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MSDS Material Safety Data Sheet
CAS

68987-90-6
7732-18-5
75-21-8
123-91-1

File Name: 68987-90-6.asp

                              SIGMA-ALDRICH

Material Safety Data Sheet

Date Printed: 07/JUN/2005
Date Updated: 14/APR/2005
Version 1.5
According to 91/155/EEC


1 - Product and Company Information

Product Name IGEPAL CA-630 MOLECULAR BIOLOGY GRADE
Product Number I8896

Company Sigma-Aldrich Pty. Ltd.
12 Anella Avenue
Castle Hill NSW 2154
Australia
Technical Phone # +61 2 9841 0555 (1800 800 097)
Fax +61 2 9841 0500 (1800 800 096)
Emergency Phone # +44 8701906777 (1800 448 465)

2 - Composition/Information on Ingredients

Product Name CAS # EC no Annex I
Index Number
IGEPAL CA-* 68987-90-6 None None

Ingredient Name Percent CAS # EC no Annex I
Index Number
WATER < 0.5 7732-18-5 231-791-2 None

ETHYLENE OXIDE < 0.0025 75-21-8 200-849-9 603-023-00-X
Carc. Cat.2 Muta. Cat.2
Symbols: F+ T
R-Phrases: 45 46 12 23 36/37/38
May cause cancer. May cause heritable genetic damage. Extremely
flammable. Also toxic by inhalation. Irritating to eyes,
respiratory system and skin.

1,4-DIOXANE < 0.002 123-91-1 204-661-8 603-024-00-5
Carc. Cat.3
Symbols: F Xn
R-Phrases: 11 19 36/37 40 66
Highly flammable. May form explosive peroxides. Irritating to eyes
and respiratory system. Limited evidence of a carcinogenic effect.
Repeated exposure may cause skin dryness or cracking.

Formula (C2H4O)n路C14H22O
Synonyms octylphenoxy poly(ethyleneoxy)ethanol, branched
* ethoxylated octylphenol, branched *
Poly(oxy-1,2-ethanediyl), alpha-(octylphenyl)-
omega -hydroxy-, branched *
Polyoxyethylene(*)octylphenyl ether, branched

3 - Hazards Identification


SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Not hazardous according to Directive 67/548/EEC.
4 - First Aid Measures

AFTER INHALATION
If inhaled, remove to fresh air. If breathing becomes difficult,
call a physician.

AFTER SKIN CONTACT
In case of contact, immediately wash skin with soap and copious
amounts of water.

AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.

AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.

5 - Fire Fighting Measures

EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam. Foam and water spray are effective but may cause frothing.

SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.

6 - Accidental Release Measures

METHODS FOR CLEANING UP
Absorb on sand or vermiculite and place in closed containers for
disposal. Ventilate area and wash spill site after material
pickup is complete.

7 - Handling and Storage

HANDLING
Directions for Safe Handling: Avoid inhalation. Avoid contact
with eyes, skin, and clothing. Avoid prolonged or repeated
exposure.

STORAGE
Conditions of Storage: Keep tightly closed.

8 - Exposure Controls / Personal Protection

ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.

GENERAL HYGIENE MEASURES
Wash thoroughly after handling.

PERSONAL PROTECTIVE EQUIPMENT
Hand Protection: Protective gloves.
Eye Protection: Chemical safety goggles.

9 - Physical and Chemical Properties


SIGMA - I8896 www.sigma-aldrich.com Page 2
Appearance Physical State: Clear liquid
Color: Faintly yellow
Form: Viscous

Property Value At Temperature or Pressure

pH 6-8 Concentration: 100 g/l
BP/BP Range > 200 掳C 760 mmHg
MP/MP Range N/A
Flash Point > 93 掳C Method: closed cup
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure < 0.01 mmHg 25 掳C
SG/Density 1.04 g/cm3 25 掳C
Partition Coefficient N/A
Viscosity 0.008 - 0.01 Pas 100 掳C
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility Solubility in Water:Miscible.

10 - Stability and Reactivity

STABILITY
Stable: Stable.
Conditions to Avoid: Heat. open flame spark
Materials to Avoid: Strong oxidizing agents, Strong reducing
agents.

HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide.

HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur

11 - Toxicological Information

ACUTE TOXICITY
LD50
Oral
Rat
3,800 mg/kg

SIGNS AND SYMPTOMS OF EXPOSURE
Diarrhea. Nausea.

ROUTE OF EXPOSURE
Skin Contact: May cause skin irritation.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: May cause eye irritation.
Inhalation: May be harmful if inhaled. Material may be


SIGMA - I8896 www.sigma-aldrich.com Page 3
irritating to mucous membranes and upper respiratory tract.
Ingestion: May be harmful if swallowed.

12 - Ecological Information

No data available.

13 - Disposal Considerations

SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.

14 - Transport Information

RID/ADR
Non-hazardous for road transport.

IMDG
Non-hazardous for sea transport.

IATA
Non-hazardous for air transport.

15 - Regulatory Information

Not hazardous according to Directive 67/548/EEC.

COUNTRY SPECIFIC INFORMATION

Germany
WGK: 1

SWITZERLAND
SWISS POISON CLASS: 4

16 - Other Information

WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.

DISCLAIMER
For R&D use only. Not for drug, household or other uses.




SIGMA - I8896 www.sigma-aldrich.com Page 4

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