Safety Data Sheet
According to NOHSC:2011(2003)
Version: 1.0 Page: 1 of 5
Revised: 28 March 07 MSDS No:416
CLASSIFIED AS HAZARDOUS ACCORDING TO NOHSC CRITERIA
1. Identification of the substance/preparation and company
Product:
Sika Primer MB Part A
Recommended use:
Solvent free 2 component epoxy-based primer of low viscosity.
Manufacturer/supplier information:
Manufacturer/supplier: Sika Australia Pty Ltd
Street/postbox: 55 Elizabeth Street
Town/city and Post Code: WETHERILL PARK NSW 2164
Country: AUSTRALIA
Phone: (02) 9725 1145
Fax: (02) 9725 3330
General information Operations Manager
Emergency information phone: 1800 033 111
2. Composition/information on ingredients
Chemical characterization:
Solvent free liquid
Hazardous ingredients:
Ingredient CAS No Concentration
Bisphenol A diglycidyl ether 25068-38-6 >60%
Bisphenol F epoxy resin 9003-36-5 1-10%
Glycidylether of C12-C14 alcohols 68609-97-2 1-10%
3. Hazard identification
Hazard Category:
Xn Harmful
Xi Irritant
Risk Phrase(s):
R36/38: Irritating to eyes and skin.
R43: May cause sensitisation by skin contact.
Safety Phrase(s):
S24/25: Avoid contact with skin and eyes.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
4. First-aid measures
Inhalation:
Remove victim from exposure - avoid becoming a casualty. Remove contaminated clothing and loosen
remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest
until fully recovered. Seek medical advice if effects persist.
Skin contact:
If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
If swelling, redness, blistering or irritation occurs seek medical assistance.
Eye contact:
If in eyes, hold eyelids apart and flush the eyes continuously with running water. Continue flushing
until advised to stop by the Poisons Information Centre or a Doctor; or for at least 15 minutes and
transport to Doctor or Hospital.
Safety Data Sheet
According to NOHSC:2011(2003)
Version: 1.0 Page: 2 of 5
Revised: 28 March 07 MSDS No:416
Ingestion:
If poisoning occurs, contact a doctor or Poisons Information Centre (Phone Australia 131 126, New
Zealand 0800 764 766). Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass
of water to drink. Never give anything by the mouth to an unconscious patient. If vomiting occurs give
further water. Seek medical advice.
Notes to physician:
Treat symptomatically. Effects may be delayed.
5. Fire-fighting measures
Specific hazards:
Combustible material.
Special protective precautions and equipment:
On burning may emit toxic fumes. Fire fighters to wear self-contained breathing apparatus and suitable
protective clothing if risk of exposure to vapour or products of combustion.
Suitable extinguishing media:
If material is involved in a fire use water fog (or if unavailable fine water spray), foam, dry agent (carbon
dioxide, dry chemical powder).
6. Accidental release measures
Small Spills:
Wear protective equipment to prevent skin and eye contamination. Avoid inhalation of vapours. Wipe
up with absorbent (clean rag or paper towels). Collect and seal in properly labelled containers or
drums for disposal.
Large spills:
Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent
skin and eye contamination and the inhalation of vapours. Work up wind or increase ventilation.
Contain - prevent run off into drains and waterways. Use absorbent (soil, sand or other inert material).
Collect and seal in properly labelled containers or drums for disposal. If contamination of sewers or
waterways has occurred advise local emergency services.
7. Handling and storage
Handling:
Avoid skin and eye contact.
Storage:
Store in a cool, dry, well-ventilated place and out of direct sunlight. Store away from incompatible
materials described in Section 10. Keep containers closed when not in use - check regularly for leaks.
8. Exposure controls/personal protection
National occupational exposure limits:
No value assigned for this specific material by the NOHSC Australia.
However for:
TWA STEL CARCINOGEN NOTICES
ppm mg/m3 ppm mg/m3 CATEGORY
Epichlorhydrin 2 7.6 - - - Sk
As published by the NOHSC Australia.
Safety Data Sheet
According to NOHSC:2011(2003)
Version: 1.0 Page: 3 of 5
Revised: 28 March 07 MSDS No:416
Biological Limit Values:
As per the "National Model Regulations for the Control of Workplace Hazardous Substances [NOHSC:
1005 (1994)]" the ingredients in this material do not have a Biological Limit Allocated.
Engineering measures:
Ensure ventilation is adequate to maintain air concentrations below Exposure Standards. Natural
ventilation should be adequate under normal use conditions.
Personal protection equipment:
OVERALLS, SAFETY SHOES, CHEMICAL GOGGLES, GLOVES.
Wear overalls, chemical goggles and impervious gloves. Due to variations in glove construction and
local conditions, the user should make an assessment of the appropriate gloves to use. Wash hands
before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective
equipment before storing or re-using. If risk of inhalation of exists, wear organic vapour/particulate
respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716.
9. Physical and chemical properties
Appearance:
Physical state: Low viscosity liquid
Colour: Blue - transparent
Odour: N Av
Data relevant to safety:
Solubility: Insoluble in water.
Specific Gravity (20 癈): 1.1
Relative Vapour Density (air=1): <7
Vapour Pressure (20 癈): N Av
Flash Point (癈): >100
Flammability Limits (%): N Av
Autoignition Temperature (癈): N Av
Melting Point/Range (癈): N Av
Boiling Point/Range (癈): >200
pH: N Av
Viscosity: 40-78 seconds (7 mm cup)
(Typical values only - consult specification sheet)
N Av = Not available N App = Not applicable
10. Stability and reactivity
Chemical stability:
This material is thermally stable when stored and used as directed.
Conditions to avoid:
Elevated temperatures and sources of ignition.
Incompatible Materials:
Oxidising agents, amines, phenols, acids and alkalis.
Hazardous decomposition products:
Oxides of carbon and nitrogen, smoke and other toxic fumes.
Hazardous reactions:
Exothermic reaction with amines (Part B).
Safety Data Sheet
According to NOHSC:2011(2003)
Version: 1.0 Page: 4 of 5
Revised: 28 March 07 MSDS No:416
11. Toxicological information
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and
the product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs
are:
Acute Effects:
Inhalation: Material may be irritant to mucous membranes and respiratory tract.
Skin contact: Contact with skin will result in irritation. A skin sensitiser. Repeated or prolonged skin
contact may lead to allergic contact dermatitis.
Eye contact: An eye irritant.
Ingestion:
Swallowing can result in nausea, vomiting and irritation of the gastrointestinal tract.
Long Term Effects:
No information available for product.
Acute toxicity / Chronic toxicity:
No LD50 data available for the product.
12. Ecological information
Avoid contaminating waterways.
Ecotoxicity:
No information available.
Persistence and degradability:
No information available.
Mobility:
No information available.
13. Disposal considerations
Refer to State/Territory Land Waste Management Authority.
14. Transport information
ADG/ADR/RID
Not classified as Dangerous Goods by the criteria of the ADG Code.
IMDG
Not classified as Dangerous Goods by the criteria of the IMDG Code for transport by sea.
IATA
Not classified as Dangerous Goods by the criteria of the IATA Dangerous Goods Regulations for
transport by air.
15. Regulatory information
Poisons Schedule (Aust):
This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with
the relevant regulations.
All the constituents of this material are listed on the Australian Inventory of Chemical Substances (AICS).
Safety Data Sheet
According to NOHSC:2011(2003)
Version: 1.0 Page: 5 of 5
Revised: 28 March 07 MSDS No:416
16. Other information
Reason(s) For Issue: Revised
Material Safety Data Sheets are updated frequently. Please ensure that you have a current copy. MSDS
may be obtained from the following website: www.sika.com.au
The information contained in this Safety Date Sheet corresponds to our level of knowledge at the time of
publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please
consult the Technical Data Sheet prior to any use and processing.
Safety Data Sheet
According to NOHSC:2011(2003)
Version: 1.0 Page: 1 of 5
Revised: 28 March 2007 MSDS No: 417
CLASSIFIED AS HAZARDOUS ACCORDING TO NOHSC CRITERIA
1. Identification of the substance/preparation and company
Product:
Sika Primer MB Part B
Recommended use:
Solvent free 2 component epoxy-based primer of low viscosity.
Manufacturer/supplier information:
Manufacturer/supplier: Sika Australia Pty Ltd
Street/postbox: 55 Elizabeth Street
Town/city and Post Code: WETHERILL PARK NSW 2164
Country: AUSTRALIA
Phone: (02) 9725 1145
Fax: (02) 9725 3330
General information Operations Manager
Emergency information phone: 1800 033 111
2. Composition/information on ingredients
Chemical characterization:
Solvent free liquid
Hazardous ingredients:
Ingredient CAS No Concentration
Benzyl alcohol 100-51-6 30-60%
m-Xylene a,a'-diamine 1477-55-0 10-30%
Cyclohexanemethanamine 2855-13-2 10-30%
Tetraethylene pentamine 112-57-2 1-10%
3. Hazard identification
Hazard Category:
Xn Harmful
C Corrosive
Risk Phrase(s):
R20/22: Harmful by inhalation and if swallowed.
R34: Causes burns.
R41: Risk of serious damage to eyes.
R43: May cause sensitisation by skin contact.
Safety Phrase(s):
S23: Do not breathe vapour.
S24/25: Avoid contact with skin and eyes.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S38: In case of insufficient ventilation, wear suitable respiratory equipment.
4. First-aid measures
Inhalation:
Remove victim from exposure - avoid becoming a casualty. Remove contaminated clothing and loosen
remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest
until fully recovered. If breathing laboured and patient cyanotic (blue), ensure airways are clear and
have a qualified person give oxygen through a facemask. If breathing has stopped apply artificial
respiration at once. In the event of cardiac arrest, apply external cardiac massage. Seek immediate
medical advice. Seek medical advice if effects persist.
Safety Data Sheet
According to NOHSC:2011(2003)
Version: 1.0 Page: 2 of 5
Revised: 28 March 2007 MSDS No: 417
Skin contact:
For gross contamination, immediately drench with water and remove clothing. Continue to flush skin
and hair with plenty of water (and soap if material is insoluble). For skin burns, cover with a clean, dry
dressing until medical help is available. If blistering occurs, do NOT break blisters. If swelling,
redness, blistering, or irritation occurs seek medical assistance.
Eye contact:
Immediately irrigate with copious quantities of water for 15 minutes. Eyelids to be held open. Remove
clothing if contaminated and wash skin. Urgently seek medical assistance. Transport to hospital or
medical centre.
Ingestion:
If poisoning occurs, contact a doctor or Poisons Information Centre (Phone Australia 131 126, New
Zealand 0800 764 766). Immediately rinse mouth with water. If swallowed, do NOT induce vomiting.
Give a glass of water to drink. Never give anything by the mouth to an unconscious patient. If vomiting
occurs give further water. Get to a doctor or hospital quickly.
Notes to physician:
Treat symptomatically. Effects may be delayed. Can cause corneal burns.
5. Fire-fighting measures
Specific hazards:
Combustible material.
Special protective precautions and equipment:
On burning may emit toxic fumes. Fire fighters to wear self-contained breathing apparatus and suitable
protective clothing if risk of exposure to vapour or products of combustion.
Suitable extinguishing media:
If material is involved in a fire use water fog (or if unavailable fine water spray), foam, dry agent (carbon
dioxide, dry chemical powder).
6. Accidental release measures
Small Spills:
Wear protective equipment to prevent skin and eye contamination. Avoid inhalation of vapours. Wipe
up with absorbent (clean rag or paper towels). Collect and seal in properly labelled containers or
drums for disposal.
Large spills:
Slippery when spilt. Avoid accidents, clean up immediately. Wear protective equipment to prevent
skin and eye contamination and the inhalation of vapours. Work up wind or increase ventilation.
Contain - prevent run off into drains and waterways. Use absorbent (soil, sand or other inert material).
Collect and seal in properly labelled containers or drums for disposal. If contamination of sewers or
waterways has occurred advise local emergency services.
7. Handling and storage
Handling:
Avoid skin and eye contact and inhalation of vapour.
Storage:
Store in a cool, dry, well-ventilated place and out of direct sunlight.
Store away from incompatible materials described in Section 10.
Keep containers closed when not in use - check regularly for leaks.
Safety Data Sheet
According to NOHSC:2011(2003)
Version: 1.0 Page: 3 of 5
Revised: 28 March 2007 MSDS No: 417
8. Exposure controls/personal protection
National occupational exposure limits:
No value assigned for this specific material by the NOHSC Australia.
However for:
TWA STEL CARCINOGEN NOTICES
ppm mg/m3 ppm mg/m3 CATEGORY
m-Xylene a,a'-diamine 0.1 Peak Limitation - - Sk
As published by the NOHSC Australia.
Biological Limit Values:
As per the "National Model Regulations for the Control of Workplace Hazardous Substances [NOHSC:
1005 (1994)]" the ingredients in this material do not have a Biological Limit Allocated.
Engineering measures:
Ensure ventilation is adequate to maintain air concentrations below Exposure Standards. Use with
local exhaust ventilation or while wearing appropriate respirator. Keep containers closed when not in
use.
Personal protection equipment:
OVERALLS, SAFETY SHOES, CHEMICAL GOGGLES, GLOVES.
Wear overalls, chemical goggles and impervious gloves. Due to variations in glove construction and
local conditions, the user should make an assessment of the appropriate gloves to use. Wash hands
before smoking, eating, drinking or using the toilet. Wash contaminated clothing and other protective
equipment before storing or re-using. If risk of inhalation of exists, wear organic vapour/particulate
respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716.
9. Physical and chemical properties
Appearance:
Physical state: Low viscosity liquid
Colour: Straw colour
Odour: Amine odour
Data relevant to safety:
Solubility: Partly soluble in water.
Specific Gravity (20 癈): 1.1
Relative Vapour Density (air=1): N Av
Vapour Pressure (20 癈): N Av
Flash Point (癈): >100
Flammability Limits (%): N Av
Autoignition Temperature (癈): N Av
Melting Point/Range (癈): N Av
Boiling Point/Range (癈): N Av
Thermal decomposition (癈): >250
pH: N App
Viscosity (20 癈): 40 mPa.s
(Typical values only - consult specification sheet)
N Av = Not available N App = Not applicable
Safety Data Sheet
According to NOHSC:2011(2003)
Version: 1.0 Page: 4 of 5
Revised: 28 March 2007 MSDS No: 417
10. Stability and reactivity
Chemical stability:
This material is thermally stable when stored and used as directed.
Conditions to avoid:
Elevated temperatures and sources of ignition.
Incompatible Materials:
Oxidising agents, acids and alkalis.
Hazardous decomposition products:
Oxides of carbon and nitrogen, smoke and other toxic fumes.
Hazardous reactions:
Exothermic reaction with epoxy resin (Part A).
11. Toxicological information
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and
the product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs
are:
Acute Effects:
Inhalation: Harmful by inhalation. Material may be irritant to mucous membranes and respiratory tract.
Skin contact: Contact with skin will result in severe irritation. Corrosive to skin - may cause skin burns.
A skin sensitiser. Repeated or prolonged skin contact may lead to allergic contact dermatitis.
Eye contact: A severe eye irritant. Corrosive to eyes: contact can cause corneal burns. Contamination
of eyes can result in permanent injury.
Ingestion: Swallowing can result in nausea, vomiting, diarrhoea, abdominal pain and chemical burns to
the gastrointestinal tract.
Long Term Effects:
No information available for product.
Acute toxicity / Chronic toxicity:
No LD50 data available for the product.
12. Ecological information
Avoid contaminating waterways.
Ecotoxicity:
No information available.
Persistence and degradability:
No information available.
Mobility:
No information available.
13. Disposal considerations
Refer to State/Territory Land Waste Management Authority.
Safety Data Sheet
According to NOHSC:2011(2003)
Version: 1.0 Page: 5 of 5
Revised: 28 March 2007 MSDS No: 417
14. Transport information
ADG/ADR/RID
UN No: 1760
Dangerous Goods Class: 8
Packing Group: III
Hazchem Code: 2R
Emergency Response Guide No: 37
Proper Shipping Name: CORROSIVE LIQUID, N.O.S. (contains CYCLOALIPHATIC AMINE)
Segregation Dangerous Goods: Not to be loaded with explosives (Class 1), dangerous when wet
substances (Class 4.3), oxidising agents (Class 5.1), organic peroxides (Class 5.2), cyanides of Class
6, radioactive substances (Class 7) or food and food packaging in any quantity, however exemptions
may apply. Note that material is incompatible with acids and alkalis.
IMDG
UN No: 1760
Dangerous Goods Class: 8
Packing Group: III
Proper Shipping Name: CORROSIVE LIQUID, N.O.S. (contains CYCLOALIPHATIC AMINE)
IATA
UN No: 1760
Dangerous Goods Class: 8
Packing Group: III
Proper Shipping Name: CORROSIVE LIQUID, N.O.S. (contains CYCLOALIPHATIC AMINE)
15. Regulatory information
Poisons Schedule (Aust):
This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with
the relevant regulations.
All the constituents of this material are listed on the Australian Inventory of Chemical Substances (AICS).
16. Other information
Reason(s) For Issue: Revised
Material Safety Data Sheets are updated frequently. Please ensure that you have a current copy. MSDS
may be obtained from the following website: www.sika.com.au
The information contained in this Safety Date Sheet corresponds to our level of knowledge at the time of
publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please
consult the Technical Data Sheet prior to any use and processing.
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