Material Safety Data Sheet
Preparation Date: 04-Jan-2010 Revision Date: 29-Dec-2009 Revision Number: 0
1. PRODUCT AND COMPANY IDENTIFICATION
Product Code F006-11WH
Trade Name TNEME-CRYL WHITE
Contact Manufacturer Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372
Emergency Telephone Number 800-535-5053 (INFOTRAC) - TNEMEC REGULATORY DEPT: 816-474-3400
2. HAZARDS IDENTIFICATION
Emergency Overview
WARNING!
HARMFUL IF INHALED.
OVEREXPOSURE MAY CAUSE KIDNEY DAMAGE.
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA.
MAY CAUSE EYE, SKIN, NOSE, THROAT AND RESPIRATORY TRACT IRRITATION.
Potential Health Effects
Principle Routes of Exposure Eye contact, Inhalation, Skin contact.
Acute Effects
Eyes Irritating to eyes.
Skin Irritating to skin.
Inhalation Irritating to respiratory system.
Ingestion May be harmful if swallowed.
Chronic Effects
NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous
system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.
See Section 11 for additional Toxicological information.
Aggravated Medical Conditions Central nervous system. Skin disorders.
Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects.
Potential Environmental Effects See Section 12 for additional Ecological information
Target Organ Effects Central nervous system, Central Vascular System, Eyes, Lungs, Respiratory system, Skin
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Components
CAS-No Weight %
Component
13463-67-7 10 - 30
TITANIUM DIOXIDE (TOTAL DUST)
14807-96-6 10 - 30
TALC (RESPIRABLE DUST)
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3. COMPOSITION/INFORMATION ON INGREDIENTS
107-21-1 4.9591
ETHYLENE GLYCOL
7631-86-9 1-5
AMORPHOUS SILICA
1344-28-1 1-5
ALUMINUM OXIDES
1897-45-6 0.1 - 1
CHLOROTHALONIL
4. FIRST AID MEASURES
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes.
Skin Contact Wash off immediately with soap and plenty of water.
Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.
Inhalation Move to fresh air. Oxygen or artificial respiration if needed.
5. FIRE-FIGHTING MEASURES
Flammable Properties No information available.
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Contact with water may cause violent frothing. Use: Carbon dioxide (CO2) -
Foam - Dry chemical
Hazardous Decomposition Products Oxides of carbon, hydrocarbons. Oxides of nitrogen. Ammonia. Formaldehyde. Hydrogen
chloride.
Specific Hazards Arising from the Chemical
Thermal decomposition can lead to release of irritating gases and vapours. In the event of fire and/or explosion do not breathe fumes.
Protective Equipment and Precautions for Firefighters
Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from
heat/sparks/open flames/hot surfaces. May cause heat and pressure build-up in closed containers.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Remove all
sources of ignition.
Environmental Precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary
sewer system.
Methods for Cleaning Up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated
absorbent, container and unused contents in accordance with local, state and federal
regulations.
Other Information Not applicable
7. HANDLING AND STORAGE
Handling
Close container after each use. Avoid contact with skin, eyes and clothing. Handle in accordance with good industrial hygiene and
safety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. When
used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling.
Storage
Prevent build-up of vapors by opening all windows and doors to achieve cross ventilation.
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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component ACGIH TLV OSHA PEL Quebec TWAEV Ontario TWAEV Mexico OEL (TWA)
TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3 STEL:
TITANIUM DIOXIDE (TOTAL
15 mg/m3 20 mg/m3
DUST)
TWA: 2 mg/m3 TWA: 2 mg/m3 TWA: 3 mg/m3 TWA: 2 mg/m3 TWA: 2 mg/m3
TALC (RESPIRABLE DUST)
Ceiling: 100 mg/m3 CEV: 100 mg/m3 Peak: 100 mg/m3
ETHYLENE GLYCOL Ceiling: 50 ppm Ceiling: Ceiling: 50 ppm Ceiling:
125 mg/m3 127 mg/m3
TWA: 1 mg/m3 3
TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3
ALUMINUM OXIDES TWA: 10 mg/m TWA: 5
mg/m3 TWA: 15 mg/m3
Engineering Measures Ensure adequate ventilation, especially in confined areas
Personal Protective Equipment
Skin Protection Lightweight protective clothing, Apron, Impervious gloves
Eye/face Protection Safety glasses with side-shields
Respiratory Protection Use only with adequate ventilation. Do not breathe dust, vapors or spray mist. Ensure
fresh air entry during application and drying. If you experience eye watering, headache or
dizziness or if air monitoring demonstrates vapor/mist levels are above applicable limits,
wear an appropriate, properly fitted respirator (NIOSH approved) during and after application.
Follow respirator manufacturer's directions for respirator use.
General Hygiene Handle in accordance with good industrial hygiene and safety practice.
Considerations Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Flash Point Not applicable
Boiling Point/Range 100 - 205癈 / 212.0 - 401.0癋
Upper Exposure Limits No information available
Lower Exposure Limits No information available
Evaporation Rate No information available
Vapour Pressure No information available
Vapour Density No information available
Specific Gravity 1.44510
Density 12.02537
VOC Content (lbs/gal) 1.430
% Volatile by Weight 39.4310
% Volatile by Volume 56.4271
10. STABILITY AND REACTIVITY
Chemical stability Stable. Conditions to Avoid Heat, flames and sparks.
Incompatible Products Strong oxidizing agents. Bases. Possibility of Hazardous None under normal processing
Acids. Reactions
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Component Information
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11. TOXICOLOGICAL INFORMATION
Component LD50 Oral LD50 Dermal LC50 Inhalation
TITANIUM DIOXIDE (TOTAL DUST) 10000 mg/kg ( Rat )
ETHYLENE GLYCOL 4000 mg/kg ( Rat ) 9530 礚/kg ( Rabbit )
AMORPHOUS SILICA 5000 mg/kg ( Rat ) 2000 mg/kg ( Rabbit ) 2.2 mg/L ( Rat ) 1 h
ALUMINUM OXIDES 5000 mg/kg ( Rat )
CHLOROTHALONIL 10 g/kg ( Rat ) 2500 mg/kg ( Rat ) 2000 mg/kg ( 0.217 mg/L ( Rat ) 4 h 0.31 mg/L (
Rabbit ) Rat ) 1 h
Irritation No information available
Corrosivity No information available
Sensitization No information available
Chronic Toxicity
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component ACGIH IARC NTP OSHA Mexico
TITANIUM DIOXIDE (TOTAL Group 2B X
DUST)
CHLOROTHALONIL Group 2B X
Mutagenic Effects No information available
Reproductive Effects No information available
Developmental Effects No information available
Teratogenicity No information available
Target Organ Effects Central nervous system, Central Vascular System, Eyes, Lungs, Respiratory system, Skin.
Endocrine Disruptor Information No information available
12. ECOLOGICAL INFORMATION
Ecotoxicity
.
Component Freshwater Algae Freshwater Fish Microtox Water Flea
TALC (RESPIRABLE DUST) LC50> 100 g/L Brachydanio
rerio 96 h
ETHYLENE GLYCOL EC50 1300 - 6500 mg/L 96 h LC50= 41000 mg/L EC50 = 620.0 mg/L 30 min EC50 = 46300 mg/L 48 h
Oncorhynchus mykiss 96 h EC50 = 620 mg/L 30 min
LC50= 27500 mg/L Lepomis EC50 = 10000 mg/L 16 h
macrochirus 96 h LC50=
40761 mg/L Oncorhynchus
mykiss 96 h LC50= 49000
mg/L Pimephales promelas 96
h LC50= 16000 mg/L Poecilia
reticulata 96 h
AMORPHOUS SILICA EC50 = 440 mg/L 72 h LC50= 5000 mg/L Brachydanio EC50 = 7600 mg/L 48 h
rerio 96 h
CHLOROTHALONIL EC50 = 0.57 mg/L 72 h LC50= 0.012 mg/L EC50 = 0.059 mg/L 48 h
Oncorhynchus mykiss 96 h
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container and unused contents in accordance
with local, state and federal regulations.
Contaminated Packaging Empty containers should be taken for local recycling, recovery or waste disposal
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14. TRANSPORT INFORMATION
DOT Ground Transportation Only. Call TNEMEC Traffic Department - 816-474-3400 for other modes of Transportation.
Proper Shipping Name PAINT,WATER BASE FREEZABLE
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL/NDSL Does not Comply
EINECS/ELINCS Does not Comply
CHINA Does not Comply
ENCS Does not Comply
KECL Does not Comply
PICCS Does not Comply
AICS Does not Comply
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product contains the following HAPs:
Component
ETHYLENE GLYCOL
U.S. Federal Regulations
SARA 313
Component CAS-No Weight % SARA 313 - Threshold
Values
ETHYLENE GLYCOL 107-21-1 4.9591 1.0
CHLOROTHALONIL 1897-45-6 0.1 - 1 0.1
SARA 311/312 Hazardous Categorization
Chronic Health Hazard No
Acute Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No
CERCLA
Component Hazardous Substances RQs CERCLA EHS RQs
ETHYLENE GLYCOL 5000 lb
U.S. State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals:
Component CAS-No California Prop. 65
CHLOROTHALONIL 1897-45-6 Carcinogen
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State Right-to-Know
Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island
TITANIUM DIOXIDE (TOTAL X X X X
DUST)
TALC (RESPIRABLE DUST) X X X X
ETHYLENE GLYCOL X X X X X
AMORPHOUS SILICA X X
ALUMINUM OXIDES X X X X
CHLOROTHALONIL X X X
Other International Regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.
WHMIS Hazard Class
D2B Toxic materials
Component NPRI
ETHYLENE GLYCOL Part 1, Group 1 Substance
ALUMINUM OXIDES Part 1, Group 1 Substance (fibrous form)
Legend
NPRI - National Pollutant Release Inventory
16. OTHER INFORMATION
Revision Date: 29-Dec-2009
Revision Summary No information available
HMIS Health 0 Flammability 0 Reactivity 1
Disclaimer
For specific information regarding occupational safety and health standards, please refer to the Code of Federal
Regulations, Title 29, Part 1910.
To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any
of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards which exist.
End of MSDS
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