Page 1/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 10.05.2006 Reviewed on 17.03.2006
Hazardous according to criteria of Worksafe Australia
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: D-Lab1 Easy Film Box F2, BL-R
?Article number: 5KW6V
?Application of the substance / the preparation Photographic bleaching concentrate
?Manufacturer/Supplier:
a&o imaging solutions GmbH
Chemische Fabrik Vaihingen/Enz (former AGFA / AgfaPhoto)
Steinbeisstrasse 49
D-71665 Vaihingen/Enz
Germany
distributed by :
Photo Direct P/L
Suite 2, 358 Whitehorse Rd
Nunawading Vic 3131
Australia
Phone: + 61 3 9894 1644
Fax: + 61 3 9894 1677
?Further information obtainable from:
Productmanagement, Tel.: + 49 7042 913-41, Fax: + 49 7042 913-18
?Information in case of emergency:
Australia / New Zealand :
The Australian Centre for Occupational Health & Safety (ACOHS Pty Ltd)
6 Burleigh Court, Nunawading, VIC 3131
Phone : 1800 638 556 (24 hours, 7 days a week)
2 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
CAS: 111687-36-6 ammonium iron(III)trimethylenediaminetetraacetate hemihydrate 13.5%
ELINCS: 400-660-3
CAS: 6484-52-2 ammonium nitrate 8.6%
EINECS: 229-347-8
CAS: 110-16-7 maleic acid 6.7%
EINECS: 203-742-5
CAS: 110-15-6 succinic acid 2.0%
EINECS: 203-740-4
CAS: 1939-36-2 trimethylenediaminetetraacetic acid 0.8%
ELINCS: 400-400-9
?Additional information: For the wording of the listed risk phrases refer to section 16.
AUS
(Contd. on page 2)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 10.05.2006 Reviewed on 17.03.2006
Trade name: D-Lab1 Easy Film Box F2, BL-R
(Contd. of page 1)
3 Hazards identification
?Hazard description: Not applicable.
?Information concerning particular hazards for human and environment:
Th e pro duct has t o be l abel led d ue to the calculat ion p rocedure of t he "General C lassifi cati on
guideline for preparations of the EU" in the latest valid version.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Classification system:
The classi ficatio n is accord ing to the latest edit ions o f the EU-li sts, a nd extended by company and
literature data.
4 First aid measures
?After inhalation: Supply fresh air; consult doctor in case of complaints.
?After skin contact: Generally the product does not irritate the skin.
?After eye contact: Rinse opened eye for several minutes under running water.
?After swallowing: If symptoms persist consult doctor.
5 Fire-fighting measures
?Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?Protective equipment: No special measures required.
6 Accidental release measures
?Person-related safety precautions: Not required.
?Measures for environmental protection:
Inform respective authorities in case of seepage into water course or sewage system.
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
7 Handling and storage
?Handling:
?Information for safe handling: No special measures required.
?Information about fire - and explosion protection: No special measures required.
?Storage:
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: None.
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(Contd. on page 3)
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Page 3/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 10.05.2006 Reviewed on 17.03.2006
Trade name: D-Lab1 Easy Film Box F2, BL-R
(Contd. of page 2)
8 Exposure controls/personal protection
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures: Wash hands before breaks and at the end of work.
?Respiratory protection: Not required.
?Protection of hands:
The g lo ve ma teri al h as to b e imp ermeab le a nd resi st an t t o th e pro du ct / th e sub st an ce/ th e
preparation.
Du e to mi ssin g tests no recommend ati on to t he glo ve ma teri al ca n be gi ven fo r the p rod uct/ t he
preparation/ the chemical mixture.
Selection of the glove material on considerat ion of the penetrati on times, rat es of diffusi on and the
degradation
?Material of gloves
The selection of the suita ble gloves does not only depen d on the material, but also on further marks
of q uality a nd varies from manufacturer to ma nufacturer. As th e product is a preparati on of several
substa nces, the resistance of the glove material can not b e calculat ed in a dvance and has therefore
to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has
to be observed.
?Eye protection: Goggles recommended during refilling
9 Physical and chemical properties
?General Information
Form: Fluid
Colour: According to product specification
Odour: Characteristic
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 100癈 (212癋)
?Flash point: Not applicable.
?Self-igniting: Product is not selfigniting.
?Danger of explosion: Product does not present an explosion hazard.
?Vapour pressure at 20癈 (68癋): 23 hPa (17 mm Hg)
?Density at 20癈 (68癋): 1.199 g/cm?br>
?Solubility in / Miscibility with
water: Fully miscible.
?pH-value at 20癈 (68癋): 3.5
(Contd. on page 4)
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Page 4/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 10.05.2006 Reviewed on 17.03.2006
Trade name: D-Lab1 Easy Film Box F2, BL-R
(Contd. of page 3)
?Viscosity:
Kinematic at 20癈 (68癋): 11 s (DIN 53211/4)
?Solvent content:
Organic solvents: 0.0 %
Water: 60.0 %
?Solids content: 40.0 %
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous decomposition products: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: No irritating effect.
?Sensitization: No sensitizing effects known.
12 Ecological information
?Ecotoxical effects:
?Remark: Harmful to fish
?General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
13 Disposal considerations
?Product:
?Recommendation
Mu st no t be d ispo sed t ogether with hou seho ld ga rba ge. Do not allo w pro duct to reach sewa ge
system.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
?Recommended cleansing agents: Water, if necessary together with cleansing agents.
AUS
(Contd. on page 5)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 10.05.2006 Reviewed on 17.03.2006
Trade name: D-Lab1 Easy Film Box F2, BL-R
(Contd. of page 4)
14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID class: 8 (C9) Corrosive substances.
?Danger code (Kemler): 80
?UN-Number: 1760
?Packaging group: III
?Hazard label: 8
?Description of goods: 1760 CORROSIVE LIQUID, N.O.S.
?Maritime transport IMDG:
?IMDG Class: 8
?UN Number: 1760
?Label 8
?Packaging group: III
?Marine pollutant: No
?Proper shipping name: CORROSIVE LIQUID, N.O.S.
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: 8
?UN/ID Number: 1760
?Label 8
?Packaging group: III
?Proper shipping name: CORROSIVE LIQUID, N.O.S.
15 Regulatory information
?Australian Inventory of Chemical Substances
All ingredients are listed.
?Labelling according to EU guidelines:
Th e produ ct h as been classified and marked in accordan ce w ith EU Directi ves / Ord ina nce on
Hazardous Materials.
?Risk phrases:
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
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(Contd. on page 6)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 10.05.2006 Reviewed on 17.03.2006
Trade name: D-Lab1 Easy Film Box F2, BL-R
(Contd. of page 5)
16 Other information
This information is based o n our present knowledg e. However, this shall not const itute a gu arantee
for any specific product features and shall not establish a legally valid contractual relationship.
?Department issuing MSDS: Productmanagement department
?Contact: Mr. Vollhofer, a&o imaging solutions, Tel.: + 49 7042 913-43
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