MATERIAL SAFETY DATA SHEET
Royal Mark Re-Inking Fluid (All Colors)
MARKING SYSTEMS
REVISION: 00002
DATE OF PREPARATION: January 2,2005
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCTICHEMICAL NAME: Royal Mark Re-Inking Fluid (All Colors)
GENERAL USE: Pre-Inked Stamps
MANUFACTURER: M&R Marking Systems Inc., 100 Springfield Avenue, Piscataway, NJ 08855
EMERGENCY TELEPHONE NUMBER: (732) 562-9500
SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS
COMPONENT OSHA PEL EXPOSURE LIMITS
CAS NUMBER ACGIH TWA
Diethylene Glycol 111-46-6 Not Listed
Not Listed
2-Ethyl- 1, 3-Hexanediol Not Listed
94-96-2 Not Listed
1,5-Pentanediol Not Listed
111-29-5 Not Listed
No other ingredients identified by OSHA as hazardous are known to be present, or the ingredients present are below levels
specified as hazardous by OSHA (29 CFR 1910.1200).
SECTION 3 - HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
ACUTE EFFECTS
INHALATION: : ROOIII temperature vapors are minimal. Inhalation of a heated or misted form may cause pulmonary edema
or respiratory tract irritation.
EYE: May cause mild irritation.
SKIN: May cause mild irritation and/or dem~atitis.
INGESTION: Small amounts swallowed are not likely to cause serious injury. Large ainou~lts inay cause digestive tract
irritation, central nervous system depression, kidney and liver damage.
CARCINOGENICITY: IARC, NTP, and OSHA do not list any components of this product as a carcinogen.
MEDICAL CONDITIONS AGGRAVATED BY LONG-TERM EXPOSURE: Skin allergies, asthma, bronchitis and
emphysema.
CHRONIC EFFECTS OF OVEREXPOSURE: Repeated skin contact may cause sensitization in some individuals
SECTION 4 - FIRST AID MEASURES
INHALATION: If coughing, irritation or tightness in the chest is experienced, remove to fresh air. Get medical attention if
sy~nptoms persist.
EYE CONTACT: Immediately flush the eyes with copious amounts of water, occasionally lifting the lower and upper eyelids.
Continue for 15 minutes. Get medical attention.
SKIN CONTACT: In case of skin contact, flush skin with plenty of soap and water then remove contaminated clothing. Seek
medical attention if rash develops. Launder containinated clothing before reuse.
INGESTION: If this material has been swallowed, Contact Physician Immediately.
SECTION 5 - FIRE-FIGHTING MEASURES
@
FLASH POINT: >200癋 (93.3"C)
POINT METHOD: Pensky-Martens Closed Cup
-
FLAMMABILITY CLASSIFICATION: Combustible if heated.
EXTINGUISHING MEDIA: Carbon dioxide foam, dry chemical powder, alcohol-resistant foam or other
appropriate media suitable for coinbustible materials in the area.
UNUSUAL FIRE OR EXPLOSION HAZARDS: Could generate carbon monoxide and carbon dioxide fumes. Keep containers
cooled with water.
Royal Mark Re-Inking Fluid (All Colors) REVISION: 00002
IFIRE-FIGHTING INSTRUCTIONS: Evacuate personnel to safe area and keep removed and upwind of fire. Do not release
runoff from fire control methods to sewers or wateiways.
FIRE-FIGHTING EQUIPMENT: Because fire may produce toxic thermal decolnposition products, wear a self-contained
breathing apparatus (SCBA) with a full facepiece operated in pressure-demand or positive-pressure mode. Wear protective
clothing to prevent contact with skin and eyes.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
SPILL /LEAK PROCEDURES: Use Personal Protective Equipment during clean up. Dike and contain spill; absorb with or
scrape up excess using dry sand or earth, then place into suitable container for disposal. Stop or reduce discharge if it can be
done safely. Do not allow to enter waterways or contaminate soil. Remove sources of ignition (if any) and provide ventilation.
REGULATORY REQUIREMENTS: Follow applicable OSHA regulations (29 CFR 1910.120).
SECTION 7 - HANDLING
I AND STORAGE
HANDLING PRECAUTIONS: Minimize breathing of vapors and avoid prolonged or repeated contact with skin. Wear proper
personal protective clothing, gloves, safety glasses, etc. If ventilation is not sufficient, wear proper respiratory equipment. Use
good general housekeeping procedures.
STORAGE REQUIREMENTS: Do not store with incompatible materials. Store in cool, dry, well-ventilated area away from
sunlight. Protect from freezing during shipping and storage. Keep away from sources of ignition.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
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ENGINEERING CONTROLS
VENTILATION: Provide general or local exhaust ventilation systems. Local exhaust ventilation is preferred because it prevents
contaminant dispersion into the work area by controlling it at its source.
ADMINISTRATIVE CONTROLS
RESPIRATORY PROTECTION: Respiratory protection is not required under normal conditions of general or local
ventilation. If respirators are used, seek professional advice prior to respirator selection and use. Follow OSHA respirator
regulations (29 CFR 1910.134) and, if necessary, wear an MSHAINIOSH-approved respirator. Select respirator based on its
suitability to provide adequate worker protection for given working conditions, level of airborne contamination, and presence of
sufficient oxygen. If respirators are used, OSHA requires a written respiratory protection program that includes at least: medical
certification, training, fit testing, periodic environmental monitoring, maintenance, inspection, cleaning, and convenient, sanitary
storage areas.
PROTECTIVE CLOTHINGIEQUIPMENT: Wear chelnically protective gloves to prevent prolonged or repeated skin contact.
Wear protective eyeglasses or chemical safety goggles, per OSHA eye- and face-protection regulations (29 CFR 1910.133).
Contact lenses are not eye protective devices. Appropriate eye protection must be worn instead of contact lenses.
COMMENTS: Emergency showers and eyewash stations should be made available. Never eat, drink, or smoke in work areas.
Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying
cosmetics.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Low viscosity liquid WATER SOLUBILITY: Insoluble
APPEARANCE : Pigmented BOILING POINT: Not Applicable
I
ODOR : Characteristic - mild FREEZINGIMELTING POINT: Not Applicable
VISCOSITY (25 O C ) : 200cps (Average)
VAPOR PRESSURE:
EVAPORATION RATE:
VAPOR DENSITY (AIR=l): Not Applicable
SPECIFIC GRAVITY (25 "C): 1.1
SECTION 10 - STABILITY AND REACTIVITY
- - - - - -
STABILITY: This product is stable at room temperature in closed containers under normal storage and handling conditions.
POLYMERIZATION: Hazardous polymerization can not occur.
CHEMICAL INCOMPATIBILITIES: Strong oxidizers, acids, bases and reducing agents.
CONDITIONS TO AVOID: Strong oxidants, ignition sources, acid chlorides and strong acids. Extremely highllow
temperatures.
THERMAL DECONIPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
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REVISION: 00002
Royal Mark Re-Inking Fluid (All Colors)
I I
SECTION 11- TOXICOLOGICAL INFORMATION
ACUTE INHALATION EFFECTS: REPRODUCTIVE TOXICITY: None Established
MUTAGENICITY: None Established
Human, inhalation, TCL: Not Determined
ACUTE ORAL EFFECTS: Not Detennined TERATOGENICITY: None Established
CARCINOGENITY: Not listed by ACGIH, NIOSH, SENSITIZATION: None Established
NTP, or OSHA.
SECTION 12 - ECOLOGICAL INFORMATION
ECOTOXICITY: None Established
ENVIRONMENTAL FATE: None Established
PHYSICAL/CHEMICAL: No information available.
SECTION 13 - DISPOSAL CONSIDERATIONS
DISPOSAL: This material inust be disposed of in accordance with applicable federal, state and local regulations.
SECTION 14 - TRANSPORT INFORMATION
I I
DOT IMDG
IATA
Not Classified Not Classified
Not Classified
Section 15 - ~ e ~ u l a t Information
or~
EPA REGULATIONS
OSHA STATUS: This product is hazardous under the criteria of the Federal OSHA Hazard Coimllunication Standard
29 CFR 1910.1200.
SARA TITLE 111: Section 302: Extremely Hazardous Substances (40 CFR 355): None listed.
Section 3 111312: Hazard Categories: Immediate Health Hazard; Delayed Health Hazard.
Section 3 13: Toxic Substances: None listed.
TSCA INVENTORY STATUS (40 CFR 710): All components of this fonnulation are listed in the TSCA Inventory.
STATE REGULATIONS:
CALIFORNIA PROPOSITION 65: This product does not contain chemicals, which in the State of California has found to cause
cancer, birth defects or other reproductive harm.
Section 16 - Other Information
PREPARED BY: Alexander R.Veress
TITLE: Technical Director, Research and Development
DISCLAIMER: The information furnished herein is believed to be accurate as of the version date and represents the best data
currently available to M&R Marking Systems, Inc. However, no warranty is expressed or implied regarding the accuracy of the
data and M&R Marking Systems, Inc. assumes no legal responsibility or liability resulting from use. Such data is offered solely
for your consideration, verification, and investigation to determine the suitability of the information for particular intended
purposes.
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