Material Safety Data Sheet
The Dow Chemical Company
Product Name: Developer DS3000 Issue Date: 02/07/2008
Print Date: 27 Mar 2008
The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS,
as there is important information throughout the document. We expect you to follow the precautions
identified in this document unless your use conditions would necessitate other appropriate methods or
actions.
1. Product and Company Identification
Product Name
Developer DS3000
COMPANY IDENTIFICATION
The Dow Chemical Company
2030 Willard H. Dow Center
Midland, MI 48674
USA
Customer Information Number: 800-258-2436
EMERGENCY TELEPHONE NUMBER
989-636-4400
24-Hour Emergency Contact:
989-636-4400
Local Emergency Contact:
2. Hazards Identification
Emergency Overview
Color: Colorless
Physical State: Liquid
Odor: Aromatic
Hazards of product:
CAUTION! Combustible liquid and vapor. Harmful if absorbed through skin. May
cause eye irritation. May cause skin irritation. May be harmful if inhaled. May cause
central nervous system effects. Aspiration hazard. Can enter lungs and cause
damage. Keep upwind of spill. Isolate area. Stay out of low areas.
OSHA Hazard Communication Standard
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29
CFR 1910.1200.
Potential Health Effects
Eye Contact: May cause slight eye irritation. May cause slight temporary corneal injury. Vapor or
mist may cause eye irritation.
?TM)*Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow
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Product Name: Developer DS3000 Issue Date: 02/07/2008
Skin Contact: Prolonged contact may cause skin irritation with local redness. Repeated contact may
cause skin burns. Symptoms may include pain, severe local redness, swelling, and tissue damage.
Skin Absorption: Prolonged or widespread skin contact may result in absorption of harmful amounts.
Signs and symptoms of excessive exposure may include: Lethargy.
Inhalation: Prolonged excessive exposure may cause adverse effects. May cause central nervous
system effects. Symptoms may include headache, dizziness and drowsiness, progressing to
incoordination and unconsciousness.
Ingestion: Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may cause
injury. Aspiration into the lungs may occur during ingestion or vomiting, causing lung damage or even
death due to chemical pneumonia.
Composition Information
3.
Component CAS # Amount
1,3,5-Triisopropylbenzene 717-74-8 >= 95.0 %
1,2,4-Triisopropylbenzene 948-32-3 <= 4.1 %
1H-Indene, 2,3-Dihydro-1,1,3-trimethyl-5-(1-methylethyl)- 74057-44-6 <= 2.0 %
1H-Indene, 1,1,3-Trimethyl-5-(1-methylethyl)- 30839-52-2 <= 2.0 %
1-Ethyl-3,5-diiospropylbenzene 15181-13-2 <= 1.1 %
4. First-aid measures
Eye Contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing. Seek medical attention if symptoms occur or irritation persists. Wash clothing
before reuse. Discard items which cannot be decontaminated, including leather articles such as
shoes, belts and watchbands.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility. Remove to fresh air if effects
occur. Call a poison control center or doctor for treatment advice. If the person is not breathing and
has no pulse, consider cardiopulmonary resuscitation (CPR); use pocket resuscitation mask, bag valve
mask etc., to avoid risk of poisoning rescuer. If breathing is difficult, oxygen should be administered by
qualified personnel.
Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility immediately.
Notes to Physician: If lavage is performed, suggest endotracheal and/or esophageal control. Danger
from lung aspiration must be weighed against toxicity when considering emptying the stomach. The
decision of whether to induce vomiting or not should be made by a physician. Maintain adequate
ventilation and oxygenation of the patient. If burn is present, treat as any thermal burn, after
decontamination. No specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.
5. Fire Fighting Measures
Extinguishing Media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire
extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose synthetic
foams (including AFFF) or protein foams may function, but will be less effective.
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Do not use
direct water stream. May spread fire. Burning liquids may be moved by flushing with water to protect
personnel and minimize property damage. Avoid accumulation of water. Product may be carried
across water surface spreading fire or contacting an ignition source. Contain fire water run-off if
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Product Name: Developer DS3000 Issue Date: 02/07/2008
possible. Fire water run-off, if not contained, may cause environmental damage. Review the
"Accidental Release Measures" and the "Ecological Information" sections of this (M)SDS.
Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire
from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer to
the relevant sections.
Unusual Fire and Explosion Hazards: Violent steam generation or eruption may occur upon
application of direct water stream to hot liquids. Dense smoke is produced when product burns.
Hazardous Combustion Products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Carbon monoxide. Carbon dioxide.
6. Accidental Release Measures
Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible. Absorb
with materials such as: Sand. Sawdust. Collect in suitable and properly labeled containers. See
Section 13, Disposal Considerations, for additional information.
Personal Precautions: Isolate area. Keep unnecessary and unprotected personnel from entering the
area. Keep upwind of spill. Keep personnel out of low areas. Ventilate area of leak or spill. No
smoking in area. Refer to Section 7, Handling, for additional precautionary measures. Use
appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and
Personal Protection.
Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information. Material will float on water.
7. Handling and Storage
Handling
General Handling: Do not swallow. Avoid contact with eyes, skin, and clothing. Avoid breathing
vapor. Use with adequate ventilation. Keep container closed. Wash thoroughly after handling.
Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or
perform similar operations on or near empty containers.
Storage
Keep container closed. Store in a dry place.
8. Exposure Controls / Personal Protection
Exposure Limits
None established
Personal Protection
Eye/Face Protection: Use safety glasses. If exposure causes eye discomfort, use a full-face
respirator.
Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task. Safety shower should
be located in immediate work area. Remove contaminated clothing immediately, wash skin area with
soap and water, and launder clothing before reuse or dispose of properly. Items which cannot be
decontaminated, such as shoes, belts and watchbands, should be removed and disposed of properly.
Hand protection: Use gloves chemically resistant to this material. Examples of preferred
glove barrier materials include: Polyethylene. Ethyl vinyl alcohol laminate ("EVAL"). Polyvinyl
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Product Name: Developer DS3000 Issue Date: 02/07/2008
alcohol ("PVA"). Polyvinyl chloride ("PVC" or "vinyl"). Styrene/butadiene rubber. Viton.
Examples of acceptable glove barrier materials include: Butyl rubber. Chlorinated
polyethylene. Natural rubber ("latex"). Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR").
NOTICE: The selection of a specific glove for a particular application and duration of use in a
workplace should also take into account all relevant workplace factors such as, but not limited
to: Other chemicals which may be handled, physical requirements (cut/puncture protection,
dexterity, thermal protection), potential body reactions to glove materials, as well as the
instructions/specifications provided by the glove supplier.
Respiratory Protection: Respiratory protection should be worn when there is a potential to exceed
the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements
or guidelines, use an approved respirator. Selection of air-purifying or positive-pressure supplied-air
will depend on the specific operation and the potential airborne concentration of the material. For
emergency conditions, use an approved positive-pressure self-contained breathing apparatus. The
following should be effective types of air-purifying respirators: Organic vapor cartridge with a
particulate pre-filter.
Ingestion: Avoid ingestion of even very small amounts; do not consume or store food or tobacco in
the work area; wash hands and face before smoking or eating.
Engineering Controls
Ventilation: Use engineering controls to maintain airborne level below exposure limit requirements or
guidelines. If there are no applicable exposure limit requirements or guidelines, use only with
adequate ventilation. Local exhaust ventilation may be necessary for some operations.
9. Physical and Chemical Properties
Liquid
Physical State
Colorless
Color
Aromatic
Odor
86.7 癈 (188.1 癋) Tag Closed Cup ASTM D56
Flash Point - Closed Cup
Lower: No test data available
Flammable Limits In Air
Upper: No test data available
402 癈 (756 癋) Literature
Autoignition Temperature
< 5 mmHg @ 20 癈 Literature
Vapor Pressure
234 癈 (453 癋) Estimated .
Boiling Point (760 mmHg)
7 Literature
Vapor Density (air = 1)
0.858 Literature
Specific Gravity (H2O = 1)
-11.1 癈 (12.0 癋) Literature
Freezing Point
Not applicable
Melting Point
Negligible
Solubility in Water (by
weight)
essentially neutral
pH
204 g/mol Calculated
Molecular Weight
3 cSt @ 38 癈 Estimated
Kinematic Viscosity
10. Stability and Reactivity
Stability/Instability
Thermally stable at typical use temperatures.
Conditions to Avoid: Exposure to elevated temperatures can cause product to decompose.
Incompatible Materials: Avoid contact with oxidizing materials.
Hazardous Polymerization
Will not occur.
Thermal Decomposition
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Product Name: Developer DS3000 Issue Date: 02/07/2008
Decomposition products depend upon temperature, air supply and the presence of other materials.
11. Toxicological Information
Acute Toxicity
Ingestion
For the major component(s): LD50, Rat, male > 2,000 mg/kg
Skin Absorption
For the major component(s): LD50, Rabbit 500 - 1,000 mg/kg
12. Ecological Information
CHEMICAL FATE
Data for Component: 1,3,5-Triisopropylbenzene
Movement & Partitioning
Bioconcentration potential is high (BCF > 3000 or Log Pow between 5 and 7). Expected to be
relatively immobile in soil (Koc > 5000).
Henry's Law Constant (H): 6.43E-2 atm*m3/mole; 25 癈 Estimated
Partition coefficient, n-octanol/water (log Pow): 6.36 Estimated
Partition coefficient, soil organic carbon/water (Koc): 20.00 Estimated
Persistence and Degradability
Indirect Photodegradation with OH Radicals
Rate Constant Atmospheric Half-life Method
3.29E-11 cm3/s 3.906 h
ECOTOXICITY
Data for Component: 1,3,5-Triisopropylbenzene
No relevant information found.
13. Disposal Considerations
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All
disposal practices must be in compliance with all Federal, State/Provincial and local laws and
regulations. Regulations may vary in different locations. Waste characterizations and compliance with
applicable laws are the responsibility solely of the waste generator. DOW HAS NO CONTROL OVER
THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING
OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE
PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION:
Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options
include sending to a licensed, permitted: Incinerator or other thermal destruction device. As a service
to its customers, Dow can provide names of information resources to help identify waste management
companies and other facilities which recycle, reprocess or manage chemicals or plastics, and that
manage used drums. Telephone Dow's Customer Information Group at 1-800-258-2436 or 1-989-
832-1556 (U.S.), or 1-800-331-6451 (Canada) for further details. Do not dump into any sewers, on the
ground, or into any body of water.
Treatment and disposal methods of used packaging: Do not dump into any sewers, on the ground,
or into any body of water.
Page 5 of 7
Product Name: Developer DS3000 Issue Date: 02/07/2008
14. Transport Information
DOT Non-Bulk
Proper Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Technical Name: 1,3,5-TRIISOPROPYL BENZENE
Hazard Class: 6.1 ID Number: UN2810 Packing Group: PG III
DOT Bulk
Proper Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Technical Name: 1,3,5-TRIISOPROPYL BENZENE
Hazard Class: 6.1 ID Number: UN2810 Packing Group: PG III
IMDG
Proper Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Technical Name: 1,3,5-TRIISOPROPYL BENZENE
Hazard Class: 6.1 ID Number: UN2810 Packing Group: PG III
EMS Number: F-A,S-A
ICAO/IATA
Proper Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Technical Name: 1,3,5-TRIISOPROPYL BENZENE
Hazard Class: 6.1 ID Number: UN2810 Packing Group: PG III
Cargo Packing Instruction: 618
Passenger Packing Instruction: 611
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Additional transportation system information can be
obtained through an authorized sales or customer service representative. It is the responsibility of the
transporting organization to follow all applicable laws, regulations and rules relating to the
transportation of the material.
15. Regulatory Information
OSHA Hazard Communication Standard
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29
CFR 1910.1200.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning
and Community Right-to-Know Act of 1986) Sections 311 and 312
Yes
Immediate (Acute) Health Hazard
No
Delayed (Chronic) Health Hazard
Yes
Fire Hazard
No
Reactive Hazard
No
Sudden Release of Pressure Hazard
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Hazardous
Substances List and/or Pennsylvania Environmental Hazardous Substance List:
To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.
Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Special Hazardous
Substances List:
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Product Name: Developer DS3000 Issue Date: 02/07/2008
To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer, birth
defects or other reproductive harm, at levels which would require a warning under the statute.
US. Toxic Substances Control Act
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements under 40 CFR 720.30
CEPA - Domestic Substances List (DSL)
This product contains one or more substances which are not listed on the Canadian Domestic
Substances List (DSL). Contact your Dow representative for more information.
16. Other Information
Recommended Uses and Restrictions
Developer solvent in photolithographic processes. Dow recommends that you use this product in a
manner consistent with the listed use. If your intended use is not consistent with Dow's stated use,
please contact Dow's Customer Information Group.
Revision
Identification Number: 50839 / 1001 / Issue Date 02/07/2008 / Version: 2.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
N/A Not available
W/W Weight/Weight
OEL Occupational Exposure Limit
STEL Short Term Exposure Limit
TWA Time Weighted Average
ACGIH American Conference of Governmental Industrial Hygienists, Inc.
DOW IHG Dow Industrial Hygiene Guideline
WEEL Workplace Environmental Exposure Level
HAZ_DES Hazard Designation
Action Level A value set by OSHA that is lower than the PEL which will trigger the need for
activities such as exposure monitoring and medical surveillance if exceeded.
The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and
consult appropriate expertise, as necessary or appropriate, to become aware of and understand the
data contained in this (M)SDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above. However, no
warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with
all federal, state, provincial or local laws. The information presented here pertains only to the product
as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is
the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to
the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and
cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have
obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current,
please contact us for the most current version.
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