Permatex, Inc.
10 Columbus Blvd.
Hartford, CT 06106 USA
Telephone: 1-87-Permatex
(877) 376-2839
Emergency: 800-255-3924
International Emergency: 813-248-0585
Material Safety Data Sheet
1. PRODUCT IDENTIFICATION
Product Name: ULTRA BLACK GASKET MAKER 8.75OZ AE
Item No: 82080
Product Type: Silicone (Barrier Pack)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient Weight Percent ACGIH TLV: OSHA PEL:
POLY (DIMETHYLSILOXANE), 30-40 Not Listed Not Listed
HYDROXY TERMINATED
70131-67-8
10 mg/m3 particulate TWA
CALCIUM CARBONATE 20-30 Not Listed
471-34-1
15 mg/m3 TWA (total dust); 5 mg/m3
LIMESTONE 10-20 Not Listed
1317-65-3 TWA (respirable)
POLYBUTYLENE RESIN 10-20 Not Listed Not Listed
9003-29-6
VINYL OXIMINOSILANE 1-10 Not Listed Not Listed
2224-33-1
STEARIC ACID 1-10 Not Listed Not Listed
57-11-4
3.5 mg/m3 TWA 3.5 mg/m3 TWA
CARBON BLACK 0.1-1.0
1333-86-4
NITROGEN **** Asphyxiant Not Listed
7727-37-9
2-BUTANONE OXIME **** Not Listed Not Listed
96-29-7
3. HAZARDS IDENTIFICATION
May cause eye and skin irritation. May irritate lips, gums, tongue, mouth, nose and throat. May be harmful
Toxicity:
if swallowed. When heated to temperatures above 300 degrees F. in the presence of air, this product can
form formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory
sensitizer. Safe handling conditions may be maintained by keeping vapor concentrations below the OSHA
permissible limit for formaldehyde. ****When this product if exposed to moisture, butanone oxime may be
formed.
Eye and skin contact, ingestion, inhalation
Primary Routes of Entry:
****Butanone oxime produced during curing is toxic and irritates eyes, nose and throat. Overexposure to
Signs and Symptoms of Exposure:
the silane may cause coma and respiratory failure..
Ingredient Weight NTP ACGIH Carcinogens IARC
Percent
CARBON BLACK 0.1-1.0 Group A4 - Not Group 2B; Monograph 65,
1333-86-4 classifiable as a 1996
human carcinogen
None known.
Medical Conditions Recognized as
Being Aggravated by Exposure:
4. FIRST AID MEASURES
Rinse mouth with water several times. If swallowed, DO NOT induce vomiting. Keep individual calm.
Ingestion:
Obtain medical attention.
Move to fresh air in case of accidental inhalation of vapors. Oxygen or artificial respiration if needed.
Inhalation:
Obtain medical attention.
Wipe off paste with paper towel or cloth. Wash off immediately with soap and plenty of water removing all
Skin Contact:
contaminated clothes and shoes. If skin irritation persists, call a physician.
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical
Eye Contact:
attention if irritation persists.
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Product name: ULTRA BLACK GASKET MAKER 8.75OZ Item No: 82080
AE
5. FIRE FIGHTING MEASURES
More than 200 degrees F. (base material) Method: Tag Closed Cup
Flash Point (癋/C):
Carbon Dioxide, Dry Chemicals, Foam.
Recommended Extinguishing Media:
***Warning: This container is pressurized with nitrogen. Do not remove
Special Fire-Fighting Procedures:
rubber plug.. Keep containers cool. Use equipment or shielding required to
protect against bursting or venting of containers. Water spray may be
ineffective on flames but should be used to keep fire-exposed containers
cool.
Silica fume, Formaldehyde, Oxides of carbon, Oxides of nitrogen, Methyl
Hazardous Products of Combustion:
ethyl ketone, possibly methyl ethyl ketoxime
Contents under pressure. Heated cans may burst. Use equipment or
Unusual Fire/Explosion Hazards:
shielding to protect personnel from bursting containers.
Not determined
Lower Explosive Limit:
Not determined
Upper Explosive Limit:
6. ACCIDENTAL RELEASE MEASURES
Wipe or scrape up spill material. Maintain good ventilation for large spills. Place scrap material in a well-
Spill Procedures:
ventilated area and allow to cure to rubber. Clean up spills thoroughly as residue is slippery.
7. HANDLING AND STORAGE
Store away from heat, sparks or open flame. Do not store at temperatures above 120 degrees F.
Storage:
Exposure to high temperatures may cause container to burst.
Avoid contact with skin and eyes. Do not inhale vapors.
Handling:
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Safety glasses
Eyes:
Rubber or plastic gloves.
Skin:
General; local exhaust ventilation as necessary to control any air contaminants to within their exposure
Ventilation:
limits (or to the lowest feasible levels when limits have not been established) during the use of this
product.
Not required under normal use. An approved respirator (i.e. NIOSH, etc.) should be worn when exposures
Respiratory Protection:
are expected to exceed the applicable limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Black paste
Appearance:
MILD
Odor:
Not applicable, polymeric material
Boiling Point:
Does not apply
pH:
Polymerized
Solubility in Water:
1.35
Specific Gravity:
3.8% by weight
VOC Content(Wt.%):
Less than 5 mm Hg @ 70 degrees F.
Vapor Pressure:
3.0
Vapor Density (Air=1):
Slower than butyl acetate
Evaporation Rate:
10. STABILITY AND REACTIVITY
Stable at normal conditions
Chemical Stability:
WILL NOT OCCUR.
Hazardous Polymerization:
Strong oxidizers, Polymerized by contact with moisture., Acids, Iron
Incompatabilities:
Exposure to moisture, Heat
Conditions to Avoid:
Silica fume, Formaldehyde, Oxides of carbon, Oxides of nitrogen, Methyl
Hazardous Products of Combustion:
ethyl ketone, possibly methyl ethyl ketoxime
11. TOXICOLOGICAL INFORMATION
See Section 3
12. ECOLOGICAL INFORMATION
No data available
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Product name: ULTRA BLACK GASKET MAKER 8.75OZ Item No: 82080
AE
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations.
D003 - (Can under pressure) Hazardous waste per 40CFR 261.23(6)
US EPA Waste Number:
14. TRANSPORTATION INFORMATION
DOT (49CFR 172)
Domestic Ground Transport
CONSUMER COMMODITY
DOT Shipping Name:
ORM-D
Hazard Class:
None
UN/ID Number:
None
Marine Pollutant:
IATA
Consumer Commodity (Not more than 1 liter)
Proper Shipping Name:
Class 9
Class or Division:
ID 8000
UN/NA Number:
IMDG
Aerosols, Limited Quantity
Proper Shipping:
Class 2.2
Hazard Class:
UN 1950
UN Number:
15. REGULATORY INFORMATION
SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical.
NONE
CALIFORNIA PROP 65:
No California Prop 65 chemicals are known to be present.
TSCA Inventory Status:
Listed on Inventory: YES All components of this product are listed (or exempt) on the EPA TSCA inventory.
16. OTHER INFORMATION
HEALTH 1, FLAMMABILITY 1 , REACTIVITY 0
Estimated NFPA Rating:
HEALTH 1, FLAMMABILITY 1, PHYSICAL HAZARD 0
Estimated HMIS Classification:
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Denise Boyd, Health and Safety Manager
Prepared By: Revision Date: 09/28/2006
Permatex. Inc. 10 Columbus Blvd. Hartford, CT USA 06106 1
Company: Revision
Number:
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