Safety Data Sheet
Revision date: 09-September-2003
replaces all previous editions
FOLIO GOLD
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND COMPANY
OR UNDERTAKING
Identification of the substance or preparation
Tradename FOLIO GOLD
Design Code A 9652 B
AGI Code 25718 / 117383
Company identification
Company Syngenta Crop Protection UK Ltd
Whittlesford, CAMBRIDGE, CB2 4QT
Phone (01223) 833621
Fax (01223) 493700
Website www.syngenta-crop.co.uk
Emergency Phone +44 (0) 1484 538444 (24h)
2. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical characteristic
Formulation type Suspension concentrate
Use Fungicide
Active ingredients 3.75 % w/v metalaxyl-M CGA329351
50 % w/v chlorothalonil ASF41
Hazardous Components
CAS Name % w/w Hazard symbols Risk phrases (R)
70630-17-0 metalaxyl-M 3.0 Xn, Xi 22, 41
1897-45-6 chlorothalonil 39.7 T+, N 26, 37, 40, 41, 43,
50/53
3. HAZARDS IDENTIFICATION
Harmful by inhalation. Irritating to eyes, respiratory system and skin. May cause
sensitisation by skin contact. Limited evidence of a carcinogenic effect. Very toxic
to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
FOLIO GOLD Safety Data Sheet Page 1 of 7
4. FIRST-AID MEASURES
First-Aid Measures
General: In case of indisposition place the patient in a well-ventilated area and
protect them from hypothermia. IN CASE OF SUSPECTED POISONING:
Immediately call a physician.
Eye Contact: Rinse eyes with clean water for several minutes and immediately
call a physician.
Ingestion: Repeatedly administer medicinal charcoal in a large quantity of water.
NOTE: Never give anything by mouth to an unconscious person. Do not induce
vomiting.
Skin Contact: Remove contaminated clothing and thoroughly wash the affected
parts of the body with soap and water, including hair and under fingernails.
Inhalation: Immediately remove to fresh air.
Medical Instructions
Antidote: No specific antidote is known! Apply symptomatic therapy.
5. FIRE-FIGHTING MEASURES
Combustibility: yes
Suitable Extinguishing Media: Dry chemical extinguisher, foam, carbon dioxide or
waterspray (do not use direct jet of water).
Special Hazards during Fire Fighting: Combustion products are toxic and/or
irritant. Measures have to be taken to prevent the contaminated extinguishing agent
from seeping into the ground or from spreading uncontrollably.
Protective Equipment for Fire Fighting: Use self contained breathing apparatus.
Wear protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Environmental Protection Measures following Accidents: Cover up product
with absorptive material such as sand, soil, diatomaceous earth, etc. and dispose of
in an incinerator approved for chemicals. Collect material in specially marked,
tightly closing containers. Spilled product cannot be used further and must be
disposed of. If safe disposal is not possible, contact the manufacturer, the dealer or
the local representative. Do not contaminate waters and sewers.
FOLIO GOLD Safety Data Sheet Page 2 of 7
7. HANDLING AND STORAGE
General: Avoid contact with skin, eyes and clothing. Avoid inhalation of fog and
vapours. Do not eat, drink or smoke while working. In addition to the measures
usually taken in chemical works like splashproof filling and measuring equipment
(including vapour stripping), further personal protection measures may have to be
implemented to avoid possible contact with the product.
Special Instructions for Storage: Store the product in closed original containers.
Protect from light and humidity.
Storage Compatibility with other Products: Store separately from feed, food and
stimulants.
Minimum Storage Temperature: -5 癈
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Occupational exposure limits;
Hazardous ingredients Syngenta Standard:
Chlorothalonil LTEL (8hr TWA): 0.1 mg/m3 Skin sensitiser; possible respiratory
sensitiser.
Personal protective equipment
When using this product refer to the label for details. In all other cases, use the
following personal protective equipment:
In General: Change working clothes daily.
Breathing Protection: In case of heavy exposure, wear: Gas mask.
Eye Protection: Goggles or face-shield.
Hand Protection: Chemical-resistant gloves.
Body Protection: Heavy duty cotton or synthetic fabric working clothes (e.g.
overalls).
Precautionary measures after work: Wash thoroughly (shower, bathe, wash
hair). Change clothing. Thoroughly clean protective gear. Thoroughly clean
contaminated equipment with soap or soda solution.
FOLIO GOLD Safety Data Sheet Page 3 of 7
9. PHYSICAL AND CHEMICAL PROPERTIES
beige to grey
Colour:
liquid
Physical State/Form:
>= 90 癈 EEC A 9
Flash-Point:
EEC A 14
Explosive Properties
not explosive
Assessment:
not shock sensitive
Shock Sensitivity:
1.24 - 1.28 g/cm3 (20 癈) OECD 109
Density:
5 - 9 (1 %; in deionised water) CIPAC MT 75.2
pH Value:
40.0 mN/m (20.0 g/l; Suspension in EEC A 5
Surface Tension:
distilled water; 20 癈)
59.3 - 60.8 mN/m (0.1 g/l; Suspension in EEC A 5
Surface Tension:
distilled water; 20 癈)
69.5 - 70.2 mN/m (0.01 g/l; in distilled EEC A 5
Surface Tension:
water; 20 癈)
miscible (1 %; ca 23 癈)
Miscibility with water:
83.1 - 199 mPa.s (50 - 250 rps; 20 癈) OECD 114
Dynamic Viscosity:
66.3 - 165 mPa.s (50 - 250 rps; 40 癈) OECD 114
Dynamic Viscosity:
10. STABILITY AND REACTIVITY
Chemical Stability Assessment: Stable under standard conditions.
Sensitivity Thermal Sensitivity: Thermally not sensitive.
11. TOXICOLOGICAL INFORMATION
OECD 401
Acute Oral Toxicity (male rat)
> 3000 mg/kg
LD50:
OECD 401
Acute Oral Toxicity (female rat)
> 2000 < 3000 mg/kg
LD50:
OECD 402
Acute Dermal Toxicity
> 4000 mg/kg (rat)
LD50:
irritant (rabbit; assessment according OECD 404
Acute Skin Irritation:
to 93/21/EEC)
irritant (rabbit; assessment according OECD 405
Acute Eye Irritation:
to 93/21/EEC)
sensitising (guinea pig; assessment OECD 406
Skin Sensitisation:
according to 93/21/EEC; Maximiza-
tion test)
FOLIO GOLD Safety Data Sheet Page 4 of 7
12. ECOLOGICAL INFORMATION
OECD 203
Acute Toxicity to Fish
0.09 mg/l (Salmo trutta (trout); 96 h)
LC50:
OECD 201
Growth Inhibition, Algae
57 mg/l (Scenedesmus subspicatus (green algae); 72 h)
ErC50:
OECD 202
Toxicity to Aquatic Invertebrates
0.58 mg/l (Daphnia magna (water flea); 48 h)
EC50:
EPPO 170 (1992)
Toxicity to Bees
> 152.2 礸/bee (Apis mellifera (honey bee); 48
LD50:
h; oral)
EPPO 170 (1992)
Toxicity to Bees
> 100 礸/bee (Apis mellifera (honey bee); 48 h;
LD50:
dermal)
OECD 207
Toxicity to Soil Dwelling Organisms
457 mg/kg (earthworm; 14 day(s))
LC50:
13. DISPOSAL CONSIDERATIONS
Product Disposal: Pay attention to protective clothing and measures. Cover up
product with absorptive material such as sand, soil, diatomaceous earth, etc.
Collect material in specially marked, tightly closing containers. Treat contaminated
surfaces with water. Collect washings in containers, to avoid any contamination of
surface and ground water, water supplies and drains. Hose down the area for a
prolonged period. Heavily contaminated soil layers have to be dug out down to
clean soil. Spilled product cannot be used further and must be disposed of. If safe
disposal is not possible, contact the manufacturer, the dealer or the local
representative and dispose of in an incinerator approved for chemicals.
Container Disposal: Manufacturer's packaging must be rinsed out after emptying.
Dispose of empty containers in an incinerator approved for chemicals. Damaged
containers: Place original containers in specially marked larger ones. Check
possibilities of recycling large empty containers, drums and barrels.
FOLIO GOLD Safety Data Sheet Page 5 of 7
14. TRANSPORT INFORMATION
Special Information: Use unbreakable containers, make sure they cannot fall, and
label in accordance with regulations.
Rail / Road (RID / ADR) Class UN no. Packaging Group Kemmler Index
9 3082 III 90
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S., (CHLOROTHALONIL)
Class UN no. Packaging Group EMS MFAG
Sea (IMDG-Code)
9 3082 III NONE NONE
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S., (CHLOROTHALONIL 50%, MARINE
POLLUTANT)
Marine pollutant: yes
Class UN no. Packaging Group
Air (ICAO / IATA)
9 3082 III
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S., (CHLOROTHALONIL)
15. REGULATORY INFORMATION
Hazard symbols/ N DANGEROUS FOR THE ENVIRONMENT.
Classifications Xn HARMFUL.
20 Harmful by inhalation.
Risk phrases (R)
36/37/38 Irritating to eyes, respiratory system and skin.
40 Limited evidence of a carcinogenic effect.
43 May cause sensitisation by skin contact.
50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment.
2 Keep out of the reach of children.
Safety phrases (S)
13 Keep away from food, drink and animal feeding
stuffs.
20/21 When using do not eat, drink or smoke.
35 This material and its container must be disposed
of in a safe way.
36/37 Wear suitable protective clothing and gloves.
57 Use appropriate containment to avoid environ-
mental contamination.
To avoid risks to man and the environment,
Special label
comply with the instructions for use.
16. OTHER INFORMATION
Product registration number: MAPP 10704.
FOLIO GOLD Safety Data Sheet Page 6 of 7
Based upon SDS release date 19-JUN-2001 with DPD update. Significant changes
in sections 2, 3 and 15.
Always read the label. Use pesticides safely.
The information contained herein is based on the present state of our
knowledge as is intended to describe our products from the point of view of
safety requirements. It should not therefore be construed as guaranteeing
specific properties.
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