3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200 - White; PN 06520 , 05220, 06534, 06535
08/08/2007
Material Safety Data Sheet
Copyright, 2007, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Marine Adhesive Sealant Fast Cure 5200 - White; PN 06520 , 05220, 06534,
06535
MANUFACTURER: 3M
DIVISION: Marine & Specialty Vehicle
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 08/08/2007
Supercedes Date: 07/18/2007
Document Group: 16-5850-9
Product Use:
Specific Use: Adhesive Sealant for fiberglass and wood.
Intended Use: Sealant
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
URETHANE PREPOLYMER 51447-37-1 40 - 70
TITANIUM DIOXIDE 13463-67-7 10 - 30
DIETHYLENE GLYCOL MONOETHYL ETHER ACETATE 112-15-2 1- 5
SILICA 7631-86-9 < 2.5
1,1'-METHYLENEBIS(ISOCYANATOBENZENE) 26447-40-5 < 2.5
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 < 2.5
ZINC OXIDE 1314-13-2 < 2.3
ALKYL ISOCYANATE SILANE 85702-90-5 <2
TOLUENE 108-88-3 < 0.05
ETHYLBENZENE 100-41-4 < 0.02
HEXAMETHYLENE DIISOCYANATE 822-06-0 < 0.02
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Paste
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200 - White; PN 06520 , 05220, 06534, 06535
08/08/2007
Odor, Color, Grade: White thixotropic paste, slight odor
General Physical Form: Solid
Immediate health, physical, and environmental hazards: May cause allergic skin reaction. May cause allergic
respiratory reaction. Contains a chemical or chemicals which can cause cancer.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Vapors released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or
hazy vision.
Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling,
pain, tearing, and blurred or hazy vision.
Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Prolonged or repeated exposure may cause:
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
Prolonged or repeated exposure may cause:
Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Target Organ Effects:
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200 - White; PN 06520 , 05220, 06534, 06535
08/08/2007
Ingredient C.A.S. No. Class Description Regulation
ETHYLBENZENE 100-41-4 Group 2B International Agency for Research on Cancer
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Not applicable.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Ventilate the area with fresh air. Avoid contact with water. Pour isocyanate decontaminant solution (90%
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200 - White; PN 06520 , 05220, 06534, 06535
08/08/2007
water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react
for more than 30 minutes. Cover with absorbent material. Place in a container approved for transportation by appropriate authorities,
but do not seal the container for 48 hours to avoid pressure build-up. Collect as much of the spilled material as possible. Collect the
resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid eye contact with
vapors, mists, or spray. Keep out of the reach of children. Avoid breathing of dust created by cutting, sanding, grinding or machining.
Do not breathe vapors. Avoid eye contact with dust or airborne particles.
7.2 STORAGE
Store in a cool place. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. Keep container
tightly closed.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Do not
use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to
control airborne exposures to below Occupational Exposure Limits and/or control dust, fume, or airborne particles. If ventilation is
not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin Protection
Avoid prolonged or repeated skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Butyl Rubber, Nitrile Rubber.
8.2.3 Respiratory Protection
Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not breathe vapors.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
1,1'- ACGIH TWA 0.005 ppm
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200 - White; PN 06520 , 05220, 06534, 06535
08/08/2007
METHYLENEBIS(ISOCYANATOBENZENE
)
1,1'- OSHA CEIL 0.02 ppm Table Z-1
METHYLENEBIS(ISOCYANATOBENZENE
)
ETHYLBENZENE ACGIH TWA 100 ppm Table A3
ETHYLBENZENE ACGIH STEL 125 ppm Table A3
ETHYLBENZENE OSHA TWA 100 ppm Table Z-1A
ETHYLBENZENE OSHA STEL 125 ppm Table Z-1A
FREE ISOCYANATES 3M TWA 0.005 ppm
FREE ISOCYANATES 3M STEL 0.02 ppm
HEXAMETHYLENE DIISOCYANATE ACGIH TWA 0.005 ppm
P,P'-METHYLENEBIS(PHENYL ACGIH TWA 0.005 ppm
ISOCYANATE)
P,P'-METHYLENEBIS(PHENYL OSHA CEIL 0.02 ppm Table Z-1
ISOCYANATE)
SILICA CMRG TWA, as respirable 3 mg/m3
dust
TIN, ORGANIC COMPOUNDS ACGIH TWA, as Sn 0.1 mg/m3 Skin Notation*; Table A4
TIN, ORGANIC COMPOUNDS ACGIH STEL, as Sn 0.2 mg/m3 Skin Notation*
TIN, ORGANIC COMPOUNDS OSHA TWA, as Sn 0.1 mg/m3 Skin Notation*; Table Z-1A
TITANIUM DIOXIDE ACGIH TWA 10 mg/m3 Table A4
TITANIUM DIOXIDE CMRG TWA, as respirable 5 mg/m3
dust
TITANIUM DIOXIDE OSHA TWA, Vacated, as 10 mg/m3
dust
TITANIUM DIOXIDE OSHA TWA, as total dust 15 mg/m3 Table Z-1
TOLUENE ACGIH TWA 20 ppm Table A4
TOLUENE CMRG STEL 75 ppm Skin Notation*
TOLUENE OSHA TWA, Vacated 100 ppm
TOLUENE OSHA STEL, Vacated 150 ppm
TOLUENE OSHA TWA 200 ppm Table Z-2
TOLUENE OSHA CEIL 300 ppm Table Z-2
ZINC OXIDE ACGIH TWA, respirable 2 mg/m3
ZINC OXIDE ACGIH STEL 10 mg/m3
ZINC OXIDE OSHA TWA, as fume 5 mg/m3 Table Z-1
ZINC OXIDE OSHA TWA, respirable 5 mg/m3 Table Z-1
ZINC OXIDE OSHA STEL, Vacated, as 10 mg/m3
fume
ZINC OXIDE OSHA TWA, Vacated, as 10 mg/m3
dust
ZINC OXIDE OSHA TWA, as total dust 15 mg/m3 Table Z-1
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,
either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200 - White; PN 06520 , 05220, 06534, 06535
08/08/2007
Paste
Specific Physical Form:
White thixotropic paste, slight odor
Odor, Color, Grade:
Solid
General Physical Form:
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
Not Applicable
Boiling point
No Data Available
Vapor Density
No Data Available
Vapor Pressure
1.3 [Ref Std: WATER=1]
Specific Gravity
Not Applicable
pH
Not Applicable
Melting point
Nil
Solubility in Water
No Data Available
Evaporation rate
0.024 lb HAPS/lb solids
Hazardous Air Pollutants
40 g/l [Test Method: tested per EPA method 24]
Volatile Organic Compounds
2.94 % weight
Percent volatile
40 g/l [Test Method: tested per EPA method 24]
VOC Less H2O & Exempt Solvents
100000 - 500000 centipoise
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Amines; Alcohols; Water
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Isocyanates During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Cyanide During Combustion
Oxides of Nitrogen During Combustion
Toxic Vapor, Gas, Particulate During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200 - White; PN 06520 , 05220, 06534, 06535
08/08/2007
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Cure (harden, set, or react) the product according to product instructions.
Dispose of waste product in a sanitary landfill. Dispose of completely cured (or polymerized) wastes in a sanitary landfill.
Incinerate in a permitted hazardous waste incinerator in the presence of a combustible material. As a disposal alternative, incinerate in
an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, incinerate uncured product in
an industrial or commercial incinerator. As a disposal alternative, incinerate uncured product in an industrial or commercial
incinerator in the presence of a combustible material.
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
60-9800-4557-3, 60-9800-4558-1, 60-9800-4562-3, 60-9801-0557-5, 62-5239-0330-0, 62-5239-0334-2, FS-9100-3615-1, FS-
9100-3648-2, LB-T000-0007-0
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
P,P'-METHYLENEBIS(PHENYL 101-68-8 < 2.5
ISOCYANATE) (Diisocyanates (EPCRA 313))
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200 - White; PN 06520 , 05220, 06534, 06535
08/08/2007
ZINC OXIDE (ZINC COMPOUNDS) 1314-13-2 < 2.3
DIETHYLENE GLYCOL MONOETHYL 112-15-2 1- 5
ETHER ACETATE (GLYCOL ETHERS)
HEXAMETHYLENE DIISOCYANATE 822-06-0 < 0.02
(Diisocyanates (EPCRA 313))
STATE REGULATIONS
Contact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No. Classification
ETHYLBENZENE 100-41-4 **Carcinogen
TOLUENE 108-88-3 *Developmental Toxin
* WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm.
** WARNING: contains a chemical which can cause cancer.
CHEMICAL INVENTORIES
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 0 Reactivity: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Revision Changes:
Section 1: Product name was modified.
Page Heading: Product name was modified.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Marine Adhesive Sealant Fast Cure 5200 - White; PN 06520 , 05220, 06534, 06535
08/08/2007
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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