SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 05/MAY/2005
Date Updated: 17/MAY/2004
Version 1.5
According to 91/155/EEC
Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.
1 - Product and Company Information
Product Name PHENANTHRENE, 98%
Product Number P11409
Company Sigma-Aldrich Pty, Ltd
Unit 2, 14 Anella Avenue
Castle Hill NSW 1765
Australia
Technical Phone # +61 2 9841 0555
Fax +61 2 9841 0500
Emergency Phone # +61 2 9841 0566
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
PHENANTHRENE 85-01-8 201-581-5 None
Formula C14H10
Molecular Weight 178.23 AMU
Synonyms Coal tar pitch volatiles: phenanthrene (OSHA) *
Phenanthren (German) * Phenantrin * Ravatite
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Harmful if swallowed. Irritating to eyes, respiratory system and
skin. Very toxic to aquatic organisms.
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
5 - Fire Fighting Measures
EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear respirator, chemical safety goggles, rubber boots, and
heavy rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe dust. Avoid contact
with eyes, skin, and clothing. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Store in a cool dry
place. Handle and store under nitrogen.
SPECIAL REQUIREMENTS: Handle and store under inert gas.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Physical State: Solid
Property Value At Temperature or Pressure
pH N/A
BP/BP Range 340 掳C 760 mmHg
ALDRICH - P11409 www.sigma-aldrich.com Page 2
MP/MP Range 98 掳C
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
SG/Density 1.063 g/cm3
Partition Coefficient Log Kow: 4.57
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Stable: Stable.
Materials to Avoid: Oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
11 - Toxicological Information
RTECS NUMBER: SF7175000
ACUTE TOXICITY
LD50
Oral
Mouse
700 mg/kg
LD50
Intraperitoneal
Mouse
700 MG/KG
LD50
Intravenous
Mouse
56 MG/KG
SENSITIZATION
Sensitization: Causes photosensitivity. Exposure to light can
result in allergic reactions resulting in dermatologic lesions,
which can vary from sunburnlike responses to edematous,
vesiculated lesions, or bullae
ALDRICH - P11409 www.sigma-aldrich.com Page 3
SIGNS AND SYMPTOMS OF EXPOSURE
The chemical, physical, and toxicological properties of this
product have not been thoroughly investigated.
ROUTE OF EXPOSURE
Skin Contact: Causes skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes eye irritation.
Inhalation: Material is irritating to mucous membranes and upper
respiratory tract. May be harmful if inhaled.
Ingestion: Harmful if swallowed.
CHRONIC EXPOSURE - CARCINOGEN
Result: This product is or contains a component that is not
classifiable as to its carcinogenicity based on its IARC, ACGIH,
NTP, or EPA classification.
Mouse
Route of Application: Skin
Result: Tumorigenic:Neoplastic by RTECS criteria. Skin and
Appendages: Other: Tumors. Tumorigenic:Tumors at site or
application.
Mouse
Route of Application: Skin
Exposure Time: 10W
Result: Tumorigenic:Equivocal tumorigenic agent by RTECS
criteria. Skin and Appendages: Other: Tumors.
IARC CARCINOGEN LIST
Rating: Group 3
CHRONIC EXPOSURE - MUTAGEN
Human
100 UMOL/L
Cell Type: lymphocyte
Mutation in mammalian somatic cells.
Rat
10 MG/L
Cell Type: Embryo
Morphological transformation.
Rat
3 MMOL/L
Cell Type: liver
DNA damage
Mouse
5 MG/L
Cell Type: Embryo
Morphological transformation.
Hamster
5 MG/L
24H
Cell Type: fibroblast
DNA damage
Hamster
ALDRICH - P11409 www.sigma-aldrich.com Page 4
5 MG/L
Cell Type: kidney
DNA damage
Hamster
40 MG/L
27H
Cell Type: lung
Cytogenetic analysis
Hamster
900 MG/KG
Intraperitoneal
24H
Sister chromatid exchange
Hamster
10 UMOL/L
Cell Type: fibroblast
Sister chromatid exchange
ZNEG
Histidine reversion (Ames)
12 - Ecological Information
ELIMINATION
Elimination: 55 - 95 %
ECOTOXICOLOGICAL EFFECTS
Test Type: EC50 Daphnia
Species: Daphnia magna
Time: 24 h
Value: 0.86 mg/l
Test Type: EC50 Daphnia
Species: Daphnia magna
Time: 48 h
Value: 0.38 mg/l
Test Type: LC50 Fish
Species: Onchorhynchus mykiss (Rainbow trout)
Time: 96 h
Value: 3.2 mg/l
Test Type: EC50 Algae
Species: Chlorella vulgaris
Time: 3 h
Value: 1.2 mg/l
Test Type: LC100 Fish
Species: other fish
Time: 1 h
Value: 1.5 mg/l
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
ALDRICH - P11409 www.sigma-aldrich.com Page 5
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.
14 - Transport Information
RID/ADR
UN#: 3077
Class: 9
PG: III
Proper Shipping Name: Environmentally hazardous
substance, solid, n.o.s
IMDG
UN#: 3077
Class: 9
PG: III
Proper Shipping Name: Environmentally hazardous
substance, solid, n.o.s
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
IATA
UN#: 3077
Class: 9
PG: III
Proper Shipping Name: Environmentally hazardous
substance, solid, n.o.s
Inhalation Packing Group I: No
Technical Name: Required
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: Xn N
Harmful. Dangerous for the environment.
R-PHRASES: 22 36/37/38 50
Harmful if swallowed. Irritating to eyes, respiratory system
and skin. Very toxic to aquatic organisms.
S-PHRASES: 26 60 61
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice. This material and its container
must be disposed of as hazardous waste. Avoid release to the
environment. Refer to special instructions/safety data sheets.
SWITZERLAND
SWISS POISON CLASS: 4
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
ALDRICH - P11409 www.sigma-aldrich.com Page 6
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
ALDRICH - P11409 www.sigma-aldrich.com Page 7
|