MATERIAL SAFETY DATA SHEET
HIGH VELOCITY MEMBRANE
ADHESIVE II (HVMA-II) Part A
WHMIS PROTECTIVE CLOTHING TRANSPORT OF DANGEROUS GOODS
Not regulated
SECTION I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: High Velocity Membrane Adhesive II (HVMA-II) ?Part A
Use: Urethane Sealant
Code of MSDS: CA U DRU SS FS 090
Formula number: Not applicable
Revision date: June 27, 2006
Revised by: Marie-Claude Fontaine, Health and safety Supervisor
(800) 567-1492
mcfontaine@soprema.ca
Distributor: Soprema USA
310 Quadral Drive
Wadsworth (Ohio) 44281
UNITED STATES
Tel.: (800) 356-3521
In case of emergency:
SOPREMA (8:00am to 5:00pm ?Eastern time): (800) 567-1492
CANUTEC (Canada) (24h.): (613) 996-6666
CHEMTREC (USA) (24h.): (800) 424-9300
Poison Control Centre: Consult local telephone directory
EMERGENCY OVERVIEW!!!
Yellow viscous liquid with negligible odour. May cause eye irritation. Skin contact: irritation, dermatitis. Ingestion of the product
can cause gastrointestinal irritation. Inhalation of particulates and fumes may result in allergic respiratory sensitization.
High Velocity Membrane Adhesive II ?Part A Revision date: June 27, 2006 Page 1 of 5
SECTION II. COMPOSITION AND INFORMATION ON DANGEROUS INGREDIENTS
EXPOSURE LIMIT
NAME CAS # % WEIGHT
(ACGIH)
TLV-TWA TLV-STEL
Trade secret 65.0 ?99.0 Not available Not available
Polyurethane Polymer
Diphenylmethane
39310-05-9 5.0 ?10.0 Not available Not available
diisocyanate
(homopolymer)
Methylenebis
101-68-8 1.0 ?5.0 0.005 ppm Not available
phenylisocyanate (MDI)
Methylene Bis
26447-40-5 < 1.0 0.005 ppm Not available
(phenylisocyanate)
isomers
SECTION III. POTENTIAL HEALTH EFFECTS
HAZARDOUS HEALTH EFFECTS
INHALATION OF PARTICULATES (SPRAYING) AND FUMES:
Irritation, coughing spell, wear mask if spraying. Inhalation of particulates and fumes may result in allergic respiratory sensitization.
EYES: Irritation.
INGESTION: Can cause gastrointestinal irritation.
SKIN: Can cause irritation, Dermatitis
ACUTE HEALTH EFFECTS: See Above at Inhalation of particles and fumes.
SECTION IV. FIRST AID MEASURES
INHALATION:
Leave area to breathe fresh air. Oxygen therapy may be necessary, seek medical attention if needed. Should be observed by physician
immediately if overexposure is severe.
EYES:
Flush immediately with running water for 15 minutes, lifting the upper and lower lids occasionally. Get medical attention immediately.
INGESTION:
Get medical attention immediately. Do not induce vomiting unless advised by a physician.
SKIN:
Wash area of contact thoroughly with hand cleaner followed by soap and water. If irritation, rash or other disorders develop, get medical
attention immediately.
SECTION V. FIRE-FIGHTING MEASURES
FLASH POINT: > 350癋 (177癈)
METHOD: PM cc
FLAMMABILITY LIMITS IN AIR: N/A
AUTO-IGNITION TEMPERATURE: Not established
FIRE AND EXPLOSION HAZARDS: N/A
SPECIAL FIRE FIGHTING PROCEDURES:
During a fire, personnel at the scene are to avoid exposure to fumes using accepted fire fighting techniques.
COMBUSTION PRODUCTS:
Hydrocyanic acid, oxides of nitrogen can form, carbon monoxide, carbon dioxide.
EXTINGUISHING MEDIA: Dry chemical powder, CO2 foam.
OTHER PRECAUTIONS: None
SECTION VI. ACCIDENTAL RELEASE MEASURES
RELEASE OR SPILL:
Absorb spill in sand, earth or other suitable material. Transfer to appropriate container for disposal. Follow all local, state, federal, and
provincial regulations for disposal of the spilled material.
SECTION VII. HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS:
Store between 65癋 ?85癋 (18癈 ?29癈). Avoid exposure to heat above 90癋 (32癈). Prevent ingestion, and contact with skin and eyes.
Keep container closed when not in use. Material will cure when exposed to atmospheric moisture.
High Velocity Membrane Adhesive II ?Part A Revision date: June 27, 2006 Page 2 of 5
SECTION VIII. EXPOSURE CONTROLS / PERSONAL PROTECTION
HANDS: Wear chemical resistant gloves.
SECTION IX. PHYSICAL AND CHEMICAL PROPERTIES
ODOUR: Negligible
COLOR: Yellow
PHYSICAL STATE: Viscous Liquid
pH: N/A
VAPOR PRESSURE: N/A
VAPOR DENSITY: N/A
BOILING POINT: N/A
MELTING POINT: N/A
FREEZING POINT: N/A
SOLUBILITY IN WATER: N/A
SPECIFIC GRAVITY: 1.02
% VOLATILE: < 0.15%
SECTION X. STABILITY AND REACTIVITY
STABILITY: This material is stable.
INCOMPATIBILITY: Avoid contact with water, acids, bases, alcohols, and metal compounds.
CONDITIONS TO AVOID POLYMERIZATION: Hazardous polymerization will not occur.
SECTION XI. TOXICOLOGICAL INFORMATION
EYES: See Section III.
INGESTION: See Section III.
INHALATION: See Section III.
SKIN: See Section III.
SUBCHRONIC: See Section III.
CHRONIC: See Section III.
SECTION XII. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL DATA: N/A
CHEMICAL FATE: N/A
SECTION XIII. DISPOSAL CONSIDERATIONS
RCRA CLASS: N/A
DISPOSAL METHOD: Not regulated by RCRA. Dispose of in compliance with local, state, federal and provincial regulations.
EPA REPORTABLE QUANTITIES: N/A
SECTION XIV. TRANSPORT INFORMATION
DOT SHIPPING NAME: Not regulated.
DOT HAZARD CLASS: N/A
UN/NA NUMBER: N/A
PACKAGING CLASS: N/A
REPORTABLE QUANTITY (RQ): 5000 Lbs Methylenebis(phenylisocyanate) (MDI)
High Velocity Membrane Adhesive II ?Part A Revision date: June 27, 2006 Page 3 of 5
SECTION XV. REGULATORY INFORMATION
WHMIS: D2A: Very toxic material causing other effects.
TSCA STATUS: On the TSCA Inventory.
OSHA STATUS: Considered hazardous based on the following criteria: Irritant, Sensitizer.
TARGET ORGANS: Liver, Blood, Reproductive, Lung, Skin, Spleen.
OSHA HAZARDOUS COMPONENTS:
Methylenebis Phenylisocyanate (101-68-8)
Not classified as a carcinogen with NTP, ACGIH, or IARC.
Nor regulated as a carcinogen with OSHA.
Classified by IARC in Group 3 (not classifiable as to its carcinogenicity to humans)
SARA 311 RATINGS
Immediate Health Hazard Y
Delayed Health Hazard Y
Fire Hazard N
Reactivity Hazard N
Sudden Release of Pressure Hazard N
SARA 313 INGREDIENTS
Methylene Bis (phenylisocyanate (101-68-8)
Proposition 65 Ingredients ?Chemicals known to the State of California to cause cancer or birth defects or other reproductive harm: None
HMIS (USA): NFPA (USA):
Flammability
HEALTH
2
0
Health
FLAMMABILITY
0
2 0 Reactivity
REACTIVITY
0
0
Specific hazard
PROTECTIVE
2 EQUIPMENT
SECTION XVI. OTHER INFORMATION
Glossary:
ACGIH: American Conference of Governmental Industrial Hygienists
ANSI: American National Standards Institute
ASTM: American Society for Testing and Materials
CAS: Chemical Abstract Services
CFR: Code of Federal Regulations (United States)
CSA: Canadian Standardisation Association
DOT: Department of Transportation (United States)
DSL: Domestic Substances List (Canada)
EPA: Environmental Protection Agency (United States)
HMIS: Hazardous Material Information System
IARC: International Agency for Research on Cancer
LC50: (Lethal concentration50) Concentration of a substance in air that causes dead of 50% mortality of a defined animal population
LD50: (Lethal dose50) Single dose of a substance that, when administrated by a define route in an animal assay, is expected to cause the
death of 50% of a defined animal population.
NFPA: National Fire Protection Association (United States)
NIOSH: National Institute for Occupational Safety and Health
NTP: National Toxicology Program
OSHA: Occupational Safety & Health Administration (United States)
PEL: Permissible Exposure Limit
RCRA: Resource Conservation and Recovery Act (United States)
RTECS: Registry of Toxic Effects of Chemical Substances
TDG: Transportation of Dangerous Goods
TLV: Threshold Limit Value
TWA: Time-weighted average
TSCA: Toxic Substances Control Act (United States)
WHMIS: Workplace Hazardous Materials Information System (Canada)
High Velocity Membrane Adhesive II ?Part A Revision date: June 27, 2006 Page 4 of 5
SECTION XVI. OTHER INFORMATION
References:
Material Safety Data Sheet of supplier
This MSDS has been prepared by: Marie-Claude Fontaine
For more information: SOPREMA Canada 1-800-567-1492
The Material Safety Data Sheets of SOPREMA Canada are available on Internet at the following site: http://www.soprema.ca
Justification of the update:
New product.
This MSDS contains all the information required by ANSI Z-400.1-1998 standard (United States), by regulation 29 CFR Part 1910.1200 of the Hazard
Communication Standard of OSHA, and is in accordance with standard DORS/88-66 OF WHMIS Canada.
FOR INDUSTRIAL USE ONLY. Keep out of reach of children. To the best of our knowledge, the information contained herein is accurate.
However, neither the above named supplier or any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the
information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist.
High Velocity Membrane Adhesive II ?Part A Revision date: June 27, 2006 Page 5 of 5
MATERIAL SAFETY DATA SHEET
HIGH VELOCITY MEMBRANE
ADHESIVE II (HVMA-II) Part B
WHMIS PROTECTIVE CLOTHING TRANSPORT OF DANGEROUS GOODS
Not regulated
SECTION I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: High Velocity Membrane Adhesive II (HVMA-II) ?Part B
Use: Sealant
Code of MSDS: CA U DRU SS FS 091
Formula number: Not applicable
Revision date: June 27, 2006
Revised by: Marie-Claude Fontaine, Health and safety Supervisor
(800) 567-1492
mcfontaine@soprema.ca
Distributor: Soprema USA
310 Quadral Drive
Wadsworth (Ohio) 44281
UNITED STATES
Tel.: (800) 356-3521
In case of emergency:
SOPREMA (8:00am to 5:00pm ?Eastern time): (800) 567-1492
CANUTEC (Canada) (24h.): (613) 996-6666
CHEMTREC (USA) (24h.): (800) 424-9300
Poison Control Centre: Consult local telephone directory
EMERGENCY OVERVIEW!!!
Black viscous liquid with negligible odour. May cause damage to eyes. Skin contact: irritation, dermatitis. Ingestion of the product
can cause gastrointestinal irritation. Inhalation of particulates and fumes may cause irritation and coughing spell.
High Velocity Membrane Adhesive II ?Part B Revision date: June 27, 2006 Page 1 of 5
SECTION II. COMPOSITION AND INFORMATION ON DANGEROUS INGREDIENTS
EXPOSURE LIMIT
NAME CAS # % WEIGHT
(ACGIH)
TLV-TWA TLV-STEL
94-96-2 5.0 ?20.0 Not available Not available
2-Ethyl 1,3-hexanediol
SECTION III. POTENTIAL HEALTH EFFECTS
HAZARDOUS HEALTH EFFECTS
INHALATION OF PARTICULATES (SPRAYING) AND FUMES:
Irritation, coughing spell, wear mask if spraying.
EYES: May cause damage to eyes.
INGESTION: Can cause gastrointestinal irritation.
SKIN: Can cause irritation, Dermatitis
SECTION IV. FIRST AID MEASURES
INHALATION:
Leave area to breathe fresh air. Should be observed by physician immediately if overexposure is severe.
EYES:
Flush immediately with running water for 15 minutes, lifting the upper and lower lids occasionally. Get medical attention immediately.
INGESTION:
Get medical attention immediately. Do not induce vomiting unless advised by a physician.
SKIN:
Wash area of contact thoroughly with soap and water. If irritation, rash or other disorders develop, get medical attention immediately.
SECTION V. FIRE-FIGHTING MEASURES
FLASH POINT: > 350癋 (177癈)
METHOD: PM cc
FLAMMABILITY LIMITS IN AIR: N/A
AUTO-IGNITION TEMPERATURE: Not established
EXTINGUISHING MEDIA: Water, foam.
FIRE AND EXPLOSION HAZARDS: N/A
SPECIAL FIRE FIGHTING PROCEDURES:
During a fire, personnel at the scene are to avoid exposure to fumes using accepted fire fighting techniques. Wear proper firefighting gear
including but not limited to SCBA.
COMBUSTION PRODUCTS:
Oxides of nitrogen, carbon monoxide, carbon dioxide, and other hydrocarbons.
SECTION VI. ACCIDENTAL RELEASE MEASURES
RELEASE OR SPILL:
Absorb spill in sand, earth or other suitable material. Transfer to appropriate container for disposal. Follow all local, state, federal, and
provincial regulations.
SECTION VII. HANDLING AND STORAGE
HANDLING AND STORAGE PRECAUTIONS:
Store between 65癋 ?85癋 (18癈 ?29癈). Avoid exposure to heat above 90癋 (32癈). Prevent ingestion, and contact with skin and eyes.
Keep container closed when not in use. Material will cure when exposed to atmospheric moisture.
SECTION VIII. EXPOSURE CONTROLS / PERSONAL PROTECTION
HANDS: Wear chemical resistant gloves.
SECTION IX. PHYSICAL AND CHEMICAL PROPERTIES
ODOUR: Negligible
COLOUR: Black
PHYSICAL STATE: Viscous Liquid
pH: N/A
High Velocity Membrane Adhesive II ?Part B Revision date: June 27, 2006 Page 2 of 5
SECTION IX. PHYSICAL AND CHEMICAL PROPERTIES
VAPOUR PRESSURE: N/A
VAPOUR DENSITY: N/A
BOILING POINT: N/A
MELTING POINT: N/A
FREEZING POINT: N/A
SOLUBILITY IN WATER: N/A
SPECIFIC GRAVITY: 0.90
% VOLATILE: < 0.15%
SECTION X. STABILITY AND REACTIVITY
STABILITY: This material is stable.
INCOMPATIBILITY: Avoid moisture to protect product quality.
CONDITIONS TO AVOID POLYMERIZATION: Hazardous polymerization will not occur.
SECTION XI. TOXICOLOGICAL INFORMATION
EYES: See Section III.
INGESTION: See Section III.
INHALATION: See Section III.
SKIN: See Section III.
SUBCHRONIC: See Section III.
CHRONIC: See Section III.
SECTION XII. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL DATA: N/A
CHEMICAL FATE: N/A
SECTION XIII. DISPOSAL CONSIDERATIONS
RCRA CLASS: N/A
DISPOSAL METHOD: Not regulated by RCRA. Dispose of in compliance with local, state, federal and provincial regulations.
EPA REPORTABLE QUANTITIES: N/A
SECTION XIV. TRANSPORT INFORMATION
DOT SHIPPING NAME: Not regulated.
DOT HAZARD CLASS: N/A
UN/NA NUMBER: N/A
TRANSPORTATION NOTES: N/A
REPORTABLE QUANTITY (RQ): N/A
High Velocity Membrane Adhesive II ?Part B Revision date: June 27, 2006 Page 3 of 5
SECTION XV. REGULATORY INFORMATION
WHMIS: D2A: Very toxic material causing other effects.
TSCA STATUS: On the TSCA Inventory.
OSHA STATUS: Considered hazardous based on the following criteria: Irritant.
TARGET ORGANS: Eyes.
OSHA HAZARDOUS COMPONENTS:
None
Compliance Quantities: N/A
SARA 311 RATINGS
Immediate Health Hazard Y
Delayed Health Hazard Y
Fire Hazard N
Reactivity Hazard N
Sudden Release of Pressure Hazard N
SARA 313 INGREDIENTS
None
Proposition 65 Ingredients ?Chemicals known to the State of California to cause cancer or birth defects or other reproductive harm: None
HMIS (USA): NFPA (USA):
HEALTH Flammability
2
0
Health
FLAMMABILITY
0
2 0 Reactivity
REACTIVITY
0
0
PROTECTIVE Specific hazard
2 EQUIPMENT
SECTION XVI. OTHER INFORMATION
Glossary:
ACGIH: American Conference of Governmental Industrial Hygienists
ANSI: American National Standards Institute
ASTM: American Society for Testing and Materials
CAS: Chemical Abstract Services
CFR: Code of Federal Regulations (United States)
CSA: Canadian Standardisation Association
DOT: Department of Transportation (United States)
DSL: Domestic Substances List (Canada)
EPA: Environmental Protection Agency (United States)
HMIS: Hazardous Material Information System
IARC: International Agency for Research on Cancer
LC50: (Lethal concentration50) Concentration of a substance in air that causes dead of 50% mortality of a defined animal population
LD50: (Lethal dose50) Single dose of a substance that, when administrated by a define route in an animal assay, is expected to cause the
death of 50% of a defined animal population.
NFPA: National Fire Protection Association (United States)
NIOSH: National Institute for Occupational Safety and Health
NTP: National Toxicology Program
OSHA: Occupational Safety & Health Administration (United States)
PEL: Permissible Exposure Limit
RCRA: Resource Conservation and Recovery Act (United States)
RTECS: Registry of Toxic Effects of Chemical Substances
TDG: Transportation of Dangerous Goods
TLV: Threshold Limit Value
TWA: Time-weighted average
TSCA: Toxic Substances Control Act (United States)
WHMIS: Workplace Hazardous Materials Information System (Canada)
High Velocity Membrane Adhesive II ?Part B Revision date: June 27, 2006 Page 4 of 5
SECTION XVI. OTHER INFORMATION
References:
Material Safety Data Sheet of supplier
This MSDS has been prepared by: Marie-Claude Fontaine
For more information: SOPREMA Canada 1-800-567-1492
The Material Safety Data Sheets of SOPREMA Canada are available on Internet at the following site: http://www.soprema.ca
Justification of the update:
New product.
This MSDS contains all the information required by ANSI Z-400.1-1998 standard (United States), by regulation 29 CFR Part 1910.1200 of the Hazard
Communication Standard of OSHA, and is in accordance with standard DORS/88-66 OF WHMIS Canada.
FOR INDUSTRIAL USE ONLY. Keep out of reach of children. To the best of our knowledge, the information contained herein is accurate.
However, neither the above named supplier or any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the
information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only
hazards that exist.
High Velocity Membrane Adhesive II ?Part B Revision date: June 27, 2006 Page 5 of 5
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