MATERIAL SAFETY DATA SHEET
CHEMCO INDUSTRIES, INC.
5731 Manchester Ave., St. Louis, MO 63110
DATE OF ISSUE: January, 05, 2006
GENERAL INFORMATION # : 314-647-1888
EMERGENCY TELEPHONE # : (800) 854-4236
I-PRODUCT IDENTIFICATION
RESIDUAL ROACH SPRAY
PRODUCT CODE: #196
CHEMICAL FORMULATION: ROACH KILLER
NFPA HAZARD IDENTIFICATION SYSTEM: HEALTH: 2 FLAMMABILITY: 0 REACTIVITY: 0
HAZARD RATING: 4- Extreme; 3 - High; 2 - Moderate; 1 - Slight; 0 - Insignificant
II - HAZARDOUS INGREDIENTS
Hazardous Components (Specific Chemical Identity; Common Name (s)) Other Limits
CAS # OSHA PEL ACGIHTLV Recommended % optional
CHLORPYRIFOS 2921-88-2 .2mgm/m3 0.5
NOTICE: THIS PRODUCT MAY CONTAIN ONE OF THE LISTED SARA TITLE III SECTION 313 CHEMICALS
67-64-1 ACETONE 71-55-6 1,1,1-TRICHLOROETHANE 13463-67-7 TITANIUM DIOXIDE
500-00-0 FORMALDEHYDE 75-09-2 METHYLENE CHLORIDE 7664-38-2 PHOSPHORIC ACID
67-56-1 METHANOL 107-21-1 ETHYLENE GLYCOL* 7761-88-8 SILVER NITRITE
95-48-7 O-CRESOL 114-26-1 PROPOXUR 7664-93-9 SULFURIC ACID
94-75-7 2,4-D 108-88-3 TOLUENE 7440-66-6 ZINC (DUST)
72-43-5 METHOXYCHLOR 127-18-4 TETRACHLOROETHYLENE 7647-01-0 HYDROCHLORIC ACID
139-13-9 NITRILOTRIACETIC ACID 1330-20-7 XYLENE, MIXED ISOMERS
78-92-2 SEC-BUTYL ALCOHOL
*POSSIBLE GLYCOL ETHERS. 1310-73-2 SODIUM HYDROXIDE SOLUTION
Key: PEL: Permissible Exposure Limit TLV: Threshold Limit Value C: Ceiling Level STEL: Short Term Exposure Limit
N/A: Not Applicable N/D: Not Determined N/E: Not Established Y: Yes N: No
302: CERCLA List of Hazardous Substances and Reportable Quantities (40 CFR 302.4).
355: SARA TITLE III/ List of Extremely Hazardous Substances for Emergency Planning and Notification (40 CFR 355).
372: SARA TITLE III/ List of Toxic Chemicals subject to Release Reporting (Community Right to Know) (40 CFR 372).
III - PHYSICAL DATA
BOILING POINT (C/F): 212oF MELTING POINT: N/E
VAPOR PRESSURE (mm Hg.)@20C N/A SPECIFIC GRAVITY (WATER = 1): 1.00
CORROSION RATE: N/E WATER REACTIVE: NONE
VAPOR DENSITY (AIR = 1): 1 VAPOR PRESSURE (NON-AEROSOLS): 17
(mm Hg and Temperature)
SOLUBILITY IN WATER: TOTAL EVAPORATION RATE (Butyl Acetate = 1): 1
pH:
APPEARANCE AND ODOR: OFF-WHITE HAZY FLUID WITH MILD ODOR
IV - FIRE AND EXPLOSION HAZARD
FLASH POINT (F/(C): NONE. TCC (TEST METHOD):
FLAMMABLE LIMITS: UPPER: N/A LOWER:N/A
EXTINGUISHING MEDIA: NONE
SPECIAL FIRE FIGHTING PROCEDURES: WATER-BASED FLUID. KEEP COOL IN CASE OF A FIRE
UNUSUAL FIRE AND EXPLOSION HAZARD: MAY EMIT FUMES OF Nox, Cl, Pox, AND Sox AT TEMPERATURES ABOVE
320-392oF
V - REACTIVITY DATA
STABILITY: STABLE
INCOMPATIBILITY: NONE
CONDITIONS TO AVOID: INGREDIENTS MAY DECOMPOSE AT TEMP.
ABOVE 160oC. (320oF)
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: MAY PRODUCE Cl, Nox, Pox, Sox IN SMALL
QUANTITIES
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITIONS TO AVOID: SEE ABOVE
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MATERIAL SAFETY DATA SHEET
PRODUCT NAME: RESIDUAL ROACH SPRAY PRODUCT CODE: #196
VI - HEALTH AND HAZARD DATA
INHALATION? YES SKIN? YES INGESTION? N/A EYE? YES
ROUTES OF ENTRY:
HEATH HAZARDS (ACUTE & CHRONIC):
CARCINOGENICITY: NTP? N/A IARC MONOGRAPHS? N/A OSHA REGULATED? N/A
EFFECTS OF OVEREXPOSURE
IF IN EYES: MAY CAUSE IRREVERSIBLE EYE DAMAGE - PUPIL CONTRACTION
IF ON SKIN: PRIMARY MEANS OF EXPOSURE - IRRITANT
IF SWALLOWED: MAY BE FATAL IN LARGE AMOUNTS
IF INHALED: NAUSEA , PUPIL CONTRACTION, MUSCLE TWITCHING
EMERGENCY AND FIRST AID PROCEDURES
IF IN EYES: WASH WITH WATER FOR 15 MINUTES. CONTACT A PHYSICIAN
IF ON SKIN: WASH WITH SOAP AND WATER
IF SWALLOWED: IF SWALLOWED INDUCE VOMITING BY DRINKING 2 GLASSES OF WATER - CALL A PHYSICIAN.
IF INHALED: REMOVE TO FRESH AIR
VII - SPILL AND LEAK PROTECTION
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: AVOID BREATHING VAPORS - TOXIC TO FISH
BIRDS AND WILDLIFE. CONTAIN SPILL BY DIKING. KEEP OUT OF SEWERS. SUCK UP WITH WET/DRY VAC.
WASTE DISPOSAL METHOD: IN ACCORDANCE WITH LOCAL, STATE, FEDERAL REGULATIONS.
VIII - SPECIAL PROTECTION INFORMATION
VENTILATION REQUIREMENTS: MECHANICAL AND LOCAL EXHAUST TO MAINTAIN VAPOR LEVELS BELOW TLV
OF CHLORPYRIFOS.
RESPIRATORY PROTECTION: DO NOT SPRAY IN CONFINED AREAS WITHOUT NIOSH APPROVED BREATHING
APPARATUS
PROTECTIVE GLOVES: RUBBER OR PLASTIC
EYE PROTECTION: GOGGLES OR SAFETY GLASSES
OTHER PROTECTIVE EQUIPMENT: CLEANED BODY COVERING AND BOOTS, IF DESIRED
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: KEEP OUT OF REACH OF CHILDREN. DO NOT GET
ON SKIN OR IN EYES. STORE IN CLOSED CONTAINERS FOR NOT MORE THAN 1 YEAR.
OTHER PRECAUTIONS: PROTECT ALL WILDLIFE AND DO NOT ALLOW PRODUCT INTO WATERWAYS
WORK/HYGIENIC PRACTICES : WASH OFF WITH SOAP AND WATER AFTER HANDLING
REVISION DATE: January 05, 2005 Prepared By: DATE OF ISSUE: January 05, 2005
This information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of this data or
the results to be obtained from the use thereof. Chemco Industries assumes no responsibility for personal injury or property damage to the vendee, users
or third parties caused by the material such vendees or users assume all risks associated with the use of this material.
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