MATERIAL SAFETY DATA SHEET - NO. M05
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Berylcoat D
None
SYNONYMS
24-HR. EMERGENCY ASSISTANCE CHEMICAL FAMILY Acid and Oxidizing Agent
Transportation Emergency
Call Chemtrec at: CUSTOMER SERVICE
Domestic: (800) 424-9300 Brush Wellman Inc.
International: (703) 527-3887 Product Stewardship Department
Other Emergency 17876 St. Clair Avenue
Call Brush Wellman at: (800) 862-4118 Cleveland, Ohio 44110
Phone: (800) 862-4118
Revised: 01-02-08 Fax: (216) 383-4091
Replaces: MSDS M05 (01-27-05) Websites www.brushwellman.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL COMPOSITION (Percent by Weight)
BRUSH WELLMAN PRODUCT
CONSTITUENTS CAS Numbers Beryl Coat D Concentrate Beryl Coat D Solution
Phosphoric Acid 7664-38-2 50 31
Potassium Dichromate 7778-50-9 4 2
Hazard Communication regulations of the U.S. Occupational Safety and Health Administration apply to this
product.
NOTE: As used in this Material Safety Data Sheet, the term 鈥減articulate鈥? refers to dust, mist, fume, fragments,
particles and/or powder.
3. HAZARD IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odorless corrosive orange liquid. See label in Section 16. If the material is involved in a fire;
pressure-demand self-contained breathing apparatus and protective clothing must be worn by
persons potentially exposed to the airborne particulate during or after a fire.
3.2 POTENTIAL HEALTH EFFECTS
Exposure to the elements listed in Section 2 by inhalation, ingestion, and skin contact can occur during routine
handling, material transfer, chemical processing, further processing or when product is spilled or released.
Page 1 of 9
Berylcoat D MSDS No. M05 January 27, 2005
3.2.1 Inhalation
Phosphoric Acid: May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of
breath and delayed lung edema. May cause chemical burns to the respiratory tract.
Potassium Dichromate: May cause asthmatic attacks due to allergic sensitization of the respiratory tract. May
cause ulceration and perforation of the nasal septum.
3.2.2 Ingestion
Ingestion can occur from hand, clothing, food and drink contact with particulate during hand to mouth
activities such as eating, drinking, smoking, nail biting, etc.
Phosphoric Acid: Causes gastrointestinal tract burns. Causes severe pain, nausea, vomiting, diarrhea, and
shock. May cause hemorrhaging of the digestive tract. May cause corrosion and permanent tissue destruction
of the esophagus and digestive tract. May cause methemoglobinemia, cyanosis, convulsions, and death.
Potassium Dichromate: May be fatal if swallowed. May cause severe and permanent damage to the digestive
tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause
methemoglobinemia, cyanosis, convulsions, and death. Methemoglobinemia is characterized by dizziness,
drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown
colored blood.
3.2.3 Skin
Skin contact with this material may cause, in some sensitive individuals, an allergic dermal response. Skin
contact may cause irritation. Symptoms include redness, itching and pain.
Phosphoric Acid: Contact with liquid is corrosive and causes severe burns and ulceration. May cause skin rash
(in milder cases), and cold and clammy skin with cyanosis or pale color.
Potassium Dichromate: May be fatal if absorbed through the skin. Causes skin burns. May cause skin
sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Chrome ulcers,
penetrating lesions of the skin, occur chiefly on the hand and forearms where there has been a break in the
epidermis.
3.2.4 Eyes
Contact with liquid or vapors will cause irritation or burns to the eyes.
Phosphoric Acid: Contact with liquid is corrosive to the eyes and causes severe burns. May cause chemical
conjunctivitis and corneal damage.
Potassium Dichromate: Causes eye burns. May cause chemical conjunctivitis and corneal damage.
3.2.5 Chronic (long-term health effects)
Phosphoric Acid: Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated eye contact
may cause conjunctivitis. Effects may be delayed. Chronic exposure may cause liver damage. May cause
cyanosis - a blue-gray coloring of the skin and lips caused by a lack of oxygen. Inhalation of vapors may
produce pulmonary edema characterized by fluid build-up in the lungs.
Page 2 of 9
Berylcoat D MSDS No. M05 January 27, 2005
Potassium Dichromate: Prolonged or repeated skin contact may cause sensitization dermatitis and possible
destruction and/or ulceration. May cause respiratory tract cancer. May cause liver and kidney damage. Chronic
inhalation may cause nasal septum ulceration and perforation. May cause reproductive and fetal effects.
Effects may be delayed. Laboratory experiments have resulted in mutagenic effects. Repeated or prolonged
exposure may cause erosion and discoloration of the teeth.
3.2.6 Carcinogenic References
Potassium Dichromate: The International Agency for Research on Cancer (IARC) lists Chromium VI
compounds as a Group 1 鈥? Known Human Carcinogen. The National Toxicology Program (NTP) lists
Chromium VI compounds as known human carcinogen. The ACGIH lists Chromium VI compounds as an A1
鈥? Confirmed Human Carcinogen.
3.2.7 Medical Conditions Aggravated by Exposure
Persons with impaired pulmonary function, airway diseases, or conditions such as asthma, emphysema,
chronic bronchitis, etc. may incur further impairment if particulate is inhaled. If prior damage or disease to the
neurologic (nervous), circulatory, hematologic (blood), or urinary (kidney) systems has occurred, proper
screening or examinations should be conducted on individuals who may be exposed to further risk where
handling and use of this material may cause exposure.
3.3 POTENTIAL ENVIRONMENTAL EFFECTS
See Ecological Information (Section 12)
4. FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
INHALATION: Breathing difficulty caused by inhalation of vapor requires immediate removal to fresh air.
If breathing has stopped, perform artificial respiration and obtain medical help.
INGESTION: Induce vomiting immediately as directed by medical personnel. Never give anything by
mouth to an unconscious person.
SKIN: In case of skin contact, flush affected area with large amounts of water.
EYES: Solution should be flushed from the eyes immediately with plenty of clean water for at least 15
minutes. Medical attention should be obtained at once. Contact lenses should not be worn when working with
this material because the contact lens must be removed to provide adequate treatment.
5. FIRE FIGHTING MEASURES
Flash Point Not Applicable
Explosive Limits Not Applicable
Extinguishing Media Not Applicable
Unusual Fire and Explosion Not Applicable
Hazards
Special Fire Fighting Procedures If this material becomes airborne as a respirable particulate during a fire
situation, pressure-demand self-contained breathing apparatus must be
worn by firefighters or any other persons potentially exposed.
Page 3 of 9
Berylcoat D MSDS No. M05 January 27, 2005
6. ACCIDENTAL RELEASE MEASURES
6.1 STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
If this material is released or spilled, establish a restricted entry zone based on the severity of the spill. Persons
entering the restricted zone must wear adequate respiratory protection and protective clothing appropriate for
the severity of the spill. Caution should be taken to minimize spillage to avoid contamination of water.
Dichromate ion can be reduced to trivalent form with ferrous sulfate. Depending upon the quantity of material
released, spills to the environment may require reporting to the National Response Center at (800) 424-8802 as
well as the State Emergency Response Commission and Local Emergency Planning Committee.
7. HANDLING AND STORAGE
7.1 HANDLING
Keep storage container tightly sealed. Transfer solution in closed systems or with local exhaust ventilation or
other controls designed to meet OSHA standards. Prevent spillage. Prevent contact with clothing. Flush
container clean before discarding.
7.2 STORAGE
Store in a dry area.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
8.1 VENTILATION AND ENGINEERING CONTROLS
General ventilation is normally adequate to control exposures to vapors. Store and transport material in tightly
sealed containers.
8.2 WORK PRACTICES
Develop work practices and procedures that prevent liquid from coming in contact with worker skin or
personal clothing. Procedures should be written that clearly communicates the facility鈥檚 requirements for
protective clothing and personal hygiene.
8.3 RESPIRATORY PROTECTION
When airborne exposures exceed or have the potential to exceed the occupational limits shown in Section
8.13, approved respirators must be used as specified by an Industrial Hygienist or other qualified professional.
Respirator users must be medically evaluated to determine if they are physically capable of wearing a
respirator. Quantitative and/or qualitative fit testing and respirator training must be satisfactorily completed by
all personnel prior to respirator use. Users of tight fitting respirators must be clean shaven on those areas of
the face where the respirator seal contacts the face. Exposure to unknown concentrations of particulate
requires the wearing of a pressure-demand airline respirator or pressure-demand self-contained breathing
apparatus (SCBA). Use pressure-demand airline respirators when performing jobs with high potential
exposures such as changing filters in a baghouse air cleaning device.
8.4 OTHER PROTECTIVE EQUIPMENT
Persons who may come in contact with liquid during activities such as maintenance and spill clean up must
wear protective overgarments. Contaminated work clothing and overgarments must be managed in a
controlled manner to prevent exposure to others.
8.5 PROTECTIVE GLOVES
Wear long cuff neoprene gloves to prevent solution from contacting the skin during handling.
Page 4 of 9
Berylcoat D MSDS No. M05 January 27, 2005
8.6 EYE PROTECTION
Wear chemical goggles or a face shield during handling, transferring, applying, etc. Emergency washing
equipment, such as an eye wash station and safety shower should be available in the work area.
8.7 HOUSEKEEPING
Absorb incidental releases observing precautions in the Protective Equipment section then place into a
chemical waste container. Provide ventilation. Clean up spills immediately. Do not permit this material to
dry.
8.8 MAINTENANCE
During repair or maintenance activities the potential exists for exposures in excess of the occupational
standards. Under these circumstances, protecting workers can require the use of specific work practices or
procedures involving the combined use of ventilation, spill clean up methods, respiratory protection,
decontamination, special protective clothing, and when necessary, restricted work zones.
8.9 EXPOSURE CHARACTERIZATION
Determine exposure by air sampling in the employee breathing zone, work area, and department. Utilize an
Industrial Hygienist or other qualified professional to specify the frequency and type of air sampling. Develop
and utilize a sampling strategy which identifies the extent of exposure variation and provides statistical
confidence in the results. Conduct an exposure risk assessment of processes to determine if conditions or
situations exist which dictate the need for additional controls or improved work practices. Make air sample
results available to employees.
8.10 MEDICAL SURVEILLANCE
8.11 OCCUPATIONAL EXPOSURE LIMITS
CONSTITUENTS OSHA* ACGIH* NIOSH RTECS
NUMBER
PEL CEILING PEAK TLV TLV-STEL
Phosphoric Acid 1 N/A N/A 1 3 TB6300000
Potassium N/A N/A N/A 0.05 N/A HX7680000
Dichromate (as Cr
VI Water Soluble)
*ALL CONCENTRATIONS ARE IN MILLIGRAMS PER CUBIC METER OF AIR
(at the concentrations noted above, these constituents may not be visible to the human eye)
A leading scientific body recommending occupational standards is the American Conference of Governmental
Industrial Hygienists (ACGIH). The ACGIH recommends standards for all listed substances. The ACGIH
defines a threshold limit value (standard) as follows: 鈥淭hreshold Limit Values refer to airborne concentrations
of substances and represent conditions under which it is believed that nearly all workers may be repeatedly
exposed day after day without adverse health effects. Because of wide variation in individual susceptibility,
however, a small percentage of workers may experience discomfort from some substances at concentrations at
or below the threshold limit; a smaller percentage may be affected more seriously by aggravation of a pre-
existing condition or by development of an occupational illness.鈥? 鈥淚ndividuals may also be hypersusceptible
or otherwise unusually responsive to some industrial chemicals because of genetic factors, age, personal habits
(smoking, alcohol, or other drugs), medication, or previous exposures. Such workers may not be adequately
protected from adverse health effects from certain chemicals at concentrations at or below the threshold
limits.鈥?
Page 5 of 9
Berylcoat D MSDS No. M05 January 27, 2005
ACGIH = American Conference of Governmental Industrial Hygienists
OSHA = Occupational Safety and Health Administration
PEL = Eight-Hour Average Permissible Exposure Limit (OSHA)
CEILING = Not To Be Exceeded Except For Peak Limit (OSHA)
PEAK = 30-Minute Maximum Duration Concentration Above Ceiling Limit (OSHA)
TLV = Eight-Hour Average Threshold Limit Value (ACGIH)
TLV-STEL = 15-Minute Short Term Exposure Limit (ACGIH)
CAS = Chemical Abstract Service
NIOSH = National Institute For Occupational Safety and Health
RTECS = Registry of Toxic Effects of Chemical Substances
NA = Not Applicable
Brush Wellman recommends following good industrial hygiene practice which includes reducing airborne
exposures to the lowest feasible level for all constituents in this product.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL PROPERTIES
Boiling Point (掳F): 219 (Solution) 237 Radioactivity: Not Applicable
(Concentrate)
Evaporation Rate: Not Available Solubility: 100%
Freezing Point (掳F): 10.4 (Solution) -58 Sublimes At (掳F): Not Applicable
(Concentrate)
Odor: None Vapor Density (Air = 1): Not Available
pH: <2 Vapor Pressure (mmHg): 0.0212 (Solution) 0.0189
(Concentrate)
Physical State: Liquid % Volatiles By Volume: 67 (Solution) 46
(Concentrate)
PHYSICAL PROPERTIES
Alloy Number/Product Color Melting Point (掳F) Density (lb/in3)
Name
Beryl Coat D Concentrate Orange -58 0.0503
Beryl Coat D Solution Orange 10.4 0.0439
10. STABILITY AND REACTIVITY
General Reactivity This material is stable.
Incompatibility (materials to Weak oxidizing agent. May react with metals to liberate minor amounts of
avoid) hydrogen. May react with chlorides to form chromyl chloride. May ignite
combustible solids if spilled on such materials and allowed to dry.
Hazardous Decomposition Acid vapors and chromium trioxide may be evolved at high temperature.
Products
Hazardous Polymerization Will Not Occur
11. TOXICOLOGICAL INFORMATION
For questions concerning toxicological information, write to: Medical Director, Brush Wellman Inc., 14710 West
Portage River South Road, Elmore, Ohio 43416-9502.
12. ECOLOGICAL INFORMATION
This material can be recycled; contact your Sales Representative.
Page 6 of 9
Berylcoat D MSDS No. M05 January 27, 2005
13. DISPOSAL CONSIDERATIONS
13.1 BYPRODUCT RECYCLING
When recycled (used in a process to recover metals), this material is not classified as hazardous waste under
federal law. Seal particulate or particulate containing materials inside two plastic bags, place in a DOT
approved container, and label appropriately.
13.2 SOLID WASTE MANAGEMENT
Spent Berylcoat D is a corrosive and toxic hazardous waste D002 and D007 under the Resource Conservation
and Recovery Act (RCRA) and should be disposed of at an approved hazardous waste facility.
14. TRANSPORT INFORMATION
The following requirements of the U.S. Department of Transportation apply to these products.
SHIPPING NAME: Corrosive Liquid, Acidic Inorganic, N.O.S. (Solution of
Potassium Dichromate and Phosphoric Acid)
HAZARD CLASS: 8
IDENTIFICATION NUMBER: UN3264
PACKING GROUP II
LABEL(S) REQUIRED: CORROSIVE
REPORTABLE QUANTITY: Phosphoric Acid: 2,370 kg. (5,000 lbs.)
Potassium Dichromate, 4.54 kg (10 lbs.)
PLACARD Required when shipping 454 kg (1,000 lbs.) aggregate
gross weight.
EMERGENCY RESPONSE Emergency response must be provided on the shipping
document
Hazard Communication regulations of the U.S. Occupational Safety and Health Administration require this
product be labeled.
15. REGULATORY INFORMATION
15.1. UNITED STATES FEDERAL REGULATIONS
15.1.1 Occupational Safety and Health Administration (OSHA)
Air contaminants, 29 CFR 1910.1000
Hazard Communication Standard, 29 CFR 1910.1200
15.1.2 Environmental Protection Agency (EPA)
AMBIENT AIR EMISSIONS: Most process air emission sources will require an air permit from a local
and/or state air pollution control agency. The use of air cleaning equipment may be necessary to achieve the
permissible emission. Tempered makeup air should be provided to prevent excessive negative pressure in a
building. Direct recycling of cleaned process exhaust air is not recommended. Plant exhausts should be
located so as not to re-enter the plant through makeup air or other inlets. Regular maintenance and inspection
of air cleaning equipment and monitoring of operating parameters is recommended to ensure adequate
efficiency is maintained.
WASTEWATER: Wastewater regulations can vary considerably. Contact your local and state governments
to determine their requirements.
Page 7 of 9
Berylcoat D MSDS No. M05 January 27, 2005
TOXIC SUBSTANCES CONTROL ACT: Component(s) of this material is/are listed on the TSCA
Chemical Substance Inventory of Existing Chemical Substances
SARA TITLE III REPORTING REQUIREMENTS: On February 16, 1988 the U.S. Environmental
Protection Agency (EPA) issued a final rule that implements the requirements of the Superfund Amendments
and Reauthorization Act (SARA) Title III, Section 313 (53) Federal Register 4525. Title III is the portion of
SARA concerning emergency planning and community right-to-know issues. Section 313 covers annual
emission reporting on specific chemicals which are manufactured, processed or used at certain U.S. Industrial
facilities.
This Brush Wellman product contains Potassium Dichromate (chromium compounds) and Phosphoric Acid
(7664-38-2) which are reportable under the Section 313.
You may obtain additional information by calling the EPA SARA Title III Hotline at 1-800-535-0202 (or
703 412 9810).
15.2 STATE REGULATIONS
Phosphoric Acid
鈥? Is listed on the following state right to know lists: California, New Jersey, Florida, Pennsylvania,
Minnesota, Massachusetts.
鈥? California No Significant Risk Level: Not Listed.
Potassium Dichromate
鈥? Is listed on the following state right to know lists: California, New Jersey, Florida, Pennsylvania,
Minnesota, (listed as ** no name **), Minnesota, (listed as ** no name **), Massachusetts.
鈥? The following statement(s) is(are) made in order to comply with the California Safe Drinking Water
Act: WARNING: This product containsCHROMIC ACID, DIPOTASSIUM SALT, listed as ` **
undefined **', a chemical known to the state of California to cause cancer.
鈥? California No Significant Risk Level: None of the chemicals in this product are listed.
15.3 CANADA
Constituent DSL/NDSL WHMIS Classification Ingredient Disclosure List
Phosphoric Acid Yes/No E, D1A Yes
Potassium Dichromate Yes/No C, D2A, D1A, E Yes
Page 8 of 9
Berylcoat D MSDS No. M05 January 27, 2005
16. OTHER INFORMATION
Following is the label which accompanies this product during shipment.
M05
BerylCoat D
WARNING
CORROSIVE MATERIAL - DIRECT CONTACT OF LIQUID OR VAPOR TO SKIN OR EYES CAN
CAUSE CHEMICAL BURNS. CANCER HAZARD
READ THE MATERIAL SAFETY DATA SHEET (MSDS) ON FILE WITH YOUR EMPLOYER BEFORE
WORKING WITH THIS MATERIAL.
This product contains chromium.
鈥? If processing or recycling produces airborne vapors or mists, use exhaust ventilation or other controls designed
to prevent exposure to workers.
鈥? The Occupational Safety and Health Administration (OSHA) has set mandatory limits on occupational
exposures.
鈥? Sold for manufacturing purposes only. This product can be recycled; contact your sales representative.
The Occupational Safety and Health Administration requires employers to provide training in the proper use of this product.
For further information, please telephone or write to: Product Stewardship Department, Brush Wellman Inc., 17876
St. Clair Avenue, Cleveland, Ohio 44110, telephone: (800) 862-4118, www.brushwellman.com. For transportation
emergency call Chemtrec at (800) 424-9300.
M05
*Label may vary in size
*Label color (light purple edge with black lettering)
This MSDS has been revised following the guidelines outlined in the American National Standard for
Hazardous Industrial Chemicals -鈥淢aterial Safety Data Sheets - Preparation.鈥? Z400.1-1998
MSDS Status: Revised issuance date in Section 1
IMPORTANT: If you have any questions or require additional information regarding the materials
described in this Material Safety Data Sheet, please telephone or write to the Product Stewardship
Department at the location given on page 1. Additional product safety information, such as Safety
Facts, is available from your sales representative or at www.brushwellman.com.
Page 9 of 9
|