SIGMA-ALDRICH



                         Material Safety Data Sheet



                                                 Date Printed: 09/FEB/2005

                                                 Date Updated: 13/MAR/2004

                                                               Version 1.1

                                                   According to 91/155/EEC



Classified as Hazardous according to the criteria of EU Annex 1 and

NOHSC.



1 - Product and Company Information



Product Name                   BORDEAUX R (C.I. 16180)

Product Number                 209627



Company                        Sigma-Aldrich Pty, Ltd

                               Unit 2, 14 Anella Avenue

                               Castle Hill NSW 1765

                               Australia

Technical Phone #              +61 2 9841 0555

Fax                            +61 2 9841 0500

Emergency Phone #              +61 2 9841 0566



2 - Composition/Information on Ingredients



Product Name                         CAS #        EC no       Annex I

                                                              Index Number

BORDEAUX R (C.I. 16180)              5858-33-3    227-489-5   None



Formula             C20H14N2O7S2.2Na

Molecular Weight    502.44 AMU

Synonyms            Acid Bordeaux * Acid Bordeaux A * Acid Bordeaux

                    B * Acid Bordeaux BN * Acid Bordeaux MB * Acid

                    Red 17 * Acilan Bordeaux B * Amacid Lake

                    Bordeaux BL * Azo Bordeaux * Azo Bordeaux SS *

                    Bordeaux B * Bordeaux R * Bordeaux Red *

                    Bordeaux Red B * Bordeaux R type 8019 for foods

                    * Brasilan Azo Bordeaux * Brilliant Bordeaux B *

                    Brilliant Bordeaux 2B * Brilliant Bordeaux 4B *

                    Calcolake Bordeaux BXL * C.I. 16180 * C.I. Acid

                    Red 17 * C.I. Acid Red 17, disodium salt (8CI) *

                    Colacid Bordeaux A * Eniacid Bordeaux BN *

                    Hidacid Bordeaux B * Hispacid Bordeaux F * Java

                    Bordeaux B * Kiton Bordeaux G * Lithosol Claret

                    B * Naphthalene Bordeaux B * Naphthalene

                    Bordeaux BS * Naphthalene Lake Bordeaux B *

                    Naphthalene Leather Bordeaux B * Rouge Bordeaux

                    B * Tertracid Bordeaux B



3 - Hazards Identification



SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT

   Irritating to eyes, respiratory system and skin.





4 - First Aid Measures



AFTER INHALATION

   If inhaled, remove to fresh air. If not breathing give

   artificial respiration. If breathing is difficult, give oxygen.

AFTER SKIN CONTACT

   In case of contact, immediately wash skin with soap and copious

   amounts of water.



AFTER EYE CONTACT

   In case of contact, immediately flush eyes with copious amounts

   of water for at least 15 minutes.



AFTER INGESTION

   If swallowed, wash out mouth with water provided person is

   conscious. Call a physician.



5 - Fire Fighting Measures



EXTINGUISHING MEDIA

   Suitable: Water spray. Carbon dioxide, dry chemical powder, or

   appropriate foam.



SPECIAL RISKS

   Specific Hazard(s): Emits toxic fumes under fire conditions.



SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS

   Wear self-contained breathing apparatus and protective clothing

   to prevent contact with skin and eyes.



6 - Accidental Release Measures



PROCEDURE(S) OF PERSONAL PRECAUTION(S)

   Wear respirator, chemical safety goggles, rubber boots, and

   heavy rubber gloves.



METHODS FOR CLEANING UP

   Sweep up, place in a bag and hold for waste disposal. Avoid

   raising dust. Ventilate area and wash spill site after material

   pickup is complete.



7 - Handling and Storage



HANDLING

   Directions for Safe Handling: Do not breathe dust. Avoid contact

   with eyes, skin, and clothing.



STORAGE

   Conditions of Storage: Keep tightly closed. Store in a cool dry

   place.



SPECIAL REQUIREMENTS: Light sensitive.



8 - Exposure Controls / Personal Protection



ENGINEERING CONTROLS

   Safety shower and eye bath. Mechanical exhaust required.



GENERAL HYGIENE MEASURES

   Wash thoroughly after handling. Wash contaminated clothing before

   reuse.



PERSONAL PROTECTIVE EQUIPMENT

   Respiratory Protection: Government approved respirator.

   Hand Protection: Compatible chemical-resistant gloves.

   Eye Protection: Chemical safety goggles.





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9 - Physical and Chemical Properties



Appearance                N/A



Property                  Value                At Temperature or Pressure



pH                        N/A

BP/BP Range               N/A

MP/MP Range               N/A

Flash Point               N/A

Flammability              N/A

Autoignition Temp         N/A

Oxidizing Properties      N/A

Explosive Properties      N/A

Explosion Limits          N/A

Vapor Pressure            N/A

SG/Density                N/A

Partition Coefficient     N/A

Viscosity                 N/A

Vapor Density             N/A

Saturated Vapor Conc.     N/A

Evaporation Rate          N/A

Bulk Density              N/A

Decomposition Temp.       N/A

Solvent Content           N/A

Water Content             N/A

Surface Tension           N/A

Conductivity              N/A

Miscellaneous Data        N/A

Solubility                N/A



10 - Stability and Reactivity



STABILITY

   Conditions of Instability: Light.

   Materials to Avoid: Strong oxidizing agents.



HAZARDOUS DECOMPOSITION PRODUCTS

   Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,

   Nitrogen oxides, Sulfur oxides.



11 - Toxicological Information



RTECS NUMBER: QJ6479500



SIGNS AND SYMPTOMS OF EXPOSURE

   To the best of our knowledge, the chemical, physical, and

   toxicological properties have not been thoroughly investigated.



ROUTE OF EXPOSURE

   Inhalation: Material is irritating to mucous membranes and upper

   respiratory tract.

   Multiple Routes: May be harmful by inhalation, ingestion, or

   skin absorption. Causes eye and skin irritation.



12 - Ecological Information



No data available.



13 - Disposal Considerations







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SUBSTANCE DISPOSAL

   Dissolve or mix the material with a combustible solvent and burn

   in a chemical incinerator equipped with an afterburner and

   scrubber. Observe all federal, state, and local environmental

   regulations.



14 - Transport Information



RID/ADR

   Non-hazardous for road transport.



IMDG

   Non-hazardous for sea transport.



IATA

   Non-hazardous for air transport.



15 - Regulatory Information



CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES

   INDICATION OF DANGER: Xi

     Irritant.

   R-PHRASES: 36/37/38

     Irritating to eyes, respiratory system and skin.

   S-PHRASES: 26 36

     In case of contact with eyes, rinse immediately with plenty of

     water and seek medical advice. Wear suitable protective

     clothing.



16 - Other Information



WARRANTY

   The above information is believed to be correct but does not

   purport to be all inclusive and shall be used only as a guide. The

   information in this document is based on the present state of our

   knowledge and is applicable to the product with regard to

   appropriate safety precautions. It does not represent any

   guarantee of the properties of the product. Sigma-Aldrich Inc.,

   shall not be held liable for any damage resulting from handling or

   from contact with the above product. See reverse side of invoice

   or packing slip for additional terms and conditions of sale.

   Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited

   paper copies for internal use only.



DISCLAIMER

   For R&D use only. Not for drug, household or other uses.









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