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Material Safety Data 24 Hour Assistance:
1-847-367-7700
Sheet
Rust-Oleum Corp.
www.rustoleum.com
Section 1 - Chemical Product / Company Information
Rust-Oleum High Performance
Product Name: Revision Date: 08/11/2004
Industrial Enamel Topcoats
1210300, 1210402, 1210504, 1282300,
1282402, 1282504, 2764300, 2764402,
2766100, 2766300, 2766402, 2766504,
412300, 412402, 412504, 559300,
559402, 634300, 634402, 634504,
721300, 721402, 721504, 7232402,
7280300, 7280402, 7290402, 7434300,
7434402, 7446300, 7446402, 7447402,
Identification 7448402, 745300, 745402, 8494402,
865300, 865402, 865504, 865504,
Number:
866300, 866402, 868402, 904300,
904402, 906300, 906402, 906504,
925300, 925402, 925504, 933402,
935300, 935402, 944300, 944402,
944504, 956300, 956402, 956504,
964300, 964402, 964504, 975300,
975402, 975504, 977300, 977402,
977504
Product Use/Class: Topcoat/Alkyd
Rust-Oleum Corporation Rust -Oleum Corporation
Supplier: Manufacturer:
11 Hawthorn Parkway 11 Hawthorn Parkway
Vernon Hills, IL 60061 Vernon Hills, IL 60061
USA USA
Preparer: Cziczo, Ray
Section 2 - Composition / Information On Ingredients
Chemical Name CAS Number Weight % Less ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA PEL-CEILING
Than
Stoddard Solvents 8052-41-3 50.0 100 PPM N.E. 500 PPM N.E.
Titanium Dioxide 13463-67 -7 25.0 10 mg/m3 N.E. 10 mg/m3 N.E.
Calcined Aluminum Silicate 1332-58-7 20.0 2 mg/m3 N.E. 5 mg/m3 N.E.
Pigment Orange 5 3468-63-1 10.0 2mg/m3. N.E 5mg/m3 N.E.
Magnesium Silicate 14807-96 -6 10.0 10 mg/m3 N.E. 15 mg/m3 N.E.
Pigment Yellow 74 6358-31-2 10.0 N.E. N.E. N.E. N.E.
Pigment Black 7 1333-86-4 5.0 3.5 mg/m3 N.E. 3.5 mg/m3 N.E.
Pigment Orange 34 15793-73 -4 5.0 2 mg/m3 N.E. 5 mg/m3 N.E.
Pigment Green 7 1328-53-6 5.0 N.E. N.E. N.E. N.E.
Ethylbenzene 100-41-4 1.0 100 PPM 125 PPM 100 PPM N.E.
Section 3 - Hazards Identification
*** Emergency Overview ***: Harmful if inhaled. May affect the brain or nervous system causing dizziness,
headache or nausea. Combustible liquid and vapor. Suspect cancer hazard. Harmful if swallowed. Causes eye
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irritation. Vapors irritating to eyes and respiratory tract.
Effects Of Overexposure - Eye Contact: Causes eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation.
Effects Of Overexposure - Inhalation: High vapor concentrations are irritating to the eyes, nose, throat and lungs.
May cause headaches and dizziness. Harmful if inhaled.
Effects Of Overexposure - Ingestion: Aspiration hazard if swallowed; can enter lungs and cause damage.
Substance may be harmful if swallowed.
Effects Of Overexposure - Chronic Hazards: IARC lists Ethylbenzene as a possible human carcinogen (group 2B).
Suspect cancer hazard--contains material which may cause cancer. Reports have associated repeated and
prolonged occupational overexposure to solvents with permanent brain and nervous system damage.
Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen,
eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have
included liver, cardiac abnormalities and nervous system damage.
Contains carbon black. Chronic inflammation, lung fibrosis, and lung tumors have been observed in some rats
experimentally exposed for long periods of time to excessive concentrations of carbon black and several insoluble
fine dust particles. Tumors have not been observed in other animal species (i.e., mouse and hampster) under
similar circumstances and study conditions. Epidemiological studies of North American workers show no evidence
of clinically significant adverse health effects due to occupational exposure to carbon black.
Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as
A4- "not classified as a human carcinogen" by the American Conference of Govermental Industrial Hygienists.
Significant exposure is not anticipated during brush application or drying. Risk of overexposure depends on
duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration
of carbon black in the formula.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact
Section 4 - First Aid Measures
First Aid - Eye Contact: Hold eyelids apart and flush with plenty of water for at least 15 minutes. Get medical
attention.
First Aid - Skin Contact: Wash with soap and water. Get medical attention if irritation develops or persists.
First Aid - Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get immediate medical attention.
First Aid - Ingestion: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material
can enter the lungs and cause severe lung damage. Get immediate medical attention.
Section 5 - Fire Fighting Measures
Flash Point: 104 F LOWER EXPLOSIVE LIMIT: 0.9 %
(Setaflash) UPPER EXPLOSIVE LIMIT : 22.7 %
Extinguishing Media: Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: Keep containers tightly closed.
Special Firefighting Procedures: Evacuate area and fight fire from a safe distance. Water may be used to cool
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closed containers to prevent pressure buildup and possible autoignition or explosion.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do
not incinerate closed containers.
Section 7 - Handling And Storage
Handling: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after
container is emptied because it may retain product residues. Avoid breathing vapor or mist. Avoid contact with
eyes.
Storage: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away
from heat, sparks, flame and sources of ignition. Keep container closed when not in use.
Section 8 - Exposure Controls / Personal Protection
Engineering Controls: Prevent build-up of vapors by opening all doors and windows to achieve cross -ventilation.
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
Respiratory Protection: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements
must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying
respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where
airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is
any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air
purifying respirators may not provide adequate protection.
Skin Protection: Use impervious gloves to prevent skin contact and absorption of this material through the skin.
Nitrile or Neoprene gloves may afford adequate skin protection.
Eye Protection: Use safety eyewear designed to protect against splash of liquids.
Other protective equipment: Refer to safety supervisor or industrial hygienist for further information regarding
personal protective equipment and its application.
Hygienic Practices: Wash thoroughly with soap and water before eating, drinking or smoking.
Section 9 - Physical And Chemical Properties
Boiling Range: 232 - 400 F Vapor Density: Heavier than air
Odor: Odor Threshold:
Solvent Like ND
Appearance: Evaporation Rate:
Liquid Slower than Ether
Solubility in H2O: Slight
Freeze Point: Specific Gravity:
ND 1.0800
Vapor Pressure: PH: NE
Physical State: Liquid
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(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Avoid all possible sources of ignition.
Incompatibility: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
Hazardous Decomposition: When heated to decomposition it emits acrid smoke and irritating fumes. By open
flame, carbon monoxide and carbon dioxide.
Hazardous Polymerization: Will not occur under normal conditions.
Stability: This product is stable under normal storage conditions.
Section 11 - Toxicological Information
Product LD50: ND Product LC50: ND
Chemical Name LD50 LC50
Stoddard Solvents N.D. N.D.
Titanium Dioxide >7500 mg/kg N.D.
(ORAL, RAT)
Calcined Aluminum Silicate N.D. N.D.
Pigment Orange 5 N.D. N.D.
Magnesium Silicate N.D. TCLo:11mg/m3
inh.
Pigment Yellow 74 >15000 mg/kg N.D.
(ORAL, RAT)
Pigment Black 7 >8000 mg/kg N.D.
(ORAL, RAT)
Pigment Orange 34 15000 mg/kg N.D.
(ORAL, RAT)
Pigment Green 7 >5000 mg/kg N.D.
(ORAL, RAT)
Ethylbenzene 3500 mg/kg N.D.
(ORAL, RAT)
Section 12 - Ecological Information
Ecological Information: Product is a mixture of listed components.
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance to local, state and federal regulations and ordinances. Do
not allow to enter storm drains or sewer systems.
Section 14 - Transportation Information
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DOT Proper Shipping Name: Paint Packing Group: III
DOT Technical Name: --- Hazard Subclass: ---
DOT Hazard Class: 3 Resp. Guide Page: 127
DOT UN/NA Number: UN 1263
Section 15 - Regulatory Information
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA "Hazard Categories" promulgated under Sections 311and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD
SARA Section 313:
Listed below are the substances (if any) contained in this product that are subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS Number
Pigment Green 7 1328-53-6
Ethylbenzene 100-41-4
Toxic Substances Control Act:
Listed below are the substances (if any) contained in this product that are subject to the reporting requirements of
TSCA 12(B) if exported from the United States:
None known
U.S. State Regulations: As follows -
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product.
Chemical Name CAS Number
Calcium Carbonate 1317-65-3
Alkyd Resin PROPRIETARY
Alkyd Resin PROPRIETARY
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%.
Chemical Name CAS Number
Calcium Carbonate 1317-65-3
Alkyd Resin PROPRIETARY
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Alkyd Resin PROPRIETARY
Red Iron Oxide 1332-37-2
Pigment Red 3 2425-85-6
Yellow Iron Oxide 51274-00-1
Iron Oxide 1309-37-1
California Proposition 65:
Warning: The following ingredients present in the product are known to the state of California to cause Cancer:
Chemical Name CAS Number
Pigment Orange 5 3468-63-1
Chlorothalonil 1897-45-6
Microcrystalline Silica 14808-60-7
Ethylbenzene 100-41-4
Beryllium Compounds NOT SPECIFIED
Nickel Compounds NOT SPECIFIED
Chromium (Hexavalent) Compounds NOT SPECIFIED
Arsenic Compounds NOT SPECIFIED
Benzene 71-43-2
Cadmium Compounds NOT SPECIFIED
Lead Compounds NOT SPECIFIED
Warning: The following ingredients present in the product are known to the state of California to cause birth defects,
or other reproductive hazards.
Chemical Name CAS Number
Toluene 108-88-3
Mercury Compounds NOT SPECIFIED
Ethylene Glycol Monoethyl Ether 110-80-5
Arsenic Compounds NOT SPECIFIED
Benzene 71-43-2
Cadmium Compounds NOT SPECIFIED
Lead Compounds NOT SPECIFIED
International Regulations: As follows -
CANADIAN WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16
headings.
CANADIAN WHMIS CLASS: B3 D2B
Section 16 - Other Information
HMIS Ratings:
Health: 2* Flammability: 2 Reactivity: 0 Personal Protection: X
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VOLATILE ORGANIC COMPOUNDS, g/l: <450
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
The information contained on this MSDS has been checked and should be accurate. However, it is the
responsibility of the user to comply with all Federal, State, and Local laws and regulations.
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