Material Safety Data Sheet
J. R. Simplot Company
AgriBusiness
M770349
Trade Name: Best One-Shot
Registration No: 2217-856-7001
SECTION 1 CHEMICAL PRODUCT AND COMPANY INFORMATION
Manufacturer or Formulator: J.R. Simplot Company Product Name: Best One-Shot
P.O. Box 70013 Common Name: 16-6-8
Boise, ID 83707 Chemical Type: Inorganic Chemical Fertilizer with Herbicide
Emergency Phone - Chemtrec: 1-800-424-9300
SECTION 2 COMPOSITION INFORMATION
Chemical Name and Synonyms C.A.S. No. Chemical Formula WT% TLV PEL
Hazardous
3 3
2,4-Dichlorophenoxyacetic acid 94-75-7 not listed <1% 10 mg/m 10 mg/m
3,6-Dichloro-o-anisic acid (dicamba) 1918-00-9 not listed <1% not indicated not indicated
Dithiopyr 97886-45-8 not listed <1% not indicated not indicated
R(+)2(2-Methyl-4-chlorophenoxy) 16484-77-8 not listed <1% not indicated not indicated
Propionic acid (MCPP)
Non-Hazardous
3 3
This is a homogeneous granular product of: balance 10 mg/m Nuisance Dust 15 mg/m Nuisance Dust
Ammonium Sulfate 7783-20-2 (NH4)2SO4
Monoammonium Phosphate 7783-28-0 (NH4)2HPO4
Muriate of Potash 7447-40-7 KCl
Iron Oxysulfate not listed not listed
SECTION 3 HAZARDS IDENTIFICATION
Ingestion: Minimal hazard under normal conditions and use. Ingestion of large quantities may cause gastrointestinal discomfort, vomiting,
weakness or other medically related problems.
Inhalation: Dusty conditions may cause mechanical aggravation to respiratory mucous membranes.
Eye Contact: Dust from this product may cause particulate discomfort to eyes.
Skin Absorption: Not normally absorbed through the skin.
Skin Contact: Slight dermal abrasion is possible with prolonged contact, especially around cuffs and collars.
Effects of Overdose: Ingestion of large doses may cause diarrhea, nausea, abdominal cramps or formation of methemoglobinemia. Seek medical
attention.
SECTION 4 FIRST AID MEASURES
Ingestion: If large amount is ingested, give 2-3 glasses of water and induce vomiting. Seek medical attention.
Inhalation: Remove to fresh air. Seek medical attention if condition persists.
Eyes: Flush eyes with running water for at least 15 minutes. Seek medical attention if condition persists.
Skin: Wash with soap and water. Seek medical attention if condition persists.
Notes to Physician: Consult standard literature. Treatment based on the sound judgment of the physician and the individual reactions of the
patient.
SECTION 5 FIRE FIGHTING MEASURES
Extinguishing Media: Use media suitable to extinguish source of fire.
Special Fire Fighting Procedures: Product is not combustible.
Unusual Fire and Explosion Hazards: During extremely high temperature fire conditions, the product may reach melting point and decompose to
release NH3, SOx, POx or CN.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Environmental Precautions: Keep out of water supplies, lakes, ponds, streams and rivers. This product is a fertilizer and may promote algae growth.
Steps to be taken in case material is released or spilled:
Keep from entering waterways. Sweep up material and place in suitable container for use as a fertilizer or for disposal.
SECTION 7 HANDLING AND STORAGE
Precautions to be taken in handling and storing:
Store in a cool, dry area. Prevent spillage and separate from strong oxidizers. Use normal safety procedures and good
personal hygiene. Keep out of the reach of children.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation Protection: Adequate ventilation.
Respiratory Protection: Approved dust respirator when necessary.
Protective Clothing: Normal clean work clothing.
Eye Protection: In dusty conditions, safety glasses with side shields or goggles may be necessary.
M770349
Trade Name: Best One-Shot
Registration No: 2217-856-7001
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
o
Boiling Point: Not applicable Solubility in Water: 60 gm/100 gm H2O @ 78 F
3
Density: 63 lbs/ft % Volatiles (by volume): Not applicable
Flashpoint: Non flammable Vapor Pressure, mm Hg: Not applicable
pH: Not listed Reaction with Water: None
Appearance: Solid, granular, dark gray with a slight acidic odor.
Extinguishing Media: Use media suitable to extinguish source of fire.
SECTION 10 STABILITY AND REACTIVITY
Stability (Normal Conditions): Stable
Conditions to Avoid: Extremely high temperatures.
Incompatibility (Material to Avoid): Strong oxidizing agents. Prolonged contact may cause oxidation of unprotected metals.
Hazardous Decomposition Products: During extremely high temperature fire conditions, the product may reach melting point and decompose to
release NH3, SOx, POx or CN.
Hazardous Polymerization: Will not occur
SECTION 11 TOXICOLOGY INFORMATION
Oral LD50 (rat) Dermal LD50 (rat) Aquatic Fish 96-hour Aquatic (other)
Mono-ammonium Phosphate >2,000 mg/kg >5,000 mg/kg > 86 mg/L (rainbow trout) none listed
Ammonium Sulfate 640-4,250 mg/kg > 2,000 mg/kg > 13.6-159.8 mg total NH3/L > 27.0 mg/total NH3/L (daphnia)
Potassium Chloride 1,500-2,600 mg/kg none listed 2,010 mg/L none listed
Dithiopyr > 5,000 mg/kg > 5,000 mg/kg Inhalation LC50 (rat): > 5.98 mg/L
Dithiopyr is toxic to fish.
All toxicity data from TFI Product Testing Results.
SECTION 12 ECOLOGICAL INFORMATION
None listed.
SECTION 13 DISPOSAL CONSIDERATIONS
Waste Disposal Procedures: Pick up with a shovel and broom and use as a fertilizer by applying to soil using good agricultural and soil management.
SECTION 14 TRANSPORT INFORMATION
Shipping name: Not regulated by DOT
Hazard Class: None C.A.S. Number: See "Ingredients"
Reportable Quantity (RQ): None D.O.T. Number: None
Labels Required: None Haz Waste No: None
Placard: None EPA Regist No: 2217-856-7001
SECTION 15 REGULATORY INFORMATION
Carcinogenicity: by IARC?: Yes ( ) No (X) by NTP?: Yes ( ) No (X)
Not on the 302 list of SARA reportable quantities.
SECTION 16 OTHER INFORMATION
Flash Point (Test Method): Non flammable Flammable Limits LOWER UPPER
Autoignition Temperature: Not applicable (% BY VOLUME) N/A N/A
MSDS Version Number: 1
Disclaimer: This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process.
Such information is to the best of our knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty or guarantee is made as to
its accuracy, reliability or completeness. NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY,
EXPRESS OR IMPLIED, IS MADE CONCERNING THE INFORMATION HEREIN PROVIDED. It is the user's responsibility to satisfy himself as to the suitability and
completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information nor do we offer
warranty against patent infringement.
Reviewed by: Environmental, Health, & Safety
January 2007 (208) 389-7394
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