MATERIAL SAFETY DATA SHEET
PRESCRIPTION TREATMENT庐 brand Tame/Orthene TR
EMERGENCY PHONE NUMBERS:
MEDICAL: 800-225-3320 (PROSAR) TRANSPORTATION: 800-424-9300 (CHEMTREC)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of
water for 15-20 minutes. Call a poison control center or doctor for treatment advice.
Product Name: PRESCRIPTION TREATMENT brand Tame/Orthene TR
庐
Eye Contact: Hold eyes open and rinse slowly and gently for 15-20 minutes. Remove
EPA Reg. No.: 499-441 contact lenses, if present, after the first 5 minutes, then continue rinsing eyes. Call a
Product Code(s): 09-1450 (12 x 17.5 oz.) poison control center or doctor for treatment advice.
EPA Signal Word: WARNING
Note to Physician: This product contains an organophosphate insecticide. If symp-
Distributed by: Whitmire Micro-Gen Research Laboratories, Inc.
toms of cholinesterase inhibition are present, atropine sulfate is antidotal. 2-PAM is
3568 Tree Court Industrial Blvd.
also antidotal and may be administered in conjunction with atropine.
St. Louis MO 63122-6682
Medical Conditions Generally Aggravated by Exposure: None known.
Emergency Telephone Number of Prosar: 800-225-3320 (for medical emer-
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
gencies.)
COMPOSITION INFORMATION
SECTION 5. FIRE FIGHTING MEASURES
ACTIVE INGREDIENTS (2.5%) % CAS NO.
Fenpropathrin 1.0% 39615-41-8 FIRE AND EXPLOSION
Acephate 1.5% 30560-19-1 Flash Point (TCC): NE
Flame Projection: > 18 inches
OTHER INGREDIENTS* (97.5%) % CAS NO.
Explodibility Limits in Air (% by volume):
Isopropanol proprietary 67-63-0
Lower (LEL) = 3.4% Upper (UEL) = 18%
Dimethyl Ether proprietary 115-10-6
NFPA 30B Flammability: Level II Aerosol
* All ingredients may not be listed. Ingredients not listed do not meet the reporting requirements of the
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
OSHA Hazard Communication Standard (HCS) as specified in 29 CFR 1910.1200.
Contents under pressure. Exposure to temperatures above 130掳 F may cause
EXPOSURE INFORMATION bursting.
OSHA PEL ACGIH TLV
IN CASE OF FIRE
Material STEL TWA STEL TWA
Extinguisher Media: Dry Chemical, Water
Fenpropathrin* NE NE NE NE Special Fire Fighting Procedures: None required.
Acephate NE NE NE NE
Isopropanol 500 ppm 400 ppm 500 ppm 400 ppm SECTION 6. ACCIDENTAL RELEASE MEASURES
Dimethyl Ether NE NE NE 1000 ppm
IN CASE OF SPILL OR LEAK
* TWA recommended by ingredient supplier = 100 ppm.
If container begins to leak (through puncture, etc.), eliminate all ignition sources
and allow to discharge completely in well ventilated area, then dispose of as
SECTION 3. HAZARDS IDENTIFICATION
directed below.
NOTES TO PHYSICIAN This product contains no Comprehensive Environmental Response, Compensation,
This product contains an organophosphate insecticide. If symptoms of
and Liability Act (CERCLA) listed chemicals. Releases of this product are NOT
cholinesterase inhibition are present, atropine sulfate is antidotal. 2-PAM is also
reportable to the National Response Center.
antidotal and may be administered in conjunction with atropine.
Emergency Telephone Number of Chemtrec: (800) 424-9300 (for trans-
SIGNS/SYMPTOMS OF EXPOSURE portation spills)
Product causes substantial eye irritation. Product may be absorbed through skin.
PROTECTIVE EQUIPMENT FOR CLEANUP PERSONNEL
Excessive exposure may cause signs of cholinesterase inhibition including dis-
Eyes: Wear goggles or face shield.
comfort or tightness in chest, difficulty in breathing, stomach pains, nausea, vom-
Skin: Wear chemical resistant gloves. (Good practice requires that gross amounts
iting, diarrhea, cramps, headache, nervousness, weakness, non-active pinpoint
of any chemical be removed from the skin as soon as practical, especially before
pupils or blurred vision. Symptoms may not occur until 1 to 12 hours after expo-
eating or smoking.)
sure. NOTE: When used according to label directions, this level of exposure will
Inhalation: Wear a NIOSH approved respirator with an organic vapor (OV) car-
not be attained.
tridge or canister with any R, P, N or HE prefilter.
ROUTES OF ENTRY
Other: Wear long sleeved shirt, long plants and shoes plus socks.
Primary: Inhalation Secondary: Skin Tertiary: Ingestion
WASTE DISPOSAL METHOD
HAZARDOUS DECOMPOSITION PRODUCTS
Take full or leaking containers to a local disposal company for biological treatment
Thermal decomposition in open flame will result in carbon dioxide and carbon
or incineration. Review all Local , State, and Federal regulations concerning health
monoxide.
and pollution to determine approved disposal procedures. Do not contaminate
UNUSUAL FIRE, EXPLOSION AND REACTIVITY HAZARDS
water, food or feed by storage or disposal of wastes.
Contents under pressure. Exposure to temperatures above 130掳 F may cause
bursting.
SECTION 7. HANDLING AND STORAGE
SECTION 4. FIRST AID MEASURES HAZARDS TO HUMANS AND DOMESTIC ANIMALS
Keep out of reach of children. WARNING 鈥? Causes substantial but temporary eye
Have the product container or label with you when calling a poison control center or
injury. Harmful if swallowed or absorbed through skin. Do not get in eyes or on
doctor or going for treatment. Describe any symptoms and follow the advice given.
clothing. Avoid contact with skin. Wear goggles or face shield. Wash thoroughly
Ingestion: Call a poison control center or doctor immediately for treatment advice. with soap and water after handling. Remove contaminated clothing and wash
Have person sip a glass of water if able to swallow. Do not induce vomiting unless clothing before reuse.
told to do so by the poison control center or doctor. Do not give anything by mouth
USER SAFETY RECOMMENDATIONS
to an unconscious person.
Users Should: Wash hands before eating, drinking, chewing gum, using tobacco
Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambu-
or using the toilet. Remove clothing immediately if pesticide gets inside. Then wash
lance, then give artificial respiration, preferably by mouth-to-mouth, if possible.
Call a poison control center or doctor for further treatment advice. thoroughly and put on clean clothing. Remove PPE immediately after handling this
Page 1 of 2
MATERIAL SAFETY DATA SHEET
PRESCRIPTION TREATMENT庐 brand Tame/Orthene TR
product. Wash the outside of gloves before removing. As soon as possible, wash Ingestion Acute oral toxicity (rats) LD50 > 2,600 mg/kg and < 5,000 mg/kg.
Inhalation: Acute inhalation toxicity (rats) LC50 > 6,880 mg/L.
thoroughly and change into clean clothing.
CHRONIC / CARCINOGENICITY
PHYSICAL OR CHEMICAL HAZARDS
Neither this product nor any of its ingredients are classified as carcinogens by the
Extremely flammable. Contents under pressure. Keep away from fire, sparks and
National Toxicity Program (NTP), the International Agency for Research on Cancer
heated surfaces. Do not puncture or incinerate container. Exposure to temperatures
(IARC) or the Occupational Safety and Health Administration (OSHA).
above 130掳 F may cause bursting. Do not use this product in greenhouses with
unvented or defective gas heating systems. This product contains a flammable
SECTION 12. ECOLOGICAL INFORMATION
propellant. It may cause a fire or explosion if not used properly.
STORAGE This product is extremely toxic to fish and aquatic organisms and is toxic to wildlife.
Do not contaminate water, food or feed by storage. Store in a cool, dry area away Do not apply directly to water, or to areas where surface water is present or to inter-
tidal areas below the mean high water mark.
from heat or open flame and inaccessible to children.
SECTION 13. DISPOSAL CONSIDERATION
SECTION 8. EXPOSURE CONTROL / PERSONAL PROTECTION
Do not contaminate water, food or feed by disposal. Dispose of container and wastes
PERSONAL PROTECTIVE EQUIPMENT (PPE)
in accordance with all Federal, state and local regulations.
Respiratory Protection: Wear a NIOSH approved respirator with an organic vapor
(OV) cartridge or canister with any N, R, P or HE prefilter. Container Disposal: Do not puncture or incinerate! Empty container by using
Protective Gloves: Wear chemical resistant gloves. (Good practice requires that the product according to the label directions. Offer empty container for recycling,
gross amount of any chemical be removed from the skin as soon as practical, if available, or place in trash if allowed by state and local regulations. If contain-
especially before eating or smoking.) er is partly full, contact your local solid waste agency or call 1-800-CLEANUP
Eye Protection: Use proper protection 鈥? safety glasses as a minimum. for disposal instructions.
Other Protective Equipment: Wear long sleeved shirt, long pants and shoes plus
Waste Disposal: Wastes resulting from the use of this product may be dis-
socks.
posed of on site or at an approved waste disposal facility.
VENTILATION
Local Exhaust: None required. SECTION 14. TRANSPORT INFORMATION
Mechanical: None required.
SHIPMENT BY GROUND WITHIN U.S. (DOT CLASSIFICATION)
Special: None required.
Proper Shipping Name: Consumer Commodity
Other: Ventilate room before re-entry.
DOT Hazard Class: ORM-D
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
SECTION 15. REGULATORY INFORMATION
Appearance: Aerosol concentrate is Odor: Slight characteristic IPA and
CERCLA
pale yellow liquid. Acephate odor.
This product contains no CERCLA listed chemicals.
Solubility in Water: NE Vapor Pressure: NE
Viscosity: 1.87 cps @ 20掳 C Vapor Density: NE SARA TITLE III SECTION 311/312 HAZARD CLASS
This product has been reviewed according to the EPA 鈥淗azard Categories鈥? prom-
Boiling Point: NE Freezing/Melting Point: NE
ulgated under Section 311 and 312 of the Superfund Amendment and Reauthoriza-
pH: NE Density: 0.7903 g/ml @ 20掳 C
tion Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
SECTION 10. STABILITY AND REACTIVITY
Acute Health Hazard
REACTIVITY Fire Hazard
Stability: Indefinite when stored as directed. Release of Pressure (Puncture) Hazard
Conditions to Avoid: Do not spray into open flame or onto very hot surfaces.
SARA TITLE III SECTION 313 CHEMICALS
Incompatibility (Material to Avoid): Caustics, amines, alkanolamines, alde-
This product contains the following substances subject to the reporting require-
hydes, strong oxidizing agents, and chlorinated compounds.
ments of Title III of the Superfund Amendments and Reauthorization Act of 1986
Hazardous Polymerization: Will not occur.
(SARA Title III) and/or 40 CFR Part 372:
HAZARDOUS DECOMPOSITION PRODUCTS
Fenpropathrin 1.0% by weight
Thermal decomposition in open flame will result in carbon dioxide and carbon
Acephate 1.5% by weight
monoxide.
TSCA
All components of this product are listed or excluded from listing on the US Toxic
SECTION 11. TOXICOLOGICAL INFORMATION
Substance Control Act (TSCA) Chemical Substance Inventory.
ROUTES OF ENTRY
Primary: Inhalation Secondary: Skin Tertiary: Ingestion SECTION 16. OTHER INFORMATION
ACUTE
Eyes: Product causes substantial but temporary eye injury. Produces conjunctival NFPA HEALTH RATING INFORMATION KEY: 4 = Severe
irritation in rabbits, reversible within 21 days. Product causes corneal opacity HEALTH - 2 FLAMMABILITY - 3 REACTIVITY - 1 3 = Serious
clearing in 48 hours and iritis clearing in 14 days. 2 = Moderate
Skin: Acute dermal LD50 > 2,000 mg/kg (rabbits). Primary skin irritation index = HMIS HAZARD RATING INFORMATION 1 = Slight
0.25 (rabbits). Not a skin sensitizer when tested on guinea pigs. HEALTH - 2 FLAMMABILITY - 3 REACTIVITY - 1 0 = Minimal
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made
with respect to the information contained herein.
Questions concerning the safe handling of the product should be referred to the Whitmire Micro-Gen Customer Service Department at 800-777-8570.
NA - Not Applicable Effective Date: 5/2/03
WHITMIRE MICRO-GEN
NE - Not Established Review Date: NA
PEL - Permissible Exposure Limit Supersedes: NA
RESEARCH LABORATORIES, INC.
TLV - Threshold Limit Value Text ID: 030313-1
STEL - Short Term Exposure Limit (15 min.) Code #: 138-044
TWA - Time Weighted Average (8 hrs) WMG Part #: 19-0162-1
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