- - - - - - - - - - - - - - - - MATERIAL SAFETY DATA SHEET - - - - - - - - - - - - - - -
Syngenta DACONIL(R) 2787 FLOWABLE FUNGICIDE
Syngenta Crop Protection Canada, Inc. HMIS RATING
Daconil(R) 2787 Flowable Fungicide Health: 2
Date issued: 03-09-18 (Y/M/D) Fire: 0
----------------------------------------------------------- Reactivity: 0
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PPE
----------------------------------------------------------- Unusual fire and explosion hazards: May decompose under
Company: Syngenta Crop Protection Canada, Inc. fire conditions emitting gases and vapors (e.g., hydrogen
140 Research Lane chloride) which may be toxic and irritating to the
Guelph, Ontario respiratory tract.
N1G 4Z3 -----------------------------------------------------------
Phone number: (519) 836-5665 Section 6 - ACCIDENTAL RELEASE MEASURES
Emergency phone: 1-800-327-8633 (1-800-FASTMED) -----------------------------------------------------------
Name used on label: Daconil(R) 2787 Flowable Fungicide PERSONAL PRECAUTIONS: Wear suitable protective clothing.
Formulation Number: A7867K ENVIRONMENTAL PRECAUTIONS: Keep out of lakes, streams or
Product use: Fungicide ponds. Do not contaminate waterways by cleaning of
Registration Number: 15724 equipment or by disposal of wastes.
A Registered Trade Mark of a Syngenta group company METHODS FOR CLEANING UP: Contain spill. Keep out of sewers
----------------------------------------------------------- and drains. Remove as much as possible by absorbing with
Section 2 - COMPOSITION/INFORMATION ON INGREDIENTS inert material. Remove any contaminated soil. Place in
----------------------------------------------------------- closed, labeled containers and store in a safe place to
Identity CAS-no. Typical % Other information await disposal.
----------------------------------------------------------- ADDITIONAL INFORMATION: Seal drum and dispose of
chlorothalonil (ISO) contaminated material in a facility permitted for
1897-45-6 40.4 % hazardous waste. Large spills should be handled according
----------------------------------------------------------- to spill plan.
Ingredients not precisely identified are proprietary or non -----------------------------------------------------------
hazardous. Section 7 - HANDLING AND STORAGE
Values are not product specifications. -----------------------------------------------------------
----------------------------------------------------------- REQUIREMENTS FOR STORAGE ROOMS: Containers should be stored
Section 3 - HAZARDS IDENTIFICATION in a cool, dry, well-ventilated area away from flammable
----------------------------------------------------------- materials and sources of heat or flame.
Physical hazards: None ADDITIONAL INFORMATION: Do not store near feed, food, or
Health hazards: Irritant (eye, skin, respiratory passages, within the reach of children. Open dumping is prohibited.
skin sensitiser). -----------------------------------------------------------
----------------------------------------------------------- Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Section 4 - FIRST AID MEASURES -----------------------------------------------------------
----------------------------------------------------------- Occupational exposure limits
IF IN EYES: Immediately flush eyes with running water for a Occupational exposure standards: Syngenta has established
minimum of 20 minutes. Hold eyelids open during flushing. an employee exposure standard of 0.1 mg/M3 (8-hour TWA)
If irritation persists, repeat flushing. Obtain medical for the active ingredient.
attention immediately. TLV or suggested control value: No TLV assigned.
IF ON SKIN: Flush skin with running water for a minimum of VENTILATION: Provide exhaust ventilation or other
20 minutes. Start flushing while removing contaminated engineering controls to keep the airborne concentrations
clothing. If irritation persists, repeat flushing. Obtain of vapors below their respective threshold limit value.
medical attention immediately. EYE PROTECTION: Wear eye/face protection.
IF SWALLOWED: Immediately contact Syngenta's Emergency BODY PROTECTION: Applicators and other handlers must wear:
Information Network at 1-800-F-A-S-T-M-E-D (327-8633). Do Long-sleeved shirt and long pants, waterproof gloves and
not induce vomiting. Vomiting should only be induced shoes plus socks. Clean clothing on a routine basis.
under the direction of a physician or a poison control Remove contaminated clothing and wash before re-wearing.
center. If spontaneous vomiting occurs, have victim lean RESPIRATORY PROTECTION: Use MSHA-NIOSH approved respirator
forward with head down to avoid breathing in of vomitus, for pesticides.
rinse mouth and administer water. Never give anything by GENERAL PERSONAL PROTECTION: Persons exposed routinely to
mouth to an unconscious person. Obtain medical attention. this product should shower after completing work each
IF INHALED: Remove victim to fresh air. Until adequate day.
ventilation or other control measures are restored, Worker Protection Standard:
employ proper respiratory protection. If symptoms Restricted Entry Interval (REI): 48 hours
develop, seek medical attention. PPE for early entry: Coveralls, waterproof gloves, shoes
MEDICAL ADVICE: Persons having a temporary allergic plus socks, protective eyewear.
reaction may respond to treatment with antihistamines or See label for more detailed information.
steroid creams and/or systemic steroids. -----------------------------------------------------------
----------------------------------------------------------- Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Section 5 - FIRE FIGHTING MEASURES -----------------------------------------------------------
----------------------------------------------------------- Form: liquid
Flash point: Nonflammable Physical state: Suspension Concentrate
Autoignition temperature: Not applicable Colour: light gray
Flammable limits (STP): Noncombustible Odour: slight
EXTINGUISHING MEDIA: Foam, carbon dioxide, water or dry Boiling point: 100 deg C (lowest boiling component)
chemical. Melting point: Not applicable
PROTECTIVE EQUIPMENT: Self-contained breathing apparatus Freezing temperature: -5 deg C
with full face-piece and protective clothing Vapor Pressure: 5.72 x 10(-7) mm Hg at 25 deg C
NFPA RATING Vapour density: Not determined
Health: 0 Bulk density: 1.23 kg/L
Fire: 0 Specific gravity: 1.24 (water = 1)
Reactivity: 0 Solubility: Dispersible in water. 0.6 - 1.2 ppm
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Syngenta DACONIL(R) 2787 FLOWABLE FUNGICIDE
Volatile by volume: 56 % (v/v) Container disposal: Empty container retains product
pH: 6 - 8 residue. Triple rinse, or equivalent, empty container,
Evaporation rate: Not determined return rinse water to dilution mixture, and dispose of
Evaporation rate: Not determined dilution mixture as a hazardous waste if it cannot be
Viscosity: 1063 cps @ 21 deg C disposed of by use according to label instructions. Do
----------------------------------------------------------- not reuse container. Offer it for recycling or
Section 10 - STABILITY AND REACTIVITY reconditioning, or puncture and dispose of in properly
----------------------------------------------------------- permitted landfill. If burned, stay out of smoke.
HAZARDOUS REACTIONS (CONDITIONS TO AVOID) -----------------------------------------------------------
Stability: Stable under normal conditions. Section 14 - TRANSPORT INFORMATION
Incompatibility: Unstable under highly alkaline -----------------------------------------------------------
conditions. TRANSPORT/ADDITIONAL INFORMATION
Hazardous polymerization: None known. Road (TDG) transport: Not Regulated By TDG
HAZARDOUS DECOMPOSITION PRODUCTS: May decompose under fire -----------------------------------------------------------
conditions emitting gases and vapors (e.g., hydrogen Section 15 - REGULATORY INFORMATION
chloride) which may be toxic or irritating to the -----------------------------------------------------------
respiratory tract. Other regulations, restrictions and prohibitions
----------------------------------------------------------- Pest Control Products (PCP) Act Registration No: 15724
Section 11 - TOXICOLOGICAL INFORMATION -----------------------------------------------------------
----------------------------------------------------------- Section 16 - OTHER INFORMATION
ACUTE TOXICITY (LETHAL DOSES) -----------------------------------------------------------
LD50 Ingestion rat We assigned NFPA and HMIS ratings to this product based on
Dose: 4200 mg/kg the hazards of its ingredient(s). Because the customer is
Additional inform.: May cause irritation of the most aware of the application of the product, he must
gastrointestinal tract following ingestion of large ensure that the proper personal protective equipment (PPE)
amounts. is provided consistent with information contained in the
LD50 Dermal rabbit product MSDS. This information is intended solely for the
Dose: > 20000 mg/kg use of individuals trained in the particular hazard rating
Additional inform.: May cause skin irritation. May be a system. The information contained herein is offered only as
potential skin sensitizer. On overexposed skin, may a guide to the handling of this specific material and has
cause moderate irritation, redness and flaky rash. been prepared in good faith by technically knowledgeable
Skin rash is seldom observed if the recommended personnel. It is not intended to be all-inclusive and the
safeguards outlined are followed. manner and conditions of use and handling may involve other
LC50 Inhalation rat and additional considerations. No warranty of any kind is
Dose: > 7.16 mg/l given or implied and Syngenta will not be liable for any
Period: 4 hours damages, losses, injuries or consequential damages which
Additional inform.: May be irritant to the respiratory may result from the use of or reliance on any information
tract. This is rarely observed. Skin absorption contained herein. This Material Safety Data Sheet is valid
Additional inform: Not readily absorbed through for three years. This product is under the jurisdiction of
intact skin. the Pest Control Products Act and is exempt from the
ACUTE TOXICITY (IRRITATION, SENSITIZATION ETC.) requirements for a WHMIS compliant MSDS. Hazardous
Eye contact properties of all ingredients have been considered in the
Results: MILD IRRITANT TO SEVERE IRRITANT preparation of this MSDS. Read the entire MSDS for the
Additional inform.: No evidence of permanent damage has complete hazard evaluation of this product.
been found. -----------------------------------------------------------
GENERAL INFORMATION ABOUT ACUTE OR OTHER TOXICITIES Prepared by: Syngenta Crop Protection Canada, Inc
Other effects of overexposure: Studies on rats and mice (519) 836-5665
have suggested that technical chlorothalonil (97%), -----------------------------------------------------------
when fed at high levels in the diet, may have oncogenic DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES:
potential to these laboratory animals. However, neither Although preparer and owner have taken reasonable
chlorothalonil nor its metabolites interact with DNA care in the preparation of this document, we
and thus are not mutagenic. Tumor formation has been extend no warranties and make no representation
related to a non-genotoxic mechanism of action for as to the accuracy or completeness of the information
which threshold levels have been established in rats contained herein, and assume no responsibility
and mice. Comprehensive dietary and worker exposure regarding the suitability of this information for
studies have shown exposure levels for humans to be the user's intended purposes or for the consequences
well below these threshold levels. In addition, of its use. Each user should make a determination as
surveillance of chlorothalonil plant workers for over to the suitability of the information for their
twenty years has not demonstrated any increase in particular purpose(s). This MSDS is the most recent
oncogenic potential to humans. received from the product manufacturer or
----------------------------------------------------------- distributor.
Section 12 - ECOLOGICAL INFORMATION -----------------------------------------------------------
----------------------------------------------------------- COMPAS Code: 46010182
ADDITIONAL INFORMATION ABOUT ECOLOGY: Toxic to fish.
-----------------------------------------------------------
Section 13 - DISPOSAL CONSIDERATIONS
-----------------------------------------------------------
Disposal Method: Disposal should be in accordance with
local, provincial or national legislation.
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