Material Safety Data Sheet
24-Hour Emergency Telephone Numbers
HEALTH : Chevron Emergency Information Center (800) 231-0623 or (510) 231-0623
TRANSPORTATION : CHEMTREC (800) 424-9300 or (703) 527-3887
Emergency Information Centers are located in the U.S.A. International collect calls accepted.
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
TEXACO Havoline DEX-COOL Extended Life Anti-Freeze/Coolant
Product Number(s): CPS227994
Company Identification Product Information
ChevronTexaco Global Lubricants Product Information: 800-LUBE-TEK
6001 Bollinger Canyon Road email : lubemsds@chevron.com
San Ramon, CA 94583
SECTION 2 COMPOSITION/ INFORMATION ON INGREDIENTS
COMPONENTS CAS NUMBER AMOUNT
Ethylene Glycol 107-21-1 80 - 96.99 %weight
Diethylene glycol 111-46-6 1 - 4.99 %weight
Potassium 2-ethylhexanoate 3164-85-0 1 - 4.99 %weight
Water 7732-18-5 1 - 2.99 %weight
SECTION 3 HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW
Orange liquid. Mild odor.
- HARMFUL OR FATAL IF SWALLOWED
- CAUSES EYE IRRITATION
- MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS BASED ON ANIMAL DATA
- POSSIBLE BIRTH DEFECT HAZARD - CONTAINS MATERIAL THAT MAY CAUSE BIRTH DEFECTS
BASED ON ANIMAL DATA
- MAY CAUSE DAMAGE TO:
- KIDNEY
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IMMEDIATE HEALTH EFFECTS
Eye: Contact with the eyes causes irritation. Symptoms may include pain, tearing, reddening, swelling
and impaired vision.
Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Not expected to be
harmful to internal organs if absorbed through the skin.
Ingestion: Toxic; may be harmful or fatal if swallowed.
Inhalation: The vapor or fumes from this material may cause respiratory irritation. Symptoms of
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respiratory irritation may include coughing and difficulty breathing.
DELAYED OR OTHER HEALTH EFFECTS:
Reproduction and Birth Defects: May cause adverse reproductive effects based on animal data.
Contains material that may be harmful to the developing fetus based on animal data.
Target Organs: Repeated ingestion of this material may cause damage to the following organ(s) based
on animal data. Kidney
See Section 11 for additional information. Risk depends on duration and level of exposure.
SECTION 4 FIRST AID MEASURES
Eye: Flush eyes with water immediately while holding the eyelids open. Remove contact lenses, if worn,
after initial flushing, and continue flushing for at least 15 minutes. Get medical attention if irritation
persists.
Skin: To remove the material from skin, use soap and water. Discard contaminated clothing and shoes
or thoroughly clean before reuse.
Ingestion: If swallowed, get immediate medical attention. Do not induce vomiting. Never give anything
by mouth to an unconscious person.
Inhalation: Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing
is difficult, give oxygen. Get medical attention if breathing difficulties continue.
SECTION 5 FIRE FIGHTING MEASURES
FIRE CLASSIFICATION:
OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible.
NFPA RATINGS: Health: 2 Flammability: 1 Reactivity: 0
FLAMMABLE PROPERTIES:
Flashpoint: (Pensky-Martens Closed Cup) 260 癋 (127 癈)
Autoignition: 752 癋 (400 癈)
Flammability (Explosive) Limits (% by volume in air): Lower: 3.2 Upper:
EXTINGUISHING MEDIA: Dry Chemical, CO2, AFFF Foam or alcohol resistant foam.
PROTECTION OF FIRE FIGHTERS:
Fire Fighting Instructions: This material will burn although it is not easily ignited. For fires involving this
material, do not enter any enclosed or confined fire space without proper protective equipment, including
self-contained breathing apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne
solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic
compounds will be evolved when this material undergoes combustion. Combustion may form oxides of:
Potassium .
SECTION 6 ACCIDENTAL RELEASE MEASURES
Protective Measures: Eliminate all sources of ignition in vicinity of spilled material.
Spill Management: Stop the source of the release if you can do it without risk. Contain release to
prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible,
observing precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as
applying non-combustible absorbent materials or pumping. Where feasible and appropriate, remove
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contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner
consistent with applicable regulations.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at
(800) 424-8802 as appropriate or required.
SECTION 7 HANDLING AND STORAGE
Precautionary Measures: Wash thoroughly after handling. Do not get in eyes. Do not breathe vapor or
fumes.
General Handling Information: Do not taste or swallow antifreeze or solution. Keep out of the reach of
children and animals.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling
this material. To minimize this hazard, bonding and grounding may be necessary but may not, by
themselves, be sufficient. Review all operations which have the potential of generating an accumulation
of electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling,
tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations)
and use appropriate mitigating procedures. For more information, refer to OSHA Standard 29 CFR
1910.106, 'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77,
'Recommended Practice on Static Electricity', and/or the American Petroleum Institute (API)
Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray
Currents'.
General Storage Information: Do not store in open or unlabeled containers.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,
and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode
and cause injury or death. Empty containers should be completely drained, properly closed, and promptly
returned to a drum reconditioner or disposed of properly.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities,
and other substances in the work place when designing engineering controls and selecting personal
protective equipment. If engineering controls or work practices are not adequate to prevent exposure to
harmful levels of this material, the personal protective equipment listed below is recommended. The user
should read and understand all instructions and limitations supplied with the equipment since protection is
usually provided for a limited time or under certain circumstances.
ENGINEERING CONTROLS:
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below the recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Eye/Face Protection: Wear eye protection such as safety glasses, chemical goggles, or faceshields if
engineering controls or work practices are not adequate to prevent eye contact.
Skin Protection: No special protective clothing is normally required. Where splashing is possible, select
protective clothing depending on operations conducted, physical requirements and other substances.
Suggested materials for protective gloves include: Natural rubber, Neoprene, Nitrile Rubber, Polyvinyl
Chloride (PVC or Vinyl).
Respiratory Protection: Determine if airborne concentrations are below the recommended exposure
limits. If not, wear an approved respirator that provides adequate protection from measured
concentrations of this material, such as: Air-Purifying Respirator for Organic Vapors, Dusts and Mists.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not
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provide adequate protection.
Occupational Exposure Limits:
Component Limit TWA STEL Ceiling Notation
Ethylene Glycol ACGIH_TLV 100 mg/m3
Ethylene Glycol OSHA_PEL 125 mg/m3
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor: Orange liquid. Mild odor.
pH: 8 - 8.6
Vapor Pressure: <0.01 mmHg @ 20 癈
Vapor Density (Air = 1): 2.1
Boiling Point: 228 癋 (109 C) (Typical)
Solubility: Miscible
Freezing Point: -34 癋 (-37 C)
Melting Point: NDA
Specific Gravity: 1.12 @ 15.6 癈 / 15.6 癈
Viscosity: 8 cSt @ 40 癈
SECTION 10 STABILITY AND REACTIVITY
Chemical Stability: This material is considered stable under normal ambient and anticipated storage
and handling conditions of temperature and pressure.
Incompatibility With Other Materials: May react with strong oxidizing agents, such as chlorates,
nitrates, peroxides, etc.
Hazardous Decomposition Products: Aldehydes (Elevated temperatures)
Hazardous Polymerization: Hazardous polymerization will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION
IMMEDIATE HEALTH EFFECTS
Eye Irritation: The eye irritation hazard is based on evaluation of data for similar materials or product
components.
Skin Irritation: The skin irritation hazard is based on evaluation of data for similar materials or product
components.
Skin Sensitization: No product toxicology data available.
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar
materials or product components.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials or
product components.
Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar
materials or product components.
ADDITIONAL TOXICOLOGY INFORMATION:
This product contains ethylene glycol (EG). The toxicity of EG via inhalation or skin contact is expected to
be slight at room temperature. The estimated oral lethal dose is about 100 cc (3.3 oz.) for an adult
human. Ethylene glycol is oxidized to oxalic acid which results in the deposition of calcium oxalate
crystals mainly in the brain and kidneys. Early signs and symptoms of EG poisoning may resemble those
of alcohol intoxication. Later, the victim may experience nausea, vomiting, weakness, abdominal and
muscle pain, difficulty in breathing and decreased urine output. When EG was heated above the boiling
point of water, vapors formed which reportedly caused unconsciousness, increased lymphocyte count,
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and a rapid, jerky movement of the eyes in persons chronically exposed. When EG was administered
orally to pregnant rats and mice, there was an increase in fetal deaths and birth defects. Some of these
effects occurred at doses that had no toxic effects on the mothers. We are not aware of any reports that
EG causes reproductive toxicity in human beings.
This product contains diethylene glycol (DEG). The estimated oral lethal dose is about 50 cc (1.6 oz) for
an adult human. DEG has caused the following effects in laboratory animals: liver abnormalities, kidney
damage and blood abnormalities. It has been suggested as a cause of the following effects in humans:
liver abnormalities, kidney damage, lung damage and central nervous system damage.
2-Ethylhexanoic acid (2-EXA) caused an increase in liver size and enzyme levels when repeatedly
administered to rats via the diet. When administered to pregnant rats by gavage or in drinking water, 2-
EXA caused teratogenicity (birth defects) and delayed postnatal development of the pups. Additionally, 2-
EXA impaired female fertility in rats. Birth defects were seen in the offspring of mice who were
administered sodium 2-ethylhexanoate via intraperitoneal injection during pregnancy.
SECTION 12 ECOLOGICAL INFORMATION
ECOTOXICITY
The toxicity of this material to aquatic organisms has not been evaluated. Consequently, this material
should be kept out of sewage and drainage systems and all bodies of water.
ENVIRONMENTAL FATE
This material is expected to be readily biodegradable.
SECTION 13 DISPOSAL CONSIDERATIONS
Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may
meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State
and local regulations. Measurement of certain physical properties and analysis for regulated components
may be necessary to make a correct determination. If this material is classified as a hazardous waste,
federal law requires disposal at a licensed hazardous waste disposal facility.
SECTION 14 TRANSPORT INFORMATION
The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate
Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and mode-
specific or quantity-specific shipping requirements.
DOT Shipping Name: NOT REGULATED AS A HAZARDOUS MATERIAL FOR TRANSPORTATION
UNDER 49 CFR
DOT Hazard Class: NOT APPLICABLE
DOT Identification Number: NOT APPLICABLE
DOT Packing Group: NOT APPLICABLE
SECTION 15 REGULATORY INFORMATION
SARA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: YES
2. Delayed (Chronic) Health Effects: YES
3. Fire Hazard: NO
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO
REGULATORY LISTS SEARCHED:
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4_I1=IARC Group 1 12=TSCA Section 8(a) PAIR 21=TSCA Section 5(a)
4_I2A=IARC Group 2A 13=TSCA Section 8(d) 25=CAA Section 112 HAPs
4_I2B=IARC Group 2B 15=SARA Section 313 26=CWA Section 311
05=NTP Carcinogen 16=CA Proposition 65 28=CWA Section 307
06=OSHA Carcinogen 17=MA RTK 30=RCRA Waste P-List
09=TSCA 12(b) 18=NJ RTK 31=RCRA Waste U-List
10=TSCA Section 4 19=DOT Marine Pollutant 32=RCRA Appendix VIII
11=TSCA Section 8(a) CAIR 20=PA RTK
The following components of this material are found on the regulatory lists indicated.
Diethylene glycol 25
Ethylene Glycol 15, 17, 18, 20, 25
CERCLA REPORTABLE QUANTITIES(RQ)/SARA 302 THRESHOLD PLANNING QUANTITIES(TPQ):
Component Component RQ Component TPQ Product RQ
Ethylene Glycol 5000 lbs None 5440 lbs
CHEMICAL INVENTORIES:
AUSTRALIA: All the components of this material are listed on the Australian Inventory of Chemical
Substances (AICS).
PEOPLE'S REPUBLIC OF CHINA: All the components of this product are listed on the draft Inventory of
Existing Chemical Substances in China.
EUROPEAN UNION: All the components of this material are in compliance with the EU Seventh
Amendment Directive 92/32/EEC.
KOREA: All the components of this product are on the Existing Chemicals List (ECL) in Korea.
PHILIPPINES: All the components of this product are listed on the Philippine Inventory of Chemicals and
Chemical Substances (PICCS).
UNITED STATES: All of the components of this material are on the Toxic Substances Control Act (TSCA)
Chemical Inventory.
NEW JERSEY RTK CLASSIFICATION:
Refer to components listed in Section 2.
WHMIS CLASSIFICATION:
Class D, Division 1, Subdivision B: Toxic Material -
Acute Lethality
Class D, Division 2, Subdivision A: Very Toxic Material -
Chronic Toxic Effects
Reproductive Toxicity
Teratogenicity and Embryotoxicity
Class D, Division 2, Subdivision B: Toxic Material -
Skin or Eye Irritation
SECTION 16 OTHER INFORMATION
NFPA RATINGS: Health: 2 Flammability: 1 Reactivity: 0
HMIS RATINGS: Health: 2* Flammability: 1 Reactivity: 0
(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index
recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or
published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint
and Coating Association (for HMIS ratings).
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REVISION STATEMENT: This revi sion updates Section 1 (Product Identification), Section 2
(Composition/Ingredient Information), Section 5 (Fire Fighting Measures), Section 11 (Toxicological
Information), and Section 15 (Regulatory Information).
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
CAS - Chemical Abstract Service Number
NDA - No Data Available NA - Not Applicable
<= - Less Than or Equal To >= - Greater Than or Equal To
Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI
MSDS Standard (Z400.1).
The above information is based on the data of which we are aware and is believed to be correct as of the
date hereof. Since this information may be applied under conditions beyond our control and with which
we may be unfamiliar and since data made available subsequent to the date hereof may suggest
modifications of the information, we do not assume any responsibility for the results of its use. This
information is furnished upon condition that the person receiving it shall make his own determination of
the suitability of the material for his particular purpose.
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Revision Number: 2 7 of 7 TEXACO Havoline DEX-COOL
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