Material Safety Data Sheet
Material Name: CALCIUM NITRATE TETRAHYDRATE 66% AND 70% SOLUTION ID: MRD-016
* * * Section 1 - Chemical Product and Company Identification * * *
Chemical Name: Inorganic Nitrate Solution
Product Use: Variety of Industrial Applications
Manufacturer Information
MINERAL RESEARCH AND DEVELOPMENT Phone: 704-454-4811
5910 Pharr Mill Road Fax: 704-454-7390
P. O. Box 1330 Emergency # CHEMTREC: (800) 424-9300
Harrisburg, NC 28075
General Comments
NOTE: Emergency telephone numbers are to be used only in the event of chemical emergencies involving a spill,
leak, fire, exposure, or accident involving chemicals. All non-emergency questions should be directed to
customer service.
* * * Section 2 - Composition / Information on Ingredients * * *
CAS # Component Percent
13477-34-4 Calcium Nitrate Tetrahydrate 66-70
7732-18-5 Water 30-34
Component Related Regulatory Information
This product may be regulated, have exposure limits or other information identified as the following: Water
Dissociable Nitrate Compounds.
Component Information/Information on Non-Hazardous Components
This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication). This product is
considered hazardous under the criteria specified in the Canadian Workplace Hazardous Materials Information
System (WHMIS).
* * * Section 3 - Hazards Identification * * *
Emergency Overview
WARNING! This product may be harmful or fatal if swallowed. This product is irritating to the eyes, respiratory
system and skin. This product is an aqueous solution which will not burn. However, if evaporated to dryness this
product is an oxidizer and can sustain combustion. Irritating and toxic fumes and gases may be released upon
thermal processing or during combustion.
Potential Health Effects: Eyes
Contact with the eyes can cause moderate irritation. Symptoms may include discomfort or pain and redness.
Severe over exposure can result in swelling of the conjunctiva along with tissue damage which may lead to
blindness.
Potential Health Effects: Skin
This product is irritating to the skin. Depending on the duration of contact, symptoms will include reddening,
discomfort, irritation, and possible tissue damage. Repeated contact with this material may produce dermatitis.
Potential Health Effects: Ingestion
This product may be harmful or fatal if swallowed. If ingested, this product will immediately cause burns to the
mouth, throat, esophagus and possibly the digestive tract. Ingestion can cause gastrointestinal irritation, nausea,
vomiting and diarrhea. This product may cause methemoglobinemia upon ingestion characterized by cyanosis,
headache, dizziness, fatigue, nausea, vomiting, drowsiness, stupor, coma and rarely death.
Potential Health Effects: Inhalation
This product is irritating to the respiratory system. Inhalation of vapors or mists of the product can cause
sneezing, coughing and difficulty breathing.
Medical Conditions Aggravated by Exposure
Pre-existing skin and eye conditions.
HMIS Ratings: Health: 2 Fire: 0 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
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CALCIUM NITRATE TETRAHYDRATE 66% AND 70% SOLUTION
Material Safety Data Sheet
Material Name: CALCIUM NITRATE TETRAHYDRATE 66% AND 70% SOLUTION ID: MRD-016
* * * Section 4 - First Aid Measures * * *
First Aid: Eyes
Immediately flush eyes with water for at least 15 minutes, while holding eyelids open. Seek medical attention at
once.
First Aid: Skin
For skin contact, wash immediately with soap and water. If irritation persists get medical attention.
First Aid: Ingestion
If material is ingested, immediately contact a physician or poison control center. Give one to two glasses of water
or milk. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to a
victim who is unconscious or is having convulsions.
First Aid: Inhalation
If inhaled, immediately remove the affected person to fresh air. If the affected person is not breathing, apply
artificial respiration. If irritation persists get medical attention.
First Aid: Notes to Physician
Provide general supportive measures and treat symptomatically.
* * * Section 5 - Fire Fighting Measures * * *
Flash Point: Not flammable Method Used: Not applicable
Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable
Auto Ignition: Not flammable Flammability Classification: Non-flammable
Rate of Burning: Not applicable
General Fire Hazards
This product is an aqueous solution which will not burn. However, if evaporated to dryness this product is an
oxidizer and can sustain combustion.
Hazardous Combustion Products
Decomposition may yield calcium compounds and oxides of nitrogen.
Extinguishing Media
Dry chemical, foam, carbon dioxide, water fog.
Fire Fighting Equipment/Instructions
Firefighters should wear full protective clothing including self contained breathing apparatus.
NFPA Ratings: Health: 2 Fire: 0 Reactivity: 0 Other: none
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
* * * Section 6 - Accidental Release Measures * * *
Containment Procedures
Stop the flow of material, if this is without risk. Wear appropriate protective equipment and clothing during clean-
up. Contain the discharged material and dike the spilled material where possible. Prevent entry into sewers,
drains, underground or confined spaces, water intakes and waterways.
Clean-Up Procedures
Absorb spill with inert material such as: lime, polypads, or other suitable absorbent material. Shovel the absorbed
material into appropriate container for disposal.
Evacuation Procedures
Isolate area. Keep unnecessary personnel away.
Special Procedures
Isolate exposure. Wear appropriate personal protective equipment. Follow all Local, State, Federal and Provincial
regulations for disposal.
* * * Section 7 - Handling and Storage * * *
Handling Procedures
Open container carefully, as needed to relieve any build up of pressure. Do not get this material in your eyes, on
your skin, or on your clothing. Do not inhale vapors or mists of this product. Use this product with adequate
ventilation. Wash thoroughly after handling.
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CALCIUM NITRATE TETRAHYDRATE 66% AND 70% SOLUTION
Material Safety Data Sheet
Material Name: CALCIUM NITRATE TETRAHYDRATE 66% AND 70% SOLUTION ID: MRD-016
Storage Procedures
Store in a cool, dry area. Do not freeze. Store away from direct sunlight and any sources of heat. Empty product
containers may contain product residue. Do not reuse empty containers. Do not store this material in open or
unlabeled containers.
* * * Section 8 - Exposure Controls / Personal Protection * * *
Exposure Guidelines
A: General Product Information
Keep formation of airborne mists to a minimum.
B: Component Exposure Limits
ACGIH, OSHA, and NIOSH have not developed exposure limits for any of this product's components.
Engineering Controls
Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists
generated from the handling of this product.
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear chemical goggles and face shield.
Personal Protective Equipment: Skin
Wear impervious (neoprene) gloves, impervious apron.
Personal Protective Equipment: Respiratory
If ventilation is not sufficient to effectively prevent buildup of vapors or mists, appropriate approved NIOSH
respiratory protection must be provided. Respirators should be selected by and used under the direction of a
trained health and safety professional following requirements found in OSHA's respirator standard (29 CFR
1910.134) and ANSI's standard for respiratory protection (Z88.2-1992). A written respiratory protection program,
including provisions for medical certification, training, fit testing, exposure assessments, maintenance, inspection,
cleaning, and convenient, sanitary storage must be implemented.
Personal Protective Equipment: General
Eye wash fountain and emergency showers are recommended. An emergency spill response will necessitate the
use of more stringent personal protective equipment.
* * * Section 9 - Physical & Chemical Properties * * *
Appearance: Odor:
Colorless None
Physical State: pH:
Liquid @ 59潞F (15潞C): 3.0 - 8.0
Vapor Pressure: Vapor Density:
Not Applicable Not Applicable
Boiling Point: Melting Point:
>212潞F (>100潞C) Not Determined
Solubility (H2O): Specific Gravity:
Completely @ 59潞F (15潞C): 1.465 - 1.475
Freezing Point: Evaporation Rate:
-31潞F (-35潞C) Similar to water
Octanol/H2O Coeff.: Not Available
Physical Properties: Additional Information
No additional information available.
* * * Section 10 - Chemical Stability & Reactivity Information * * *
Chemical Stability
This is a stable material.
Chemical Stability: Conditions to Avoid
Avoid contact with extreme heat and incompatible materials.
Incompatibility
This product is incompatible with flammable and combustible materials, strong reducing agents and finely
powdered metals.
Hazardous Decomposition
Decomposition may yield calcium compounds and oxides of nitrogen.
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CALCIUM NITRATE TETRAHYDRATE 66% AND 70% SOLUTION
Material Safety Data Sheet
Material Name: CALCIUM NITRATE TETRAHYDRATE 66% AND 70% SOLUTION ID: MRD-016
Hazardous Polymerization
Will not occur.
* * * Section 11 - Toxicological Information * * *
Acute and Chronic Toxicity
A: General Product Information
No information available for the product.
The nitrate component of this product may cause methemoglobinemia upon ingestion characterized by cyanosis,
headache, dizziness, fatigue, nausea, vomiting, drowsiness, stupor, coma and rarely death.
B: Component Analysis - LD50/LC50
Calcium Nitrate Tetrahydrate (13477-34-4)
Oral LD50 Rat : 3900 mg/kg
Carcinogenicity
A: General Product Information
No carcinogenicity data available for this product.
B: Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP.
Chronic Toxicity
No information available for the product.
Epidemiology
No epidemiological data is available for this product.
Neurotoxicity
No data available for this product.
Mutagenicity
No data available for this product.
Teratogenicity
No data available for this product.
Other Toxicological Information
No additional information available.
* * * Section 12 - Ecological Information * * *
Ecotoxicity
A: General Product Information
In high concentrations, this product may be harmful to both terrestrial and aquatic plant or animal life.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
No ecotoxicity data are available for this product's components.
Environmental Fate
No data available for this product.
* * * Section 13 - Disposal Considerations * * *
US EPA Waste Number & Descriptions
A: General Product Information
You must test your waste using methods described in 40 CFR Part 261 to determine if it meets applicable
definitions of hazardous wastes.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
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CALCIUM NITRATE TETRAHYDRATE 66% AND 70% SOLUTION
Material Safety Data Sheet
Material Name: CALCIUM NITRATE TETRAHYDRATE 66% AND 70% SOLUTION ID: MRD-016
* * * Section 14 - Transportation Information * * *
US DOT Information
This material is not hazardous as defined by 49CFR 172.101 by the US Department of Transportation.
Canada Transportation of Dangerous Goods Information
This material is not considered as dangerous goods, per regulations of Transport Canada.
International Transportation Regulations
No additional information available.
* * * Section 15 - Regulatory Information * * *
US Federal Regulations
A: General Product Information
No additional information available.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302
(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Calcium Nitrate Tetrahydrate (13477-34-4)
SARA 313: form R reporting required for 1.0% de minimis concentration; Chemical Category N511 (related
to Water Dissociable Nitrate Compounds)
SARA 311/312: Acute Health Yes Chronic Health No Fire No Pressure No Reactive No
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
None of this product's components are listed on the state lists from CA, FL, MA, MN, NJ, or PA.
Canadian WHMIS Information
A: General Product Information
All components are on the Canadian Domestic Substances or Non-Domestic Substances Inventory Lists.
B: Component Analysis - WHMIS IDL
No components are listed in the WHMIS IDL.
WHMIS Classification: Class D2B: Material Causing Other Toxic Effects
Additional Regulatory Information
A: General Product Information
All components are on the U.S. EPA TSCA Inventory List.
Calcium Nitrate Tetrahydrate is a hydrate of an anhydrous form that is on the US TSCA and Canadian DSL
inventories, and can be referenced under the parent compound name.
B: Component Analysis - Inventory Component Analysis - Inventory
Component CAS # TSCA DSL NDSL EINECS AUST MITI PHIL KOREA ELINCS CHINA CAN
Calcium Nitrate 13477-34-4 No No No No Yes Yes Yes No No Yes No
Tetrahydrate
Water 7732-18-5 Yes Yes No Yes Yes Yes No Yes No Yes DSL
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CALCIUM NITRATE TETRAHYDRATE 66% AND 70% SOLUTION
Material Safety Data Sheet
Material Name: CALCIUM NITRATE TETRAHYDRATE 66% AND 70% SOLUTION ID: MRD-016
* * * Section 16 - Other Information * * *
Other Information
Disclaimer: Supplier gives no warranty of merchantability or of fitness for a particular purpose. Any product
purchased is sold on the assumption the purchaser will make his own tests to determine the quality and suitability
of the product. Supplier expressly disclaims any and all liability for incidental and/or consequential property
damage arising out of the use of this product. No information provided shall be deemed to be a recommendation
to use any product in conflict with any existing patent rights. Read the Material Safety Data Sheet before handling
product.
Key/Legend
NA = Not available or Not Applicable. CERCLA = Comprehensive Environmental Response Compensation &
Liability Act; SARA = Superfund Amendments & Reauthorization Act; RCRA = Resource Conversation &
Recovery Act. TLV = Threshold Limit Value. NFPA = National Fire Protection Association. HMIS = Hazardous
Material Information System. CFR = Code of Federal Regulations. HEPA = High Efficiency Particulate Air EPA =
Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of
Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National
Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety
and Health Administration., NJTSR = New Jersey Trade Secret Registry.
This is the end of MSDS # MRD-016
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CALCIUM NITRATE TETRAHYDRATE 66% AND 70% SOLUTION
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