MATERIAL SAFETY DATA SHEET
POLYAZIRIDINE, LLC
P.O. BOX 637
MEDFORD, NJ 08055
PAGE 1 OF 4
THE EMERGENCY PHONE NUMBERS ARE: CHEMTREC (800) 424-9300
POLYAZIRIDINE, LLC. (610) 913-7121
For (non EMERGENCY) Product information call: POLYAZIRIDINE, LLC. (610) 913-7125
PRODUCT INDENTIFICATION
PRODUCT NAME: PZ-33 VERSION DATE: 9/23/06
SYNONYMS: DATE PRINTED: 9/23/06
Polyfunctional Aziridine MSDS Number: PZ-33-001
CHEMICAL FAMILY: CAS/TSCA Number: 57116-45-7
Pentaerythritol-tris-(B-(-aziridinyl)propionate) ECION/EINECS Number: 501286
HAZARDOUS INGREDIENTS
INGREDIENT: Percent: Hazard Data
Pentaerythritol-tris-(B-(aziridinyl)propionate) >99 -
PHYSICAL DATA
PHYSICAL DATA Low High Units Comments
Solubility in water - >50% - -
Specific Gravity - 1.185 - Water =1
Vapor Pressure - <0.1 mm Hg @ 20飩癈
Freezing Point - <-10飩癈 - -
Appearance - - - Liquid
Molecular Weight 427 500 - -
D.N.A.= DOES NOT APPLY N.M.= NOT MEASURED
FIRE AND EXPLOSION HAZARD
FLASH POINT: >100飩癈 TCC >230飩癋 TCC
EXTINGUISHING MEDIA: USE ALCOHOL TYPE FOAM, DRY CHEMICAL
SPECIAL PROCEDURES:
Wear self-contained positive breathing apparatus (SCBA) and complete personal protective equipment.
Remove all ignition sources. Use a water spray to cool fire-exposed containers.
UNUSUAL HAZARDS:
Closed containers may rupture (due to buildup of pressure) when exposed to extreme heat. Auto
ignition temperature 482飩癈.
MATERIAL SAFETY DATA SHEET
POLYAZIRIDINE, LLC
P.O. BOX
PAGE 2 OF 4
THE EMERGENCY PHONE NUMBERS ARE: CHEMTREC (800) 424-9300
POLYAZIRIDINE, LLC. (610) 913-7121
For (non EMERGENCY) Product information call: POLYAZIRIDINE, LLC. (610) 913-7125
PRODUCT INDENTIFICATION
PRODUCT NAME: PZ-33 VERSION DATE: 9/23/06
SYNONYMS: DATE PRINTED: 9/23/06
Polyfunctional Aziridine MSDS Number: PZ-33-001
CHEMICAL FAMILY: CAS/TSCA Number: 57116-45-7
Pentaerythritol-tris-(B-(-aziridinyl)propionate) ECION/EINECS Number: 501286
HEALTH INFORMATION
Primary Route of Exposure:
Inhalation: YES Skin Absorption: YES Ingestion: YES
TOXICITY: Route Test Dose Units Comments
Oral LD50 2000 MG/KG Slightly toxic
Skin LD50 >3000 MG/KG (1)
TOXICITY TEST:
(1) Slightly toxic by absorption. May cause mild skin irritation and sensitization.
May cause severe eye irritation. Positive results were obtained in a battery of short-term, in-vitro
genotoxicity assay, (Ames cho/hgprt, cell transformation).
CARCINOGEN: IARC: NO NTP: NO OSHA: NO
OCCUPATIONAL EXPOSURE LIMITS
TEST: NOT ESTABLISHED
EMERGENCY AND FIRST AID PROCEDURE
INHALATION: Remove to fresh air. Obtain medical attention.
EYE CONTACT: Hold eyes open and flush eyes for at least 15 minutes with large quantities of water.
Seek medical attention.
SKIN CONTACT: Wash affected areas thoroughly with soap and water. Remove and wash contaminated
clothing before reuse.
INGESTION: Remove from exposure. Induce vomiting. Obtain medical attention.
ADDITIONAL MEASURES: None found
MATERIAL SAFETY DATA SHEET
POLYAZIRIDINE, LLC
P.O. BOX
PAGE 3 OF 4
THE EMERGENCY PHONE NUMBERS ARE: CHEMTREC (800) 424-9300
POLYAZIRIDINE, LLC. (610) 913-7121
For (non EMERGENCY) Product information call: POLYAZIRIDINE, LLC. (610) 913-7125
PRODUCT INDENTIFICATION
PRODUCT NAME: PZ-33 VERSION DATE: 9/23/06
SYNONYMS: DATE PRINTED: 9/23/06
Polyfunctional Aziridine MSDS Number: PZ-33-001
CHEMICAL FAMILY: CAS/TSCA Number: 57116-45-7
Pentaerythritol-tris-(B-(-aziridinyl)propionate) ECION/EINECS Number: 501286
REACTIVITY DATA
CHEMICAL STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur
CONDITIONS TO AVOID: Temperatures above 50飩癈
HAZARDOUS DECOMPOSITION PRODUCTS: Combustion may produce nitrous oxide and carbon
monoxide.
SPILL OR LEAK PROCEDURES/WASTE DISPOSAL
SPILL OR LEAK PROCEDURES:
Wear butyl rubber protective equipment. Stop leak at source. Flush with water; react with ammonium
thiosulfate; flush again with water. Uncontrolled spills exceeding 100 lbs may be reportable to the
national response center (1-800-424-8802).
WASTE DISPOSAL:
Incinerate or dispose of in approved landfill. Dispose of as an aqueous waste after reaction with
ammonium thiosulfate, with approval of local, state or federal agency.
EMPLOYEE PROTECTION
RESPIRATORY PROTECTION:
Use a half-mask respirator with organic vapor cartridge approved by NIOSH/MSHA where excessive
exposure to vapors or mist may occur. For fire-fighting or other emergency situations use a
NIOSH/MSHA approved positive pressure self-contained breathing apparatus.
PROTECTIVE CLOTHING:
Nitrile or butyl rubber gloves. Chemical goggles or splash shield. Use impervious clothing to protect
exposed body areas where liquid contact is likely.
ADDITIONAL PROTECTIVE MEASURES:
Local exhaust when appropriate to control employee exposure. Safety showers and eyewash facilities
must be immediately available.
MATERIAL SAFETY DATA SHEET
POLYAZIRIDINE, LLC
P.O. BOX
PAGE 4 OF 4
THE EMERGENCY PHONE NUMBERS ARE: CHEMTREC (800) 424-9300
POLYAZIRIDINE, LLC. (610) 913-7121
For (non EMERGENCY) Product information call: POLYAZIRIDINE, LLC. (610) 913-7125
PRODUCT INDENTIFICATION
PRODUCT NAME: PZ-33 VERSION DATE: 9/23/06
SYNONYMS: DATE PRINTED: 9/23/06
Polyfunctional Aziridine MSDS Number: PZ-33-001
CHEMICAL FAMILY: CAS/TSCA Number: 57116-45-7
Pentaerythritol-tris-(B-(-aziridinyl)propionate) ECION/EINECS Number: 501286
SPECIAL PRECAUTIONS
Keep away from heat. Segregate from acids and oxidizers.
Safety showers and eyewash facilities must be immediately available.
OTHER REGULATORY CONTROLS
SARA HAZARD CLASS:
ACUTE: NO CHRONIC: NO FIRE HAZARD: NO
PRESSURE: NO REACTIVITY: NO
HMIS - H=2, F=1, R=1, PP=D
California Proposition 65 (SWDA): Not Listed
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