83-4717 PAGE 1 OF 8
June 9, 1999
*** MATERIAL SAFETY DATA SHEET ***
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NUMBER ..................... 83-4717
PRODUCT NAME ....................... ABLEBOND 7950
SYNONYM NAME(S) .................... Filled Epoxy
Ablestik Laboratories
Subsidiary of National Starch and Chemical Company
20021 Susana Road
Rancho Dominguez, CA 90221
USA
Emergency Telephone:
1-800-424-9300 (24 hours, CHEMTREC}
2. COmPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL FAMILY .................... Epoxy Resin
COMPONENT CAS NUMBER CONCENTRATION
RANGES (%)
Diglycidylether of 54208-63-8 1 - I0
bisphenol-F
Epoxy Resin Proprietary 1 - 15
Methyl 19438-60-9 1 - 20
hexahydrophthalic
anhydride
Cycloaliphatic epoxy 2386-87-0 1-5
resin
Modified Epoxy Resin Proprietary i-5
3. HAZARDS IDENTIFICATION
EYE IRRITANT. TOXIC IF SWALLOWED. Sensitizer.
Irritating, and may injure eye
EYE ................................
tissue if not removed promptly.
SKIN CONTACT ....................... Frequent or prolonged skin contact
may irritate the skin and cause skin
sensitization.
INHALATION ......................... Vapors and/or aerosols which may be
PAGE 2 OF 8
JUne 9, 1999
*** MATERIAL SAFETY DATA SHEET ***
3. HAZARDS IDENTIFICATION ( Continued
formed at elevated temperatures may
be irritating to eyes and
respiratory tract. Avoid breathing
vapors or mists. If cured material
is sanded resulting powder would be
considered hazardous.
INGESTION .......................... May cause gastrointestinal
irritation, abdominal pain, nausea
and vomiting.
4. FIRST-AID MEASURES
EYE ................................ Immediately flush eyes with large
amounts of water for at least 15
minutes, lifting upper and lower
lids. Get prompt medical attention.
SKIN CONTACT ....................... Flush exposed areas thoroughly with
soap and water until all chemical is
removed. Remove contaminated
clothing and launder before reuse.
If irritation persists, get medical
attention.
INHALATION ......................... Remove to fresh air. Get medical
attention if irritation persists.
INGESTION .......................... Treat symptomatically and
supportively. Get medical attention.
DO NOT att--~.t to give anything h~
mouth to an unconscious person.
5. FIREFIGHTINGMEASURES
AUTO~GNITION ....................... Not available.
FLASH POINT ........................ Not available.
Foam; CO2; Dry chemical
EXTINGUISHING MEDZA ................
SPECIAL FIREFIGHTING PROCEDURES .... Fire fighters should be equipped
with self-contained breathing
apparatus to protect against
potentially toxic and irritating
fumes
Emits toxic fumes under fire
FIRE & EXPLOSION HAZARDS ...........
conditions.
HAZARDOUS CCt4BUSTION PRODUCTS ...... Carbon dioxide, carbon monoxide,
oxides of nitrogen and unknown
83-4129 P~.GE 7 OF 8
June 9, 1999
*** ~RL~L SAFETY DATA SHEET ***
14. TRANSPORTATION INFORMATION
DOT INFORMATION
DOT SHIPPING NAMZ .................. Not regulated
DOT HAZARD CLASS ................... Not Regulated
DOT RZPORTABLE QUANTITY ............ Not noted
REGULATORY INFORMATION
15.
TSCA ............................... All components are on the TSCA
inventory.
STATE LAWS ......................... Product contains one ingredient
which is subject to the reporting
requiremmnt of the California Safe
Drinking Water And Toxic Enfor=emgnt
Act of 1986 (Proposition 65).
Epichlorohydrin 106-89-8, < 15ppm
SARA/TITLE Ill ..................... This product contains no substances
at or above the reporting threshold
under Section 313, based on data
available.
The information given and the recommendations made herein apply to our
product(s) alone and are not combined with other product(s}. Such
based on our research and on data from other reliable sources and are
believed to be accurate. No guaranty of accuracy is made. It is the
purchaser's responsibility before using any product to verify this data
under their own operating conditions and to determine whether the product
is suitable for their purposes.
16. O~R INFORMATION
MSDS DATE .......................... ~umo*~1999"
CHANGES SINCE PREVIOUS ISSUE ....... Section II
FOR REGULATORY INFORMATION, CONTACT:
Health & Safety Coordinator
Ables tik Laboratories
National Starch & Ch~mlcal Company
20021 Susana Road
Rancho Dominguez, CA 90221
USA
83-4129 PAGE 8 OF 8
June 9, 1999
16. OTHZR INFORMATION ( Continued
Telephone: 310-764-4600
FAX: 310-763-2725
83-4717 PAGE 3 F 8
June 9, 1999
*** MATERIAL SAFETY DATA SHEET ***
5. FIREFIGHTING MEASURES ( Continued
organics. Thermal decomposition
products are hazardous and/or toxic.
UPPER EXPLOSION LIMIT (%) .......... Not Applicable
LOWER EXPLOSION LIMIT (%) .......... Not Applicable
6. ACCIDENTAL RELEASE MEASURES
SPILL AND T.w~K PROCEDURES .......... Scrape up and place in suitably
labeled container for disposal.
For safety and environmental precautions, please review entire Material
Safety Data Sheet for necessary information.
7. HANDLING AND STORAGE
STORAGE TEMPERATURE ................ - 40 DEGREE F
SPECIAL SENSITIVITY ................ Keep away from heat.
HANDLING/STORAGE ................... While this product is supplied in
wet form, processes involving
sanding or grinding after curing
could release airborne toxic dust.
Product can ONLY be used for thin
bond line applications or rapid
exothermic curing reaction may
result.
VENTILATION REQUIREMENTS ........... Vent curing oven to outdoors.
SENSITIVITY TO STATIC ELECTRICITY.. No
SENSITIVITY TO MECHANICAL IMPACT... No
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
VENTILATION REQUIREMENTS ........... Vent curing oven to outdoors.
EYE PROTECTION REQUIR]34ENTS ........ Wear safety glasses with side
shields.
En~ployee must wear appropriate
GLOVE REQUIREMENTS .................
protective gloves to prevent contact
with this substance.
Employee must wear appropriate
CLOTHING REQUIRE~4ENTS ..............
protective clothing and equipment to
prevent any possibility of skin
83-4717 PAGE 4 OF 8
June 9, 1999
*** MATERIAL SAFETY DATA SHEET ***
8. EXPOSURE CONTROLS/PERSONAL PROTECTION ( Continued
contact with this substance.
Remove contaminated clothing and
CHANGE/REMOVAL OF CLOTHING .........
launder before reuse.
Wash before eating, drinking, or
WASH REQUIREMENTS ..................
using toilet facilities.
RESPIRATOR REQUIREMENTS ............ If operating conditions create a
high vapor/mist concentration or if
the product is sanded or ground, use
of a NIOSH approved TC-23C organic
vapor/ hepa filter combination
cartridge is recommended.
PHYSICAL AND CHEMICAL PROPERTIES
9.
Mixture
PURE SUBSTANCE OR MIXTURE ..........
Paste
PHYSICAL FORM ......................
APPEARANCE/ODOR .................... Black; Pungent odor
ODOR THRESHOLD ..................... Not available.
PH AS IS ........................... Not available.
BOILING POINT ...................... Not available.
Not Applicable
MELTING/FREEZING POINT .............
Insoluble
SOLUBILITY IN WATER ................
PARTITION COEFFICIENT
(n-octanol/water) ................ Not Applicable
1.800
SPECIFIC GRAVITY (WATER-l} .........
Not Applicable
BULK DENSITY .......................
Not available.
EVAPORATION RATE ...................
Not available.
VAPOR PRESSURE (~nHg) ..............
Not available.
VAPOR DENSITY (air -- I) ............
Not available.
VISCOSITY ..........................
None.
VOLATILES ..........................
Not available.
AUTOZGNITION .......................
Not available.
FLASH POINT ........................
OXIDIZING PROPERTIES ............... Not Applicable
i0. STABILITY AND REACTIVITY
Stable
STABILITY ..........................
Carbon dioxide, carbon monoxide,
HAZARDOUS DECOMPOSITION PRODUCTS...
oxides of nitrogen and unknown
organics. Thermal decomposition
products are hazardous and/or toxic.
83-4717 PAGE 5 OF 8
June 9, 1999
*** MATERIAL SAFETY DATA SHEET ***
ii. TOXICOLOGICAL INFORI4ATION
CHRONIC (LONG TERM) E~CTS OF EXPOSURE
ROUTE OF ENTR~ ..................... Skin absorption
EFFECTS OF CHRONIC EXPOSURE ........ This product has not been tested for
mutagenicity. Epoxy resins s~m~lar
to those used in this formulation
have been tested and have produced
equivocal mutagenic activity. The
relevance of those find/ngs to
toxicological in, pact on humans is
unknown.
TARGET ORGANS ...................... Skin
CARCINOGEN ......................... No.
SENSITIZER ......................... Yes.
TOXICOLOGY INFORMATION
RAW MATERIAL NAME .................. Diglycidylether of bisphenol-F
>3.0 g/kg Rat
ORAL LDS0, SPECIES TESTED ..........
NOTES ON ORAL TOXICITY ............. Low order of toxicity. Irritating to
mouth, throat and stomach. May cause
gastric tract disorder and/or
damage.
NOTES ON DERMAL TOXICITY ........... Mild skin irritant. May cause skin
sensitization, a partial or
whole-body dermatitic rash
experienced after exposure, however
minimal.
NOTES ON INHALATION TOXICITY ....... Irritating to eyes and respiratory
tract. May cause breathing disorders
and/or lung damage. Avoid breathing
vapors or mists.
NOTES ON EYE IRRITATION ............ Irritating, and will injure eye
tissue if not removed promptly.
OTHER NOTES ON TOXICITY ............ Sensitizer.
RAW MATERIAL NAME .................. Methyl hexahydrophthalic anhydride
NOTES ON ORAL TOXICITY ............. Slightly toxic.
Frequent or prolonged skin contact
NOTES ON DERMAL TOXICITY ...........
may irritate the skin and cause skin
sensitization.
NOTES ON INHALATION TOXICITY ....... Irritating to eyes and respiratory
tract. May cause allergic
respiratory reaction.
83-4717 PAGE 6 - OF 8
June 9, 1999
*** MATERIAL SAFETY DATA SHEET ***
II. TOXICOLOGICAL INFORMATION ( Continued
Maybe irritating.
NOTES ON EYE IRRITATION ............
OTHER NOTES ON TOXICITY ............ Sensitizer.
Cycloaliphatic epoxy resin
RAW MATERIAL NAME ..................
>5.0 g/kg Rat; 4.5 g/kg Rat
ORAL LDS0, SPECIES TESTED ..........
NOTES ON ORAL TOXICITY ............. Low order of toxicity. May cause
gastrointestinal irritation,
abdominal pain, nausea and vomiting.
>4.0 g/kg Rabbit
DERMAL LDS0, SPECIES TESTED ........
NOTES ON DERMAL TOXICITY ........... Frequent or prolonged contact may
irritate the skin. May cause skin
sensitization, a partial or
whole-body dermatitic rash
experienced after exposure, however
minimal.
Vapors and/or aerosols which may be
NOTES ON INHALATION TOXICITY .......
formed at elevated temperatures may
be irritating to eyes and
respiratory tract.
NOTES ON EYE IRRITATION ............ Irritating, and may injure eye
tissue if not removed promptly.
OTHIR NOTES ON TOXICITY ............ Sensitizer.
12. ECOLOGICAL INFORMATION
Not available.
13. DISPOSAL CONSIDERATIONS
W~STE DISPOSAL METHODS ........ ..... Waste disposal should be in
accordance with existing federal,
state and local environmental
regulations.
EMPTY CONTAINER WARNINGS ........... Empty containers may contain product
residue;followMSDS and label
warnings even after they have been
~-~.tied.
83-4717 PAGE 7 OF 8
June 9, 1999
*** MATERIAL SAFETY DATA SHIET ***
14. TRANSPORTATION INFORMATION
DOT INFORMATION
DOT SHIPPING NAME .................. Not noted
DOT HAZARD CLASS ................... Not noted
DOT REPORTABLE QUANTITY ............ Not not~
15. REGULATORY INFOP~ATION
TSCA ............................... Exempted from the TSCA Inventory.
STATE LAWS ......................... California Proposition 65: WARNING:
This product contains a chemical
known to the state of California to
cause cancer: Trace amount of
Epichlorohydrin. WARNZNG: This
product contains a chemical known to
the State of California to cause
birth defects or other reproductive
harm: Trace amount of
Eplchlorohydrin.
SARA/TITLE III, THIS PRODUCT CONTAINS (OR IS) A TOXIC CHEMICAL FOR
ROUTINE ANNUAL CHEMICAL RELEASE REPORTING UNDER SECTZON 313:
Chromium .... CAS#7440-47-3
The information given and the reco~ndations made herein apply to our
product(s) alone and are not combined with other product(s). Such
based on our research and on data from other reliable sources and are
h41ieved to be acc~Irate. No guaranty of accuracy is made. It is the
purchaser's responsibility before using any product to verify~his data
under their own operating c0nditions and to determine whether the product
is suitable for their purposes.
16. OTHER INFORMATION
~DS DATE ..........................;~y ~ 1~9~
CHANGES SINCE PREVIOUS ISSUE ....... Section ii
FOR REGULATORY INFORMATION, CONTACT:
Health & Safety Coordinator
Ablestik Laboratories
"83-4717 PAGE 8 OF 8
June 9, 1999
*** MATERIAL SAFETY DATA SHEET ***
16. OTHER INFORMATION ( Continued
National Starch & Ch!m~cal Company
20021 Susana Road
Rancho Dominguez, CA 90221
USA
Telephone: 310-764-4600
FAX: 310-763-2725
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