Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MERLIN 1/8
Version 1 / GB Revision Date: 12.05.2006
102000008825 Print Date: 14.07.2008
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product information
Trade name MERLIN
Product code (UVP) 05934664
Usage fungicide
Company Bayer CropScience Limited
230 Cambridge Science Park
Milton Road
Cambridge
Cambridgeshire CB4 0WB
Great Britain
Telephone +44(0)1223 226500
Telefax +44(0)1223 426240
Emergency telephone number 0800-220876 (UK 24 hr)
+44(0)1603-242424 (Overseas 24 hr)
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Suspension concentrate (=flowable concentrate)(SC)
31% Propamocarb Hydrochloride (375 g/l), 31% Chlorothalonil (375 g/l)
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Chlorothalonil 1897-45-6 T+, N R26, R37, 31.00
217-588-1 R40, R41,
R43, R50/53
Propamocarb hydrochloride 25606-41-1 Xi R43 31.00
247-125-9
1,2-Propanediol 57-55-6 > 1.00 - < 5.00
200-338-0
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Harmful by inhalation.
Limited evidence of a carcinogenic effect.
Risk of serious damage to eyes.
May cause sensitization by skin contact.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
General advice
Remove contaminated clothing immediately and dispose of safely.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MERLIN 2/8
Version 1 / GB Revision Date: 12.05.2006
102000008825 Print Date: 14.07.2008
Inhalation
Call a physician or poison control center immediately. Move to fresh air. Keep patient warm and
at rest.
Skin contact
Wash off immediately with soap and plenty of water. If symptoms persist, call a physician.
Eye contact
In the case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
Ingestion
Do not induce vomiting. Rinse out mouth and give water in small sips to drink. Ingest activated
charcoal. Call a physician or poison control center immediately.
Notes to Physician
Symptoms
gastrointestinal discomfort, eye and mucous membrane irritation, erythema, sensitization,
bloody urine
Risks
Risk of respiratory disorders.
This product, although being a carbamate, is NOT a cholinesterase inhibitor.
Treatment
Treat symptomatically.
Treat skin and mucous membranes with antihistamine and corticoids.
By irritation of the lungs: First treatment with Corticord-Spray, e.g.Auxilon, Pulmicort - Dosing
aerosol. (Auxilon and Pulmicort are registered Trade Marks)
In the event of a mouthful or more being ingested, the following measures should be
considered:
Gastric lavage with charcoal, if necessary further treatment.
N-Acetylcysteine (Fluimucil; registered trademark).
Monitor kidney and respiratory functions.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Product itself is non-combustible; fire extinguishing measures to suit surroundings.
Specific hazards during fire fighting
The product itself does not burn.
Cool closed containers exposed to fire with water spray.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus.
Wear full protective suit.
Further information
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Wear personal protective equipment. Unprotected persons must be kept away.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MERLIN 3/8
Version 1 / GB Revision Date: 12.05.2006
102000008825 Print Date: 14.07.2008
Environmental Precautions
Do not discharge into the drains/surface water/groundwater.
If spillage enters drains leading to sewage works inform local water company immediately.
If spillage enters rivers or watercourses, inform the Environment Agency (emergency telephone
number 0800 807060).
Methods for Cleaning Up
Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary absorbent
material).
Keep in suitable, closed containers for disposal.
Additional Advice
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
Keep container tightly closed.
Avoid subsoil penetration.
Advice on protection against fire and explosion
No special precautions required.
Storage
Requirements for storage areas and containers
Store in original container.
Storage temperature should ideally lie between 0 and 30 癈, however, storage for two weeks at
54 癈 has shown no adverse effects regarding product safety or stability.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Storage stability
Storage period 24 Months
Storage temperature < 28 癈
Other data Stable under recommended storage conditions.
Suitable materials
HDPE (high density polyethylene)
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Refer to COSHH assessment (Control of Substances Hazardous to Health (Amendment)
Regulations 2004). Engineering controls should be used in preference to personal
protective equipment wherever practicable. Refer also to COSHH Essentials.
Components with workplace control parameters
Components CAS-No. Control parameters Update Basis
1,2-Propanediol 57-55-6 10 mg/m3 2005 EH40 WEL
(Particulate.) (TWA)
1,2-Propanediol 57-55-6 474 mg/m3 / 150 ppm 2005 EH40 WEL
(Vapor and particulates.) (TWA)
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MERLIN 4/8
Version 1 / GB Revision Date: 12.05.2006
102000008825 Print Date: 14.07.2008
Additional Advice
none
Engineering measures
See section 7; no measures exceeding those mentioned are necessary.
Personal protective equipment
Respiratory Protection No personal respiratory protective equipment normally required.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.
Hand Protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum
thickness 0,40 mm). Wash when contaminated. Dispose of when
contaminated inside, when perforated or when contamination
outside cannot be removed. Wash hands always before eating,
drinking, smoking or using the toilet.
Eye protection Wear goggles conforming to EN166 (Field of Use 5 or equivalent).
Skin and body protection Wear standard coverall and type 3 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
Hygiene measures
Keep away from food, drink and animal feedingstuffs.
Remove soiled clothing immediately.
Avoid contact with the skin and the eyes.
After worktime and during work intervals the affected skin areas must be thoroughly cleaned.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form liquid, suspension
Colour light grey
Odour slight, product specific
Safety data
pH 6.0 - 7.5 at 10 % (20 癈)
Boiling point/ range ca. 100 癈
Flash Point > 100 癈
No flash point - Determination conducted up to the boiling point.
Autoignition Temperature The product is not self-ignitable.
Density ca. 1.210 g/cm?at 20 癈
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MERLIN 5/8
Version 1 / GB Revision Date: 12.05.2006
102000008825 Print Date: 14.07.2008
Water Solubility dispersible
Viscosity, dynamic 140 - 210 mPa.s at 20 癈
Surface tension 0.04 N/m at 22 癈
Explosivity Not explosive
10. STABILITY AND REACTIVITY
Conditions to Avoid Extremes of temperature and direct sunlight.
Materials to avoid None.
Hazardous Decomposition No hazardous decomposition products known.
Products
Thermal decomposition No decomposition if used as directed.
Hazardous Reactions No hazardous reactions known.
11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity LD50 (rat) > 2,000 mg/kg
Acute Inhalation Toxicity LC50 (rat) 2.28 mg/l
Exposure time: 4 h
Acute Dermal Toxicity LD50 (rat) > 4,000 mg/kg
Skin Irritation No skin irritation. (rabbit)
Eye Irritation Risk of serious damage to eyes. (rabbit)
Sensitization sensitizing (guinea pig)
OECD Test Guideline 406, Buehler test
Further information
Indication of a possible carcinogenic activity in animal tests.
12. ECOLOGICAL INFORMATION
Elimination information (persistence and degradability)
Bioaccumulation Lepomis macrochirus (Bluegill sunfish)
Exposure time: 42 d
Bioconcentration factor (BCF): 264
The value mentioned relates to the active ingredient chlorothalonil.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MERLIN 6/8
Version 1 / GB Revision Date: 12.05.2006
102000008825 Print Date: 14.07.2008
Bioaccumulation Lepomis macrochirus (Bluegill sunfish)
Exposure time: 42 d
Bioconcentration factor (BCF): 1.5 - 3.0
The value mentioned relates to the active ingredient propamocarb-
hydrochloride.
Ecotoxicity effects
Toxicity to Fish LC50 (Rainbow trout (Oncorhynchus mykiss)) 0.177 mg/l
semi-static test Exposure time: 96 h
Toxicity to daphnia EC50 (Daphnia) 0.46 mg/l
static test Exposure time: 48 h
Toxicity to algae IC50 (Algae) 0.56 mg/l
Exposure time: 72 h
Further information on ecology
Additional ecological information
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
The product should not be allowed to reach either ground or open waters.
13. DISPOSAL CONSIDERATIONS
Product
In accordance with current regulations may be taken to waste disposal site or incineration plant,
after consultation with site operator and/or with the responsible authority.
Advice may be obtained from the local waste regulation authority (part of the Environment
Agency in the UK).
Contaminated packaging
Small containers (< 10 l or < 10 kg) should be rinsed thoroughly using an integrated pressure
rinsing device, or, by manually rinsing three times.
Add washings to sprayer at time of filling.
Dispose of empty and cleaned packaging safely.
Large containers (> 25 l or > 25 kg) should not be rinsed or re-used for any other purpose.
Return large containers to supplier.
Follow advice on product label and/or leaflet.
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
ADR/RID/ADNR
UN-No 3082
Labels 9
Packaging group III
Hazard no. 90
Description of the goods UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(CHLORTHALONIL SOLUTION)
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MERLIN 7/8
Version 1 / GB Revision Date: 12.05.2006
102000008825 Print Date: 14.07.2008
IMDG
UN-No 3082
Class 9
Packaging group III
EmS F-A , S-F
Marine pollutant Marine pollutant
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(CHLORTHALONIL SOLUTION )
IATA
UN-No 3082
Class 9
Packaging group III
Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(CHLORTHALONIL SOLUTION )
UK 'Carriage' Regulations
UN-No 3082
Labels 9
Packaging group III
Hazard no. 90
Emergency action code 3Z
Description of the goods UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
(CHLORTHALONIL SOLUTION)
15. REGULATORY INFORMATION
This product has been classified in accordance with The Chemicals (Hazard Information and
Packaging for Supply) Regulations 2002: CHIP 3 and any subsequent amendments.
Classification:
Labelling according to EC Directives
Hazardous components which must be listed on the label:
?Chlorothalonil
?Propamocarb hydrochloride
Symbol(s)
Xn Harmful
N Dangerous for the environment
R-phrase(s)
R20 Harmful by inhalation.
R40 Limited evidence of a carcinogenic effect.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
MERLIN 8/8
Version 1 / GB Revision Date: 12.05.2006
102000008825 Print Date: 14.07.2008
S-phrase(s)
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S35 This material and its container must be disposed of in a safe way.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S57 Use appropriate container to avoid environmental contamination.
Exceptional labelling
To avoid risks to man and the environment, comply with the instructions for use.
Further information
WHO-classification: III (Slightly hazardous)
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2:
R26 Very toxic by inhalation.
R37 Irritating to respiratory system.
R40 Limited evidence of a carcinogenic effect.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The above information is intended to give general health and safety guidance on the storage and
transport of the product.
It is not intended to apply to the use of the product for which purposes the product label and any
appropriate technical usage literature available should be consulted and any relevant licenses,
consents or approvals complied with.
The requirements or recommendations of any relevant site or working procedure, system or policy in
force or arising from any risk assessment involving the substance or product should take precedence
over any of the guidance contained in this safety data sheet where there is a difference in the
information given.
The information provided in this safety data sheet is accurate at the date of publication and will be
updated as and when appropriate.
No liability will be accepted for any injury, loss or damage resulting from any failure to take account
of information or advice contained in this safety data sheet.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
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