48 hours.
Repeated exposure to cholinesterase inhibitors may without warning cause prolonged susceptibility to very
small doses of any cholinesterase inhibitor. Allow no further exposure until cholinesterase regeneration has
been attained and determined by blood test. Probable mucosal damage may contraindicate the use of gastric
lavage. Contains petroleum hydrocarbons 鈥? vomiting may cause aspiration pneumonia
Section 4: Physical Data
Liquid
Physical state and
appearance
Odor Aromatic
PH (1% soln/water) Approximately 3; acidic Taste Not available
Odor threshold Not available Color Clear amber to pink
Volatility Not available
Melting/Sublimation point Not available
Boiling/Condensation >300掳F
point
Specific gravity 1.08
(Water=1)
Vapor density (Air=1) >5
Vapor pressure <2 mm Hg @ 25掳C
Water/oil dist. Coeff. Not available
Ionicity (surface active Not available
agent)
Critical temperature Not available
Instability temperature Not available
Conditions of instability Not available
Dispersion properties Not available
Solubility Not available
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Vapona Concentrate Insecticide
Section 5: Fire and Explosion Data
The product is: Combustible
Auto-ignition Not available
temperature
Fire degradation Products of combustion may be inorganic acids, phosphorus compounds and chlorinated organic compounds.
products Vapors of the unburned product may also be hazardous. Contact with the fumes and vapors should be
avoided by staying upwind and by wearing impervious clothing and positive pressure self-contained breathing
apparatus.
Flash points TCC: 144掳F
Flammable limits Not available
Fire extinguishing Small Fire: Use dry chemical, CO2, alcohol foam or water spray. Large Fire: Use alcohol foam, water spray
procedures or fog. Cool containing vessels with water jet in order to prevent pressure build-up, auto ignition or explosion.
Special Fire Fighting Procedures: Recommend positive pressure self-contained breathing apparatus (SCBA).
Wear full protective equipment.
Flammability With sufficient heat or burning, toxic and/or noxious vapors may be emitted including hydrogen chloride and
carbon monoxide. Treat as combustible liquid.
Risks of explosion No specific information is available in our database regarding the product鈥檚 risks of explosion in the presence
of various materials.
Section 6: Reactivity Data
Stability The product is stable.
Hazardous Products of combustion may be inorganic acids, phosphorus compounds and chlorinated organic
decomp. products compounds.
Degradability Not available
Product of Possibly hazardous short term degradation products are not likely. However, long term degradation
degradation products may arise.
Corrosivity Corrosive to black iron and mild steel. In absence of moisture, non-corrosive to aluminum, nickel, hastelloy
B and stainless steel (type 316).
Reactivity DDVP will slowly react with water for form acids. Incompatible with strong oxidizers, strong acids, strong
bases, heat and sources of ignition.
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Vapona Concentrate Insecticide
Section 7: Toxicological Properties
Routes of entry Absorbed through skin, eye contact, inhalation, ingestion
TLV Not available
Toxicity for animals LD50: Not available
LC50: Not available
Environmental hazards Highly toxic to fish, birds and other wildlife. Drift and runoff from treated areas may be hazardous to
aquatic organisms in adjacent areas. Do not apply directly to water, or to areas where surface water is
present or to intertidal areas below the mean high water mark. Do not apply where runoff is likely to
occur or when weather conditions favor drift from areas treated. Do not contaminate water when
cleaning equipment or when disposing of equipment washwaters.
Chronic effects on humans Carcinogenic Effects: California Prop 65: This product contains the following ingredients for which the
State of California has found to cause cancer, birth defects or other reproduction harm, which would
require a warning under the statue: dichlorvos
Mutagenic Effects: Not available
Teratogenic Effects: Not available
Developmental Toxicity: Not available
Causes lowered cholinesterase levels increasing vulnerability to cholinesterase depression. Repeated
inhalation or skin contact may, without symptoms, progressively increase susceptibility to
organophosphate insecticide poisoning. Chronic poisoning can cause damage to kidney or liver and
may be fatal. Medical conditions generally aggravated by exposure: Pre-existing conditions with
lower cholinesterase levels increase vulnerability to cholinesterase depressions such as (for plasma)
genetic cholinesterase deficiency, advanced liver disease, chronic alcoholism, dermatomyositis, and
(for RBC) hemolytic anemia. The substance is toxic to eyes. Repeated or prolonged exposure to this
substance can cause damage to target organs.
Acute effects on humans Poisonous if swallowed, inhaled or absorbed through the skin and eyes. Rapidly absorbed through
skin. Repeated inhalation or skin contact may without symptoms, progressively increase susceptibility
to dichlorvos (DDVP) poisoning. Poisoning symptoms include weakness, headache, tightness in
chest, blurred vision, non-reactive pinpoint pupils, salivation, sweating, nausea, vomiting, diarrhea and
abdominal cramps. Corrosive, can cause eye/skin damage. May produce acute cholinesterase
depression.
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Vapona Concentrate Insecticide
Section 8: Preventive Measures
Waste information Neutralize residue with dilute alkaline or ammonia (less than 5%) solution and detergent. Absorb with
clay, sand or other absorbent materials. Dispose of in accordance with all City, State and Federal
regulations. Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture or
rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label
instructions, contact your State Pesticide or Environmental Control Agency or the hazardous waste
representative at your nearest EPA Regional office for guidance. Container disposal: Triple rinse (or
equivalent), then offer for reconditioning or puncture and dispose of in a sanitary landfill or by other
approved State and Local procedures.
Waste stream Toxic to fish, birds and other wildlife.
Storage Not for use or storage in and around the home. Do not contaminate water, food or feed by storage or
disposal. Store in original container only. Store in a safe place where children and animals cannot
reach the product or its diluted emulsion. Combustible, do not use, store or spill near heat or open
flame. Do not store above 120掳F for an extended period of time. Do not store diluted product. Protect
from freezing.
Precautions Keep out of reach of children. Do not get on skin. Do not breathe vapor. Do not contaminate food or
feed products. Corrosive, do not get on skin, eyes or clothing. Wash thoroughly with soap and water
after using and before smoking or eating. Do not apply directly to water. Do not contaminate water by
cleaning of equipment or improper disposal of waste. Prolonged or repeated skin contact may cause
allergic reaction in some individuals. Wash PPE and clothing separately from normal laundry.
Small spill and leak Avoid any contact. Keep people away from spill. Wear impervious, protective clothing and respirator.
Notify State and Federal agencies according to Spill Plan (reportable quantity 10 lbs). Dike area.
Keep liquid from entering sewers, waterways or low areas. Absorb material with sawdust, shredded
vermiculite, newspaper, or other commercial absorbents. Neutralize residue with alkaline solution and
adhere to recommended disposal procedures.
Combustible liquid, keep away from heat and sources of ignition. Stop leak if without risk. Absorb with
Large spill and leak
dry earth, sand or other non-combustible material. Do not touch spilled material. Prevent entry into
sewers, basements or confined areas, dike if needed.
Protective Clothing Splash goggles, full protective suit or coveralls over long sleeved shirt and long pants, NIOSH
approved respirator with an organic vapor removing cartridge with a prefilter approved for pesticides
(MSHA/NIOSH approval number prefix TC-23C) or a canister approved for pesticides (MSHA/NIOSH
approval number prefix TC-14G) or a NIOSH approved respirator with an organic vapor cartridge or
canister with any R, P or HE prefilter, chemical resistant footwear plus socks, chemical resistant
headgear for overhead exposure, chemical resistant gloves; chemical resistant apron required for
mixing/loading and cleaning equipment, self-contained breathing apparatus should used to avoid
inhalation of the product when concentration is unknown. Discard clothing and other absorbent
material that have been drenched or heavily contaminated with this products concentrate. Do not
reuse them. Follow manufacturer鈥檚 instructions for cleaning/maintaining PPE. If no such instructions
for washables, use detergent and hot water. Keep and wash PPE separately from other laundry.
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Vapona Concentrate Insecticide
Section 9: Classification
DOT RQ Organophosphorus pesticide, Liquid, Toxic, N.O.S. (Dichlorvos), 6.1, UN3018, PGIII
Maritime Marine pollutant
transportation
HCS Class: Poison
HCS
Federal and CERCLA: Reportable Quantity DDVP - 10 lbs
State
Regulations
HMIS (U.S.A.)
National Fire Protection
Health Hazard * 3
Fire Hazard
2
Association (U.S.A.)
Fire Hazard 2
3 0
Reactivity 0
Reactivity
J
Personal Protection
Specific hazard
Section 10: Protective Measures
Protective
Splash goggles, full protective suit or coveralls over long sleeved shirt and long pants, NIOSH
clothing approved respirator with an organic vapor removing cartridge with a prefilter approved for pesticides
(MSHA/NIOSH approval number prefix TC-23C) or a canister approved for pesticides (MSHA/NIOSH
approval number prefix TC-14G) or a NIOSH approved respirator with an organic vapor cartridge or
canister with any R, P or HE prefilter, chemical resistant footwear plus socks, chemical resistant
headgear for overhead exposure, chemical resistant gloves; chemical resistant apron required for
mixing/loading and cleaning equipment, self-contained breathing apparatus should used to avoid
inhalation of the product when concentration is unknown. Discard clothing and other absorbent
material that have been drenched or heavily contaminated with this products concentrate. Do not
reuse them. Follow manufacturer鈥檚 instructions for cleaning/maintaining PPE. If no such instructions
for washables, use detergent and hot water. Keep and wash PPE separately from other laundry.
Engineering Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors
controls below their respective threshold limit value. Ensure that eyewash stations and safety showers are
proximal to the work station location.
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Vapona Concentrate Insecticide
Section 11: Other Information
References Not available
Validated by Company: 3/28/05
CALL 1(800) 821-7467
Emergency Medical: (800)530-5432
Chemtrec: (800)424-9300
The information provided herein is offered by Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?) in good faith as accurate as of the date hereof, but
without guarantee. This information includes information which has been generated by other parties and provided to BIV, and which BIV has
not independently verified. The information provided herein relates only to the specific product designated, and may not be valid where such
product is used in combination with any other materials or in any process. The information provided herein is offered solely for your
consideration, investigation and verification, and Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?) expressly disclaims all liability for reliance
thereon. BIV EXPRESSLY DISCLAIMS ALL WARRANTIES OF EVERY KIND AND NATURE (INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE) WITH RESPECT TO THE USE OR SUITABILITY OF THE
PRODUCT. In addition, since the conditions of use and suitability of the product for particular uses are beyond BIV鈥檚 control, ALL RISKS OF
USE OF THE PRODUCT ARE THEREFORE ASSUMED BY THE USER, AND BIV EXPRESSLY DISCLAIMS ANY AND ALL LIABILITY AS
TO ANY RESULTS OBTAINED OR ARISING FROM ANY USE OF THE PRODUCT. Use or retransmission of the information contained
herein in any other format than the format as presented is strictly prohibited. Nothing herein shall be construed as a permission or
recommendation for the use of the product in a manner that might infringe an existing patent. BIV neither represents nor warrants that the
format, content or product formulas contained in this document comply with the laws of any other country except the United States of America.
漏 Copyright 2001 Boehringer Ingelheim Vetmedica, Inc. All rights reserved.
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The information provided herein is offered by Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?) in
good faith as accurate as of the date hereof, but without guarantee. This information includes
information which has been generated by other parties and provided to BIV, and which BIV has
not independently verified. The information provided herein relates only to the specific product
designated, and may not be valid where such product is used in combination with any other
materials or in any process. The information provided herein is offered solely for your
consideration, investigation and verification, and Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?)
expressly disclaims all liability for reliance thereon. BIV EXPRESSLY DISCLAIMS ALL
WARRANTIES OF EVERY KIND AND NATURE (INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE) WITH RESPECT
TO THE USE OR SUITABILITY OF THE PRODUCT. In addition, since the conditions of use
and suitability of the product for particular uses are beyond BIV鈥檚 control, ALL RISKS OF USE
OF THE PRODUCT ARE THEREFORE ASSUMED BY THE USER, AND BIV EXPRESSLY
DISCLAIMS ANY AND ALL LIABILITY AS TO ANY RESULTS OBTAINED OR
ARISING FROM ANY USE OF THE PRODUCT.
Use or re-transmission of the information contained herein in any other format than the format as
presented is strictly prohibited. Nothing herein shall be construed as a permission or
recommendation for the use of the product in a manner that might infringe an existing patent.
BIV neither represents nor warrants that the format, content or product formulas contained in this
document comply with the laws of any other country except the United States of America.
漏 Copyright 2001 Boehringer Ingelheim Vetmedica, Inc. All rights reserved.
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